Chlorine Water
Chlorine Water
Chlorine Water
chloramines has not correlated to experience in the field for some applications. The effect
exposure ratio of ductile-iron pipe gaskets. To investigate this, side-by-side tests of elastomer
sheet materials and ductile-iron pipe push-on and mechanical joint gaskets exposed to
110 mg/L total chloramine solution were conducted. The push-on and mechanical joint
gaskets were tested in assembled joints. The tests, done over 364 days, revealed that
although the majority of the elastomer sheet materials experienced significant visual
degradation and large changes in mass, volume, and hardness, the ductile-iron pipe push-
on and mechanical joint gaskets showed no visual degradation and only slight detectable
chlorine penetration.
effect of Chloramines
on Ductile-iron Pipe Gaskets
of various elastomer
compounds
oday, disinfection of potable water systems normally is accomplished by
†
Joint A*—3–24 in. (76–610 mm), joint B —4–36 in. (102–914 mm)
350 FKM 60
mercially available for both the push-
on and mechanical joint ductile-iron
250 pipe were tested. A simple exposure
test was selected in order to directly
compare the effect of chloramines on
150
sheet material to that of assembled
ductile-iron pipe joint gaskets.
50
DESCRIPTION
–50 Test specimens. Six 6 in. (150 mm)
0 50 100 150 200 250 300 diameter, cement mortar-lined, duc-
350 400
Exposure Time—days tile-iron pipe push-on joint sections
CR—neoprenes, EPDM—ethylene-propylene, FKM—fluorocarbons, NBR—nitriles, and six mechanical joint sections were
SBR—styrene butadiene
assembled in accordance with stan-
dard C600 (ANSI/AWWA, 1999)
FIGURE 7 Effect of chloramine on push-on joint gasket sheet material using approved gasket lubricant as
volume indicated by standard 61 (ANSI/NSF,
1999). Each joint section was approx-
650 imately 22 in. (550 mm) in length.
SBR 60 (control) Two sections of each type joint were
SBR 60
550 assembled utilizing SBR gaskets. The
NBR 65
CR 65 remaining four joint sections of each
450
EPDM 65 type joint were assembled using
FKM 60
Change in Volume—%
Change in Hardness—durometer*
–5
total Cl2 strength of approximately
–10
110 mg/L ± 10% as determined by a
high-range total Cl2 test kit.5 –15
The immersion period lasted 364
–20
days during which time the test solu-
tion was prepared and replaced –25
approximately twice a week. –30
Test conditions.
–35
• Chloramine test solution with
approximately 110 mg/L ± 10% to- –40
tal Cl2,
–45
• pH of 5.5–6.5, 0 50 100 150 200 250 300 350 400
• room temperature—73oF (23oC), Exposure Time—days
• test solution replaced approxi- CR—neoprenes, EPDM—ethylene-propylene, FKM—fluorocarbons, NBR—nitriles,
SBR—styrene butadiene
mately twice a week, and
• exposure period of 364 days. *Shore A durometer, Shore Instrument and Mfg. Co., Freeport, N.Y.
350 FKM 75
with a minimum of 0.25 in. (6.3 mm)
separation. The pipe joint gasket elas- 250
tomers used in each assembled joint
corresponded to the elastomer test
150
sheet pieces suspended in that joint.
The test pieces were suspended using
nylon fishing line, which did not affect 50
Overall, for the push-on joint vul- *SBR—styrene butadiene, NBR—nitrile, CR—neoprene, EPDM—ethylene-propylene, FKM—fluorocarbon
†SBR control test sheets were subjected to distilled water.
canized sheet test pieces subjected to
the chloramine solution, the perfor-
mance from best to worst was: FKM, TABLE 2 Summary of Cl2* penetration depth in gaskets exposed
SBR, CR, EPDM, and NBR. For the to chloramine by Cl2 X-ray dot mapping
mechanical joint vulcanized test pieces
subjected to the chloramine solution,
the performance from best to worst
Compound and Durometer Depth of Penetration—µm (in.)
was: FKM, EPDM, NBR, CR, and
SBR. The best performance was de- Push-on joint
More important than the ratings NBR 65 28.2 (0.00111) and 32.7 (0.00129) when repeated
pliers other than the one used in this *Cl2—chlorine, SBR—styrene butadiene, NBR—nitrile, CR—neoprene, EPDM—ethylene-
study3 or from the same supplier at propylene, FKM—fluorocarbon
†SBR control gaskets were subjected to distilled water.
an earlier or later date may result in a ‡ND—not detected
different order of rating from best to
worst when tested. However, any
EPDM, NBR, CR, or SBR vulcanized
sheet material would be expected to result in significant revealed that all the gaskets’ mechanical properties exceeded
degradation when subjected to the identical testing the requirements for new gaskets (ANSI/AWWA, 1990).
reported here. Results of Cl2 penetration depth tests are reported
Push-on and mechanical joint gaskets. None of the push- in Table 2. Only the SBR 60, NBR 65, EPDM 65, and
on or mechanical joint gaskets showed any visual degra- NBR 75 showed detectable depths of Cl2 penetration.
dation after the joint sections were disassembled. Testing also Even after exposure to extreme concentrations of chlor-
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Aqueous Solutions With Available Chlo- Materials, Equipment, and Procedures Jour. AWWA, 85:8:101.