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Stimulus

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Mendeleev’s Periodic Table

Scientists had identified over 60 elements by the time of Mendeleev's Periodic Table
construction. Today 112 elements are ordered on the Periodic Table. In Mendeleev's
day the atom was considered the most basic particle of matter. The building blocks of
atoms (electrons, protons, and neutrons) were discovered later. What Mendeleev and
chemists of his time could determine however, was a more accurate atomic weight of
each element, i.e., how heavy its atoms were in comparison to an atom of hydrogen, the
lightest element, which is known today as relative atomic masses.
“I began to look about and write down the elements with their
atomic weights and typical properties, analogous elements and like
atomic weights on separate cards, and this soon convinced me that
the properties of elements are in periodic dependence upon their
atomic weights.”
--Mendeleev, Principles of Chemistry, 1905, Vol. II
Overall understanding of how the elements are related to each other and why they
exhibit their particular chemical and physical properties was slow in coming. Between
1868 and 1870, in the process of writing his book, The Principles of Chemistry,
Mendeleev created a table or chart that listed the known elements according to
increasing order of atomic weights. When he organized the table into horizontal rows, a
pattern became apparent--but only if he left blanks in the table. If he did so, elements
with similar chemical properties appeared at regular intervals--periodically--in vertical
columns on the table.

Mendeleev was bold enough to suggest that new elements not yet discovered would be
found to fill the blank places. He even went so far as to predict the properties of the
missing elements. Although many scientists greeted Mendeleev's first table with
scepticism, its predictive value soon became clear. The discovery of gallium in 1875, of
scandium in 1879, and of germanium in 1886 supported the idea underlying
Mendeleev's table.

Each of the new elements displayed properties that accorded with those Mendeleev had
predicted, based on his realization that elements in the same column have similar
chemical properties. The three new elements were respectively discovered by a French,
a Scandinavian, and a German scientist, each of whom named the element in honour of
his country or region. (Gallia is Latin for France.) Discovery of a new element had
become a matter of national pride--the rare kind of science that people could read about
in newspapers, and that even politicians would mention.

Claiming a new element now meant not only identifying its unique chemical properties,
but finding the atom's atomic weight so the element could be fitted into the right slot in
the periodic table. For radioactive atoms that was a tough challenge. At first these atoms
were isolated only in microscopic quantities. The straightforward way to identify them
was not by their chemical properties at all, but by their radiations. Until the radioactive
atoms could be sorted out with traditional chemistry, some scientists were reluctant to
call them new elements
Criteria that will be addressed: Science as a Human Endeavour
“Critical analysis of how and why models and theories have developed over
time and justified discussion of the factors that prompted their review.”

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