Location via proxy:   [ UP ]  
[Report a bug]   [Manage cookies]                
Scribd
Upload
31 views

Lecture 06 - Thermodynamic Functions

The document discusses Clausius Inequality which states that the inequality holds for an irreversible cycle while equality holds for a reversible cycle. It also discusses change in entropy for irreversible processes like conduction or radiation where heat is lost by a hot body and gained by a cold body. The document further discusses entropy of a perfect gas occupying a volume at pressure and temperature.

Uploaded by

Kowser mahmud
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
31 views

Lecture 06 - Thermodynamic Functions

The document discusses Clausius Inequality which states that the inequality holds for an irreversible cycle while equality holds for a reversible cycle. It also discusses change in entropy for irreversible processes like conduction or radiation where heat is lost by a hot body and gained by a cold body. The document further discusses entropy of a perfect gas occupying a volume at pressure and temperature.

Uploaded by

Kowser mahmud
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
You are on page 1/ 19

To Study:

Clausius Inequality
𝑑𝑄
∮ ≤0
𝑇
The equality holds good for a reversible cycle and the inequality holds good for an irreversible cycle.
The complete expression is known as Clausius Inequality.

𝑑𝑄 = 𝑇 𝑑𝑆

𝜃1 𝑄2
∮ 𝑑𝑆 = − = 0 ⇒ 𝑆 = 𝑐𝑜𝑛𝑠𝑡𝑎𝑛𝑡
𝑇1 𝑇2
Change in Entropy in an Irreversible Process
In an irreversible process like conduction or radiation, heat is lost by a body at a higher
temperature T1 and is gained by a body at a lower temperature T2. Here T1>T2.
Entropy of a perfect gas
Consider unit mass of a perfect gas, occupying a volume V at Pressure P and temperature T. Let dQ
be the heat supplied to the gas. Then according to first law of thermodynamics,
Thermodynamic Potentials/Functions
The state of a system can be completely described by any two of the state variables P, V, T, S
and U. Out of these, U is the internal energy and can be determined by the remaining four.
According to first law of thermodynamics,
Brijlal

You might also like