(As on 18.9.

2001)

THE MAJOR ACCIDENT HAZARD CONTROL RULES, 1997

ARRANGEMENT OF RULES

1. Short title and commencement

2. Definitions
3. Collection, development and dissemination of information
3A. Duties of Inspector
4. General responsibility of the occupier
5. Notification of major accidents
6. Industrial activities to which Rules 7 to 15 apply
7. Notification of sites
8. Updating of the notification under Rule 7
9. Deleted
10. Safety reports and Safety audit reports
11. Updating of reports under Rule 10
12. Requirements for further information to be sent to the Inspector and
the Chief Inspector
13. Preparation of on-site emergency plan by the occupier
14. Deleted
15. Information to be given to persons liable to be affected by a major
accident
16. Disclosure of information notified under the Rules
17. Deleted
18. Power of the State Government to modify the Schedules
19. Repeals and Modifications to the Rules for the Factories
(Amendment) Act, 1987

Schedule 1 Indicative criteria and list of chemicals

Schedule 2 Isolated storage
Schedule 3 List of hazardous chemicals
Schedule 4 Industrial installations within the meaning of Rule 2(b)
Schedule 5 Safety data sheet
Schedule 6 Information to be furnished regarding notification of a major
accident
Schedule 7 Information to be furnished for the notification of sites
Schedule 8 Information to be furnished in a safety report
Schedule 8A Details to be furnished in the On-site Emergency Plan
Schedule 9 Repeals and Modifications to the Rules for the Factories
(Amendment) Act, 1987

1. Short title and commencement –

(1) These Rules may be called The Major Accident Hazard

Control Rules, 1997
(2) They shall come into force on the date of their publication in
the Official Gazette as per the procedure laid down under the
Factories Act, 1948.
(3) These Rules supplement the Rules already notified under
Chapter IV-a of the Factories Act, 1948

2. Definition –

In these Rules, unless the context otherwise requires –

(a) “hazardous chemical” means, -
i) any chemical which satisfies any of the criteria laid down in
Part I of Schedule 1 or is listed in Column 2 of Part II of this
Schedule; or
ii) any chemical listed in Column 2 of Schedule 2; or
iii) any chemical listed in Column 2 of Schedule 3;

(b) “industrial activity” means : -

an operation or process carried out in a factory referred to in

Schedule 4 involving or likely to involve one or more hazardous
chemicals and includes on-site storage or on-site transport which
is associated with that operation or process, as the case may be;

(c) “isolated storage” means storage which no other manufacturing

process other than pumping of hazardous chemicals is carried
out and that storage involves at least a quantity of that chemical
set out in Schedule 2, but does not include storage associated
with a factory specified in Schedule 4 on the same site.

(d) “major accident” means an incident involving loss of life inside or

outside the site or 10 or more injuries inside and / or one or more
injuries outside or release of toxic chemical or explosion or fire or
spillage of hazardous chemicals resulting in ‘on-site’ or ‘off-site’
emergencies or damage to equipment leading to stoppage of
process or adverse effects to the environment.
 (e) “pipeline” means a pipe (together with any apparatus and works
associated therewith), or system of pipes (together with any
apparatus and works associated therewith), for the conveyance of
a hazardous chemical, other than a flammable gas as set out in
Column 2 of Part II of Schedule 3 at a pressure of less than 8 bars
absolute;

(f) “Schedule” means Schedule appended to these Rules;

(g) ** ** **

(h) Words and expressions not defined in these Rules but used
thereunder have the same meaning as assigned therein.

3. (1) This Rule shall apply to an industrial activity or isolated

storage in which a hazardous chemical which satisfies any of
the criteria laid down in Part I of Schedule 1 or listed in
Column 2 of Part II of this Schedule is or may be involved.

(2) An occupier of an industrial activity or isolated storage in

terms of Sub-rule (1) of this Rule, shall arrange to obtain or
develop information in the form of Safety Date Sheet as
specified in Schedule 5. The information shall be made
accessible to workers upon request for reference.

(3) The occupier while obtaining or developing safety data

sheet as specified in Schedule 5 in respect of hazardous
chemical handled by him shall ensure that the information is
recorded accurately and reflects the scientific evidence used
in making the hazard determination. In case, any significant
information regarding hazard of a chemical is available, it
shall be added to the safety data sheet as specified in
Schedule 5 as soon as practicable.

(4) Every container of a hazardous chemical shall be clearly

labeled or
marked to identify,
(a) the contents of the container;
(b) the name and address of the manufacturer or
importer
of the hazardous chemicals; and
(c) the physical, chemical and toxicological data of the
hazardous chemical.
 (5) In terms of sub-rule (4) of this Rule where it is impractical to
label a chemical in view of the size of the container or the
nature of the package, provision should be made for other
effective means like tagging or accompanying documents.

3A. Duties of Inspector –

The Inspector shall –

(a) inspect the industrial activity or isolated storage at least

once in a
calendar year;
(b) send annually status report on the compliance with the
Rules by occupiers to the Ministry of Environment & Forests
through the Directorate General Factory Advice Service and
Labour Institutes and Ministry of Labour, Govt. of India
(c) enforce directions and procedures in respect of industrial
activities or isolated storages covered under the Factories
Act 1948 and in respect of pipelines upto a distance of 500 m
from the outside of the perimeter of the factory, regarding –
(i) Notification of the major accidents as per Rules 5(1) &
5 (2).
(ii) Notification of sites as per Rules 7 & 8
(iii) Preparation of Safety Reports as per Rules 10-12.
(iv) Preparation of on-site emergency plans as per Rule
13 ad involvement in the preparation of off-site
emergency plans in consultation with District Collector
or District Emergency Authority.

4. General responsibility of the occupier –

(1) This Rule shall apply to –

(a) an industrial activity in which a hazardous chemical, which

satisfies any of the criteria laid down in Part I of Schedule 1
or is listed in Column 2 of Part II of this Schedule is or may
be involved; and
(b) isolated storage in which there is involved a quantity of a
hazardous chemical listed in Column 2 of Schedule 2 which
is equal to or more than the threshold quantity specified in
this Schedule for than chemical in Column 3 thereof.
 (2) An occupier in terms of sub-rule (1) shall provide information on
demand to
show that he has –
(a) identified the major accident hazards; and
(b) taken adequate steps to –

(i) prevent such major accidents and to limit their

consequences to
persons and the environment; and
(ii) provide to the persons working on the site with the
information, training
and equipment including antidotes necessary to ensure
their
safety and health.

5. Notification of Major Accident –

(1) where a major accident occurs on a site or in a pipeline the

occupier shall with 48 hours notify the Inspector and Chief
Inspector of than accident, and furnish thereafter to the
inspector and Chief inspect a report relating to the accident in
installments, if necessary, in Schedule 6.

(2) The Inspector and Chief Inspector shall on receipt of the report
in accordance with sub-rule (1) of this Rule, shall undertake a
full analysis of the major accident and send the requisite
information to the Ministry of Environment and Forests through
the Directorate General Factory Advice Service and Labour
Institutes and Ministry of Labour, Government of India.

(3) An occupier shall notify to the Inspector steps taken to avoid

any repetition of such occurrence on a site.

(4) The Inspector and Chief Inspector shall compile information

regarding major accidents and made available a copy of the
same to the Ministry of Environment and Forests through
Directorate General Factory Advice Service and Labour
Institutes and Ministry of Labour, Government of India.

(5) The Inspector and the Chief Inspector shall inform the occupier
in writing, of any lacunae which in their pinion needs to be
rectified to avoid major accidents.

6. Industrial activities to which Rules 7 to 15 apply

 (1) (a) Rules 7, 8, 13 and 15 shall apply to an industrial activity, other
than isolated storage, in which there is chemical listed in
Column 2 of Schedule 3 which is equal to or more than the
threshold quantity specified in the entry for that chemical in
Column 3;

(b) Rules from 10 to 12 shall apply to an industrial activity other

than isolated storage, in which there is involved a quantity of a
hazardous chemical listed in Column 2 of Schedule 3 which is
equal to ore more than the threshold quantity specified in the
entry for that chemical in Column 4;

(c) Rules 7 and 8 shall apply to an isolated storage in which there

is involved a quantity of a hazardous chemical listed in Column
2 of Schedule 2 which is equal to ore more than the threshold
quantity specified in the entry for that chemical in Column 3;

(d) Rules 10 to 13 and 15 shall apply to an isolated storage in

which there is involved a quantity of a hazardous chemical
listed in Column 2 of Schedule 2 which is equal to ore more
than the threshold quantity specified in the entry for that
chemical in Column 4;

7. Notification of sites

(1) An occupier shall not undertake any industrial activity or

isolated storage unless he has submitted a written report to
Chief Inspector containing the particulars specified in Schedule
7 at least 90 days before commencing that activity or isolated
storage; or before such shorter time as Chief inspector may
agree and for the purposes of this sub-rule, an activity in which
subsequently there is or is liable to be threshold quantity given
in Column 3 of Schedules 2 and 3 or more of an additional
hazardous chemical shall be deemed to be a different activity
and shall be notified accordingly.

(2) The Chief Inspector within 60 days from the date of receipt of
the report in accordance with sub-rule(1) of this Rules shall
examine and on examination of the report if he is of the opinion
that contravention of the provision of the Act or the Rules made
thereunder has taken place, he may issue notice for obtaining
compliance.
8. Updating of the notification under Rule 7

Where an industrial activity or isolated storage has been reported in

accordance with Rule 7(1) and the occupier makes a change in it
(including an increase or decrease in the maximum quantity of a
hazardous chemical to which this Rule applies which is or is liable to
be at the site or in the pipeline or at the cessation of the activity)
which affects the particulars specified in that report or any
subsequent report made under this Rule, the occupier shall forthwith
furnish a further report to the Inspector and Chief Inspector.

9. ** ** **

10. Safety reports and Safety audit reports

(1) Subject to the following sub-rules of this Rule, an occupier shall

not undertake any industrial activity or isolated storage to which
this Rule applies, unless he has prepared a safety report on that
industrial activity or isolated storage containing the information
specified in Schedule 8 and has sent a copy of that report to
Chief Inspector at least 90 days before commencing that
activity.

(2) After the commencement of these Rules, the occupiers of both

the new and the existing industrial activities or isolated storages
shall arrange to carry out once in a year safety audit by a
competent agency to be accredited by an Accreditation Board to
be constituted by the Ministry of Labour, Government of India in
this behalf and in absence of such Accreditation Board by a
competent agency approved by Chief inspector of Factories.

(3) The occupier, within 30 days of the completion of the audit, shall
send a report to the Chief Inspector with respect to the
implementation of the audit recommendations.

11. Updating of reports under Rule 10

(1) Where an occupier has made a safety report in accordance

with sub-rule (1) of Rule 10 he shall not make any modification
to the industrial activity or isolated storage to which tat safety
report relates which could materially affect the particulars in that
report, unless he has made a further report to take account of
 those modifications and has sent a copy of that report to the
Inspector and Chief Inspector at least 90 days before making
those modifications.

(2) Where an occupier has made a report in accordance with Rule

10 and sub-rule (1) of this Rule and than industrial activity or
isolated storage is continuing, the occupier shall, within three
years of the date of the last such report, make a further report
which shall have regard in particular to new technical knowledge
which has affected the particulars in the previous report relating
to safety and hazard assessment and shall, within 30 days or in
such longer time, as the Inspector and Chief Inspector may
agree in writing, send a copy of the report to the Inspector and
Chief Inspector.

12. Requirements for further information to be sent to the Inspector and

the Chief Inspector

Where in accordance with Rules 10 and 11 an occupier has sent

safety report and safety audit report relating to an industrial activity
or isolated storage to the Inspector and Chief Inspector, the
Inspector and Chief Inspector may by a notice served on the
occupier, require him to provide such additional information as may
be specified in the notice and the occupier shall send that
information to the Inspector and Chief Inspector within 90 days.

13. Preparation of on-site emergency plan by the occupier

(1) The occupier shall prepare, keep up-to-date and furnish to the
Inspector and Chief Inspector an On-site emergency plan
containing details specified in Schedule 8A and detailing how
major accidents will be dealt with on the site on which the
industrial activity or isolated storage is carried on and that plan
shall include the name of the person who is responsible for
safety on the site and the names of those who are authorized to
take action in accordance with the plan incase of an emergency.

(2) The occupier shall ensure that the emergency plan prepared in
accordance with sub-Rule (1) of this Rule takes into account any
modification made in the industrial activity or isolated storage
and that every person on the site who is concerned with the plan
is informed of its relevant provisions.
 (3) The occupier shall prepare the emergency plan required under
sub-rule (1)
of this Rule-

(a) before the commencement of industrial activity or isolated

storage.

(b) Within 90 days of coming into operation of these Rules in

case of an existing industrial activity or isolated storage.

(4) The occupier shall ensure that a mock drill of the on-site
emergency is conducted at least once in every six months.

(5) A detailed report of the mock drill conducted under sub-rule (4)
shall be made immediately available to the Inspector and Chief
Inspector.

14. ** ** **

15. Information to be given to persons liable to be affected by a major

accident

(1) The occupier shall take appropriate steps to inform persons

outside the site who are likely to be in an area which may be
affected by a major accident about –

a. the nature of the major accident hazard; and

b. the safety measures and the Do’s and Don’ts which should
be adopted in the event of a major accident.

(2) The occupier shall take the steps required under sub-Rule(1) of
this Rule to inform persons about an industrial activity or
isolated storage before that activity is commenced, except that
in respect of an existing industrial activity or isolated storage the
occupier shall comply with the requirements of sub-Rule(1) of
this Rule within 90 days of coming into operation of these Rules.

16. Disclosure of information notified under the Rules

Where for the purpose of evaluating information notified under Rule

5 or Rules 7 to 15, the Inspector or the Chief Inspector discloses that
information to some other person, that other person shall not use
that information for any purpose except a purpose of the Inspector or
the Chief Inspector disclosing it, as the case may be, and before
 disclosing that information the Inspector or the Chief Inspector as
the case may be shall inform that other person of his obligations
under this Rule.

17. ** ** **

18. Power of the State Government to modify the Schedules

The State Government may, at any time, by notification in the

Official Gazette, make suitable changes in the Schedules.

19. Repeals and Modifications to the Rules for the Factories

(Amendment) Act, 1987

(1) The Rules set out in Part I of Schedule 9 be repealed.

(2) The Rules set out in Part II of Schedule 9 be modified to the

extent specified in column 4 of that Schedule.

SCHEDULE I

[see Rules 2(a)(i), 3(1) and 4(1)(a)]

Indicative Criteria and List of Chemicals

Part I INDICATIVE CRITERIA

(a) Toxic Chemicals:

Chemicals having the following values of acute toxicity and which, owing
to their physical and chemicals properties, are capable of producing
major accident hazards.

Sl.No. Degree of Medium Medium lethal Medium lethal

Toxicity lethal dose dose by the dermal concentration by
by the oral route (dermal inhalation route
route (oral toxicity) LD 50 (four hours (LC50
toxicity) LD (mg.kg body (mg/1 inhalation in
(Mg/kg body weight of test test animals)
weight of test animals)
animals)
1. Extremely 1-50 1-200 0.1-0.5
toxic
2. Highly 51-500 201-2000 0.5-2.0
 toxic

(b) Flammable chemicals:

(i) Flammable gases : Chemicals which in the gaseous state

at normal pressure and mixed with air become flammable
and the boiling point of which at normal pressure is
20O degree C or below;
(ii) Highly flammable liquids : Chemicals which have a flash
point lower than 23O
(iii) Flammable liquids : Chemicals which have a flash point
lower than 65o degree C and which remain liquid under
pressure, where particular processing conditions, such as
high pressure and high temperature, may create major
accident hazards.

(c) Explosives :

Chemicals which may explode under the effect of flame, heat or

photochemical conditions, or which are more sensitive to shocks or
friction than dinitrobenzene.

PART-II LIST OF HAZARDOUS CHEMICALS

(1) ACETONE
(2) ACETONE CYANOHYDRINE
(3) ACETYL CHLORIDE
(4) ACETYLENE (ETHYLENE)
(5) ACROLEIN (2-PROPENAL)
(6) ACRYLONITRILE
(7) ALTICARB
(8) ALDRIN
(9) ALCYL PHTHALATE
(10) ALLYL ALCHOHOL
(11) ALLYLAMINE
(12) ALPHA NAPHTHYL THIOUREA (ANTTU)
(13) AMINODIPHENYL-4
(14) AMINOPHENOL-2
(15) AMIDON
(16) AMMONIA
(17) AMMONIUM NITRATE
(18) AMMONIUM NITRATE IN FERTILIZERS
(19) AMMONIUM SULFAMATE
(20) ANABASINE
(21) ANILINE
(22) ANISIDNIE-p
(23) ANTIMONY & COMPOUNDS
(24) ANTIMONY HIDRIDE (STIBINE)
(25) ARSYNIC HYDRIDE (ARSINE)
(26) ARSYNIC PENTOXIDE, ARSYNIC (V) ACID & SALTS
(27) ARSYNIC TRYOSIDE, ARSENIOUS (III) ACID & SALTS
(28) ASBESTOS
(29) AZINPHOS-ETHYL
(30) AZINPHOS-METHYL
(31) BARIUM AZIDE
(32) BENZENE
(33) BENZIDINE
(34) BENZIDINE SALTS
(35) BENZOQUINONE
(36) BENZOYL CHLORIDE
(37) BENZOYL PHOROXIDE
(38) BENZYL CHLORIDE
(39) BENZYL CYANIDE
(40) BERYLLIUM (POWDERS, COMPOUNDS)
(41) BIPHENYL
(42) BIS (2-CHLOROMETHYLE) KETONE
(43) BIS (2, 4, 6 –TRINITROPHENYL) AMINE
(44) BIS (2-CHLOROETHYL) SULPHIDE
(45) BIS (CHLOROMETHYL) ETHER
(46) 2, 2-BIS (tert– BUTYLPEROXY) BUTANE
(47) 1, 1 – BIS (tert– BUTYLPEROXY) CYCLOHEXANE
(48) BIS – 1, 2 (TRYVROMOPHENOXY) ETHANE
(49) BISPHENOL
(50) BORON & COMPOUNDS
(51) BROMINE
(52) BROMINE PENTA FLOURIDE
(53) BROMOFORM
(54) 1,3-BUTADIENE
(55) BUTANE
(56) N-BUTANETHIOL
(57) 2-BUTANONE
(58) BUTOXY ETHANOL
(59) BUTYL GLYCIDAL EITHER
(60) BUTYL PEROXYISOBUTYRATE tert
(61) BUTYL PEROXYACETATE tert
(62) BUTYL PEROXYISOPROPYL CARBONATE tert
(63) BUTYL PEROXYMALEATIE tert
(64) BUTYL PEROXYPIVALATE tert
(65) BUTYL VINYL ETHER
(66) BUTYL-n-MERCAPTAN
(67) BUTYLAMINE
(68) C9-AROMATIC HYDROCARBON FRACTIONCADMIUM &
COMPOUNDS
(69) CADMIUM & COMPOUNDS
(70) CADMIUM OXIDE (fumes)
(71) CALCIUM CYANIDE
(72) CAPTAN
(73) CAPTOFOL
(74) CARBARYL (SEVIN)
(75) CARBOFURAN
(76) CARBON DISULPHIDE
(77) CARBON MONOXIDE
(78) CARBON TETRACHLORIDE
(79) CARBOPHENOTHION
(80) CELLULOSE NITRATE
(81) CHLORATES (used in explosives)
(82) CHLORDANE
(83) CHLORFENVINPHOS
(84) CHLORINATED BENZENES
(85) CHLORINE
(86) CHLORINE DIOXIDE
(87) CHLORINE OXIDE
(88) CHLORINE TRIFLUORIDE
(89) CHLORMEQUATE CHLORIDE
(90) CHLORACETAL CHLORIDE
(91) CHLOROACETALDEHYDE
(92) CHLOROANILINE-2
(93) CHLOROANILE-4
(94) CHLOROBENZENE
(95) CHLORODIPHENYL
(96) CHLOROEPOXYPROPANE
(97) CHLOROETHANOL
(98) CHLOROETHYL CHLOROFORMATE
(99) CHLOROFLUOROCARBONS
(100) CHLOROFORM
(101) CHLOROFORMYL, -4, MORPHOLINE
(102) CHLOROMETHANE
(103) CHLOROMETHYL ETHER
(104) CHLOROMETHYL METHYL ETHER
(105) CHLORONITROBENZENE
(106) CHLOROPRENE
(107) CHLOROSULPHONIC ACID
(108) CHLOROTRINITROBENZENE
(109) CHLOROXURON
(110) CHROMIUM & COMPOUNDS
(111) COBOLT & COMPOUNDS
(112) COPPER & COMPOUNDS
(113) COUMAFURYL
(114) COUMAPHOS
(115) COUMATERALYL
(116) CRESOLS
(117) CRIMIDINE
(118) CUMENE
(119) CYANOPHOS
(120) CYANOTHOATE
(121) CYANURIC FLUORIDE
(122) CYCLOHEXANE
(123) CYCLOHEXANOL
(124) CYCLOHEXANONE
(125) CYCLOHEXAMIDE
(126) CYCLOPENTADIENE
(127) CYCLOPENTANE
(128) CYCLOTETRAMETHYLENETETRANITRAMINE
(129) CYCLOTRIMETHYLENETRINITRAMINE
(130) DDT
(131) DECABROMODIPHENYL OXIDE
(132) DEMETON
(133) Di-ISOBUTYRYL PEROXIDE
(134) Di-n-PROPYL PEROXYDICARBONATE
(135) Di-sec-BUTYL PEROXYDICARBONATE
(136) DIALIFOS
(137) DIAZODINTROPHENOL
(138) DIAZOMETHANE
(139) DIBENZYL PEROXYDICARBONATE
(140) DICHLOROACETYLENE
(141) DICHLOROBENZENE-O
(142) DICHLOROBENZENE-P
(143) DICHLOROETHANE
(144) DICHLOROETHYL ETHER
(145) DICHLOROPHENOL, -2, 4
(146) DICHLOROPHENOL, -2, 6
(147) DICHLOROPHENOXY ACETIC ACID, -2, 4(2, 4-D)
(148) DICHLOROPROPANE, -1, 2
(149) DICHLOROSALICYLIC ACID, -3, 5
(150) DICHLOROVOS (DDVP)
(151) DICROTOPHOS
(152) DIELDRIN
(153) DIEPOXYBUTANE
(154) DIETHYL PEROXYDICARBONATE
(155) DIETHYLENE GLYCOL DINITRATE
(156) DIETHYLENE TRIAMINE
(157) DIETHYLENEGLYCOL BUTYL ETHER/
DIETHYLENEGLYCOLBUTYL ACETATE
(158) DIETHYLENETRIAMINE (DETA)
(159) DIGLYCIDYL ETHER
(160) DIHYDROPEROXYPROPANE, -2, 2
(161) Di-ISOBUTYRYL PEROXIDE
(162) DIMEFOX
(163) DIMETHOATE
(164) DIMETHYL PHOSPHORAMIDOCY ANIDIC ACID
(165) DIMETHYL PHTHALATE
(166) DIMETHYLCARBOMOYL CHLORIDE
(167) DIMETHYLNITROSAMINE
(168) DINITROPHENOL, SALTS
(169) DINITROTOLUENE,
(170) DINITRO-o-CRESOL
(171) DIOXANE
(172) DIOXATION
(173) DIOXOLANE
(174) DIPHACINONE
(175) DIPHOSPHORAMIDE OCTAMETHYL,
(176) DIPROPYLENE GLYCOLMETHYLETHER
(177) DISULFOTON
(178) ENDOSULFAN
(179) ENDRIN
(180) EPICHLOROHYDRINE
(181) EPN
(182) EPOXYPROPANE 1,2
(183) ETHION
(184) ETHYL CARBAMATE
(185) ETHYL ETHER
(186) ETHYL HEXANOL, -2
(187) ETHYL MERCAPTAN
(188) ETHYL METHACRYLATE
(189) ETHYL NITRATE
(190) ETHYLAMINE
(191) ETHYLENE
(192) ETHYLENE CHLOROHYDRINE
(193) ETHYLENE DIAMINE
(194) ETHYLENE DIBROMIDE
(195) ETHYLENE DICHLORIDE
(196) ETHYLENE GLYCOL DINITRATE
(197) ETHYLENE OXIDE
(198) ETHYLENE IMINE
(199) ETHYLTHIOCYANATE
(200) FENSULPHOTHION
(201) FLUENETIL
(202) FLUORO, -4, -2-HYDROXYBUTYRIC ACID & SALTS, ESTERS,
AMIDES
(203) FLUOROACETIC ACID & SALTS, ESTERS, AMIDES
(204) FLUOROBUTYRIC ACID, -4, & SALTS, ESTERS, AMIDES
(205) FLUOROCHROTONIC ACID, -4 & SALTS, ESTERS, AMIDES
(206) FORMALDEHYDE
(207) GLYCOLONITRILE (HYDROXYACETONITRILE)
(208) GUANYL, -1, -4-NITROSAMINOGUANYL-TETRAZENE
(209) HEPTACHLOR
(210) HEXACHLORO CYCLOPENTADIENE
(211) HEXACHLOROCYCLOHEXANE
(212) HEXACHLOROCYCLOMETHANE
(213) HEXACHLORODIBENZO-p-DIOXINE 1,2,3,7,8,9
(214) HEXAFLUOPROPENE
(215) HEXAMETHYLPHOSPHORAMIDE
(216) HEXAMETHYL, -3,3,6,9,9-1,2,4,5 – TETROXACYCLOMONANE
(217) HEXAMETHYLENEDIAMINE
(218) HEXANE
(219) HEXANITROSTILBENE
(220) HEXAVALENT CHROMIUM
(221) HYDRAZINE
(222) HYDRIZINE NITRATE
(223) HYDROCHLORIC ACID
(224) HYDROGEN
(225) HYDROGEN BROMIDE (HYDROBROMIC ACID)
(226) HYDROGEN CHLORIDE (LIQUIFIED GAS)
(227) HYDROGEN CYANIDE
(228) HYDROGEN FLUORIDE
(229) HYDROGEN SELENIDE
(230) HYDROGEN SULPHIDE
(231) HYDROQUINONE
(232) IODINE
(233) ISOBENZAN
(234) ISODRIN
(235) ISOPHORONE DIISOCYANATE
(236) ISOPROPYL LETHER
(237) JUGLONE (5-HYDROXYNAPHTHALENE-1, 4-DIONE)
(238) LEAD (INORGANIC FUMES & DUSTS)
(239) LEAD 2, 4, 6-TRINITRORESORCINOXIDE (LEAD STYPHNATE)
(240) LEAD AZIDE
(241) LEPTOPHOS
(242) LINDANE
(243) LIQUEFIED PETROLEUM GAS (LPG)
(244) MALEIC ANHYDRIDE
(245) MANGANESE & COMPOUNDS
(246) MERCAPTO BENZOTHIAZOLE
(247) MERCURY ALKYL
(248) MERCURY FULMINATE
(249) MERCURY METHYL
(250) METHACRYLIC ANHYDRIDE
(251) METHACRYLONITRILE
(252) METHACRYLOYLCHLORIDE
(253) METHAMIDOPHOS
(254) METHANESSUPHONYL FLOURIDE
(255) METHANETHIOL
(256) METHOXY ETHANOL (2-METHYL CELLOSOLVE)
(257) METHOXYETHYMERCURIC ACETATE
(258) METHYL ACRYLATE
(259) METHYL ALCOHOL
(260) METHYL AMYLKETONE
(261) METHYL BROMIDE (BROMOMETHANE)
(262) METHYL CHLORIDE
(263) METHYL CHLOROFORM
(264) METHYL CYCLOHEXENE
(265) METHYL ETHYL KETONE PEROXIDE
(266) METHYL HYDRAZINE
(267) METHYL ISOBUTYL KETONE
(268) METHYL ISOBUTYL KETONE PEROXIDE
(269) METHYL ISOCYANATE
(270) METHYL ISOTHIOCYANATE
(271) METHYL MERCAPTAN
(272) METHYL METHACRYLATE
(273) METHYL PARATHION
(274) METHYL PHOSPHONIC DICHLORIDE
(275) METHYL-N, 2,4,6-TETRANITROANLINE\
(276) METHYLENE CHLORIDE
(277) METHYLENEBIS-4,4,(2-CHLOROANLINE)
(278) METHYL TRICHLOROSILANE
(279) MEVINPHOS
(280) MOLYBDENUM & COMPOUNDS
(281) N-METHYL-N-2,4,6-TETRAITROANILINE
(282) NAPHTHA (COAL TAR)
(283) NAPHTHLAMINE,2
(284) NICKEL & COMPOUNDS
(285) NICKEL TETRACARBONYL
(286) NITROANILINE-O
(287) NITROANILINE-P
(288) NITROBENZENE
(289) NITROCHLOROBENZENE-P
(290) NITROCYCLOHEXANE
(291) NITROETHANE
(292) NITROGEN DIOXIDE
(293) NITROGEN OXIDES
(294) NITROGEN TRIFLUORIDE
(295) NITROGLYCERINE
(296) NITROPHENOL-P
(297) NITROPROPANE-1
(298) NITROPROPANE-2
(299) NITROSODIMETHYLAMINE
(300) NITROTOLUNE
(301) OCTABROMOPHENYL OXIDE
(302) OLEUM
(303) OLEYLAMINE
(304) OO-DIETHYL S-ETHYLSULPHONYLMETHYL
(305) OO-DIETHYL S-ETHYLSULPHONYLMETHYL
PHOSPHOROTHIOATE
(306) OO-DIETHYL S-ETHYLTHIOMETHYL PHOSPHOROTHIOATE
(307) OO-DIETHYL S-ISOPROPYLTHIOMETHYL
PHOSPHOROTHIOATE
(308) OO-DIETHYL S-PROPYLTHIOMETHYL PHOSPHOROTHIOATE
(309) OXYAMYL
(310) OXYDISULFOTON
(311) OXYGEN (LIQUID)
(312) OXYGEN DIFLUORIDE
(313) OZONE
(314) PARAOXON (DIETHYL 4-NITROPHENYL PHOSPHATE)
(315) PARAQUAT
(316) PARATHION
(317) PARATHION METHYL
(318) PARIS GREEN (BIS ACETO HEXAMETAARSENITOTETRA
COPPER)
(319) PENTABORANE
(320) PENTAROMODIPHENYL OXIDE
(321) PENTABROMOPHENOL
(322) PENTACHLORO NAPHTHALENE
(323) PENTACHLOROETHANE
(324) PENTACHLOROPHENOL
(325) PENTAERYTHRITOL TETRANITRATE
(326) PENTANE
(327) PERACETIC ACID
(328) PERCHLOROETHYLENE
(329) PERCHLOROMETHYL MERCAPTAN
(330) PENTANONE, 2, 4-METHYL
(331) PHENOL
(332) PHENYL GLYVCIDAL ETHER
(333) PHENYLENE P-DIAMINE
(334) PHENYLMERCURY ACETATE
(335) PHORATE
(336) PHOSACETIM
(337) PHOSALANE
(338) PHOSFOLAN
(339) PHOSGENE (CARBONYL CHLORIDE)
(340) PHOSMET
(341) PHOSPHAMIDON
(342) PHOSPHINE (HYDROGEN PHOSPHIDE)
(343) PHOSPHORIC ACID AND ESTERS
(344) PHOSPHORIC ACID, BROMOETHYL BROMO (2,2-
DIMETHYLPROPYL) BROMOETHYL ESTER
(345) PHOSPHORIC ACID, BROMOETHYL BROMO (2,2-
DIMETHYLPROPYL) CHLOROETHYL ESTER
(346) PHOSPHORIC ACID CHLOROETHYLBROMO (2,2-
DIMETHYLPROPYL) CHLOROETHYL ESTER
(347) PHOSPHOROUS & COMPOUNDS
(348) PHOSTALAN
(349) PICRIC ACID (2,4,6-TRINITROPHENOL)
(350) POLYBROMINATED BIPHENYLS
(351) POTTASIUM ARSENITE
(352) POTASSIUM CHLORATE
(353) PROMURIT (1-(3,4-DICHLOROPHENYL)-3
TRIAZENETHIOCARBOXAMIDE)
(354) PROPANESULTONE-1,3
(355) PROPEN-2-CHLORO-1,3-DIOU DIACETATE
(356) PROPYLENE DICHLORIDE
(357) PROPYLENE OXIDE
(358) PROPYLENE IMINE
(359) PRYAZOXON
(360) SELENIUM HEXAFLUORIDE
(361) SEMICARBAZIDE HYDROCHLORIDE
(362) SODIUM ARSENITE
(363) SODIUM AZIDE
(364) SODIUM CHLORATE
(365) SODIUM CYANIDE
(366) SODIUM PICRAMATE
(367) SODIUM SELENATE
(368) STYRENE, 1,1,2,2-TETRACHLOROETHANE
(369) SULPHOTEP
(370) SULPHUR DICHLORIDE
(371) SULPHUR DIOXIDE
(372) SULPHUR TRIOXIDE
(373) SULPHURIC ACID
(374) SULPHOXIDE 3-CHLOROPROPYL OCTYL
(375) TELLURIUM
(376) TELLURIUM HEXAFLUORIDE
(377) TEPP
(378) TERBUFOS
(379) TERABROMOSBISPHENOL-A
(380) TETRACHLORO, 2,2,5,6,2,5-CYCLOHEXADIENE-1,4-DIONE
(381) TETRACHLORODIBENZO-p-DIOXIN 2,3,7,8 (TCDD)
(382) TETRAETHYL LEAD
(383) TETRAFLUORIETHYNE
(384) TETRAMETHYLENE DISULPHOTETRAMINE
(385) TETRA METHYL LEAD
(386) TETRA NITROMETHANE
(387) THALLIUM & COMPOUNDS
(388) THIONAZIN
(389) THIONYL CHLORIDE
(390) TIRPATE
(391) TOLUENE
(392) TOLUENE 2.4-DIISOCYANATE
(393) TOLUIDINE-O
(394) TOLUENE 2,6-DIISOCYANATE
(395) TRANS-1,4-DI CHLORO-BUTENE
(396) TRI-I ()
(397) TRIAMINO, 1,3,5,2,4,6-TRINITROBENZENE
(398) TRIBROMOPHENOL 2,4,6
(399) TRICHLORO ACETYL CHLORIDE
(400) TRICHLOROETHANE
(401) TRICHLORO NAPTHALENE
(402) TRICHLORO (CHLOROMETHYL) SILANE
(403) TRICHLORODICHLOROPHENYLSILANE
(404) TRICHLOROETHANE 1,1,1
(405) TRICHLOROETHYL SILANE
(406) TRICHLOROETHYLENE
(407) TRICHLOROMETHANE SULPHENYL CHLORIDE
(408) TRICHLOROPHENOL 2, 2, 6
(409) TRICHLOROPHENOL 2, 4, 5
(410) TRIETHYLAMINE
(411) TRIETHYLENE MELAMINE
(412) TRIMETHYL CHLOROSILANE
(413) TRIMETHYL PROPANE PHOSPHITE
(414) TRINITRO ANILINE
(415) TRINITRO ANISOLE 2,4,6
(416) TRINITRO BENZENE
(417) TRINITRO BENZOIC ACID
(418) TRINITROCRESOL
(419) TRINITRO PHENETOLE2,4,6
(420) TRINITRORESORCINOL 2,4,6 (STYPHNICACID)
(421) TRI ORTHOCRESYL PHOSPHATE
(422) TRIPHENYL TIN CHLORIDE
(423) TURPENTINE
(424) URANIUM & COMPOUNDS
(425) VANADIUM & COMPOUNDS
(426) VINYL CHLORIDE
(427) VINYL FLUORIDE
(428) VINYL TOLUENE
(429) VINYLEDENE CHLORIDE
(430) WARFARIN
(431) XYLENE
(432) XYLIDINE
(433) ZINC& COMPOUNDS
(434) ZIRCONIUM & COMPOUNDS

SCHEDULE 2

[See Rule 2(a)(ii), 4(1)(b) and 6(1)(c) and (d)]

Isolated storage of Installation other than those covered by Schedule 4.

a. The quantities set out below relate to each installation or group of

installations belonging to the same occupier where the distance
between installations is not sufficient to avoid, in foreseeable
circumstances, any aggravation of major accident hazards. These
quantities apply in any case to each of the installations belonging to
 the same occupier where the distance between the installations is
less than 500 metres.

b. For the purpose of determining the quantity of a hazardous

chemical at an isolated storage, account shall also be taken of any
hazardous chemical which is : -

(i) in that part of any pipeline under the control of the occupier
having control of the site, which is within 500 metres of that site
and connected to it,
(ii) at any other site under the control of the occupier having control
of the site, which is 500 metres of the said site, and
(iii) in any vehicle, vessel, aircraft or hovercraft under the control of
the same occupier which is used for storage purpose either at
the site or within 500 metres of it,

but no account shall be taken of any hazardous chemical which is

in a vehicle, vessel, aircraft or hovercraft for transporting it.

Sl. Chemicals Threshold Quantities (tonnes)

No. For application For application
of Rules 4,5,7 of Rules 10 to 15

1. 2. 3. 4.
1. Acrylonitrile 350 5000
2. Ammonia 60 600
3. Ammonium nitrate (a) 350 2,500
4. Ammonium nitrate fertilizers 1,250 10,000
(b)
5. Chlorine 10 25
6. Flammable gases as defined 50 300
in Schedule 1, paragraph (b)
(i)
7. Highly flammable liquids as 10,000 10,000
defined in Schedule 1,
paragraph (b)(ii)
8. Liquid oxygen 200 2000
9. Sodium chlorate 25 250
10. Sulphur dioxide 20 500
11. Sulphur trioxide 15 100
12. Carbonyl chloride 0.750 0.750
13. Hydrogen sulphide 5 50
14. Hydrogen fluoride 5 50
15. Hydrogen cyanide 5 20
16. Carbon disulphide 20 200
17. Bromine 50 500
 18. Ethylene Oxide 5 501
19. Propylene Oxide 5 50
20. 2-Propenal (Acrolein) 20 200
21. Bromomethane (Methyl 20 200
bromide)
22. Methyl Isocyanate 0.150 0.150
23. Tetraethyl lead or 5 50
tetramethyl lead
24. 1,2 Dibromoethane 5 50
(Ethylene dibromide)
25. Hydrogen chloride (Liquified 25 250
gas)

Sl. Chemicals Threshold Quantities (tonnes)

No. For application For application
of Rules 4,5,7 & of Rules 10 to 15
8

1. 2. 3. 4.
26. 1,2 Diphynel methane di- 20 200
isocyanate (MDI)
27. Tolune di-isocyanate (TDI) 10 100

Foot notes:

(a) This applies to ammonium nitrate and mixtures of ammonium

nitrate where the nitrogen content derived from the ammonium
nitrate is greater than 28 per cent by weight and to aqueous
solutions of ammonium nitrate where the concentration of
ammonium nitrate is greater than 90 percent by weight.
(b) This applies to straight ammonium nitrate fertilizers and to
compound fertilizers where the nitrogen content dertived from
the ammonium nitrate is greater than 28 percent by weight (a
compound fertilizer contains ammonium nitrate together with
phosphate and / or potash).

SCHEDULE 3

[See Rule 2(a)(iii), 5 and 6(1)(a)]

List of Hazardous Chemicals for Application of Rules 5 and 7 to 15

c. (a) The quantities set out below relate to each installation or group
of installations belonging to the same occupier where the distance
 between installations is not sufficient to avoid, in foreseeable
circumstances, any aggravation of major accident hazards. These
quantities apply in any case to each of the installations belonging to
the same occupier where the distance between the installations is
less than 500 metres.

d. For the purpose of determining the quantity of a hazardous

chemical at an isolated storage, account shall also be taken of any
hazardous chemical which is : -

(iv) in that part of any pipeline under the control of the occupier
having control of the site, which is within 500 metres of that site
and connected to it,
(v) at any other site under the control of the occupier having control
of the site, which is 500 metres of the said site, and
(vi) in any vehicle, vessel, aircraft or hovercraft under the control of
the same occupier which is used for storage purpose either at
the site or within 500 metres of it,

but no account shall be taken of any hazardous chemical which is

in a vehicle, vessel, aircraft or hovercraft for transporting it.

Sl.No. Chemical Threshold Quantity CAS

For For Number
applicatio applicatio
n of Rules n of Rules
5,7,8,13 10 to 12
and
1. 2. 3. 4. 5.

1. Aldicarb 100 kg 116-

06-3
2. 4-Aminodiphenyl 1 kg 92-67-
1
3. Amiton 1 kg 78-53-
5
4. Anabasine 100 kg
5. Arsynic pentoxide, arsynic (v) acid & 500 kg
salts
6. Arsynictryoside, arsenious (iii) acid & 100 kg
salts
7. Arsine (Arsynic hydride) 10 kg 7784-
42-1
8. Azinphos-ethyl 100 kg 2642-
71-9
9. Azinphos-methyl 100 kg 86-50-
0
10. Benzidine 1 kg 92-87-
5
11. Benzidine salts 1 kg
12. Beryllium (powders, compounds) 10 kg
13. Bis (2-chloroethyl) sulphide 1 kg 55-60-
2
14. Bis (chloromethyl) ether 1 kg 542-
88-1
15. Carbofuran 100 kg 1563-
66-2
16. Carbophenothion 100 kg 786-
19-6
17. Chlorfenvinphos 100 kg 470-
90-6
18. Chloroformyl, -4, morpholine 1 kg 15159-
40-7
19. Chloromethyl methyl ether 1 kg 107-
30-2
20. Cobolt metal, oxides, 1t
carbonates, sulphides as
powders
21. Crimidine 100 kg 535-
89-7
22. Cyanthoate 100 kg 3734-
95-0
23. Cyclohexamide 100 kg 66-81-
9
24. Demeton 100 kg 8065-
48-3
25. Dialifos 100 kg 10311-
84-9
26. oo-Diethyl S-ethylsulphinyl methyl 100 kg 2588-
phosphorothioate 05-8
27. oo-Diethyl S-ethylsulphonyl methyl 100 kg 2588-
phosphorothioate 06-9
28. oo-Diethyl S- 100 kg 2600-
ethylthiomethylphosphorodithioate 06-9
29. oo-Diethyl S- 100 kg 78-52-
isopropylthylthiomethylphosphorodithio 4
ate
30. oo-Diethyl S- 100 kg 3309-
propylthylthiomethylphosphorodithioate 68-0
31. Dimefox 100 kg 115-
26-4
32. Dimethylcarbomoyl chloride 1 kg 79-44-
7
33. Dimethylnitrosamine 1 kg 62-57-
9
34. Dimethyl phosphoramidocyanidic acid 1t 63917-
41-9
35. Diphacinone 100 kg 82-66-
6
36. Disulfoton 100 kg 298-
04-4
37. EPN 100 kg 2104-
 64-5
38. Ethion 100 kg 563-
12-2
39. Fensulphothion 100 kg 115-
90-2
40. Fluenetil 100 kg 4301-
50-2
41. Fluoroacetic acid 1 kg 144-
49-0
42. Fluoroacetic acid, salts 1 kg
43. Fluoroacetic acid esters, 1 kg
44. Fluoroacetic acid, amides 1 kg
45. 4-Fluorobutyric acid 1 kg 462-
23-7
46. 4-Fluorobutyric acid, salts 1 kg
47. 4-Fluorobutyric acid, esters 1 kg
48. 4-Fluorocrotonic acid, amides 1 kg
49. 4-Fluorocrotonic acid 1 kg 37759-
72-1
50. 4-Fluorocrotonic acid, salts 1 kg
51. 4-Fluorocrotonic acid, esters 1 kg
52. 4-Fluorocrotonic acid, amides 1 kg
53. 4-Fluoro-2-hydroxybutyric acid, 1 kg
54. 4-Fluoro-2-hydroxybutyric acid, salts 1 kg
55. 4-Fluoro-2-hydroxybutyric acid, esters 1 kg
56. 4-Fluoro-2-hydroxybutyric acid, amides 1 kg
57. Glycolonitrile (hydroxyacetonitrile) 100 kg 107-
16-4
58. 1,2,3,7,8,9-Hexachlorodibenzo-p- 100 kg 19408-
dioxine 74-3
59. Hexamethylphosphoramide 1 kg 680-
31-9
60. Hydrogen selenide 10 kg 7783-
07-5
61. Isobenzan 100 kg 297-
78-9
62. Isodrin 100 kg 465-
73-6
63. Juglone (5-hydroxynaphthalene-1, 4- 100 kg 481-
dione) 39-0
64. Methylenebis-4,4,(2-chloroanline) 10 kg 101-
14-4
65. Methyl isocyanate 150 kg 150 kg 624-
83-9
66. Mevinphos 100 kg 7786-
34-7
67. Naphthlamine, 2 1 kg 91-59-
8
68. Nickel metal, oxides, carbonates, 1t
sulphide, as powders
69. Nickel tetra carbonyl 10 kg 13463-
39-3
70. Oxydisulfoton 100 kg 2497-
07-6
71. Oxygen diflouride 10 kg 7783-
41-7
72. Paraxon (diethyl 4-nitorphenyl 100 kg 311-
phosphate) 45-5
73. Parathion 100 kg 56-38-
2
74. Parathion-methyl 100 kg 298-
00-0
75. Pentaborane 100 kg 19624-
22-7
76. Phorate 100 kg 298-
02-2
77. Phosacetim 100 kg 4104-
14-7
78. Phosgene (carbonyl chloride) 750 kg 750 kg 75-44-
5
79. Phosphamidon 100 kg 13171-
21-6
80. Phosphine (hydrogen phosphide) 100 kg 7803-
51-2
81. Promurit (1-(3,4-dichlorophenyl)-3 100 kg 5836-
triazenethiocarboxamide) 73-7
82. Propanesultone-1,3 1 kg 1120-
71-4
83. Propen-2-chloro-1,3-diou diacetate 10 kg 10118-
72-6
84. Pryazoxon 100 kg 108-
34-9
85. Selenium hexafluoride 10 kg 7783-
79-1
86. Sodium selenite 100 kg 10102-
18-8
87. Stibine (Antimony hydride) 100 kg 7803-
52-3
88. Sulphotop 100 kg 3689-
24-5
89. Sulphur dichloride 1t 10545-
99-0
90. Tellurium hexafluoride 100 kg 7783-
80-4
91. TEPP 100 kg 107-
49-3
92. Tetrachlorodibenzo-p-dioxin 2,3,7,8 1 kg 1746-
(TCDD) 01-6
93. Tetramethylene-disulphotetramine 1 kg 80-12-
6
94. Thionazin 100 kg 297-
97-2
95. Tirpate (2,4-Dimethyl-1,3-dithiolane-2- 100 kg 26419-
carboxaldehyde O- 73-8
methylcarbomoyloxime))
96. Trichloromethanesulphenyl chloride 100 kg 594-
 42-3
97. 1-Tri(cyclohexyl) stannyl-IH-1,2,4- 100 kg 41083-
triazole 11-8
98. Triethylene melamine 10 kg 51-18-
3
99. Warfarin 100 kg 81-81-
2

Group 2-Toxic Chemicals

100. Acetone cyanohydrine (2-Cyanoproan-2-(1) 200 t 75-86-

5
101. Acrolein (2-propenal) 20 t 200 t 107-
02-8
102. Acrylonitrile 20 t 200 t 107-
13-1
103. Allyl alchohol 200 t 107-
18-6
104. Allylamine 200 t 107-
11-9
105. Ammonia 50 t 500 t 7664-
41-7
106. Bromine 40 t 500 t 7726-
95-6
107. Carbon disulphide 20 t 200 t 75-15-
0
108. Chlorine 10 t 25 t 7782-
50-5
109. Diphyenl methane di-isocyanate (MDI) 20 t 200 t 101-
68-8
110. Ethylene dibromide (1,2-Dibromoethane) 5t 50 t 106-
93-4
111. Ethyleneimine 50 t 151-
56-4
112. Formaldehyde (concentration>=90%) 5t 50 t 50-00-
0
113. Hydrogen chloride (liquified gas) 25 t 250 t 7647-
01-0
114. Hydrogen cyanide 5t 20 t 74-90-
8
115. Hydrogen fluoride 5t 50 t 7664-
39-3
116. Hydrogen sulphide 5t 50 t 7783-
06-4
117. Methyl bromide (bromomethane) 20 t 200 t 74-83-
9
118. Nitrogen oxides 50 t 11104-
93-1
119. Propyleneimine 50 t 75-55-
8
120. Sulphur dioxide 20 t 250 t 7446-
09-5
 121. Sulphur trioxide 15 t 75 t 7446-
11-9
122. Tetraethyl lead 5t 78-00-
2
123. Tetra methyl lead 5t 200 t 75-74-
1
124. Toluene 2.4-di-isocyanate(TDI) 10 t 100 t 584-
84-9
75-01-
4

Group 3- Highly Reactive Chemicals

125. Acetylene (ethylene) 5t 74-86-

2
126. a. Ammonium nitrate(1) 350 t 2500 t 6484-
b. Ammonium nitrate in the form of 52-2
fertilizers(2) 1250 t
127. 2, 2-bis (tert– butyl-peroxy) butane 5t 2167-
(concentration>=70%) 23-9
128. 1, 1 – bis (tert– butylperoxy) 5t 3006-
cyclohexane (concentration>=70%) 86-8
129. Tert Butyl peroxyacetate 5t 107-
(concentration>=70%) 71-1
130. Tert Butylperoxyisobutyrate 5t 109-
(concentration>=80%) 13-7
131. Tert Butylperoxyisopropyl carbonate 5t 2372-
(concentration>=80%) 21-6
132. Tert Butyl peroxymaleate 5t 1931-
(concentration>=80%) 62-0
133. Tert Butylperoxypivalate 50 t 927-
(concentration>=77%) 07-1
134. Dibenzylperoxydicarbonate 5t 2144-
(concentration>=90%) 45-8
135. Di-sec-butyl peroxydicarbonate 5t 19910-
(concentration>=80%) 65-7
136. Diethyl peroxydicarbonate 50 t 14666-
(concentration>=30%) 78-5
137. Dihydroperoxypropane, -2, 2 5t 2614-
(concentration>=30%) 76-8
138. Di-isobutryl peroxide 50 t 3437-
(concentration>=50%) 84-1
139. Di-n- propyl peroxydicarbonate 5t 16066-
(concentration>=80%) 38-9
140. Ethylene oxide 5t 75-21-
8
141. Ethyl nitrate 50 t 625-
58-1
142. 3,3,6,9,9-Hexamethyl, -1,2,4,5 – 50 t 22397-
tetroxacyclomonane 33-7
(concentration>=75%)
 143. Hydrogen 2t 50 t 1333-
74-0
144. Liquid oxygen 200 t 2000 t 7782-
44-7
145. Methyl ethyl ketone peroxide 5t 1338-
(concentration>=60%) 23-4
146. Methyl isobutyl ketone peroxide 50 t 37206-
(concentration>=60%) 20-5
147. Peracetic acid 50 t 79-21-
0
148. Propylene oxide 5t 50 t 75-56-
9
149. Sodium chlorate 25 t 7775-
09-9

Group 4 – Explosive Chemicals

150. Barium azide 50 18810

t -58-7
151. Bis (2, 4, 6 –trinitrophenyl) amine 50 131-
t 73-7
152. Chlorotrinitrobenzene 50 28260
t -61-9
153. Cellulose nitrate (containing > 12.6% 50 9004-
nitrogen) t 70-0
154. Cyclotetramethylenetetranitramine 50 2691-
t 41-0
155. Cyclotrimethylenetrinitroamine 50 121-
t 82-4
156. Diazodintrophenol 10 7008-
t 81-3
157. Diethylene glycol dinitrate 10 693-
t 21-0
158. Dinitrophenol, salts 50
t
159. Ethylene glycol dinitrate 10 628-
t 96-6
160. 1-,Guanyl, -4-nitrosaminoguanyl- 10 109-
tetrazene t 27-3
161. 2,2’,4,4’,6,6’-Hexanitrostilbene 50 20062
t -22-0
162. Hydrizine nitrate 50 13464
t -97-6
163. Lead azide 50 13424
t -46-9
164. Lead styphnate (Lead 2, 4, 6- 50 15245
trinitroresorcinoxide) t -44-0
165. Mercury fulminate 10 208-2-
t 45-5
628-
 86-4
166. N-methyl-N-2,4,6-tetraitroaniline 50 479-
t 45-8
167. Nitroglycerine 10 10 t 55-63-
t 0
168. Pentaerythritoltetranitrate 50 78-11-
t 5
169. Picric acid (2,4,6-trinitrophenol) 50 88-89-
t 1
170. Sodium picramate 50 831-
t 52-7
171. Styphnic acid (2,4,6-Trinitroresorcinol) 50 82-71-
t 3
172. 1,3,5-Triamino-2,4,6-trinitrobenzene 50 3058-
t 38-6
173. Trinitro aniline 50 26952
t -42-1
174. 2,4,6Trinitro anisole 50 606-
t 35-9
175. Trinitro benzene 50 25377
t -32-6
176. Trinitro benzoic acid 50 35860
t -50-5
129-
66-8
177. Trinitrocresol 50 28905
t -71-7
178. 2,4,6-Trinitro phenetole 50 4732-
t 14-3
179. 2,4,6-Trinitroluene 50 50 t 118-
t 96-7

PART – II CLASSES OF CHEMICALS NOT SPECIFICALLY NAMED IN

PART-I

Sl.No. Chemical Threshold Quantity CAS

For For Number
application application
of Rules of Rules
5,7,8,13 10 to 12
and
1. 2. 3. 4. 5.

Group –5-Flammable Chemicals

1. Flammable Gases: 15 t 200 t

Chemicals which in gaseous
state at normal pressure and
 mixed with air become
flammable and the boiling
point of which at normal
pressure is 20 degree C or
below;
2. Highly flammable liquids: 1000 t 50000 t
Chemicals which have a
flash point lower than 23
degree C and the boiling
point of which at normal
pressure is above 20 degree
C;
3. Flammable liquids: 25 t 200 t
Chemicals which a flash
point lower than 65 degree C
and which remain liquid
under pressure, where
particular processing
conditions, such as high
pressure and high
temperature, may create
major accident hazards.

Footnotes:

1) This applies to ammonium nitrate and mixtures of ammonium

nitrate where the nitrogen content derived from the ammonium
nitrate is greater than 28% by weight and aqueous solutions of
ammonium nitrate where the concentration of ammonium nitrate is
greater than 90% by weight.

2) This applies to straight ammonium nitrate fertilizers and to

compound fertilizers where the nitrogen content derived from the
ammonium nitrate is greater than 28% by weight (a compound
fertilizer contains ammonium nitrate together with phosphate and/
or potash)

SCHEDULE 4

[See Rule 2(b)(1)]

1. Factories involved in the production, processing or treatment of

organic or inorganic chemicals using for this purpose, among others:

(a) alkylation
 (b) amination by amonolysis
(c) carbonylation
(d) condensation
(e) dehydrogenation
(f) esterification
(g) halogenation& manufacture of halogens
(h) hydrogenation
(i) hydrolysis
(j) oxidation
(k) polymerization
(l) sulphonation
(m) desulphurization, manufacture and transformation of
sulphur-containing compounds
(n) nitration and manufacture of nitrogen-containing
compounds
(o) manufacture of phosphorous-containing compounds
(p) formulation of pesticides and of pharmaceutical products
(q) distillation
(r) extraction
(s) solvation
(t) mixing

2. Factories involved in distillation, refining or other processing of

petroleum or petroleum products.

3. Factories involved in the total or partial disposal of solid or liquid

chemicals by incineration or chemical decomposition.

4. Factories involved in the production, processing or treatment of

energy gases, for example, LPG, LNG, SNG.

5. Factories involved in the dry distillation of coal or ignite.

6. Factories involved in the production of metals or non-metals by a

wet process or by means of electrical energy.

SCHEDULE 5

Format of a Material Safety Data Sheet

[See Rule 3(2) and (3)]

1. IDENTITY OF MATERIAL

Product Name Chemical Classification

Trade name Synonyms

Formula Label: Category CAS Number UN Number

class

Regulated Shipping Name HAZCHEM Code:

Identification Codes/ Label
Hazardous Waste
Identification Number

Hazardous Ingredients CAS Number

(1)
(2)
(3)
(4)

2. PHYSICAL AND CHEMICAL PROPERTIES

Physical state: Boiling Point in degree Vapour Pressure at 35 degree

(Gas, Liquid, C C …..…….. mm Hg.
Solid)

Appearance Melting/ Freezing Evaporation rate at 30 degree C

Point in degree C

Odour Vapour Density Solubility in water at 30 degree

(air=1) C.

Others Specific Gravity pH

(corrosivity, etc.)
3. FIRE AND EXPLOSIVE HAZARDS DATA

Explosion / Flash LEL % Auto ignition

Flammability Point (deg.) C Temperature
degree C

Flash ULEL % TDG

Point (deg.) C Flammability
(Classification)

4. REACTIVE HAZARDS

Stability To Impact (Hazardous Combustion

Products)
Static Discharge (Hazardous Decomposition
Products)
Reactivity (conditions to avoid)
Hazardous May/May not accur (conditions to avoid)
Polymerisation
Incompatibility Materials to avoid

5. HEALTH HAZARD DATA

Routes of Entry : (inhalation, skin, membranes and eye contact and ingestion)

Effects of Exposure/ Symptoms :

LD50 (in rat) (Orally or persutaneous LC50(in rat)

absorption) (mg/1) / 4 hours
Mg/kg body weight)

Permissible Exposure ppm mg/cu.m Limit Short Term ppm mg/cu.m

Exposure Limit (STEL)

Threshold Limit ppm/mg.m Value (TLV) of Odour ppm mg/cu.m Threshold

ACGIH

Emergency Treatment :

6. HAZARD SPECIFICATION

NFPA Health Flammability Stability Special

Hazard
Signal

Known hazards

Combustible Liquid Water Reaction Irritant

Material
Flammable material Oxidizer Sensitizer
Pyrophoric material Organic peroxide Carcinogen
Explosive material Corrosive Material Mutagen
Unstable material Compressed Gas Others (Specify)

7. SAFE USAGE DATA

Ventilation General/ Mechanical

Local Exhaust
Protective equipment required Eyes (Specify)
Respiratory (Specify)
Gloves (Specify)
Clothing (Specify)
Others (Specify)
Precautions Handling & Storage (Specify)
Others (Specify)

8. EMERGENCY RESPONSE DATA

Fire Extinguishing Media

Fire Special Procedure
Unusual Hazards
Exposure (inhalation, skin and eye
contact, ingestion) Fire Aid Measures

Spills Steps to be taken

Waste Disposal Method

9. ADDITIONAL INFORMATION

10. SOURCES USED

Reference to books, journals, etc.

-------------------------------------------------------------------------------------------------
------------------

11. MANUFACTURER/ SUPPLIER DATA

Firm’s Name Standard Packing

Mailing Address
Telephone Number
Telex Number Other
Telegraphic Address
Contact Person in Emergency Other

Emergency Tel. In Transit Area

Acronyms and Glossary of terms :

CAS : Chemical Abstract Service Registration Number

UN Number | United Nations Number

HAZCHEM Code : Emergency Action Code (EAC), allocated by the

Joint Committee of Fire Brigade Operations, UK.

TDG Flammability : Transport of Dangerous Goods – Flammability

Classification by United Nations.

NEPA | National Fire Protection Association, USA.

LD50 and LC50 represent the dose in mg/kg of body weight and the
concentration in mg/1 for 4 hours having lethal effect on 50% of the
animals (rats) treated

PEL: Permissible Exposure Limit as laid down in the statutes or by the

ACGIH.

TLV : Threshold Limit Value as laid down by the American Conference of

Governmental Industrial Hygienists, (ACGIH), USA.
STEL : Short Term Exposure Limit as laid down in the statutes or by
ACGIH.
GUIDELINES :

All efforts should be made to fill in all the columns. No column should be
left blank. In case certain information is not applicable or
available. N/App. or N/Av. Sign may be used.

SCHEDULE 6

[See Rule 5 (1)]

Information to be furnished regarding Notification of a Major Accident

Report number …………

of the particular accident

1. General data.

(c) Name of the site

(d) Name and address of the occupier

(Also state the telephone/ telex number)

(e) (i) Registration number

(ii) Licence Number

(As may have been allotted under any
statute applicable to the site, e.g. the Factories Act)

(f) (i) Nature of industrial activity

(Mention what is actually manufactured, stored, etc.)

(ii) National Industrial Classification, 1987 at the four digit level

2. Type of major accident Explosion

Explosion Fire Name of the Hazardous

chemical
3. Description of the major accident

(a) Date, shift and hour of the accident

(b) Department / Section and exact place where the accident took
place

(c) The process/ operation under taken in the department/ section

where the accident took place. (Attach a flow chart, if
necessary)

(d) The circumstances of the accident and the hazardous

chemical involved.

4. Emergency measures taken and measures envisaged to be taken

to alleviate short term effects of the accident.

5. Causes of the major accident known

(to be specified)

Not known

Information will be supplied as

Soon as possible

6. Nature and extent of damage

(a) Within the establishment

- casualities ……………………. Killed

……………………. Injured

……………………. Poisoned

- persons exposed to the

major accident ……………………………

- material damage

- the danger is still present

 - danger no longer exists

(b) Outside the establishment

- casualities ……………………. Killed

……………………. Injured

……………………. Poisoned

- persons exposed to the

major accident ……………………………

- damage to
environment

- the danger is still present

- danger no longer exists

7. Data available for assessing the effects of the accident on persons

and environment

8. Steps already taken or envisaged

(g) to alleviate medium or long term effects of the accidents

(h) to prevent recurrence of similar major accidents
(i) any other relevant information.

SCHEDULE 7

[See Rule 7 (1)]

Information to be furnished for the Notification of Activities/ Sites

1. The name and address of the occupier making the notification.

2. The full postal address of the site where the notifiable industrial
activity will be carried on.

3. The area of the site covered by the notification and of any adjacent
site which is required to be taken into account by virtue of Schedule
2(b) and Schedule 3(b).

4. The data on which it is anticipated that the notifiable industrial

activity will commence or if it has already commenced a statement to
that effect.

5. The name and maximum quantity liable to be on the site of each

hazardous chemical for which notification is being made.

6. Organisation structure, namely, organization diagram for the

proposed industrial activity and set up for ensuring safety and
health.

7. Information relating to the potential for major accidents, namely –

(a) Identification of major accident hazards;

(b) The conditions or events which could be significant in bringing
one about; and
(c) A brief description of the measures taken.

8. Information relating to the site namely –

(a) a map of the site and its surrounding area to a scale large
enough to show any features that may be significant in the
assessment of the hazard of risk associated with the site;
(i) area likely to be affected by the major accident,
(ii) population distribution in the vicinity.

(b) A scale plan of the site showing the location and quantity of all
significant inventories of the hazardous chemicals;

(c) A description of the processes or storages involving the

hazardous chemicals, the maximum amount of such a hazardous
chemical in the given process or storage and an indication of the
conditions under which it is normally held;
(d) The maximum number of persons likely to be present on site.
9. The arrangement for training of workers and equipment necessary
to ensure safety of such workers.

SCHEDULE 8

[See Rule 10 (1)]

Information to be furnished in a Safety Report

1. The name and address of the person furnishing the information.

2. Description of the industrial activity, namely –

(a) site,
(b) construction design,
(c) protection zones (explosion protection, separation distances),
(d) accessibility of plant,
(e) maximum number of persons working on the site and particularly
of those persons exposed to the hazard.

3. Description of the processes, namely –

(a) technical purpose of the industrial activity,

(b) basic principles of the technological process,
(c) process and safety-related data for the individual process stages,
(d) process description,
(e) safety-related types of utilities.

4. Description of the hazardous chemicals, namely –

(a) chemicals (quantities, substance data on physical and chemical

properties, safety related data on explosive limits, flash point,
thermal stability, toxicological data and threshold limit values, lethal
concentrations)

(b) the form in which the chemicals may occur or into which they may
be transformed in the event of abnormal conditions,

(c) the degree of purity of the hazardous chemical.

5. Information on the Preliminary Hazard Analysis, namely –

(a) type of accident,
(b) system elements or events that can lead to a major accident.
(c) Hazards,
 (d) safety-relevant components

6. Description of safety-relevant units, among others;

(a) special design criteria,

(b) controls and alarms,
(c) special relief systems,
(d) quick-acting valves,
(e) collecting tanks/ dump tanks,
(f) sprinkler systems,
(g) fire protection.

7. Information on the hazard assessment, namely –

(a) identification of hazards,

(b) the causes of major accidents,
(c) assessment of hazards according to their occurrence frequency,
(d) assessment of accident consequences,
(e) safety systems,
(f) known accident history.

8. Description of information on organizational systems used to carry

on industrial activity safely, namely –

(a) maintenance and inspection schedules,

(b) guidelines for the training of personnel,
(c) allocation and delegation of responsibility for plant safety,
implement of safety procedures.

9. Information on assessment of the consequences of major

accidents, namely –

(a) assessment of the possible release of hazardous chemicals or of

energy,
(b) possible dispersion of released chemicals;
(c) assessment of the effects of the releases (size of the affected
area, health effects, property damage)

10. Information on the mitigation of major accidents, namely –

(a) fire brigade;

(b) alarm systems;
(c) emergency plan containing system of organization used to fight
the emergency, the alarm and the communications routes,
 guidelines for fighting the emergency, examples of possible
accident sequences,
(d) coordination with the District Collector or the District Emergency
Authority and its off-site emergency plan,
(e) notification of the nature

Schedule 8A
[See Rule 13(1)]
Details to be furnished in the On-site Emergency Plan

1. Name and address of the person furnishing the information.

2. Key personnel of the organization and responsibilities assigned to
them in case of an emergency.
3. Outside organization if involved in assisting during on-site
emergency.
(a) Type of accidents
(b) Responsibility assigned.
4. Details of liaison arrangement between the organizations.
5. Information on the preliminary hazard analysis
(a) Type of accidents
(b) System elements or events that can lead to a major accident
(c) Hazards
(d) Safety relevant components

6. Details about the site

(a) Location of dangerous substances
(b) Seat of key personnel
(c) Emergency control room
7. Description of hazardous chemicals at plant site.
(a) Chemicals (Quantities and toxicologies data)
(b) Transformation if any which could occur
(c) Purity of hazardous chemicals
8. Likely dangers to the plant
9. Enumerate effects of :
(i) stress and strain caused during normal operation;
(ii) fire and explosion inside the plant and effect if any, or fire
and explosion outside.
 10. Details regarding
(i) Warning, alarm & safety and security systems;
(ii) Alarm and hazard control plans in line with disaster control and
hazard control planning, ensuring the necessary technical and
organizational precautions;
(iii) Reliable measuring instruments, control units and servicing of
such equipments;
(iv) Precautions in designing of the foundation and load bearing parts
of the building;
(v) Continuous surveillance of operations;
(vi) Maintenance and repair work according to the generally
recognized rules of good engineering practices;

11. Details of communication facilities available during emergency and

those required for an off-site emergency.
12. Details of fire fighting and other facilities available and those
required for an off-site emergency.
13. Details of first aid and hospital services available and its adequacy.

Schedule 9

[See Rule 19(1) & (2)]

PART I. MODEL RULES TO BE REPEALED

Sl.No. Model Rule Title

No.
1. 82 C Collection, development and dissemination of
information
2. 82 E Disclosure of information to general public
3. 82 F Disclosure of information to the Local Authority
4. 82 I Emergency Plan
5. 82 J Disaster Control and Management Plan

PART II MODEL RULES TO BE MODIFIED

Sl.No. Model Rule Title Modification Suggested

No.
1. 82 H Disclosure of The modified sub rule (1)
 information to the will read as “the occupier of
Chief Inspector. every factory carrying on
‘hazardous process’ shall
furnish, in writing, to the
Chief Inspector, a copy of
all the information
furnished to the workers”.
2. 82 K Information on The modified sub rule (1)
Industrial Wastes will read as “the information
furnished under Rule 82 D
and 82 H shall include the
quantity of the solid and
liquid wastes generated per
day, their characteristics
and the method of
treatment such as
incineration of solid wastes,
chemicals and biological
treatment of liquid wastes
and arrangements for their
final disposal”.
3. 82 L Review of the The modified sub rule (1)
information will read as “the occupier
furnished to shall review once in every
workers, etc. calendar year and modify,
if necessary, the
information furnished under
Rule 82 D and 82 H to the
workers and the Chief
Inspector”.
4. 82 M Confidentiality of The modified sub rule (1)
information will read as “the occupier of
a factory carrying on
‘hazardous process’ shall
disclose all information
needed for protecting
safety and health of the
workers to –
(a) his workers; and
(b) Chief Inspector as
required under Rules 82 D
and 82 H. If the occupier is
of the opinion that the
disclosure of the details
regarding the process and
details regarding the
process and formulations
will adversely affect his
business interests, he may
make representation to the
 Chief Inspector stating the
reasons for withholding
such information. The
Chief Inspector shall give
an opportunity to the
occupier of being heard
and pass an order to the
representation. An
occupier aggrieved by an
order of Chief Inspector
may prefer a appeal before
the State Government
within a period of 30
days. The State
Government shall give an
opportunity to the occupier
of being heard and pass an
order. The order of the
State Government shall be
final”.

FOOT NOTE:

After deleting the Model rules 82 E, 82 F, 82 G, 82 J and 82 I the

remaining Model Rules may be renumbered suitably.