Exercise - Nomenclature of Organic Compounds Final

ChemTech Enrichment Series 2021
Organic Chemistry – Nomenclature.
General Instruction. In a separate answer sheet, shade the letter of the correct answer.
1.
The IUPAC name for is:

A) 6-Ethyl-3,4-dimethylheptane
B) 2-Ethyl-4,5-dimethylheptane
C) 3,4,6-Trimethyloctane
D) 3,5,6-Trimethyloctane
E) 2-(1-Methylpropyl)-4-methylhexane
2.
An IUPAC name for is:

A) 5-Methyl-4-(1-methylpropyl)hexane
B) 2-Methyl-3-(1-methylpropyl)hexane
C) 2-Methyl-3-(2-methylpropyl)hexane
D) 3-Methyl-4-(1-methylethyl)heptane
E) 5-Methyl-4-(1-methylethyl)heptane
3. The correct IUPAC name for the following compound is:
A) 1-Hydroxy-3-sec-butylcyclopentane
B) 3-sec-Butyl-1-cyclopentanol
C) 1-sec-Butyl-3-cyclopentanol
D) 4-sec-Butyl-1-cyclopentanol
E) 3-Isobutyl-1-cyclopentanol
4. What is a correct name for the following compound?
A) 3-Isobutyl-2-methylheptane
B) 3-sec-Butyl-2-methyloctane
C) 5-Isobutyl-6-methylheptane
D) 2-Ethyl-3-isopropyloctane
E) 4-Isopropyl-3-methylnonane
5. What is the correct IUPAC name for the following compound?
A) 3-Hydroxymethylheptane
B) 3-Hydroxymethylhexane
C) 3-Methyloxyheptane
D) 2-Ethyl-1-hexanol
E) 2-Ethyl-1-heptanol
6.
A correct IUPAC name for is:

A) 2-Ethyl-4-pentanol
B) 4-Ethyl-2-pentanol
C) 3-Methyl-5-pentanol
D) 5-Methyl-2-hexanol
E) 4-Methyl-2-hexanol
7. A correct IUPAC name for isobutyl alcohol is:

A) 2-Methyl-1-propanol
B) 2-Methyl-1-butanol
C) 1-Methyl-1-propanol
D) 1,1-Dimethyl-1-ethanol
E) 3-Methyl-1-propanol
8. The correct structure for benzyl alcohol is:
A) I
B) II
C) III
D) IV
E) V
9.
The correct IUPAC substitutive name for is:

A) 4-Penten-2-methyl-2-ol
B) 4-Methyl-1-penten-2-ol
C) 2-Methyl-4-penten-2-ol
D) 4-Methyl-1-penten-4-ol
E) 4-Hydroxy-4-methyl-1-pentene
10.
The IUPAC name of compound is:

A) 1,1,1-Triethylmethanol
B) 1,1-Diethyl-1-propanol
C) 2-Ethyl-3-pentanol
D) 3-Ethyl-3-pentanol
E) tert-Heptanol
11. The correct IUPAC name for tert-butyl alcohol is:

A) 1-Butanol
B) 2-Methyl-1-propanol
D) 2-Butanol
E) 1,1-Dimethyl-1-ethanol
12. Which is a correct IUPAC name for CH3OCH2CH2OCH3?

A) 1,4-Dioxane
B) Ethylene glycol dimethyl ether
C) 1,4-Dioxapentalene
D) 1,2-Dimethoxyethane
E) 1,2-Diethoxymethane
13. Select the structure of benzyl methyl ether.
A) I
B) II
C) III
D) IV
E) V
14.
is properly named:
A) cis-1,2-Cyclopentanediol
B) meso-1,2-Cyclopentanediol
C) (1R,2R)-1,2-Cyclopentanediol
D) (1R,2S)-1,2-Cyclopentanediol
E) (1S,2S)-1,2-Cyclopentanediol
15. Which of these is the most accurate name for the molecule
A) sec-Butyl phenyl ether

B) Isobutyl phenyl ether
C) tert-Butyl phenyl ether
D) (R)-2-Phenoxybutane
E) (S)-2-Phenoxybutane
16.
A correct name for is which of the following?

A) (R)-3-Pentyn-2-ol
B) (S)-3-Pentyn-2-ol
C) (R)-2-Pentyn-4-ol
D) (S)-2-Pentyn-4-ol
E) (S)-2-Hydroxy-3-pentyne
17. Which of these, though commonly used, is an incorrect name for (CH3)3COH?
A) tert-Butyl alcohol
B) tert-Butanol
D) More than one is incorrect.
E) Each is a correct name.
18.
A correct name for the compound, , is:

A) 2-Methyl-4-hexanone D) Ethyl isopropyl ketone
B) 2-Methyl-3-hexanone E) Isobutylpropanone
C) 5-Methyl-3-hexanone
19. What would be a correct name for the compound shown below?
A) tert-Butyl methyl ketone D) Isohexanone

B) 2,2-Dimethyl-4-pentanone E) Isopentyl methyl ketone
C) 4,4-Dimethyl-2-pentanone
20.
A correct name for is?

A) 3-Benzylpropanone D) Nonanone
B) 3-Phenylpropanal E) Nonanal
C) 3-Benzylpropanal
21. A correct name for the following compound would be which of those below?
A) 2,5-Dimethyl-6-hexanal D) 3,5-Dimethylheptanone
B) 2,5-Dimethylhexanal E) 1-Hydro-2,5-dimethyl-1-hexanone
C) 2-Aldehydoisohexane
22.
What is the IUPAC name for ?

A) 4-Oxo-5-phenyl-2-hexanol D) 2-Hydroxypropyl-1-phenylethyl
ketone
B) 5-Hydroxy-2-phenyl-3-hexanone E) 5-Hydroxy-3-keto-2-phenylhexane
C) 2-Hydroxy-5-phenyl-4-hexanone
23. Which is the proper name for the structure shown?
A) 2-Chloro-5-aldehydotoluene D) 4-Chloro-3-methylbenzaldehyde
B) 6-Chloro-3-aldehydotoluene E) 4-Methyl-5-chloro-2-benzaldehyde
C) 2-Methyl-4-aldehydochlorobenzene
24. Which of the following compounds is an acetal?
A) I B) II C) III D) IV E) None of these
25. Which of the following is the best name for the following compound?
A) Propyl isopropanoate D) Ethyl isopropyl ketone

B) Propanoyl isopropoxide E) 1-Methylethyl propionate
C) Isopropyl propanoate
26.
A correct name for is:

A) 2-Methylbutyl 2-methylbutanoate D) Isopentyl isovalerate
B) 2-Methylbutyl 3-methylbutanoate E) Isopentyl isobutyrate
C) 3-Methylbutyl isovalerate
27.
What is the IUPAC name for

A) -Chlorovaleryl chloride D) 1,2-Dichloropentanal
B) 2-Chloropentanoyl chloride E) 1-Chloro-1-butanecarbonyl chloride
C) 1-Chloropentanoyl chloride
28.
Which is a correct common name for ?

A) Ethylethylisobutylamine D) Ethylethyl-sec-butylamine
B) Diethylisobutylamine E) 2-Diethylaminobutane
C) sec-Butyldiethylamine
29. Which of the following is a tertiary amine?

A) CH3CH2NH2 D) (CH3CH2)4N+ OH-
B) CH3CH2NHCH2CH3 E)
C)
30. A student named a particular compound 2-ethyl-1-butene. Assuming that the student's choice
actually corresponded to the correct distribution of the double bond and the substituents, what is the
correct IUPAC name for this compound?
a. 2-ethyl-1-butene c. 2-methylene-1-pentene
b. 3-ethyl-3-butene d. none of these
31. Cis-trans isomers do not exist for which of the following molecules, all of which have the formula
C3H4Br2?
a. 1,1-dibromopropene c. 1,3-dibromopropene
b. 1,2-dibromopropene d. all of these
32. Cis-trans isomers exist for which of the following molecules, all of which have the formula C 6H12?
a. 2-methyl-1-pentene c. 3-methyl-2-pentene
b. 2-methyl-2-pentene d. all of them
33. Which of the following is a correct IUPAC name?

a. 4-ethyl-1-methylcyclohexene c. 1-methyl-4-ethylcyclohexene
b. 5-ethyl-2-methylcyclohexene d. 5-methyl-2-ethylcyclohexene
34. Which of the following compounds is anisole?

a. b. c. d.
35. Which of the following compounds is an aldehyde?

a. b. c. d.
36. Which of the following compounds is a carboxylic acid?
a. b. c. d.

a. 2-chloro-3-bromotoluene c. 2-chloro-4-bromotoluene
b. 3-bromo-2-chlorotoluene d. 6-bromo-4-chlorotoluene
38. What is the IUPAC name of ?

a. 2,2-dimethyl-4-butanol c. 1-tert-butyl-2-ethanol
b. 3,3-dimethyl-1-butanol d. 2-sec-butyl-1-ethanol
39. Which of the following is a glycol?

a. HOCH2CH2CH2OH c. HOCH2CH2OH
b. d. none of these is a glycol
40. Which of the following would be the IUPAC name for the ether commonly called ethyl methyl ether?
a. ethoxymethane b. ethoxyethane c. methoxymethane d. methoxyethane
41. Which of the following is the IUPAC name for ?

a. isobutyl mercaptan c. 2-methyl-1-propanthiol
b. sec-butyl mercaptan d. 2-methyl-1-propanethiol
42. Which of the following is a heterocyclic amine?

a. aniline b. benzylamine c. piperidine d. none of these

a. 1-amino-4-methylbenzene c. 4-methylaniline
b. 4-aminotoluene d. p-toluidine

a. 1-amino-4-ethylbenzene c. 1-ethyl-4-aminobenzene
b. 4-ethylaniline d. p-ethyltoluidine

a. ethylaniline c. phenylethylamine
b. ethylphenylamine d. N-ethylaniline
46. What is the IUPAC name of isopropyl amine?
a. propanamine b. 1-propanamine c. 2-propanamine d. 2-propylamine
47. What is the IUPAC name of CH3 NH C2H5?

a. ethylmethylamine c. N-methylethanamine
b. methylethylamine d. propanamine
48. What is the common name of ?

a. methylisopropylamine c. N-methyl-2-propanamine
b. isopropylmethylamine d. none of these

a. methylisopropylamine c. N-methyl-2-propanamine
b. isopropylmethylamine d. none of these
50. What is the IUPAC name of (CH3)2NC2H5?

a. ethyldimethylamine c. N,N-dimethylethanamine
b. dimethylethylamine d. none of these
51. What is the common name of ?

a. ethylpropylmethylamine c. N-ethyl-N-methyl-1-propanamine
b. N-ethyl-N-methylpropanamine d. N-ethyl-N-methyl-2-propanamine
52. What is the name of ?

a. aniline bromine c. anilinium bromine
b. aniline bromide d. anilinium bromide

a. 4-aldyltoluene c. methylbenzaldehyde
b. 4-toluylaldehyde d. 4-methylbenzaldehyde

a. 1- b. 2- c. 3- d. none of these
methylpropanal methylpropanal methylpropanal
55. How is a compound which contains an aldehyde functionality and a hydroxyl group named?
a. as an aldehyde with a substituent c. as an aldohol
b. as an alcohol with a substituent d. as an alcoal
56. How is a compound which contains an aldehyde functionality and an amine functionality named?
a. as an aldehyde with a substituent c. as an aldamine
b. as an amine with a substituent d. as an aminoal
57. How is a compound which contains an aldehyde functionality and both hydroxyl and amine
functionalities named?
a. as an aldehyde with substituents c. as an amine with substituents
b. as an alcohol with substituents d. such compounds do not exist
58. What is the IUPAC name of HOCH2CH2CHO ?

a. aldopropanol c. 3-hydroxypropanol
b. 2-hydroxypropanol d. 1,3 propanedial
59. How is a compound which contains a ketone functionality and an alcohol functionality named?
a. as an alcohol with a substituent c. as an alkatone
b. as an ketone with a substituent d. as an ketohol

a. 2-hydroxybuatnoic acid c. -hydroxybutanoic acid
b. 3-hydroxybutanoic acid d. -hydroxybutanoic acid

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ChemTech Enrichment Series 2021

Organic Chemistry – Nomenclature.

The IUPAC name for is:

An IUPAC name for is:

3. The correct IUPAC name for the following compound is:

4. What is a correct name for the following compound?

A correct IUPAC name for is:

7. A correct IUPAC name for isobutyl alcohol is:

8. The correct structure for benzyl alcohol is:

The correct IUPAC substitutive name for is:

The IUPAC name of compound is:

11. The correct IUPAC name for tert-butyl alcohol is:

12. Which is a correct IUPAC name for CH3OCH2CH2OCH3?

A) sec-Butyl phenyl ether

A correct name for is which of the following?

A correct name for the compound, , is:

A) tert-Butyl methyl ketone D) Isohexanone

A correct name for is?

What is the IUPAC name for ?

24. Which of the following compounds is an acetal?

A) I B) II C) III D) IV E) None of these

A) Propyl isopropanoate D) Ethyl isopropyl ketone

A correct name for is:

What is the IUPAC name for

Which is a correct common name for ?

29. Which of the following is a tertiary amine?

33. Which of the following is a correct IUPAC name?

34. Which of the following compounds is anisole?

35. Which of the following compounds is an aldehyde?

37. Which of the following is a correct IUPAC name?

38. What is the IUPAC name of ?

39. Which of the following is a glycol?

41. Which of the following is the IUPAC name for ?

42. Which of the following is a heterocyclic amine?

43. What is the IUPAC name of ?

44. What is the IUPAC name of ?

45. What is the IUPAC name of ?

47. What is the IUPAC name of CH3 NH C2H5?

48. What is the common name of ?

49. What is the IUPAC name of ?

50. What is the IUPAC name of (CH3)2NC2H5?

51. What is the common name of ?

52. What is the name of ?

53. What is the IUPAC name of ?

54. Which of the following is a correct IUPAC name?

58. What is the IUPAC name of HOCH2CH2CHO ?

60. What is the IUPAC name of ?

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