Devoir 1

Applications de
Aminata
la
crodynamique
à remettre le 2 octobre

= -
L
E B E

· 4
 Methane (CH4)

LiI
2 a
I
.

I
S ↳
46 1 bar
,

Tep= 111k - P =

T bar

T bar

P ? =
Ts =

91 2k ,
+ P =
7 bar

1Hsub 9
"
=

.
2 mol

91 , 2k 190 , 6K-
IIIK
I
90 , 67k

b AHrap= ? strap
P
.
In =
I
-
I

R Tr Te

sHfus =?
strap= I
In

in -

is

314Enol
/44
strap =
In
E .

R =
In , /bar 8 = 8443 13 "Nol
, ,
.

I bar
in -

is l I =8 ,
465R)/mol
IIIs 190 , K

SHSub= AHfus+sHrap - SHAus-SHsub AHrap -

/mo
*
=9 2 -8 5
,
,
=

0, 735

c .

Priple" ? In P2 =
svap I
-
I

Pi R Tr Te

Frap
I
1
exp
=

R T Te
 P =
Pr

exp Frap 1
-
I

R Tr Tr

- 46 ,
I bar =0 ,
128 bar

se
I I
exp
mal
~ 90 47
, 190.

d Etat stable
. à P 1 bar
=

~solide ,
car To<91 , 2k-Tfus ,
donc reste â
l'état
solide
T 05k
=
.

P
Tus= ? Tbar 9120k
91 2k -
e
,
->
I
=

91 2 100
,
.

fus
AT Tfus 100 bar 7
↓
P =

100 bar