somol

Ateed mintue contiring o moly. henone & .

poesue edcng valve &tehed int

ito a pipe atill though a ferd converte O-335 O.409
Fint the ompssltion o
Gìven Ze =0.
Baeis : oo kmol tee
43.2
17.8

= Ao kmol D- bokmol
--0661 Stem DEtillaten.
.: slope pesting line
For a binay leyud mtue ABB

fracien of feat vapouized &collecte au litilate

Monseneomepe)
4bitilkte
uppese #A-tget ompound
B- non vokile
trord nget steam) Pos an ilea bina mitue

AB e ron keible wt eRoh btes

y*

A miortue of tomoly. benzane amd 6omoi toluene bing

Calcuation ef stean requirement
Case u) The shstme A s sonmt cib le
ash etilled ot a rate o vo kma ust water
The lioutl pqalc shoud not ontain moe Hm 20 (mal) o Fecd antais A &treo of non votetile mpurtie
benzene. Calcetate the amount A Lompetitione of the top &bottom
pradutt. The metatie voltilrty of benzene in mjocuue is as. Solve tË m s moles ef castrces oltilized bt by uppyin
ammitiay as uell as qraphally
soln
te kmer Pa
Oveall balanee, F p t W D D-)to = D+N -

Compenen balAne , F Ze = DyptNnn0 io

aaeil'erium
’(et) SE-vapaurizbi en etticieny ob -o4
P- EA
Graphia meted, we hane
Pvaute Caepe o cpetiy line ) Beth A 2 C Are inssuble usrt wat
Inbm 14 ma - mo les at A at ny time
ind W, D. thn itbs moe tozLtir is t
|autl present in thee ti||.
 Vapeuizeten efueney Amotb a pauct
amout ot wateColeamactual
P-E9
Amout ed nuct
eieramiot CCoHig o) s o ementia! oil conventinal y eiven E=sr. amout ot wateateamfecretial
prtied by stean eitillatte . Á pi Lot sale unt ehagel A
o.5 Ka of cule qesmiol ontaining a Small amDut of non

volaile impeity: Hve stuate teann at tos'e is

Rnouh e sti tt at a ate of ao Catutate te
istil ktien
ttme asuming trat griol is immicjble uiti wate &negct
the onlenation uf teamC 0 . 8 Pte atosc
CA -mrn H,T-ink)
son
H
VP of qraniol (A) = .48 Me
.'. sfearo
mained PA
z0.44 2 kmal
(o.8)CT:48)
-.493) I )
154
- 8-814 kg
Shearn lo rate stearn

Time tea eistiltien &.814 kg

Ntobentene has to be stero eistilled. Df he

8s%.Gstite
o m t f troenzene in the sillte, if too ka of stem
le pneiert in tfe tillcte.The listilletic taes blae at a Pr

84.9 139.4 lgs.

lo AO (oo

bo
Ss-3 141.4 35S1
 Fractionatien t,

Fractionat iilktien. Consicler a se etien f e

Snacfinatos entirey above the

Cohtchsnle
fe.
h-) point ot intraluion ef
onceenoeL emoves all e
The
latet het fonon t e bvehead p r l d

stem but aloes not tool te mesettir tthe.

a total coneenses ic wset 4,=o

Total M.B for emehing sectien.

Des'o continLos foochenatien coumn Pefun gtio =) &= t ( t )

Hecabe - Thiete metRoo Enn'ehuing eetitying sectien

1)
:) Ponchon - Savait method.
Comperent balonee

) Nelabe Thiete mcihod

Assemptiens: +

Be+) ble+)
* constat mola ovetto A, =k,z.
dor pectitying seetim
oant. (4)
Hiy dor otripping section wits t lates
Ean A is percting line fos ectitying sechen

t ContAt mda heat e vapoBisathion Thteept =

Enmchng (o3) rectifying sectien.

 sectien.
operting line tor stoppirg
belo
Ha
Consiees the letien

teet
Dverall balane do (E- =(G- G) Ha tFH
<Stippin sectie, Np
3)
(--) G-G) He -t HF 4)
-g or ) toroo es u (),
&-)+F]
F

-4 (H-Ha) = HF-H

<olope of opeuting line, H-Ha

L-W
opeating line equ becormes (whan m= n) p.he
wtlh Sub. for G-G)
(F-) -E =)
He-H
F H -Ha
H-F
Ha-H
Eguatien tor feed line The RHs ot e aboe equ ie the auetity of
Maws balane ove t e Seed plate
heat eauiret to conhet Imol ot feet at s
F+ L+ G = L t to the
fher conlition to a stuatea vapou
Vapouizhes
molal latert heat ot
e-HF = I-L
F
Ha-HL
Enthaly kalme on teed plate
F
F
F. H +LH ,tÛ Hc.. - GHay
 Soute balnce above feet pktc
step )

2) Aicgoral
Scwte bakare below the feed phte
oete tte
orrpain ot fs (I),
mesie
Aep)
step 3)
is
Etimein n.
value he
seute balme U.

se 4) Join DaS e
qph.tet it be point

Tota balanee, step s From polrt F, row ta -tine

feet

oubtracting eqe (io) tom (9), Shep bj Join T h bo gd

tipping sec: p ine.
step 1) ontut steps eg ve and op li nes a
New equ W) becomes
pnt the no f steps
FG-)4- Fqr-FzF 3)
A miatire ef benxene toliene ontaining 3g mol.
- ZF
’l4) benyee ks o be
Seperated to give
This ic opersing line equ to feed tine. qmol, benzene t the bop &te bottmpiuet
-
satuted ia, - liy t apou with 4 molr benzene. The teest enteu tre ctum at itt
A- Satte vap -supuhated vap
Feed ontition Vae etlun rtio 20 oate te eed plate
line detmine te no. ot theei cel
Ha-t blatea. The V'p of pe
}Cod la (fet betow BP)

Vae af

stuated vaP To f o VE lta

I+.rh
I+Co-i)
 At total nefun
terdrt al tte istilkte

ien

Tectitying mchiern R+
The Bp. ine tor
bp tine
rectrfing sectin
Refun rotio
Arnount Dt top prlet retuned to (Pr)

Anpunt f top praluct wrtfdauh

(aistilaay At total etCm D=D;
=)
niimuun meun matie (Rin
t This is the minimum amount ot eflun ery
meteen atio =) Trinte no. D plAtes wil be reied.
Dneeete i R2 lecesse irte no. ct ptate neaded Me labe Thiele methad agtn at total
Detemingtion ef minius RR: retlun eonitie .

Frorm inteAlept ua,

Rointl
Dptimurn/eonomic meplua ntio

optim
Tati'o
 a roiott
t is eesiet to upes *ilers wsed in
b2 ttteol Iiaid in a platcd stillatiun a.
cotunne
ontineous foachieneting
top odt
The tec ontain tsmol. A & the
) Roenl ReboileReboile
.he bottom pod
is to contaio q6 moly. A
)
t tontaismol.
A.Detemine Rroi 6 the Tadketted kettte Reboile
nD.tha A) Eutena Debole.
1hetmoyFhe
vapo Jackettet eltte

mol tactiens Belto

Eteara

Tquid in the feed mintue

tondensate
= -A.

From qrTaph, Hpes of coneunse

o.46 ) P a t l ondense
=032 =) Rin 909
Ronint! Rmntl
e) Totl ceneense.
= 3.8I8

Aetial y-avis ntercept tor top prdnet

= D114
attyig secten p. ne 3.848+

4
 Fenkis quatim.
Deivaien ef
I-2d

equatin
For (hn)" pate At bota
mtlun, minimun no. o pates ae eed

|-9n+1
0) Npoint
total ebur,
Taking Ln on bot sie
Rectitying
Setien op. lie equ

on (2)

Sb. (1) in 0)
Nrn+| = b
For (o)" plate
|-Rn

n =0,

Plate i
=

Plate
Alabootory mectication oum t peateal at atm
(3)
freisue 2at total etln fog benyne aAlbenzene mite
Forr plate Samplas el liuid toom the conlnse reboile malyze
1 moly. benene & 98mol . ehtorobenzene mespectirey

Now uttipy all the eqctine

n y
Aasuning pefect rebolea totel conlenae, onitant
oat ovetow b no heAt o to +Re towel. al outate

acta no. ef plateA in the aotmn. he

 phtes No.
Analytioally,
Fenskin'seat
e |-o.S
Theny
intheoretia Np+t
#.8 =
the NpH
ournn Np+l
sstages Npt}
Np+l
o.0
YoThe
plates =)
stages
no.
in
(Dneluding
o o
the
heoreti of
efenuy
Plate comn
(endudiny
column
ebila bengene
a oelaoile)
plates =s-
to
in |=A
the
ohe

fecd

(epeatrita olumn

Azeotropie

Distilktien.