Properties of Refractories

This is a measure of the resistance of a refractory body to the

combined effects of heats of load. This test helps to study the
behavior of a refractory product when subjected to a constant
load under conditions of progressively rising temperature.
 Classification Based on Physical Form
Refractories are classified according to their physical form. These are the shaped
and unshaped refractories. The shaped is commonly known as refractory bricks
and the unshaped as “monolithic” refractories.
Shaped Refractories:
Shaped refractories are those which have fixed shaped when delivered to the user.
These are what we call bricks. Brick shapes maybe divided into two: standard
shapes and special shapes.
Standards shapes have dimension that are conformed to by most refractory
manufacturers and are generally applicable to kilns and furnaces of the same type.
Special shapes are specifically made for particular kilns and furnaces. This
may not be applicable to another furnaces or kiln of the same type. Shaped
refractories are almost always machine-pressed, thus, high uniformity in
properties are expected. Special shapes are most often hand-molded and are
expected to exhibit slight variations in properties.

Unshaped Refractories:
Unshaped refractories are without definite form and are only given shape
upon application. It forms jointless lining and are better known as monolithic
refractories. These are categorized as Plastic refractories, ramming mixes,
castables, gunning mixes, fettling mixes and mortars.

Plastic refractories are tempered with water and/or added with a binder. They
have sufficient plasticity to be pounded or rammed into place

Mouldable mixes are refractories which are installed by hammering or ramming

and have sufficient plasticity to mould to whatever shape is required. Ramming
mixes usually contain a plastic clay which is tempered with water, de-aired and
extruded into blocks
Classification Based on The Refractoriness
Types of Refractories

Refractories are classified as dense or insulating types.

 The most high-temperature refractories, such as firebricks, are
high-density (>1,92 gr/cm3). They offer excellent resistance in
challenging operating environments, such as slags with different
chemical compositions, fumes, dust, and gases.

 Insulating refractories have lower densities (0,06 to 1,12 gr/cm3)

and provide insulating properties, while offering resistance to
corrosion and chemical reactions with the operating environment.

The following is the discussion of the outstanding characteristics of

the various types of refractories :
1) Fire-clay Brick Refractories

 Fire-clay brick comprise about 75% of the production of

refractories on a volume basis and are essentially hydrated
aluminum silicates with minor proportions of other minerals.

 Typical composition consists of SiO2<78% and Al2O3< 44%.

 As a type they are extremely versatile; least costly of all

refractory bricks and are extensively used in the iron and steel
industry, non ferrous metallurgy, glass industry, pottery kilns,
cement industry and by many others.

 All fire-clay brick are not alike and the total ranges of their
properties are quite broad.

 ASTM subdivides fire-clay brick into four major classifications

depending primarily upon fusion temperature (Pyrometric Cone
Equivalent, PCE).
 The four standard classes of fireclay brick are: super duty, high-duty,
medium-duty, low-duty, and also semi-silica.
 These classes cover the range from approximately 18% to 44%
alumina, and from about 50% to 80% silica.
 Table below shows that as the quantity of impurities increases and
the amount of Al2O3 decreases, the melting point of fireclay brick
decreases.

-32 x 5/9  932 F = 500 C

 Characteristically, fire-clay brick begin to soften far below their
fusion temperature and under load actual deformation takes place.
 The amount of deformation depends upon the load, and, once
started, this deformation is a slow but continuous process unless
either the load or the temperature is reduced.
 It is for this reason that fire-clay brick are not well adapted for use
in wide sprung arches in furnaces operating continuously at high
temperatures.
 2) High Alumina Refractories
 Alumina refractory which consists of aluminum oxide and traces of
other materials is the most mature of the engineering ceramics.
 Alumina is one of the most chemically stable oxides known, which
offers excellent hardness, strength and spallingresistance.
 It is insoluble in water and super heated steam, and in most
inorganic acids and alkalis.
 Alumina refractories carry the all purpose characteristics of fire-
clay brick into higher temperature ranges that makes it suitable for
lining furnace operating up to 3350°F.
 It has a high resistance in oxidizing and reducing atmosphere and is
extensively used in heat processing industries.
 The refractoriness of high alumina refractories increases with
increase of alumina percentage.
 The 50%, 60%, 70% and 80% alumina classes contain their
respective alumina contents with an allowable range of plus or
minus 2.5%.
 High-alumina brick are classified by their alumina content
according to the following ASTM convention. These are:
Mullite refractory: Mullite brick is about 72wt% alumina with 28wt%
silica. These have excellent volume stability and strength at high
temperatures.

Corundum refractories: The 99% alumina class of refractories is called

corundum. These refractories comprise single phase, polycrystalline, and
alpha-alumina.

High alumina bricks are most commonly used in cement, lime and
ceramic kilns, glass tanks, crucibles for melting a wide range of
metals, hearth & shaft of blast furnaces and in lead drossing furnaces.
 3) Silica Brick

Silica brick is a refractory that contains at least 93 percent SiO2. The

raw material is high quality rocks. Various grades of silica brick have
found extensive use in the iron and steel melting furnaces and the glass
industry. In addition to high fusion point multi-type refractories, other
important properties are their high resistance to thermal shock and
their high refractoriness. The outstanding property of silica brick is
that it does not begin to soften under high loads until its fusion point is
approached. This behavior contrasts with that of many other
refractories, for example alumina silicate materials, which begin to fuse
and creep at temperatures considerably lower than their fusion points.
Other advantages are flux and stag resistance, volume stability and
high spalling resistance.
4) Magnesite Brick

Magnesite refractories are chemically basic materials, containing

at least 85 percent magnesium oxide. They are made from
naturally occurring magnesite (MgCO3). The properties of
magnesite refractories depend on the concentration of silicate
bond at the operating temperatures. Good quality magnesite
usually results from a CaO-SiO2 ratio of less than two with a
minimum ferrite concentration, particularly if the furnaces lined
with the refractory operate in oxidizing and reducing conditions.
The slag resistance is very high particularly to lime and iron rich
slags.
5) Chromite Refractories

Two types of chromite refractories are distinguished:

 Chrome-magnesite refractories, which usually contain 15-35
percent Cr2O3 and 42-50 percent MgO. They are made in a wide
range of qualities and are used for building the critical parts of
high temperature furnaces. These materials can withstand
corrosive slags and gases and have high refractoriness.
 Magnesite-chromite refractories, which contain at least 60
percent MgO and 8-18 percent Cr2O3. They are suitable for
service at the highest temperatures and for contact with the
most basic slags used in steel melting. Magnesite-chromite
usually has a better spalling resistance than chrome-magnesite.
 6) Zirconia Refractories

Zirconium dioxide (ZrO2) is a polymorphic material. It is essential to

stabilize it before application as a refractory, which is achieved by
incorporating small quantities of calcium, magnesium and cerium oxide,
etc. Its properties depend mainly on the degree of stabilization, quantity
of stabilizer and quality of the original raw material. Zirconia refractories
have a very high strength at room temperature, which is maintained up
to temperatures as high as 15000C. They are therefore useful as high
temperature construction materials in furnaces and kilns.
 6) Zirconia Refractories

The thermal conductivity of zirconium dioxide is much lower than that of

most other refractories and the material is therefore used as a high
temperature insulating refractory. Zirconia exhibits very low thermal
losses and does not react readily with liquid metals, and is particularly
useful for making refractory crucibles and other vessels for metallurgical
purposes. Glass furnaces use zirconia because it is not easily wetted by
molten glasses and does not react easily with glass.
7) Alumina Refractories

Alumina refractory materials that consist of aluminium oxide

with little traces of impurities are known as pure alumina.
Alumina is one of the most chemically stable oxides known. It is
mechanically very strong, insoluble in water, super heated steam,
and most inorganic acids and alkalies. Its properties make it
suitable for the shaping of crucibles for fusing sodium carbonate,
sodium hydroxide and sodium peroxide. It has a high resistance
in oxidizing and reducing atmosphere. Alumina is extensively
used in heat processing industries. Highly porous alumina is used
for lining furnaces operating up to 1850oC.
 8) Monolithic Refractories
Monolithic refractories are single piece casts in the shape of
equipment, such as a ladle as shown in Figure 9. They are rapidly
replacing the conventional type fired refractories in many
applications including industrial furnaces. The main advantages of
monolithics are:
 Elimination of joints which is an inherent weakness
 Faster application method
 Special skill for installation not required
 Ease of transportation and handling
 Better scope to reduce downtime for repairs
 Considerable scope to reduce inventory and eliminate special
shapes
 8) Monolithic Refractories

 Heat savings
 Better spalling resistance
 Greater volume stability

Monolithics are put into place using various methods, such as ramming,
casting, gunniting, spraying, and sand slinging. Ramming requires
proper tools and is mostly used in cold applications where proper
consolidation of the material is important. Ramming is also used for air
setting and heat setting materials. Because calcium aluminate cement
is the binder, it will have to be stored properly to prevent moisture
absorption. Its strength starts deteriorating after 6 to 12 months.
Basic Steps in Refractory Brick Production