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    At STRC DPP 14

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    Mofazzel Hussain
    The document is a practice problem set for physical chemistry covering atomic structure. It contains 10 multiple choice and subjective questions testing concepts like photoelectric effect, Bohr model, wavelengths of electromagnetic radiation, potential and kinetic energy of electrons in different atomic orbitals. The answer key and hints/solutions are also provided to explain the reasoning behind the answers.

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    At STRC DPP 14

    Uploaded by

    Mofazzel Hussain
    14 views3 pages
    The document is a practice problem set for physical chemistry covering atomic structure. It contains 10 multiple choice and subjective questions testing concepts like photoelectric effect, Bohr model, wavelengths of electromagnetic radiation, potential and kinetic energy of electrons in different atomic orbitals. The answer key and hints/solutions are also provided to explain the reasoning behind the answers.

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    AT STRC DPP 14

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    The document is a practice problem set for physical chemistry covering atomic structure. It contains 10 multiple choice and subjective questions testing concepts like photoelectric effect, Bohr model, wavelengths of electromagnetic radiation, potential and kinetic energy of electrons in different atomic orbitals. The answer key and hints/solutions are also provided to explain the reasoning behind the answers.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    14 views3 pages

    At STRC DPP 14

    Uploaded by

    Mofazzel Hussain
    The document is a practice problem set for physical chemistry covering atomic structure. It contains 10 multiple choice and subjective questions testing concepts like photoelectric effect, Bohr model, wavelengths of electromagnetic radiation, potential and kinetic energy of electrons in different atomic orbitals. The answer key and hints/solutions are also provided to explain the reasoning behind the answers.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 3

    PHYSICAL CHEMISTRY Total Marks : 37

    DPP
    DAILY PRACTICE PROBLEMS
    DPP No. 14 Max. Time : 41 min.

    Topic: Atomic Structure

    Type of Questions M.M., Min.


    Single choice Objective ('-1' negative marking) Q.3 to Q.9 Subjective (3 marks, 3 min.) (4 [21, 21]
    Questions ('-1' negative marking) Q.1 to Q.2 Match the Following (no marks, 5 min.) (8 [8, 10] [8,
    negative marking) (2 x 4) Q.10 marks, 10 min.) 10]
    1. In I experiment, electromagnetic radiations of a certain frequency are irradiated on a metal surface ejecting
    photoelectrons having a certain value of maximum kinetic energy. However, in II experiment,on doubling the
    frequency of incident electromagnetic radiations, the maximum kinetic energy of ejected photoelectrons
    becomes three times. What percentage of incident energy is converted into maximum kinetic energy of
    photoelectrons in II experiment ?
    2. The potential difference applied on the metal surface to reduce the velocity of photoelectron to zero is known
    as Stopping Potential. When a beam of photons of wavelength 40 nm was incident on a surface of a particular
    pure metal, some emitted photoelectrons had stopping potential equal to 18.6 V, some had 12 V and rest had
    lower values. Calculate the threshold wavelength (Xo) of the metal (in A) assuming that at least one
    photoelectron is ejected with maximum possible kinetic energy, (he = 12400 eVA)
    3. For which of the following species, Bohr model is not valid :
    (A) He+ (B) H (C) Li2+ (D) H+
    4. Wavelength of radiations emitted when an electron in a H-like atom jumps from a state A to C is 2000 A and it
    is 6000 A, when the electron jumps from state B to state C. Wavelength of the radiations emitted when an
    electron jumps from state Ato B will be :
    (A) 2000 A (B) 3000 A (C) 4000 A (D) 6000 A

    8. The potential energy of the electron present in the ground state of Li 2+ ion is represented by :
    (A) (B) _4rb (C) (D)

    If the angular momentum of an electron in a Bohr orbit is , then the value of potential energy of this electron
    9. present in He+ ion is :
    (A)-13.6 eV (B) - 3.4 eV
    (C)-6.8eV (D) - 27.2 eV.

    10 Match the following :


    . En = total energy, £n = angular momentum, Kn = K.E. , Vn = P.E., Tn = time period, rn = radius of nth orbit
    Column (I) Column (II)
    (A) En_y« rn/Z, then y is (P) 1/2 (q)-2
    (B) tn x nx ,then x is
    En
    (C) Value of vr is (0-3
    ▽n
    z‘
    (D) Tn « — , t & m are respectively (s)1
    n
    Answer Key
    DPP No. # 14
    1, 75% 2. 1000 A s. CD)
    + (B) 5. (C)

    6. (C) 7. (A) i. (D) 9. (C)

    10, (A-S) ； (B-S)：(C-P): (D-q. r).

    Hints & Solutions


    DPP No, # 14
    1. For I experiment, (1)
    For I! experiment. H w + KE_ (2)
    here, Vs : 2v; and KE_ =
    _,
    3 KE

    2hv, = W + 3 KE_ ,,■■(3)


    •r ■
    =2
    From (1) and (3): hv^KE^ or
    % of incident energy converted into max KE in II experiment

    =X 100= |x 100 =75%.

    2. The maximum KE of potoelectron is corresponding to maximum stopping = 18.6 eV -- E


    .c^= W+KEmax

    12400
    —eV = W+ 18.6 eV 400
    W= 12.4 eV

    Only for Single electron species.


    J__ J__1__ 1
    A-j 3000
    ?^ = 3000 A.

    3.

    J_____1_
    4. n
    c nA

    1 1
    n
    B
    5. For r= 0.52 A x —

    For L2* r, = 0.529 x y

    6. ^-r3 = 7xri

    7. Use Vn = 2.185 x cm/sec.

    8. PE = -

    nh = 2h
    9. 2K x

    2 -13.6x1^ =
    P.E. = 2(T.E.)= -6.8 eV.

    10. (A) En-"xrn/Z

    4x13.6 eV -y
    n
    J O
    C
    —x 0.529 A

    y=1

    a n<
    (B) x= 1

    (C) Potential energy = 2 (total energy)

    (D) Tn p- t = -2 m = - 3.

    5. If the radius of the first Bohr orbit of the H atom is r, then for Li 2+ ion,
    it will be :
    (A) 3r (B) 9r (C) r/3
    (D) r/9
    6. In a certain electronic transition in the Hydrogen atom from an initial
    state i to a final state f, the difference in the orbit radius (r - rf) is
    seven times the first Bohr radius. Identify the transition :
    (A) 4 1 ' (B) 4 2 (C) 4 3
    (D) 3 1
    7. The velocity of electron in the ground state of H atom is 2.184 x 10 5 6
    78
    cm/sec. The velocity of electron in the second orbit of Li 2+ ion in
    cm/sec would be :
    (A) 3.276 x 108 (B) 2.185 x 108 (C) 4.91 x 1O8
    (D) 1.638 x 10 8

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