Major

No. of page(s): 1 Exam. No.
UCH20C22
THIAGARAJAR COLLEGE (AUTONOMOUS), MADURAI – 9
B.Sc. (Chemistry) Degree Examination, APRIL 2021
II SEMESTER SUMMATIVE EXAMINATIONS
ESSENTIAL CONCEPTS IN PHYSICAL CHEMISTRY
(2020)
Time: 3 Hours Maximum: 75 Marks
SECTION – A
Answer ALL questions: (5 x 5 = 25 Marks)
1. a) Explain catalytic poison and promoters with suitable examples.
(OR)
b) Relate exo and endothermic catalysis by graphical representation.
2. a) Discuss on number average and weight average molecular weights of polymer.

(OR)
b) Classify polymers as thermoplastic and thermosetting resins.
3. a) Discuss on Russell-Soddy group displacement law.

(OR)
b) i) What are Magic numbers?
ii) Discuss the stability of nuclei with binding energy per nucleon.
4. a) Derive Nernst distribution law.

(OR)
b) Apply Nernst distribution law and discuss association of solute in one of the solvent.
5. a) Derive Clausius-Mosotti equation.

(OR)
b) Apply the concept of dipole moment and predict the molecular structure of NH 3.
SECTION – B
6. a) Describe Michaelis-Menton mechanism of enzyme catalysis.
(OR)
b) Summarize the following:
(i) Types of catalyst
(ii) Types of catalysis
7. a) Discuss on addition and condensation polymerization.

(OR)
b) Elaborate the applications of polymer.
8. a) Outline the detection and measurement of radioactivity by using GM counter method.

(OR)
b) Summarize the applications of radioactive isotopes.
9. a) i) Apply Nernst distribution law for the dissociation of solute in one of the solvent.
ii) What are the limitations of Nernst distribution law.
(OR)
b) Give thermodynamic derivation of solute entering in a chemical combination with
one of the solvent.
10. a) Apply Guoy balance method for the measurement of magnetic susceptibility.
(OR)
b) Identify and write all types of magnetism.
*****
UPH20GE21C

BASIC ELECTRONICS
(2020)
SECTION – A
1. (a) Distinguish between an intrinsic and extrinsic semiconductor.

(OR)
(b) What is meant by semiconductor diode? Mention any three applications of a
semiconductor diode.
2. (a) Explain the characteristics of PNP transistor in common emitter configuration.

(OR)
(b) Difference between NPN and PNP transistor.
3. (a) Convert the Hexadecimal number 10016 into decimal number.

(OR)
(b) Distinguish between Hexadecimal and Decimal number system.
4. (a) Explain the AND and OR basic logic gates with their truth tables.
(OR)
(b) Illustrate the NOT and NAND basic logic gates with their truth tables.
5. (a) Explain in detail the commutative law.

(OR)
(b) Show that A+BC = (A+B) (A+C)
SECTION – B
6. (a) Draw and explain the V-I characteristic of PN junction diode.

(OR)
(b) Explain the forward and reverse characteristics of PN junction diode.
7. (a) What is a transistor? Explain working principle of transistor as an amplifier.

(OR)
(b) Explain single stage transistor amplifier with proper circuit diagram.
8. (a) What is BCD system? What are its demerits as compared to hexadecimal system?
Convert the decimal number 61910 into binary number.
(OR)
(b) Convert the decimal number 25510 into the following (i) binary number and
(ii) hexadecimal number. What is binary addition?
9. (a) Show that NAND gate is an universal gate.

(OR)
(b) Write a brief note on the following (i) Logic gates, (ii) X-OR gate & (iii) NOR gate.
10. (a) State and prove De-Morgan’s theorems.

(OR)
(b) Explain with neat circuits, the working of binary adders.

No. of Page(s): 1 Exam. No.
AC21
B.Sc. Degree Examination, APRIL 2021
ALLIED GENERAL CHEMISTRY - II
(1987 – 2018)
SECTION - A
1. (a) What are buffer solution? Explain how a solution of a weak base and its salt
behaves as a buffer?
(OR)
(b) Discuss the enzyme catalysis mechanism.
2. (a) Write a note on nuclear binding energy.

(OR)
(b) Compare the properties of , , and - rays.
3. (a) Derive Oswald’s dilution law of weak electrolytes.

(OR)
(b) Discuss the chemical properties of amino acids.(carboxyl group & amino group)
4. (a) Describe the advantages of microwave synthesis.

(OR)
(b) How lead affect the enzyme reaction?
5. (a) What is sol – gel synthesis? Give its applicators.

(OR)
(b) Discuss about water soluble vitamins.
SECTION - B
6. (a) Define Kohlraush’s law. Explain its applications.

(OR)
(b) Explain strong acid V & strong base and mixture of acids V & strong base in
conductometric titrations.
7. (a) Discuss the adsorption theory of heterogeneous catalysis.

(OR)
(b) Mention the uses of radioactive isotopes.
8. (a) Describe the components and working of a nuclear reactor.

(OR)
(b) Explain the top down and bottom up paths in nano sciences.
9. (a) Explain the effects of toxic chemicals on enzymes in detail.

(OR)
(b) Write note on: (i) homogenous catalyst (ii) heterogenous catalyst
(iii) auto catalyst (iv) promoters
(v) acid-base catalyst
10. (a) Illustrate the colour reactions of proteins.

(OR)
(b) Discuss the source, deficiency of vitamin A,B,C,D and K.
****
AC44
IV SEMESTER SUMMATIVE EXAMINATIONS
ANCILLARY CHEMISTRY ORGANIC & PHYSICAL
(1987 - 2007)
SECTION - A
1. (a) Elucidate the Hess’s law of heat of summation.

(OR)
(b) Explain Gibbs free energy concept.
2. (a) State and explain Arrehenius theory of electrolysis.

(OR)
(b) Give an account on buffers.
3. (a) Write a note on optical isomerism.

(OR)
(b) Write a note on the isomerism exhibited by maleic and furmaic acids.
4. (a) What are active mehtylene compounds? Give any two examples. Mention their
structures.
(OR)
(b) Write down the structure and uses of conine and salvarasan.
5. (a) Give the preparation of glycine and alanine.

(OR)
(b) Write the sources and uses of Vitamin B complex.
SECTION - B
6. (a) Explain Carnot’s cycle and the theorem in detail.

(OR)
(b) What are the conductometric titrations? Explain.
7. (a) Describe the principle and methods of electroplating.

(OR)
(b) Give a detailed account of sulpha drugs and anaesthetics.
8. (a) (a) Explain Walden inversion.

(b) Explain any one method of separation of racemic mixture.
(OR)
(b) Describe the preparation. Properties and uses of amionoacetic acid.
9. (a) Write and explanatory note on the isomerism exhibited by 1,2 dihydroxy succinic
acid.
(OR)
(b) (a) What are vitamins? How are they classified? Give examples.
10. (a) Give the structure of penicillin and tetracycline.

(OR)
(b) Write the outline classification and role of enzymes.
****
No. of Page(s):2 Exam. No.
AM41
ALLIED MATHEMATICS - II
(1987 - 2016)
SECTION – A
1.
(a) Solve the differential equation (D3 – D2 – D + 1)y = 2ex
(OR)
(b) Solve x2y’’+4xy’+2y=ex.
d2y dy
2. (a) Solve x 2 2
x 3y x2 .
dx dx
(OR)
(b) Solve (D2 + 3D + 2) y = sinx.
3. (a) Form the P.D.E by eliminating the arbitrary functions f and from z = f(x +ay) + (x-ay).
(OR)
(b) Solve pq + p + q = 0.
4. (a) Find L[sin 3t cos 2t].

(OR)
1
(b) Find L 1
(s 2)2 16
s2
5. (a) Find L 1
(s 4) 4
(OR)
(b) Find the orthogonal trajectories of the family of curves r = a sin .
SECTION – B
6. (a) Solve (D2 + 2D + 5) y = e-x cos 2x

(OR)
2
y z
(b) Solve p xzq y 2 .
x
7. (a) Using Laplace transform, solve (D2+6D+5)y = e-2t given that y = 0, Dy = 1

when t = 0.
(OR)
(b) Using Laplace transformation to solve y”+4y’+13y = 2e-x given y(0) = 0 and
y’(0) = -1.
7s 1
8. (a) Find L 1
( s 1) s 2 s 3
(OR)
2
d y dy dy
(b) Solve: 2
4 5y 5 given that y = 0, 2 when t = 0.
dt dt dt
9. (a) Calculate Karl Pearson coefficient of correlation for the data given below:
X: 45 70 65 30 90 40 50 75 85 60
Y: 35 90 70 40 95 40 60 80 80 60
(OR)
. . .2 . . .
// 2 //
AM41
(b) In a culture of bacteria the rate of increase is proportional to the number

present. If it is found that the number doubles in 4 hours, how many may be
expected at the end of 12 hours?
10. (a) A bank pays interest by continuously compounding interest to investors. A man
invests Rs.20,000 in the bank and accrued interest in 15% per year
compounded continuously. How much will he get after 10 years?
(OR)
(b) Calculate the coefficient of correlation between expenditure on advertisement
in x and sales in y.
x: 40 45 47 50 53 60 57 51
y: 65 64 70 71 75 83 90 92
* * * * *
AP44
OPTICS, SPECTROSCOPY AND MODERN PHYSICS
(1987 – 2005)
SECTION – A
1. (a) Derive an expression for the equivalent focal length of two thin lenses separated
by a finite distance.
(OR)
(b) Describe the construction and working of direct vision spectroscope.
2. (a) Explain the method of determination of wavelength of sodium light by forming

Newton’s rings.
(OR)
(b) Explain the construction and working of a Jamin’s refractometer.
3. (a) Explain the construction and working of a Quarter Wave plate.

(OR)
(b) What is Raman Effect? Give the quantum theory of Raman Effect.
4. (a) Write short notes on length contraction.

(OR)
(b) Obtain Einstein’s mass-energy relation.
5. (a) State the laws of photo electricity.

(OR)
(b) Derive Einstein’s Photo electric equation.
SECTION – B
6. (a) What is chromatic aberration? Explain with necessary theory for the method of
correcting chromatic aberration in a system of lenses in contact.
(OR)
(b) Two thin convex lenses having focal lengths 20cm and 50cm are coaxial and
separated by a distance of 10cm. Find the equivalent focal length and power of
the combination.
7. (a) Give the theory of plane transmission grating.

(OR)
(b) In a Newton’s rings experiment, the diameter of the 5th ring was 0.356cm and
the diameter of the 20th ring was 0.618cm. Find the radius of curvature of the
plano convex lens if the wavelength of light used is 5893 A
8. (a) Explain the method of determination of specific rotator power using Half Shade
Polarimeter.
(OR)
(b) Calculate the least thickness of a calcite plate which would convert plane polarized light
into circularly polarized light. Given 0 = 1.658; e = 1.486 and the wavelength of the
light is 5890 A .
9. (a) Derive an expression for variation of mass with velocity.

(OR)
(b) How fast would a rocket have to go relative to an observer for its length to be
contracted to 99% of its length at rest?
10. (a) Describe the different types of photo-electric cells and explain their working.
Mention some important uses of photoelectric cells.
(OR)
(b) Calculate the work function of sodium, in electron volts, given that the threshold
wavelength is 6800 A and h = 6.625 x 10-34 Js.
AC41
(1987 – 2018)
SECTION - A
1. (a) What are buffer solution? Explain how a solution of a weak base and its salt
behaves as a buffer?
(OR)
(b) Discuss the enzyme catalysis mechanism.
2. (a) Write a note on nuclear binding energy.

(OR)
(b) Compare the properties of , , and - rays.
3. (a) Derive Oswald’s dilution law of weak electrolytes.

(OR)
(b) Discuss the chemical properties of amino acids.(carboxyl group & amino group)
4. (a) Describe the advantages of microwave synthesis.

(OR)
(b) How lead affect the enzyme reaction?
5. (a) What is sol – gel synthesis? Give its applicators.

(OR)
(b) Discuss about water soluble vitamins.
SECTION - B
6. (a) Define Kohlraush’s law. Explain its applications.

(OR)
(b) Explain strong acid V & strong base and mixture of acids V & strong base in
conductometric titrations.
7. (a) Discuss the adsorption theory of heterogeneous catalysis.

(OR)
(b) Mention the uses of radioactive isotopes.
8. (a) Describe the components and working of a nuclear reactor.

(OR)
(b) Explain the top down and bottom up paths in nano sciences.
9. (a) Explain the effects of toxic chemicals on enzymes in detail.

(OR)
(b) Write note on: (i) homogenous catalyst (ii) heterogenous catalyst
(iii) auto catalyst (iv) promoters
(v) acid-base catalyst
10. (a) Illustrate the colour reactions of proteins.

(OR)
(b) Discuss the source, deficiency of vitamin A,B,C,D and K.
****
MC41/EMC41(O)/MC41

ORGANIC CHEMISTRY - II
(2017 & 2018/2008 – 2016/1987 - 2007)
SECTION - A
1. (a) Bring the conversion of tartaric acid to succinic acid. How does succinic acid
converted into (a) Succinimide (b) Polyester.
(OR)
(b) Outline the synthesis of amines by
(i) Gabriels Phrhalimide synthesis (ii) Curtius reaction
2. (a) What is Gilman’s reagent? Discuss its synthetic applications.

(OR)
(b) Distinguish ethyl cyanide from ethyl isocyanide.
3. (a) Outline Killiani – Fischer synthesis.

(OR)
(b) Give the following reactions of acid chlorides:
(a) Rosenmund reduction (b) HVZ reaction.
4. (a) Outline the chemistry of Lactic acid.

(OR)
(b) Aceto acetic esters can undergo ketonic, acid hydrolysis leads to ketones,
alkyl substituted acids, justify.
5. (a) Discuss Michael addition and Mannich reactions of nitroalkanes.

(OR)
(b) Elaborate Ruff’s degradation of an aldohexose to aldopentose.
SECTION - B
6. (a) Explain the following with equation.

(i) Esterification (ii) Transesterification
(iii) saporificaiton (iv) Alcoholisis of ester
(OR)
(b) Write in detail on the preparation and chemical properties of amides.
7. (a) Discuss any five synthetic importance of acetoacetic ester.

(OR)
(b) Outline the properties of Maleic and Fumaric acids.
8. (i) Write note on basicily of amines

(ii) How is diazo methane react with the following (a) HCl (b) RNH2
(C) Cyclohexanone
(OR)
(b) What are the alkyl lithium compounds? How does alkyl lithium reacts with the
followings: (a) Formaldehyde (b) Vinyl bromide (c) Pyridine
9. (a) Discuss the synthetic applications of Grignard reagents.

(OR)
(b) Elucidate the structure of glucose.
10. (a) Discuss the preparation, properties and uses of nitroalkanes.

(OR)
(b) Elaborate the structural elucidation of fructose.
****
MCME61
VI SEMESTER SUMMATIVE EXAMINATIONS
COORDINATION CHEMISTRY
(2017 & 2018)
SECTION - A
1. (a) Discuss the different types of isomerism found in coordination compounds. Give
one example for each.
(OR)
(b) Describe jobs method of determining the stoichiometry / composition of the
complex using suitable example.
2. (a) Among K4 [Fe(CN)6] and [Co F6]3- which one is more paramagnetic and why?
Explain using VBT.
(OR)
(b) Discuss the factors affecting crystal field splitting.
3. (a) How are the oh complexes classified as labile (or) inert?

(OR)
(b) Identify each of the oh complexes as labile (or) inert.
(i) Co3+ [high spin]
(ii) Co2+ [low spin]
(iii) Fe2+ [high spin]
(iv) Fe2+ [low spin]
And give suitable explanation for your choices.
4. (a) What are the different types of metal carbonyls? How are they be differentiated?
(OR)
(b) Explain the phenomenon of back bonding in M-Co interaction. How does it reflect
in their properties.
5. (a) Elaborate the role of metal complexes in biological systems.

(OR)
(b) A man has ingested (eaten) mercury accidentally as a chemist, can you suggest
a method to save him. Discuss the reason for your choice.
SECTION - B
6. (a) (i) Discuss the Werner’s theory of coordination.

(ii) Give any method to identify the foly complexes A,B & C
[Co(NH6)]cl3 – A
[Co(NH5)]cl2 – B
[Co(NH4)]cl – C
(OR)
(b) Derive stepwise and overall stability constant and how can they be related?
7. (a) (i) What are the electronic transitions responsible for the bands shown by the
complexes below
2
(i) Ti H 2O 6 a band at 20,400 cm+
2
(ii) Cu H 2O 6 a band at 12,000 cm+
2
(iii) Cr H 2O 6 a band at 14,000 cm+
Also calculate their crystal field stabilization energy (10 Dq)
(OR)
(b) (i) What decides the magnetic properties of the complexes? Explain giving
examples.
(ii) construct an orgel diagram for d2 oh complexes and explain the probable
transition.
8. (a) Discuss in detail about inner sphere and outer sphere electron transfer reaction.
(OR)
(b) Discuss the mechanism of substitution reaction in oh complexes.
9. (a) (i) Discuss the EAN rule and any 4 complexes that okey’s this rule.
(ii) Also mention 2 gs in which EAN rule is not obeyed.
(iii) What happens to bond order of co on coordination to metal.
(OR)
Contd…………2
//2//
MCME61
(b) Discuss the preparation & structure of (i) Fe2(Co)9 (ii) Mn2 Co10 (iii) Fe3(Co)12
(iv) Co2(Co)8 (v)Os (Co)12
10. (a) How can complex emetic titrations help in determining temporary and permanent
hardness of water?
(OR)
(b) Elucidate the industrial applications of complexes.
****
UCH19C41
ORGANIC CHEMISTRY - II
(2019)
SECTION - A
1. (a) What is the action of heat on Lactic acid & Tartaric acid?
(OR)
(b) Write short notes on relative strength of acidity of carboxylic acids.
2. (a) Explain the preparation and properties of Pyruvic acid and Laevulic acid.
(OR)
(b) Write short on the preparation and synthetic importance of Acetoacetic esters.
3. (a) Write the distinction between Ethyl cyanide and Ethyl isocyanide.
(OR)
(b) Distinguish between Primary, secondary and tertiary amines.
4. (a) Explain the preparation, reactions and synthetic uses of TEL.

(OR)
(b) Explain about the preparation, reactions and synthetic uses of Lithium Dialkyk
Copper.
5. (a) Explain Killiani Fischer synthesis of Glucose.

(OR)
(b) Draw the structure of Starch and Cellulose.
SECTION - B
6. (a) Write the preparation and chemical properties of Acid chlorides and Esters.
(OR)
(b) Write the preparation and chemical properties of Acrylic acids and Crotonic acids.
7. (a) How is Maleic acid and Fumaric acid prepared? What are its chemical properties?
(OR)
(b) How is Malonic acid and Glutaric acid prepared? What are its chemical properties?
8. (a) Explain the preparation, properties and structure of Nitroalkanes.

(OR)
(b) Explain in detail the (i) Separation of mixture of amines.
(ii) Primary amine preparation
9. (a) Elucidate the preparation, reactions and synthetic uses of Organo Lithium
compounds.
(OR)
(b) Elucidate the preparation, reactions and synthetic uses of Organo Magnesium
halide compounds.
10. (a) Elaborately explain the structural elucidation of Glucose.

(OR)
(b) Explain the structural elucidation of Sucrose.
****
UCH19C42

PHYSICAL CHEMISTRY – II
(2019)
SECTION – A
1. (a) Explain the terms, ‘Closed system and Isothermal process’.

(OR)
(b) Differentiate between intensive and extensive properties.
2. (a) Explain the concept of entropy from the second law of thermodynamics. Show
that entropy is a state function.
(OR)
(b) Derive Gibbs-Helmholtz equation. Write its significance.
3. (a) State and explain Nernst Heat theorem.

(OR)
(b) State and explain Third Law of Thermodynamics. How would you verify it experimentally?
4. (a) State Hess’ Law of constant heat of summation and explain some of its important
applications.
(OR)
(b) Explain the terms : (i) Enthalpy of combustion (ii) Enthalpy of neutralisation
5. (a) State and Explain: Law of Mass Action. Apply it to determine K pvalue for decomposition of
Calcium carbonate.
(OR)
(b) Discuss the following physical equilibria: (i) Effect of pressure on the boiling point
of liquid (ii) Effect of temperature on the solubility.
SECTION – B
6. (a) (i) State and explain First Law of thermodynamics.

(ii) Define the terms: Heat capacity at constant pressure and at constant volume. Show
that Cp - Cv = R
(OR)
(b) (i) Prove that the value of Joule Thomson effect is zero for an ideal gas.
(ii) Write notes on objectives and limitations of thermodynamics.
7. (a) (i) Derive Clausius – Clapeyron equation and write its integrated form.
(ii) Discuss the physical significances of entropy.
(iii) Write the Maxwell’s relationships.
(OR)
(b) (i) How does Carnot’s Cycle led to the definition of Second Law of thermodynamics.
(ii) Entropy is a measure of probability – Justify.
(iii) Define the term: Entropy of mixing. Show that it is always positive.
Contd……2
//2//
UCH19C42
8. (a) (i) Define the term ‘Residual entropy’. Explain the reason for unattainability of zero
Kelvin.
(ii) How would you determine absolute entropies of Solids, Liquids and Gases?
(OR)
(b) (i) Define the term: ‘Absolute Entropy’. Is it possible to attain absolute zero?
Ascertain your answer.
(ii) Calculate the absolute entropy of Uranium metal in JK-1 at 20 K, given that Cv for
uranium metal is 3.04 JK-1 mol-1
9. (a) (i) Compare thermodynamics and thermochemistry.

(ii) Calculate the heat of formation of benzene at 25 C, if the heats of combustion of
benzene, carbon and hydrogen are -780, - 94, -68 kCal respectively at 25 C.
(iii) Define the term : Bond energy. List its applications.
(OR)
(b) (i) Derive thermodynamically Kirchoff’s equation and explain how this law is
applicable to calculate H.
(ii) With sketch, explain the working principle of Bomb Calorimeter.
10. (a) (i) State and explain Le Chatelier’s Principle.

(ii) Apply the Principle to explain the Haber process in view of the following :
(i) Effect of Pressure, Effect of Concentration and (iii) Effect of Temperature
(OR)
(b) (i) Obtain the expressions of Kp, Kc and Kx and relate them. When do they become
equal?
(ii) The dissociation of PCl 5 was studied at 229 C at a total pressure of 1 atm. The
value of Kpwas found to be 0.460 atm. Calculate the degree of dissociation of
PCl5, if keeping temperature constant, the pressure on the system is raised to 10
atm, what will be the degree of dissociation?
***********
UCH19GE41(P)&UCH19GE41(B)
(2019)
SECTION – A
1. a) Discuss Ostwald’s dilution law and its significance.

(OR)
b) Define the following conductance:
(i) Specific conductance
(ii) Equivalent conductance
(iii) molar conductance
2. a) Explain auto catalysis.

(OR)
b) Explain catalytic poison and promoters with suitable examples.
3. a) Compare the properties of alpha , beta and gamma rays.

(OR)
b) What are the advantages and disadvantages of nuclear reactor?
4. a) Discuss the preparation, properties and uses of glycine.

(OR)
b) Summarize the colour reactions of proteins.
5. a) Discuss on green solvents used in green chemistry.

(OR)
b) Explain sol-gel method for the synthesis of nano materials.
SECTION – B
6. a) i) State Kohlrausch’s law.
ii) Explain conducttometric titrations of strong ascid vs strong base and strong
acid vs weak base with graphical representation.
(OR)
b) i) Calculate pH of 0.2 M HCl solution.
ii) Discuss the theory of buffer action.
7. a) Discuss the mechanism of heterogeneous catalytic reactions.

(OR)
b) Explain the mechanism of enzyme catalysis.
8. a) i) Differentiate nuclear fusion and nuclear fission.

ii) Mention the places where nuclear reactors situated in India.
(OR)
b) i) Explain the principle of hydrogen bomb.
ii) Write the uses of radioactive isotopes as traces.
9. a) Discuss the biochemical effects caused by lead, mercury and cyanide pollution.
(OR)
b) i) Define vitamins.
ii) Write the sources and deficiency symptoms of vitamins A, C, D and K.
10. a) Discuss the basic postulates of green chemistry.

(OR)
b) Describe the top-down approach and bottom-up approach in the preparation of
nano materials.
*********
UCH19SE41

B.Sc.(Chemistry) Degree Examination, APRIL 2021
SKILL BASED ELECTIVE
FORENSIC CHEMISTRY
(2019)
SECTION – A
Answer any THREE questions: (3 x 5 = 15 Marks)
1. Classify type of adulterants.

2. Write any five common adulterants in wheat and dhal.
3. How UV detector pen is used to detect forgery in bank cheques/drafts and
educational recorded and currency notes?
4. Discuss about (a) latent image and (b) Micro lettering in Indian rupees note.
5. Write a short note on World Gold Council?
SECTION – B
Answer any TWO questions: (2 x 10 = 20 Marks)
6. How the arsenic poison is determined from hair by neutron activation method?
7. What are the common food adulterants in food grains and how are they identified?
8. Demonstrate the methods to detect gold purity in gold ornaments.
9. (i) List the differences between cube zirconia and diamonds.
(ii) Write the gold mines and diamond mines in India.
****
UCH19SE41

SKILL BASED ELECTIVE
DAIRY CHEMISTRY
(2019)
SECTION – A
Answer any THREE questions: (3 x 5 = 15 Marks)
1. What are the constituents present in milk?

2. What are neutralizers? Give example.
3. What is Rosalic acid test? How it will be useful for milk?
4. Describe the types of butter.
5. What is special milk? Constituents present in special milk.
SECTION – B
Answer any TWO questions: (2 x 10 = 20 Marks)
6. Write short notes on Vacuum pasteurization.

7. Write the method of isolation of fat from milk and method of detecting ammonium
compound.
8. What is Falvoured milk? Describe its types and uses.
9. Describe types of cream separation.
****
UMA19GE41C
ALLIED MATHEMATICS - II
(2019)
SECTION - A
Contd……..2
//2//
UMA19GE41C
SECTION - B
UMB19GE41C
CLINICAL CHEMISTRY
(2019)
SECTION - A
1. (a) Explain working principle and applications colorimeter.

(OR)
(b) Describe the various types of centrifuges.
2. (a) Explain the collection and preservation of urine sample.

(OR)
(b) Enlist the major physical properties of urine.
3. (a) Draw a neat diagram and explain about the functions of kidney.
(OR)
(b) Write a short account on blood sugar and diabetics.
4. (a) Describe the process separation of serum.

(OR)
(b) Define billirubin. Explain the composition of serum.
5. (a) Write short note on creating phosphokinase.

(OR)
(b) What is amylase? Add note on pancreaitis.
SECTION - B
6. (a) Give a detailed account on principle and types of ELISA.

(OR)
(b) Discuss the principle, working and applications of PCR.
7. (a) Write a short note on components of urine.

(OR)
(b) Explain detailed account about abnormal components of urine and its associated
disease.
8. (a) Discuss the collection of blood samples, anticoagulants anemia and its
composition.
(OR)
(b) Explain detail about structure of hemoglobin and ESR.
9. (a) Give a detailed account about liver function test.

(OR)
(b) Explain the different test involved in lipid profile in serum analysis.
10. (a) Explain detailed account about types of thyroid hormones.

(OR)
(b) Give a detailed account on alkaline phosphatase in clinical significance.
****
EMC61(G)
GROUP THEORY & SPECTROSCOPY
(2006 – 2016)
SECTION – A
1. (a) Define group. Explain the properties of a group.
(OR)
(b) Explain the Abelian group and cyclic group with examples.
2. (a) Construct C2V point group.

(OR)
(b) What is the point group of trans dichloro ethylene? Explain the symmetry
elements present in the molecule.
3. (a) Explain the various types of molecular energies.

(OR)
(b) Write note on the direct product representation.
4. (a) Differentiate ESR and NMR.

(OR)
(b) Give a brief an account of rigid rotator.
5. (a) Explain about the finger print region.

(OR)
(b) What are the factors affecting chemical shift?
SECTION – B
6. (a) Construct the character table of a C3V point group. Explain the steps involved it.
(OR)
(b) (i) Discuss the great orthoganlity theorem.
(ii) Find out the hybridization of BF3 molecule by using group theory
7. (a) Explain: (a) Franck Condon principle (b) Group frequency.

(OR)
(b) Determine the hybridization scheme for BF3 molecule from group theory.
8. (a) Discuss the applications of microwave spectroscopy.

(OR)
(b) (i) Give the Hook’s law of potential energy for a diatomic vibrator and show that
the frequency of vibrational transition is wave number = e.
(ii) The vibrationa frequency of 1H35Cl is 2990 cm-1 with our calculating the bond
force constant, estimate the frequency of 1H35Cl.
9. (a) (i) Explain isotopic effect on rotational spectra.

(ii) Write note on group frequencies.
(OR)
(b) Elucidate the instrumentation and applications of ESR spectroscopy.
10. (a) (i) Explain Larmor precession in NME.

(ii) Distinguish between NMR and ESR.
(iii) What is meant by shielding and de shielding of magnetic nuclei?
(OR)
(b) (i) Draw and explain NMR spectra of CH3 CHO molecule.
(ii) Define coupling constant and factors influencing coupling constant.
MC61
INORGANIC CHEMISTRY & COMPUTER APPLICATION
(2017 & 2018)
SECTION – A
1. (a) What is a complexes o metric titrations? Why is EDTA used in these titrations?
Name any one indicator for complexometric reactions.
(OR)
(b) Explain with examples the iodometric and iodimetric tiltrations.
2. (a) Discuss the principle and application of cyclic voltammetry.

(OR)
(b) What is the principle behind the working TGA instruarent? Give any one
application.
3. (a) Explain polymeric phosphorus compounds.

(OR)
(b) What are Coordination polymers? Discuss giving suitable examples.
4. (a) (i) What are low level and high level languages? Give examples.
(ii) Name the 2 types of translators in Computers.
(OR)
(b) “Imagine at present that you are in the world where there are no computers”
Describe your experiences.
5. (a) What are the different datatypes available in C?

(OR)
(b) Write a program to calculate the energy of Lyman line series (x2 = 3,4,5)
SECTION – B
6. (a) (i) State Lambert beer law. (ii) How can the Ni(II) and Fe (III) be determined
spectrophotometrically?
(OR)
(b) (i) Discuss about redox titration and how can it be used for determination
of iron. (ii) What are the ceharaeteristics for a redox indicator?
7. (a) Discuss the use of thermo gravimetric procedures (TGA/DTA) in determining
the water of hydration of a compound and glass transition temperature of a
polymer.
(OR)
(b) Write notes on the following (i) Amperometric titrations (ii)Electrogravrimetry.
8. (a) Write an essay on inorganic polymers.

(OR)
(b) (i) What are linear and Goss linked polymers? Give egs. Give the advantages
of Gosslinked polymers.
9. (a) Discuss the evolution of conbuters

(OR)
(b) (i) What are the input output devices available?
(ii) Comment on “UNIX” as superior operation system.
10. (a) What are operators? Discuss the different operators in C?

(OR)
(b) (i) Write a program to calculate RMS and average velocity of O2.
(ii) What are the Control statements in C.
MC62
ORGANIC CHEMISTRY - IV
(2017 & 2018)
SECTION - A
1. (a) Complete the followings.

(i) pyrrole + HNO3 + ? ? + 2CH3 Co oH.
(ii) Thiophene + ? ? + 2 – Bromo chiophene.
(OR)
(b) How is malachite green prepared from Benzaldehyde?
2. (a) Write a detailed notes on Hoffmann exhaustive methylation.

(OR)
(b) (i) Define isoprene rule.
(ii) identify the following.
CH 3COON 9 H 2O O
- piene + ? ? ? Camphor.
3. (a) Explain Norrish type II reaction with suitable examples.

(OR)
(b) Describe Diel’s Alder reactions in detail.
4. (a) Write notes on Nin hydrin test.

(OR)
(b) Write notes on
(i) Co – enzyme
(ii) Holo - enzyme
5. (a) Write a detailed notes on solvent free organic synthesis.

(OR)
(b) Differentiate between microwave heating and conventional heating.
SECTION - C
6. (a) (i) Write notes on Fisher – indole synthesis.

(ii) Complete the following.
(a) Furan Diels – Alder adduct.
(b) Quinoline 2 –amino quinoline.
(OR)
(b) (i) Explain the process of preparation of Indigo from amtine.
(ii) Describe the applications of congored and phenopthalein.
7. (a) Write a detailed notes on the synthesis of Menthol.

(OR)
(b) Explain the structure of citrol.
8. (a) (i) Describe Jablonski diagram.

(ii) Explain the photo chemical reaction existing in carbonyl compounds.
(OR)
(b) (i) Describe photo reduction and oxidation with example.
(ii) Write a detailed notes on wood ward Hoffmann rule.
9. (a) (i) Write notes on

- Isoeletrtic point
- Zwitter ion.
(ii) Describe strecker synthesis of amino acids.
(OR)
(b) Write a detailed notes on the mechanism involved and applications of enzymes.
10. (a) (i) What are the principles involving in solid state reactions.
(ii) Explain the Characteristics of microwave heating.
(OR)
(b) (i) Explain the microwave assisted reactions involved in
(a) aqueous media.
(b) supercritical CO2.
MC63
PHYSICAL CHEMISTRY - IV
(2017 & 2018)
SECTION – A
1 (a) State and explain Faraday’s Laws of Electrochemistry.

(OR)
1 (b) State and explain: Ostwald’s dilution Law.
2(a) Deduce Nernst equation for the emf of the cell.
(OR)
2 (b) Write a note on the importance of lead storage battery.
3 (a) Differentiate thermal and photochemical reactions.
(OR)
3 (b) Highlight the term: Photosensitization.
4 (a) Differentiate: Lyophilic and Lyophobic colloids.
(OR)
4 (b) Explain the terms (i) True Solution and Suspension (ii) Gold number
5 (a) Compare physisorption with chemisorption
(OR)
5 (b) Enumerate the application of the concept of adsorption in chromatographic techniques and paint industry
SECTION - B
6(a ) (i) Define the terms :
(i) Specific conductance
(ii) Ionic product of water
(iii) Buffer Solution
(iv) Common ion effect
(ii) With the plot, explain the variation of conductance with dilution.
(iii) Calculate pH of 0.1 N NaOHsolution.
(OR)
6(b ) (i) Write Kohlrausch’s Law and list its applications.
Contd..2...
// 2 //
MC63
(ii) With neat plots, explain the principle of the following conductometric titrations :
(1)Strong acid vs weak base (2) Weak acid vs Strong bases.
(iii) List any two applications of conductometric titrations.
7(a ) (i) Distinguish between Galvanic Cells and Electrolytic Cell.
(ii) Briefly explain the principle of potentiometric titrations. What are its advantages over other titrations?
(OR)
7(b) (i) Write Cell reactions for the following cells.
Cd Cd2+ KCl Hg2Cl2 Hg, Zn CZn2+ Fe2+,Fe3+ Pt
(ii) Account on : H2-O2 Fuel Cell
8(a ) (i) State and explain the Laws of Photochemistry.

(ii) Draw Jablonski Diagram and indicate various photo physical processes in it.
(iii) Differentiate Fluorescence and Phosphorescence
(OR)
8(b ) (i) With examples, Explain the terms :Chemiluminescence and bioluminescence.
(ii) Define the term : Quantum efficiency.
When irradiated with the light of 5000A wavelength, 1 x 10-4 moles of a substance decomposed. How
many photos are absorbed during the reaction if quantum efficiency is 1.00
(iii) With mechanism explain the photochemical formation of HI and give the reason for its maximum quantum
efficiency.
9(a ) (i) What is meant by(i) Electrical double layer (ii) Zeta potential ?
(ii) Write a short note on :Hofmeister Series.
(iii) With one example each tabulate the different types of colloidal solutions.
(OR)
9(b ) (i) Describe the method of preparation of colloids.
(ii) Discuss the applications of colloids for purification of water.
10(a) (i) Define the terms : Negative absorption and positive adsorption.
(ii) Deduce the expression for Langmuir’s unimolecularAdsorption isotherm. List the limitations of this
theory,
(OR)
10(b) (i) With two examples each, define the terms :Adsorbent and Adsorbate.
(ii) Explain Freundlich Adsorption Isotherm. At what pressure it is applied?
* * * * *

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No. of page(s): 1 Exam. No.

2. a) Discuss on number average and weight average molecular weights of polymer.

3. a) Discuss on Russell-Soddy group displacement law.

4. a) Derive Nernst distribution law.

5. a) Derive Clausius-Mosotti equation.

7. a) Discuss on addition and condensation polymerization.

8. a) Outline the detection and measurement of radioactivity by using GM counter method.

THIAGARAJAR COLLEGE (AUTONOMOUS), MADURAI – 9

1. (a) Distinguish between an intrinsic and extrinsic semiconductor.

2. (a) Explain the characteristics of PNP transistor in common emitter configuration.

3. (a) Convert the Hexadecimal number 10016 into decimal number.

5. (a) Explain in detail the commutative law.

6. (a) Draw and explain the V-I characteristic of PN junction diode.

7. (a) What is a transistor? Explain working principle of transistor as an amplifier.

9. (a) Show that NAND gate is an universal gate.

10. (a) State and prove De-Morgan’s theorems.

2. (a) Write a note on nuclear binding energy.

3. (a) Derive Oswald’s dilution law of weak electrolytes.

4. (a) Describe the advantages of microwave synthesis.

5. (a) What is sol – gel synthesis? Give its applicators.

6. (a) Define Kohlraush’s law. Explain its applications.

7. (a) Discuss the adsorption theory of heterogeneous catalysis.

8. (a) Describe the components and working of a nuclear reactor.

9. (a) Explain the effects of toxic chemicals on enzymes in detail.

10. (a) Illustrate the colour reactions of proteins.

1. (a) Elucidate the Hess’s law of heat of summation.

2. (a) State and explain Arrehenius theory of electrolysis.

3. (a) Write a note on optical isomerism.

5. (a) Give the preparation of glycine and alanine.

6. (a) Explain Carnot’s cycle and the theorem in detail.

7. (a) Describe the principle and methods of electroplating.

8. (a) (a) Explain Walden inversion.

10. (a) Give the structure of penicillin and tetracycline.

4. (a) Find L[sin 3t cos 2t].

6. (a) Solve (D2 + 2D + 5) y = e-x cos 2x

7. (a) Using Laplace transform, solve (D2+6D+5)y = e-2t given that y = 0, Dy = 1

(b) In a culture of bacteria the rate of increase is proportional to the number

2. (a) Explain the method of determination of wavelength of sodium light by forming

3. (a) Explain the construction and working of a Quarter Wave plate.

4. (a) Write short notes on length contraction.

5. (a) State the laws of photo electricity.

7. (a) Give the theory of plane transmission grating.

9. (a) Derive an expression for variation of mass with velocity.

2. (a) Write a note on nuclear binding energy.

3. (a) Derive Oswald’s dilution law of weak electrolytes.

4. (a) Describe the advantages of microwave synthesis.

5. (a) What is sol – gel synthesis? Give its applicators.

6. (a) Define Kohlraush’s law. Explain its applications.

7. (a) Discuss the adsorption theory of heterogeneous catalysis.

8. (a) Describe the components and working of a nuclear reactor.

9. (a) Explain the effects of toxic chemicals on enzymes in detail.

10. (a) Illustrate the colour reactions of proteins.

THIAGARAJAR COLLEGE (AUTONOMOUS), MADURAI – 9

2. (a) What is Gilman’s reagent? Discuss its synthetic applications.

3. (a) Outline Killiani – Fischer synthesis.

4. (a) Outline the chemistry of Lactic acid.

5. (a) Discuss Michael addition and Mannich reactions of nitroalkanes.

6. (a) Explain the following with equation.