EC-SAFETY DATA SHEET

MARLIPAL O 13/89
Version: 4.12 Revision Date 07.09.2018

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

1.1 Product identifier

Trade name MARLIPAL O 13/89

INCI Trideceth-8

1.2 Relevant identified uses of the substance or mixture and uses advised against
Use Industrial use
raw material for cosmetic agents
raw material for washing and cleaning agents
raw material for textile auxiliary agents
surface-active substance
Uses advised against

1.3 Details of the supplier of the safety data sheet

Company SASOL Germany GmbH
Anckelmannsplatz 1
20537 Hamburg

Telephone: +49 40 63684-1000

Telefax: +49 40 63684-3700

Information (Product safety): Telephone: + 49 (0) 23 65 - 49 47 05

Telefax: + 49 (0) 23 65 - 49 92 40

E-mail address msds-info.germany@de.sasol.com

1.4 Emergency telephone number

Emergency telephone number + 49 (0) 23 65 - 49 22 32

SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)

Acute toxicity, Category 4 (Oral) Harmful if swallowed.
Serious eye damage, Category 1 Causes serious eye damage.

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms

Signal word Danger

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Hazard statements
H302 Harmful if swallowed.
H318 Causes serious eye damage.

Precautionary statements
P264 Wash skin thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/ eye protection/ face protection.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P501 Dispose of contents/ container to an approved waste disposal plant.

Hazardous components which must be listed on the label:

 Isotridecanol,ethoxylated (CAS#: 69011-36-5)

2.3 Other hazards

Danger of slipping after spill or leakage.

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS

This product is a mixture in the meaning of regulation (EC) 1907/2006.

COMPONENTS TO BE NAMED IN ACCORDANCE WITH REGULATION (EC) 1907/2006 AS WELL AS OTHER

HAZARDOUS INGREDIENTS AND CONTAINED SUBSTANCES WITH WORK PLACE LIMIT VALUES

isotridecanol, ethoxylated (>= 2.5 EO)

content: >= 90 - < 95 % component type: Active ingredient

EC-No.: 931-138-8 Index-No.: CAS-No.: 69011-36-5

REACH No.: Not relevant (polymer)
Substance name (REACH / CLP): Isotridecanol,ethoxylated (CAS#: 69011-36-5)
Classification (Regulation Acute Tox. 4 (Oral) H302
(EC) No 1272/2008): Eye Dam. 1 H318

For the full text of the H-Statements mentioned in this Section, see Section 16.
Other data Synonyms: isotridecanol, ethoxylated; CAS-No.: 9043-30-5

SECTION 4: FIRST AID MEASURES

4.1 Description of first aid measures

General advice If you feel unwell, seek medical advice (show the label where possible). Take off all
contaminated clothing immediately.
If inhaled Remove from exposure, lie down. If breathing is irregular or stopped, administer
artificial respiration. Monitor breathing, give oxygen if necessary. Consult a
physician.

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In case of skin contact Wash off immediately with plenty of water. Consult a physician if necessary.
In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
If swallowed Consult a physician. Do not induce vomiting without medical advice. Never give
anything by mouth to an unconscious person.

4.2 Most important symptoms and effects, both acute and delayed
Most important symptoms and Symptoms: No information available.
effects, both acute and delayed
Risks: No information available.

4.3 Indication of any immediate medical attention and special treatment needed
Indication of any immediate Treatment: No information available.
medical attention and special
treatment needed

SECTION 5: FIREFIGHTING MEASURES

5.1 Extinguishing media

Suitable extinguishing media Water spray, Dry powder, Foam, Carbon dioxide (CO2)

5.2 Special hazards arising from the substance or mixture

Specific hazards during Dangerous gases or fumes may occur in case of fire.
firefighting

5.3 Advice for firefighters

Special protective equipment Wear self-contained breathing apparatus for firefighting if necessary.
for firefighters
Further information Standard procedure for chemical fires.

SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions Use personal protective equipment.

6.2 Environmental precautions

Environmental precautions Avoid subsoil penetration.
Do not flush into surface water or sanitary sewer system.

6.3 Methods and materials for containment and cleaning up

Methods for cleaning up Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal
binder, sawdust). The material taken up must be disposed of in accordance with
regulations.

6.4 Reference to other sections

For personal protection see section 8.

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SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling

Advice on safe handling Wear personal protective equipment.
Avoid contact with skin and eyes.
Advice on protection against Normal measures for preventive fire protection.
fire and explosion Do not spray on a naked flame or any incandescent material.
Fire-fighting class B: Fires involving liquids or liquid containing substances. Also includes substances
which become liquid at elevated temperatures.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage areas Keep tightly closed in a dry and cool place.
and containers
Storage class (TRGS 510) 10-13: German Storage Class 10 to 13
Other data Stable at normal ambient temperature and pressure.

7.3 Specific end use(s)

Specific use(s) This information is not available.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters

COMPONENTS WITH WORKPLACE CONTROL PARAMETERS
National occupational exposure limits
No data available

EUROPEAN OCCUPATIONAL EXPOSURE LIMITS

No data available

Derived No Effect Level (DNEL)

No data available

Predicted No Effect Concentration (PNEC)

No data available

8.2 Exposure controls

PERSONAL PROTECTIVE EQUIPMENT

Respiratory protection No personal respiratory protective equipment normally required. In inadequately
ventilated areas, where workplace limits are exceeded, where unpleasant odours
exist or where aerosols are in use, or smoke and mist occur, use self-contained
breathing apparatus or breathing apparatus with a type A filter or appropriate
combined filter (e.g. where aerosols are in use, or smoke and mist occur, A-P2 or
ABEK-P2), in compliance with EN 141.
Hand protection The choice of an appropriate glove does not only depend on its material but also
on other quality features and is different from one producer to the other., Please
observe the instructions regarding permeability and breakthrough time which are

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provided by the supplier of the gloves. Also take into consideration the specific
local conditions under which the product is used, such as the danger of cuts,
abrasion, and the contact time., Be aware that in daily use the durability of a
chemical resistant protective glove can be notably shorter than the break through
time measured according to EN 374, due to the numerous outside influences (e.g.
temperature).

gloves suitable for permanent contact:

Material: butyl-rubber
Break through time: >= 480 min
Layer thickness: >= 0,7 mm

gloves suitable for splash protection:

Material: Nitrile rubber/nitrile latex
Break through time: >= 30 min
Layer thickness: >= 0,4 mm

Eye protection Tightly fitting safety goggles, Safety glasses with side-shields
Skin and body protection Wear suitable protective equipment.
Hygiene measures Avoid contact with the skin and the eyes. Handle in accordance with good
industrial hygiene and safety practice. Keep away from food, drink and animal
feedingstuffs. When using do not eat, drink or smoke.
Protective measures Avoid contact with the skin and the eyes. Wear suitable gloves and eye/face
protection.

ENVIRONMENTAL EXPOSURE CONTROLS

General advice Avoid subsoil penetration.
Do not flush into surface water or sanitary sewer system.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties

Physical state liquid; 20 °C; 1.013 hPa
Form liquid
Colour colourless
Odour mild
Odour Threshold No valid method available

pH 5 - 7; 20 g/l; 20 °C
Melting point/range < -10 °C
Boiling point/boiling range Not applicable
Flash point Not applicable
Evaporation rate No data available
Flammability (solid, gas) not applicable (liquid)

Lower explosion limit No data available

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Upper explosion limit No data available

Vapour pressure < 0,1 hPa; 20 °C
Relative vapour density No data available
Density ca.1,0 g/cm3; 20 °C
Relative density No data available
Water solubility 20 °C; completely miscible
Partition coefficient: n- Not relevant / not applicable
octanol/water Justification: surface-active substance
Ignition temperature ca. 360 °C; DIN 51794
Auto-ignition temperature not auto-flammable
Viscosity, dynamic ca. 130 mPas; 20 °C; Brookfield method
Explosive properties Constituents do not contain chemical groups associated with explosivity.
Oxidizing properties not expected based on structure and functional groups

9.2 Other data

None known.

SECTION 10: STABILITY AND REACTIVITY

10.1 Reactivity
Note Stable at normal ambient temperature and pressure.

10.2 Chemical stability

Note No decomposition if stored and applied as directed.

10.3 Possibility of hazardous reactions

Hazardous reactions None known.

10.4 Conditions to avoid

Conditions to avoid Direct heating, dirt, chemical contamination, sunlight, UV or ionising radiation.

10.5 Incompatible materials to avoid

Materials to avoid Strong acids and oxidizing agents;

10.6 Hazardous decomposition products

Hazardous decomposition No decomposition if stored and applied as directed.
products
Thermal decomposition Hazardous decomposition products formed under fire conditions.

SECTION 11: TOXICOLOGICAL INFORMATION

11.1 Information on toxicological effects

Acute toxicity

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Acute oral toxicity isotridecanol, ethoxylated (>= 2.5 EO):

LD50 Rat: > 300 - 2.000 mg/kg
own test results/literature values
Category approach
Harmful if swallowed.
Acute inhalation toxicity isotridecanol, ethoxylated (>= 2.5 EO):
No data available
Acute dermal toxicity isotridecanol, ethoxylated (>= 2.5 EO):
LD50 Rabbit: > 2.000 mg/kg;
(literature value)
Category approach
Based on available data, the classification criteria are not met.

Skin corrosion/irritation
Skin irritation isotridecanol, ethoxylated (>= 2.5 EO):
Rabbit: not irritating
own test results/literature values
Category approach
Based on available data, the classification criteria are not met.

Serious eye damage/eye irritation

Eye irritation isotridecanol, ethoxylated (>= 2.5 EO):
Rabbit: Irreversible effects on the eye
own test results/literature values
Category approach
Causes serious eye damage.

Respiratory or skin sensitisation

Sensitisation isotridecanol, ethoxylated (>= 2.5 EO):
Maximisation Test Guinea pig: not sensitizing
(literature value)
Category approach
Based on available data, the classification criteria are not met.

Germ cell mutagenicity

Genotoxicity in vitro isotridecanol, ethoxylated (>= 2.5 EO):
In vitro tests did not show mutagenic effects
own test results/literature values
Category approach
Genotoxicity in vivo isotridecanol, ethoxylated (>= 2.5 EO):
In vivo tests did not show mutagenic effects
(literature value)
Category approach
Remarks isotridecanol, ethoxylated (>= 2.5 EO):
Based on available data, the classification criteria are not met.

Carcinogenicity
Carcinogenicity isotridecanol, ethoxylated (>= 2.5 EO):
The substance has been shown to be not genotoxic, therefore it is not expected to
have a carcinogenic potential.
(literature value)
Category approach
Remarks isotridecanol, ethoxylated (>= 2.5 EO):
Based on available data, the classification criteria are not met.

Reproductive toxicity
Reproductive toxicity isotridecanol, ethoxylated (>= 2.5 EO):
Animal testing did not show any effects on fertility.
(literature value)
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Category approach
RemarksReproductive isotridecanol, ethoxylated (>= 2.5 EO):
toxicity Based on available data, the classification criteria are not met.
Teratogenicity isotridecanol, ethoxylated (>= 2.5 EO):
Did not show teratogenic effects in animal experiments.
(literature value)
Category approach
Remarks-Teratogenicity isotridecanol, ethoxylated (>= 2.5 EO):
Based on available data, the classification criteria are not met.

STOT - single exposure

Remarks isotridecanol, ethoxylated (>= 2.5 EO):
The substance or mixture is not classified as specific target organ toxicant, single
exposure.

STOT - repeated exposure

Remarks isotridecanol, ethoxylated (>= 2.5 EO):
The substance or mixture is not classified as specific target organ toxicant,
repeated exposure.
Repeated dose toxicity isotridecanol, ethoxylated (>= 2.5 EO):
Rat; Oral; 2 years
NOAEL: 50 mg/kg (based on body weight and day)
Target Organs: Heart, Liver, Kidney
Symptoms: reduced body weight gain, increased relative organ weights
(literature value)
Category approach

Aspiration hazard
Aspiration toxicity isotridecanol, ethoxylated (>= 2.5 EO):
Not applicable

Toxicological information isotridecanol, ethoxylated (>= 2.5 EO):

Toxicokinetics
The substance is expected to be rapidly absorbed and excreted.
(literature value)
Category approach

SECTION 12: ECOLOGICAL INFORMATION

12.1 Toxicity
Toxicity to fish isotridecanol, ethoxylated (>= 2.5 EO):
LC50 (96 h) Cyprinus carpio (Carp): > 1 mg/l ; flow-through test; OECD Test
Guideline 203
own test results/literature values
Category approach
Toxicity to daphnia and other isotridecanol, ethoxylated (>= 2.5 EO):
aquatic invertebrates EC50 (48 h) Daphnia magna (Water flea): > 1 - 10 mg/l ; static test; OECD Test
Guideline 202
own test results/literature values
Category approach
Toxicity to daphnia and other isotridecanol, ethoxylated (>= 2.5 EO):
aquatic invertebrates - Chronic EC10 (21 d) Daphnia magna (Water flea): 2,6 mg/l; reproduction rate; semi-static
test; OECD Test Guideline 211; own test results/literature values

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toxicity Category approach

Toxicity to aquatic plants isotridecanol, ethoxylated (>= 2.5 EO):
EC50 (72 h) Desmodesmus subspicatus (green algae): > 1 mg/l ; static test;
OECD Test Guideline 201; own test results/literature values
Category approach
isotridecanol, ethoxylated (>= 2.5 EO):
EC10 (72 h) Desmodesmus subspicatus (green algae): > 1 - 10 mg/l ; static test;
OECD Test Guideline 201; own test results/literature values
Category approach
Toxicity to bacteria isotridecanol, ethoxylated (>= 2.5 EO):
EC50 activated sludge: 140 mg/l; Respiration inhibition
(literature value)
Category approach
Toxicity to soil dwelling isotridecanol, ethoxylated (>= 2.5 EO):
organisms NOEC Eisenia foetida: 220 mg/kg; reproduction rate; artificial soil
(literature value)
Category approach
Toxicity to terrestrial flora isotridecanol, ethoxylated (>= 2.5 EO):
emergence, growth; NOEC: 10 mg/kg; Lepidium sativum (cress); OECD Test
Guideline 208
own test results/literature values
Category approach
Toxicity for other terrestrial isotridecanol, ethoxylated (>= 2.5 EO):
non-mammalian fauna No data available

12.2 Persistence and degradability

Biodegradability isotridecanol, ethoxylated (>= 2.5 EO):
Readily biodegradable.; > 60 %; 28 d; aerobic; OECD Test Guideline 301B
own test results/literature values
Category approach
isotridecanol, ethoxylated (>= 2.5 EO):
Biodegradable; > 60 %; 60 d; anaerobic; OECD 311 or equivalent test method
own test results/literature values
Category approach

12.3 Bioaccumulative potential

Bioaccumulation isotridecanol, ethoxylated (>= 2.5 EO):
Bioaccumulation is unlikely.
(literature value)

12.4 Mobility in soil

Mobility isotridecanol, ethoxylated (>= 2.5 EO):
Koc: > 5000
immobile
strong adsorption to soil
(literature value)

12.5 Results of PBT and vPvB assessment

Results of PBT assessment This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative
(vPvB) at levels of 0.1% or higher.
Results of PBT assessment isotridecanol, ethoxylated (>= 2.5 EO):
Based on available data, the classification criteria are not met.

12.6 Other adverse effects

General advice isotridecanol, ethoxylated (>= 2.5 EO):
None known.

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SECTION 13: DISPOSAL CONSIDERATIONS

13.1 Waste treatment methods

Product Can be incinerated, when in compliance with local regulations.
waste code of the European A waste code in accordance with the European Waste Catalogue (EWC) may not
Union: EWC be assigned to this product since it admits of a classification only when the
consumer uses it for some purpose. The waste code must be determined in
agreement with the regional waste disposal authority or company.

SECTION 14: TRANSPORT INFORMATION

14.1 UN number
ADR Not dangerous goods
RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
ICAO/IATA Not dangerous goods

14.2 Proper shipping name

ADR Not dangerous goods
RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
ICAO/IATA Not dangerous goods

14.3 Transport hazard class

ADR Not dangerous goods
RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
ICAO/IATA Not dangerous goods

14.4 Packing group

ADR Not dangerous goods
RID Not dangerous goods
ADN Not dangerous goods
IMDG Not dangerous goods
ICAO/IATA Not dangerous goods

14.5 Environmental hazards

ADR Environmentally hazardous no
RID Environmentally hazardous no
ADN Environmentally hazardous no
IMDG Marine pollutant no

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ICAO/IATA Environmentally hazardous no

14.6 Special precautions for user

Not classified as dangerous in the meaning of transport regulations.

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Remarks No information available.

SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Occupational restrictions Employment restrictions for children and young workers in accordance with
Directive 94/33/EC and the respective national provisions are to be observed.

NATIONAL/OTHER REGULATIONS
Legislation on the control of Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on
major-accident hazards the control of major-accident hazards involving dangerous substances.
involving dangerous
substances list entry in the directive:: Not applicable

Other regulations The surfactant(s) contained in this preparation complies (comply) with the
biodegradability criteria as laid down in Regulation (EC) No.648/2004 on
detergents. Data to support this assertion are held at the disposal of the competent
authorities of the Member States and will be made available to them, at their direct
request or at the request of a detergent manufacturer.

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NOTIFICATION STATUS
Switzerland. Consolidated Inventory CH INV listed (product or constituents
are listed)
US. Toxic Substances Control Act TSCA listed (product or constituents
are listed)
Canada. Canadian Environmental Protection Act (CEPA). DSL listed (product or constituents
Domestic Substances List (DSL) are listed)
Australia. Industrial Chemical (Notification and Assessment) Act AICS listed (product or constituents
are listed)
Japan. Kashin-Hou Law List ENCS (JP) listed (product or constituents
are listed)
Japan. Industrial Safety & Health Law (ISHL) List ISHL (JP) listed (product or constituents
are listed)
Korea. Existing Chemicals Inventory (KECI) KECI (KR) listed (product or constituents
are listed)
Philippines. The Toxic Substances and Hazardous and Nuclear PICCS (PH) listed (product or constituents
Waste Control Act are listed)
China. Inventory of Existing Chemical Substances INV (CN) listed (product or constituents
are listed)

Please note: the names and CAS numbers which are used for this product in the stated inventories may deviate from
the information which is listed in chapter 3.

15.2 Chemical safety assessment

Isotridecanol,ethoxylated (CAS#: 69011-36-5)

A Chemical Safety Assessment is not required for this substance (exempted from obligation to register).

SECTION 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3.

H302 Harmful if swallowed.
H318 Causes serious eye damage.

Safety datasheet sections which have been updated:

2. Hazards identification
15. Regulatory information

Further information: The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information
given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or
quality specification. The information relates only to the specific material
designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
This safety datasheet only contains information relating to safety and does not

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replace any product information or product specification.

Key or legend to abbreviations and acronyms used in the safety data sheet

ADN Accord européen relatif au transport international des marchandises dangereuses par voie de navigation intérieure
ADR Accord européen relatif au transport international des marchandises Dangereuses par Route
AICS Australian Inventory of Chemical Substances
ANSI American National Standards Institute
ASTM American Society of Testing and Materials (US)
BCF Bioconcentration factor
CLP Regulation on Classification, Labelling and Packaging of Substances and Mixtures
DIN Deutsches Institut für Normung
DNEL Derived No-Effect Level
DSL Domestic Substances List
EC… Effect concentration ... %
ENCS Existing Notified Chemical Substances (Japan)
EWC European Waste Catalogue
IATA International Air Transport Association
IBC Intermediate Bulk Container
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods
IMO International Maritime Organization
ISHL Industrial Safety and Health Law (Japan)
ISO International Organization for Standardization
IUAPC International Union of Pure and Applied Chemistry
KECI Korea Existing Chemicals Inventory
LC… Lethal Concentration, ...%
LD… Lethal Dose, ...%
MARPOL International Convention for the Prevention of Pollution From Ships
NDSL Non-Domestic Substances List
NOAEL no observable adverse effect level
NOEL/NOEC No Observed-effect level/concentration
NZIoC New Zealand Inventory of Chemicals
OECD Organisation for Economic Co-operation and Development
PBT persistent, bioaccumulative, toxic
PICCS Philippine Inventory of Chemicals and Chemical Substances
PNEC Predicted No-Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals
RID Règlement concernant le transport international ferroviaire de marchandises dangereuses
TG Test Guideline
TRGS Technische Regeln für Gefahrstoffe
TSCA Toxic Substances Control Act
vPvB very persistent, very bioaccumulative
WGK Wassergefährdungsklasse

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