17/1/23, 10:51 equilibrio tarea

equilibrio tarea
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Chapter 15 Algorithmic Question 1

Part A
Express the equilibrium constant for the following reaction.

4CH3 Cl(g) + 2Cl2 (g) ⟺ 4CH2 Cl2 (g) + 2H2 (g)

ANSWER:

4 2
[CH2 Cl2 ] [H2 ]
K =
4 2
[CH3 Cl] [Cl2 ]

4 2
[CH3 Cl] [Cl2 ]
K =
4 2
[CH2 Cl2 ] [H2 ]

[CH Cl][Cl ]
3 2
K = −
[CH Cl ][H ]
2 2 2

5
[CH2 Cl2 ][H2 ]
K =
5
[CH3 Cl][Cl2 ]

[CH3 Cl][Cl2 ]
K =
[CH2 Cl2 ][H2 ]

Chapter 15 Algorithmic Question 5

Part A
Express the equilibrium constant for the following reaction.

10PCl5 (g) ↔ 10PCl3 (g) + 10Cl2 (g)

ANSWER:

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10 10
[PCl3 ] [Cl2 ]
K =
10
[PCl5 ]

2
[PCl3 ][Cl2 ]
K =
[PCl5 ]

[PCl5 ]
K =
[PCl3 ][Cl2 ]

10
[PCl5 ]
K =
10 10
[PCl3 ] [Cl2 ]

[PCl3 ][Cl2 ]
K =
[PCl5 ]

Chapter 15 Algorithmic Question 7

Part A
Express the reverse equilibrium constant for the following reaction.
8H2 (g) + 8Br2 (g) ⇌ 16HBr(g)
ANSWER:

16
[HBr]
K =
8 8
[H2 ] [Br2 ]

2
[HBr]
K =
[H2 ][Br2 ]

[H2 ][Br2 ]
K =
2
[HBr]

8 8
[H2 ] [Br2 ]
K =
16
[HBr]

[H2 ][Br2 ]
K =
[HBr]

Chapter 15 Algorithmic Question 10

Part A
Express the equilibrium constant for the following reaction.

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20CH3 Br(g) + 10Br2 (g) ⟺ 20CH2 Br2 (g) + 10H2 (g)

ANSWER:

20 10
[CH3 Br] [Br2 ]
K =
20 10
[CH2 Br2 ] [H2 ]

1/2
[CH3 Br] [Br2 ]
K =
1/2
[CH2 Br2 ] [H2 ]

2
[CH2 Br2 ] [H2 ]
K =
2
[CH3 Br] [Br2 ]

[CH3 Br][Br2 ]
K =
[CH2 Br2 ][H2 ]

20 10
[CH2 Br2 ] [H2 ]
K =
20 10
[CH3 Br] [Br2 ]

Chapter 15 Algorithmic Question 6

Part A
Express the equilibrium constant for the following reaction.

8H2 (g) + 8Br2 (g) ↔ 16HBr(g)

ANSWER:

2
[HBr]
K =
[H2 ][Br2 ]

[H2 ][Br2 ]
K =
2
[HBr]

[H2 ][Br2 ]
K =
[HBr]

16
[HBr]
K =
8 8
[H2 ] [Br2 ]

8 8
[H2 ] [Br2 ]
K =
16
[HBr]

For Practice 15.11 - Enhanced - with Feedback

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You may want to reference (Pages 693 - 702) section 15.8 while completing this problem.

Consider the following reaction:

∘
I 2 (g) + Cl2 (g) ⇌ 2ICl(g), Kp = 81.9 (at 25 C)

A reaction mixture at 25∘ C initially contains PI = 0.200 atm , PCl = 0.200 atm , and PICl = 0.00 atm .
2 2

Part A
Find the equilibrium partial pressure of I 2 at this temperature.
Express the pressure to three decimal places and include the appropriate units.
ANSWER:

PI
2
=

Part B
Find the equilibrium partial pressure of Cl2 at this temperature.
Express the pressure to three decimal places and include the appropriate units.

ANSWER:

PCl
2
=

Part C
Find the equilibrium partial pressure of ICl at this temperature.
Express the pressure to three decimal places and include the appropriate units.

ANSWER:

PICl =

For Practice 15.10 - Enhanced - with Feedback

Consider the following reaction:

∘
N 2 O4 (g) ⇌ 2NO2 (g), Kc = 0.36 at 2000 C

The reaction mixture initially contains only the reactant, [N2 O4 ] = 0.0210M , and no NO2 .

You may want to reference (Pages 693 - 702) Section 15.8 while completing this problem.

Part A
Find the equilibrium concentration of N2 O4 .
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Express the concentration to three decimal places and include the appropriate units.

ANSWER:

[N 2 O4 ] =

Part B
Find the equilibrium concentration of NO2 .
Express the concentration to three decimal places and include the appropriate units.
ANSWER:

[NO2 ] =

For Practice 15.12 - Enhanced - with Feedback

Consider the reaction for the decomposition of hydrogen disulfide: 2H2 S(g) ⇌ 2H 2 (g) + S 2 (g),
Kc = 1.67 × 10  at 800 C−7 ∘

A 0.500 L reaction vessel initially contains 6.25×10−2 mol of H2 S and 0.100 mol of H2 at 800∘ C.
You may want to reference (Pages 693 - 702) Section 15.8 while completing this problem.

Part A

Find the equilibrium concentration of [S2 ] .

Express your answer to three significant figures and include the appropriate units.
ANSWER:

[S 2 ] =

Exercise 15.56 - Enhanced - with Feedback

Consider the reaction

CO (g) + H 2 O (g) ⇌ CO2 (g) + H 2 (g)

Kc = 102 at 500 K

A reaction mixture initially contains 0.145 M CO and 0.145 M H2 O .

You may want to reference (Pages 693 - 702) Section 15.8 while completing this problem.

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Part A
What will be the equilibrium concentration of CO?
Express the concentration in molarity to two significant figures.
ANSWER:

[CO] = M

Part B Complete previous part(s) Instructors: View all hidden parts

Part C Complete previous part(s) Instructors: View all hidden parts

Part D Complete previous part(s) Instructors: View all hidden parts

Exercise 15.44 - Enhanced - with Feedback

Consider the following reaction:

SO2 Cl 2 (g) ⇌ SO2 (g) + Cl 2 (g)

A reaction mixture is made containing an initial [SO2 Cl 2 ] of 2.3×10−2 M . At equilibrium, [Cl 2 ] = 1.0×10−2 M .

You may want to reference (Pages 693 - 702) Section 15.8 while completing this problem.

Part A

Calculate the value of the equilibrium constant (Kc ) .

Express your answer to two significant figures.

ANSWER:

Kc =

Question for Group Work 15.107

Consider the reaction:N2 (g) + 3H2 (g)→2NH3 (g)

Part A
Write the equilibrium constant expression for this reaction.

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ANSWER:

3
[NH2 ]
K =
2
[N2 ][H3 ]

3
[H2 ]
K =
2
[N2 ][NH3 ]

3
[H 2 ] [N 2 ]
K =
2
[NH3 ]

2
[NH3 ]
K =
3
[N2 ][H2 ]

Part B
If some hydrogen is added, before the reaction shifts, how will the numerator and denominator of the expression in part a
compare to the value at equilibrium?

ANSWER:

Adding H2 will decrease the denominator and increase numerator.

Adding H2 will increase the denominator and decreasee numerator.

Adding H2 will increase the denominator and not change the numerator.

Adding H2 will decrease the denominator and not change the numerator.

Part C
If some hydrogen is added, before the reaction shifts, will Q be larger or smaller than K ? Why?
ANSWER:

Since the denominator is larger, Q will be greater than K .

Since the denominator is larger, Q will be less than K .

Since the denominator does not change, Q will be equal to K .

Since the numerator is larger, Q will be less than K .

Part D
If some hydrogen is added, before the reaction shifts, will the reaction have to shift forward or backward to retain
equilibrium? Explain.
ANSWER:

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Since Q is greater than K , the denominator needs to be decreased—so the reaction will shift to the left or in the
forward direction.

Since Q is greater than K , the denominator needs to be decreased—so the reaction will shift to the right or in
the forward direction.

Since Q is less than K , the denominator needs to be decreased—so the reaction will shift to the right or in the
forward direction.

Since Q is less than K , the denominator needs to be increased—so the reaction will shift to the left or in the
forward direction.

Part E
Are your answers above consistent with Le Châtelier's principle? Explain.

ANSWER:

Yes, the reaction will shift to return Q to K .

Yes, the reaction will shift to return K to Q.

Chapter 15 Algorithmic Question 20

Part A
What is Δn for the following equation in relating Kc to Kp ?

CH 4 (g) + H2 O(g) ⇋ CO (g) + 3H2 (g)

ANSWER:

1/3

1/2

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Chapter 15 Algorithmic Question 23

Part A
What is Δn for the following equation in relating Kc to Kp ?

N 2 O4 (g) ⇋ 2NO2 (g)

ANSWER:

-4

-1/2

Chapter 15 Algorithmic Question 30

Part A
In which of the following reactions will Kc = Kp ?
ANSWER:

N2 (g) + 3H2 (g) ⇋ 2NH3 (g)

N 2 O4 (g) ⇋ 2NO2 (g)

CO (g) + 2H2 (g) ⇋ CH 3 OH (g)

H2 (g) + Cl2 (g) ⇋ 2 HCl(g)

CH 4 (g) + H2 O(g) ⇋ CO (g) + 3H2 (g)

Chapter 15 Non-Algorithmic Question 15

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Part A
At 900.0 K, the equilibrium constant (Kp) for the following reaction is 0.345.

2SO2 + O2(g) → 2SO3(g)

At equilibrium, the partial pressure of SO2 is 35.0 atm and that of O2 is 15.9 atm. The partial pressure of SO3 is ________
atm.

ANSWER:

6.20 × 10-4

192

40.2

82.0

4.21 × 10-3

Chapter 15 Multiple Choice Question 19

Part A
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 3.6 M, [O2]eq =
4.1 M, [N2O]eq = 3.3 × 10-18 M.

2 N2(g) + O2(g) ↔ 2 N2O(g)

ANSWER:

2.2 × 10-19

4.5 × 1018

2.0 × 10-37

4.9 × 10-17

5.0 × 1036

Chapter 15 Multiple Choice Question 20

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Part A
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 1.5 M, [H2]eq =
1.1 M, [NH3]eq = 0.47 M.

N2(g) + 3 H2(g) ↔ 2 NH3(g)

ANSWER:

9.1

0.78

3.5

0.28

0.11

Chapter 15 Multiple Choice Question 21

Part A
Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [HCl]eq = 0.13 M, [HI]eq
= 5.6 × 10-16 M, [Cl2]eq = 0.0019 M.

2 HCl(g) + I2(s) ↔ 2 HI(g) + Cl2(g)

ANSWER:

1.2 × 1017

3.5 × 10-32

2.8 × 1031

1.4 × 10-19

8.2 × 10-18

Exercise 15.10

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Part A
Does the value of the equilibrium constant depend on the initial concentrations of the reactants and products?
ANSWER:

yes

no

Part B
Do the equilibrium concentrations of the reactants and products depend on their initial concentrations?

ANSWER:

yes

no

Chapter 15 Multiple Choice Question 15

Part A

The reaction below has a Kp value of 3.3 x 10-5. What is the value of Kc for this reaction at 700 K?

2 SO3(g) ↔ 2 SO2(g) + O2(g)

ANSWER:

3.0 × 104

3.3 × 10-5

1.9 × 10-3

1.7 × 106

5.7 × 10-7

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