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Safety Data Sheet: Section 1. Identification

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Akzo Nobel Coatings, Inc.

SAFETY DATA SHEET


High Solids Epoxy Fuel Tank Primer 10P30-1

Section 1. Identification

GHS product identifier : High Solids Epoxy Fuel Tank Primer 10P30-1
Other means of identification : 10P30-1_Integral Fuel Tank Primer

Relevant identified uses of the substance or mixture and uses advised against
: FOR INDUSTRIAL USE ONLY

Supplier/Manufacturer : Akzo Nobel Coatings, Inc.


1 East Water Street
Waukegan, IL 60085
USA
Tel. 1 847 623 4200
Email: customer.
service@akzonobel.com
Canadian Supplier : Akzo Nobel Coatings Ltd.
110 Woodbine Downs Blvd.
Unit #4 Etobicoke, Ontario
Canada M9W 5S6
+1 (800) 618-1010

Emergency telephone number : CHEMTREC +1 (800) 424-9300 (Inside the US)


CHEMTREC International +1 (703) 527-3887 (Outside the US, collect calls
accepted)
Date of issue / Date of revision : 6 August 2020
Safety Data Sheet Version : 4.01
Date of printing : 6 August 2020
Akzo Nobel Coatings Inc. encourages and expects you to read and understand this entire MSDS, as there is important information
throughout the document. Further, Akzo Nobel Coatings Inc. expects you to follow the precautions identified in this document unless
your use conditions would necessitate other appropriate methods or actions.

To promote safe handling, each customer or recipient should: 1) Notify its employees, agents, contractors, and others whom it knows
or believes will use this material of the information contained in this MSDS and any other information regarding hazards and safety; 2)
Furnish this same information to each of its customers for the product; 3) Request its customers to notify their employees, customers,
and other users of the product of this information; and 4) Notify its employees, agents, contractors, and others that the precautions
identified for this product and any other products with which mixtures may be created are transferable and cumulative to the mixture.

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 1A
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (lungs) - Category 1

For additional information call Akzo Nobel at (847) 625-4200


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Section 2. Hazards identification


GHS label elements
Hazard pictograms :

Signal word : Danger


Hazard statements : Highly flammable liquid and vapor.
Causes serious eye irritation.
Causes skin irritation.
May cause cancer.
Causes damage to organs through prolonged or repeated exposure. (lungs)
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Ground/bond container and receiving equipment.
Keep container tightly closed. Do not breathe vapor. Do not eat, drink or smoke when
using this product. Wash hands thoroughly after handling.
Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical
attention. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse
skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off
contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical
attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists:
Get medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture

Ingredient name % CAS number


crystalline silica, respirable powder 20 - 25 14808-60-7
heptan-2-one 15 - 20 110-43-0
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin 15 - 20 25068-38-6
Methyl isobutyl ketone 10 - 15 108-10-1
titanium dioxide 5 - 10 13463-67-7
Mica-group minerals 5 - 10 12001-26-2
C.I. Pigment Yellow 36 1-5 37300-23-5
strontium chromate 1-5 7789-06-2
crystalline silica, respirable powder 0-1 14808-60-7
barium chromate 0-1 10294-40-3

For additional information call Akzo Nobel at (847) 625-4200


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Section 3. Composition/information on ingredients


ethylbenzene 0-1 100-41-4
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention. If
unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Wash contaminated clothing thoroughly with water before removing it, or wear
gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. Never give
anything by mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open airway. Loosen tight
clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

For additional information call Akzo Nobel at (847) 625-4200


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Section 4. First aid measures

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large
quantities have been ingested or inhaled.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. Runoff to sewer
may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
halogenated compounds
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

For additional information call Akzo Nobel at (847) 625-4200


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Section 6. Accidental release measures

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not breathe
vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and drink.
Store locked up. Eliminate all ignition sources. Separate from oxidizing materials.
Keep container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.

For additional information call Akzo Nobel at (847) 625-4200


To request an updated SDS please visit http://www.formstack.com/forms/AkzoNobel-document_request_form
International Paint LLC

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Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
crystalline silica, respirable powder OSHA PEL Z3 (United States, 6/2016).
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:
Respirable
TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:
Respirable
OSHA PEL (United States, 6/2016).
TWA: 50 µg/m³ 8 hours. Form: Respirable
dust
ACGIH TLV (United States, 3/2016).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable fraction
NIOSH REL (United States, 10/2016).
TWA: 0.05 mg/m³ 10 hours. Form: respirable
dust
heptan-2-one ACGIH TLV (United States, 3/2016).
TWA: 50 ppm 8 hours.
TWA: 233 mg/m³ 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 100 ppm 10 hours.
TWA: 465 mg/m³ 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 100 ppm 8 hours.
TWA: 465 mg/m³ 8 hours.
reaction product: bisphenol-A-(epichlorhydrin); epoxy resin None.
Methyl isobutyl ketone ACGIH TLV (United States, 3/2018).
STEL: 75 ppm 15 minutes.
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2016).
STEL: 300 mg/m³ 15 minutes.
STEL: 75 ppm 15 minutes.
TWA: 205 mg/m³ 10 hours.
TWA: 50 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 410 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
titanium dioxide OSHA PEL (United States, 6/2016).
TWA: 15 mg/m³ 8 hours. Form: Total dust
ACGIH TLV (United States, 3/2016).
TWA: 10 mg/m³ 8 hours.
Mica-group minerals ACGIH TLV (United States, 3/2016).
TWA: 3 mg/m³ 8 hours. Form: Respirable
fraction
NIOSH REL (United States, 10/2016).
TWA: 3 mg/m³ 10 hours. Form: Respirable
fraction
OSHA PEL Z3 (United States, 6/2016).
TWA: 20 mppcf 8 hours.

For additional information call Akzo Nobel at (847) 625-4200


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Section 8. Exposure controls/personal protection


C.I. Pigment Yellow 36 OSHA PEL (United States, 6/2016).
TWA: 0.005 mg/m³, (as Cr) 8 hours.
OSHA PEL Z2 (United States, 2/2013).
CEIL: 1 mg/10m³
NIOSH REL (United States, 10/2016).
TWA: 0.0002 mg/m³, (as CR) 8 hours.
ACGIH TLV (United States, 3/2016).
TWA: 0.01 mg/m³, (measured as Cr) 8 hours.
strontium chromate ACGIH TLV (United States, 3/2016).
TWA: 0.0005 mg/m³, (measured as Cr) 8
hours.
OSHA PEL Z2 (United States, 2/2013).
CEIL: 1 mg/10m³
OSHA PEL (United States, 6/2016).
TWA: 0.005 mg/m³, (as Cr) 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 0.0002 mg/m³, (as CR) 8 hours.
crystalline silica, respirable powder OSHA PEL Z3 (United States, 6/2016).
TWA: 250 mppcf / (%SiO2+5) 8 hours. Form:
Respirable
TWA: 10 mg/m³ / (%SiO2+2) 8 hours. Form:
Respirable
OSHA PEL (United States, 6/2016).
TWA: 50 µg/m³ 8 hours. Form: Respirable
dust
ACGIH TLV (United States, 3/2016).
TWA: 0.025 mg/m³ 8 hours. Form:
Respirable fraction
NIOSH REL (United States, 10/2016).
TWA: 0.05 mg/m³ 10 hours. Form: respirable
dust
barium chromate OSHA PEL Z2 (United States, 2/2013).
CEIL: 1 mg/10m³
ACGIH TLV (United States, 3/2016).
TWA: 0.01 mg/m³, (measured as Cr) 8 hours.
Form: Insoluble
OSHA PEL (United States, 6/2016).
TWA: 0.005 mg/m³, (as Cr) 8 hours.
NIOSH REL (United States, 10/2016).
TWA: 0.0002 mg/m³, (as CR) 8 hours.
ethylbenzene ACGIH TLV (United States, 3/2017).
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2016).
STEL: 545 mg/m³ 15 minutes.
STEL: 125 ppm 15 minutes.
TWA: 435 mg/m³ 10 hours.
TWA: 100 ppm 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 435 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.

For additional information call Akzo Nobel at (847) 625-4200


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Section 8. Exposure controls/personal protection


Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
controls or other engineering controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Yellow.
Odor : Solvent.
Odor threshold : Not available.
pH : Not available.

For additional information call Akzo Nobel at (847) 625-4200


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Section 9. Physical and chemical properties


Melting/freezing point : Not available.
Boiling point : 117°C (242.6°F)
boiling range : Not available.
Flash point : Closed cup: 16°C (60.8°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Upper/lower flammability or explosive limits
Upper: : Not determined.
Lower: : Not determined.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 1.355
Density : 11.31 lbs/gal 1.355 g/cm³
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): 0.3 cm2/s (30 cSt)

Weight Volatiles : 29.77% (w/w)


Volume Volatiles : 49.80 %(v/v)
Weight Solids : 70.23 %(w/w)
Volume Solids : 50.2 %(v/v)
Regulatory VOC : 3.4 lbs/gal 403 g/l minus water and exempt solvents
VOC Actual : 3.4 lbs/gal 403 g/l

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Reactive or incompatible with the following materials:


oxidizing materials

For additional information call Akzo Nobel at (847) 625-4200


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Section 10. Stability and reactivity


Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
heptan-2-one LD50 Oral Rat 1600 mg/kg -
Methyl isobutyl ketone LD50 Oral Rat 2080 mg/kg -
C.I. Pigment Yellow 36 LD50 Oral Rat 640 mg/kg -
strontium chromate LD50 Oral Rat 3118 mg/kg -
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
heptan-2-one Skin - Mild irritant Rabbit - 24 hours 14 -
milligrams
reaction product: bisphenol- Eyes - Mild irritant Rabbit - 100 -
A-(epichlorhydrin); epoxy milligrams
resin
Skin - Moderate irritant Rabbit - 24 hours 500 -
microliters
Skin - Severe irritant Rabbit - 24 hours 2 -
milligrams
Methyl isobutyl ketone Eyes - Moderate irritant Rabbit - 24 hours 100 -
microliters
Eyes - Severe irritant Rabbit - 40 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
titanium dioxide Skin - Mild irritant Human - 72 hours 300 -
Micrograms
Intermittent
ethylbenzene Eyes - Severe irritant Rabbit - 500 -
milligrams
Skin - Mild irritant Rabbit - 24 hours 15 -
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification

For additional information call Akzo Nobel at (847) 625-4200


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Section 11. Toxicological information


Product/ingredient name OSHA IARC NTP
crystalline silica, respirable - 1 Known to be a human carcinogen.
powder
Methyl isobutyl ketone - 2B -
titanium dioxide - 2B -
C.I. Pigment Yellow 36 + 1 Known to be a human carcinogen.
strontium chromate + 1 Known to be a human carcinogen.
crystalline silica, respirable - 1 Known to be a human carcinogen.
powder
barium chromate + 1 Known to be a human carcinogen.
ethylbenzene - 2B -
Reproductive toxicity
Not available.
Teratogenicity
Not available.

Specific target organ toxicity (single exposure)


Not available.
Specific target organ toxicity (repeated exposure)
Name Category Route of Target organs
exposure
crystalline silica, respirable powder Category 1 Inhalation lungs
Aspiration hazard
Name Result
ethylbenzene ASPIRATION HAZARD - Category 1

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

For additional information call Akzo Nobel at (847) 625-4200


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Section 11. Toxicological information

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : Causes damage to organs through prolonged or repeated exposure.
Carcinogenicity : May cause cancer. Risk of cancer depends on duration and level of exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 2649.8 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
heptan-2-one Acute LC50 131000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Methyl isobutyl ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - 33 days
Embryo
ethylbenzene Acute EC50 4600 µg/l Fresh water Algae - Pseudokirchneriella 72 hours
subcapitata
Acute EC50 3600 µg/l Fresh water Algae - Pseudokirchneriella 96 hours
subcapitata
Acute EC50 2930 to 4400 µg/l Fresh Daphnia - Daphnia magna - 48 hours
water Neonate
Acute LC50 40000 µg/l Marine water Crustaceans - Cancer magister - 48 hours
Zoea
Acute LC50 4200 µg/l Fresh water Fish - Oncorhynchus mykiss 96 hours

For additional information call Akzo Nobel at (847) 625-4200


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Section 12. Ecological information


Persistence and degradability
Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
heptan-2-one 2.26 - low
reaction product: bisphenol-A- 2.64 to 3.78 31 low
(epichlorhydrin); epoxy resin
Methyl isobutyl ketone 1.9 - low
ethylbenzene 3.6 - low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.

Section 14. Transport information

Special precautions for user : Please Note: The information provided in section 14 is based on a bulk package
shipment via ground transport in North America. All shippers are responsible for
ensuring the proper transportation classification and package/container requirements
are followed for the relevant mode of transport.
Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

For additional information call Akzo Nobel at (847) 625-4200


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Section 14. Transport information


DOT TDG Mexico IMDG IATA
Classification Classification Classification
UN number UN1263 UN1263 UN1263 UN1263 UN1263

UN proper PAINT PAINT PAINT PAINT PAINT


shipping name
Transport 3 3 3 3 3
hazard class(es)

Packing group II II II II II
Environmental No. Yes. No. Yes. No.
hazards

Section 15. Regulatory information


U.S. Federal regulations

Regulatory Information : The zinc tetraoxy chromate in this product is identified in the EU by CAS number
49663-84-5 and EC number 256-418-0.

United States inventory (TSCA 8b): All components are listed or exempted.

SARA 311/312
Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
SARA 313
Product name CAS number %
Form R - Reporting Methyl isobutyl ketone 108-10-1 10 - 15
requirements C.I. Pigment Yellow 36 37300-23-5 1-5
strontium chromate 7789-06-2 1-5
barium chromate 10294-40-3 0.1 - 1
ethylbenzene 100-41-4 0.1 - 1
lead 7439-92-1 0.00
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.

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Section 15. Regulatory information


Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
crystalline silica, respirable powder Yes. No. No. No.
Methyl isobutyl ketone Yes. No. No. No.
titanium dioxide Yes. No. No. No.
C.I. Pigment Yellow 36 No. Yes. No. No.
strontium chromate Yes. Yes. No. No.
barium chromate Yes. Yes. No. No.
ethylbenzene Yes. No. No. No.
toluene No. Yes. No. 7000 µg/day
(ingestion)
phenyl glycidyl ether Yes. No. Yes. No.
lead Yes. Yes. No. Yes.
Cadmium (Non-pyrophoric) Yes. Yes. 0.05 µg/day 4.1 µg/day
(inhalation) (ingestion)

International lists
National inventory
Australia : At least one component is not listed.
Canada : At least one component is not listed.
China : All components are listed or exempted.
Europe : All components are listed or exempted.
Japan : Japan inventory (ENCS): At least one component is not listed.
Japan inventory (ISHL): At least one component is not listed.
Malaysia : At least one component is not listed.
New Zealand : At least one component is not listed.
Philippines : At least one component is not listed.
Republic of Korea : At least one component is not listed.
Taiwan : All components are listed or exempted.
Turkey : At least one component is not listed.

Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 2

Flammability 3
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or
products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be
used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American
Coatings Association, Inc.

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Section 16. Other information


The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal
Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

National Fire Protection Association (U.S.A.)

3 Flammability
Health 2 0 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response
Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete
and official position of the National Fire Protection Association, on the referenced subject which is represented only by
the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals.
The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325,
which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704
systems to classify chemicals does so at their own risk.

History
Date of issue/Date of revision : 6 August 2020
Version : 4.01
MSDS # : 002988 0010 001B5A4220
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier,
nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information
contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards that exist.

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Akzo Nobel Coatings, Inc.

SAFETY DATA SHEET


High Solids Epoxy Primer Fuel Tank Primer EC-242

Section 1. Identification

GHS product identifier : High Solids Epoxy Primer Fuel Tank Primer EC-242
Other means of identification : EC-242_INTEGRAL FUEL TANK PRIMER ACTIVATOR

Relevant identified uses of the substance or mixture and uses advised against
: FOR INDUSTRIAL USE ONLY

Supplier/Manufacturer : Akzo Nobel Coatings, Inc.


1 East Water Street
Waukegan, IL 60085
USA
Tel. 1 847 623 4200
Email: customer.
service@akzonobel.com
Canadian Supplier : Akzo Nobel Coatings Ltd.
110 Woodbine Downs Blvd.
Unit #4 Etobicoke, Ontario
Canada M9W 5S6
+1 (800) 618-1010

Emergency telephone number : CHEMTREC +1 (800) 424-9300 (Inside the US)


CHEMTREC International +1 (703) 527-3887 (Outside the US, collect calls
accepted)
Date of issue / Date of revision : 7 July 2021
Safety Data Sheet Version : 5.12
Date of printing : 7 July 2021
Akzo Nobel Coatings Inc. encourages and expects you to read and understand this entire MSDS, as there is important information
throughout the document. Further, Akzo Nobel Coatings Inc. expects you to follow the precautions identified in this document unless
your use conditions would necessitate other appropriate methods or actions.

To promote safe handling, each customer or recipient should: 1) Notify its employees, agents, contractors, and others whom it knows
or believes will use this material of the information contained in this MSDS and any other information regarding hazards and safety; 2)
Furnish this same information to each of its customers for the product; 3) Request its customers to notify their employees, customers,
and other users of the product of this information; and 4) Notify its employees, agents, contractors, and others that the precautions
identified for this product and any other products with which mixtures may be created are transferable and cumulative to the mixture.

Section 2. Hazards identification


OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 2
substance or mixture ACUTE TOXICITY (oral) - Category 4
SKIN IRRITATION - Category 2
EYE IRRITATION - Category 2A
CARCINOGENICITY - Category 2

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Section 2. Hazards identification


GHS label elements
Hazard pictograms :

Signal word : Danger


Hazard statements : Highly flammable liquid and vapor.
Harmful if swallowed.
Causes serious eye irritation.
Causes skin irritation.
Suspected of causing cancer.
Precautionary statements
Prevention : Obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Wear protective gloves. Wear eye or face protection.
Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and
other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting
and all material-handling equipment. Use only non-sparking tools. Take precautionary
measures against static discharge. Ground/bond container and receiving equipment.
Keep container tightly closed. Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Response : IF exposed or concerned: Get medical attention. IF SWALLOWED: Call a POISON
CENTER or physician if you feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN:
Wash with plenty of soap and water. Take off contaminated clothing and wash it before
reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing. If eye irritation persists: Get medical attention.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

Section 3. Composition/information on ingredients


Substance/mixture : Mixture

Ingredient name % CAS number


toluene 15 - 20 108-88-3
benzyl alcohol 15 - 20 100-51-6
Methyl isobutyl ketone 10 - 15 108-10-1
N-(3-(trimethoxysilyl)propyl)ethylenediamine 5 - 10 1760-24-3
2-piperazin-1-ylethylamine 5 - 10 140-31-8
Isopropyl alcohol 5 - 10 67-63-0
bisphenol A 5 - 10 80-05-7
2,4,6-tris(dimethylaminomethyl)phenol 1-5 90-72-2
4-nonylphenol, branched 1-5 84852-15-3
benzyldimethylamine 1-5 103-83-3

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Section 3. Composition/information on ingredients


3,6,9-triazaundecamethylenediamine 1-5 112-57-2
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures


Description of necessary first aid measures
Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10
minutes. Get medical attention.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation. Get medical attention. If
unconscious, place in recovery position and get medical attention immediately.
Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and
shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing
before reuse. Clean shoes thoroughly before reuse.
Ingestion : Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and
keep at rest in a position comfortable for breathing. If material has been swallowed and
the exposed person is conscious, give small quantities of water to drink. Stop if the
exposed person feels sick as vomiting may be dangerous. Do not induce vomiting
unless directed to do so by medical personnel. If vomiting occurs, the head should be
kept low so that vomit does not enter the lungs. Get medical attention. If necessary,
call a poison center or physician. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt
or waistband.

Most important symptoms/effects, acute and delayed


Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : Harmful if swallowed.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.

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Section 4. First aid measures


Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Indication of immediate medical attention and special treatment needed, if necessary


Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may
be dangerous to the person providing aid to give mouth-to-mouth resuscitation.

See toxicological information (Section 11)

Section 5. Fire-fighting measures


Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam.
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Highly flammable liquid and vapor. In a fire or if heated, a pressure increase will occur
from the chemical and the container may burst, with the risk of a subsequent explosion. Runoff to sewer
may create fire or explosion hazard.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
metal oxide/oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures


Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.

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Section 6. Accidental release measures


For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).

Methods and materials for containment and cleaning up


Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.

Section 7. Handling and storage


Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Avoid exposure -
obtain special instructions before use. Do not handle until all safety precautions have
been read and understood. Do not get in eyes or on skin or clothing. Do not ingest.
Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Do not enter storage areas and confined
spaces unless adequately ventilated. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed when not in use. Store
and use away from heat, sparks, open flame or any other ignition source. Use
explosion-proof electrical (ventilating, lighting and material handling) equipment. Use
only non-sparking tools. Take precautionary measures against electrostatic discharges.
Empty containers retain product residue and can be hazardous. Do not reuse container.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in original container protected from direct sunlight in a dry, cool and well-
incompatibilities ventilated area, away from incompatible materials (see Section 10) and food and drink.
Store locked up. Eliminate all ignition sources. Separate from oxidizing materials.
Keep container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in
unlabeled containers. Use appropriate containment to avoid environmental
contamination.

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Section 8. Exposure controls/personal protection


Control parameters
Occupational exposure limits
Ingredient name Exposure limits
toluene NIOSH REL (United States, 10/2016).
STEL: 560 mg/m³ 15 minutes.
STEL: 150 ppm 15 minutes.
TWA: 375 mg/m³ 10 hours.
TWA: 100 ppm 10 hours.
OSHA PEL Z2 (United States, 2/2013).
AMP: 500 ppm 10 minutes.
CEIL: 300 ppm
TWA: 200 ppm 8 hours.
ACGIH TLV (United States, 3/2016).
TWA: 20 ppm 8 hours.
benzyl alcohol AIHA WEEL (United States, 10/2011).
TWA: 10 ppm 8 hours.
Methyl isobutyl ketone ACGIH TLV (United States, 3/2018).
STEL: 75 ppm 15 minutes.
TWA: 20 ppm 8 hours.
NIOSH REL (United States, 10/2016).
STEL: 300 mg/m³ 15 minutes.
STEL: 75 ppm 15 minutes.
TWA: 205 mg/m³ 10 hours.
TWA: 50 ppm 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 410 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
N-(3-(trimethoxysilyl)propyl)ethylenediamine None.
2-piperazin-1-ylethylamine None.
Isopropyl alcohol ACGIH TLV (United States, 3/2016).
STEL: 400 ppm 15 minutes.
TWA: 200 ppm 8 hours.
NIOSH REL (United States, 10/2016).
STEL: 1225 mg/m³ 15 minutes.
STEL: 500 ppm 15 minutes.
TWA: 980 mg/m³ 10 hours.
TWA: 400 ppm 10 hours.
OSHA PEL (United States, 6/2016).
TWA: 980 mg/m³ 8 hours.
TWA: 400 ppm 8 hours.
bisphenol A None.
2,4,6-tris(dimethylaminomethyl)phenol None.
4-nonylphenol, branched None.
benzyldimethylamine None.
3,6,9-triazaundecamethylenediamine AIHA WEEL (United States, 10/2011).
Absorbed through skin. Skin sensitizer.
TWA: 5 mg/m³ 8 hours.

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Section 8. Exposure controls/personal protection


Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation
controls or other engineering controls to keep worker exposure to airborne contaminants below
any recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures


Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product. When there is a risk of ignition from static electricity, wear anti-
static protective clothing. For the greatest protection from static discharges, clothing
should include anti-static overalls, boots and gloves.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties


Appearance
Physical state : Liquid.
Color : Yellow to red.
Odor : Pungent.
Odor threshold : Not available.
pH : Not available.
Melting/freezing point : Not available.

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Section 9. Physical and chemical properties


Boiling point : 83°C (181.4°F)
boiling range : Not available.
Flash point : Closed cup: 4°C (39.2°F)
Evaporation rate : Not available.
Flammability (solid, gas) : Not available.
Upper/lower flammability or explosive limits
Upper: : Not determined.
Lower: : Not determined.
Vapor pressure : Not available.
Vapor density : Not available.
Relative density : 0.946
Density : 7.89 lbs/gal 0.946 g/cm³
Solubility : Not available.
Solubility in water : Not available.
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Kinematic (room temperature): 0.42 cm2/s (42 cSt)

Weight Volatiles : 53.8% (w/w)


Volume Volatiles : 57.79 %(v/v)
Weight Solids : 46.20 %(w/w)
Volume Solids : 42.21 %(v/v)
Regulatory VOC : 4.2 lbs/gal 509 g/l minus water and exempt solvents
VOC Actual : 4.2 lbs/gal 509 g/l

Section 10. Stability and reactivity


Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.

Incompatible materials : Reactive or incompatible with the following materials:


oxidizing materials

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

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Section 11. Toxicological information


Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
toluene LD50 Oral Rat 636 mg/kg -
benzyl alcohol LC50 Inhalation Vapor Rat 1000 ppm 8 hours
LD50 Dermal Rabbit 2000 mg/kg -
LD50 Oral Rat 1230 mg/kg -
Methyl isobutyl ketone LD50 Oral Rat 2080 mg/kg -
N-(3-(trimethoxysilyl)propyl) LD50 Oral Rat 2413 mg/kg -
ethylenediamine
Isopropyl alcohol LD50 Dermal Rabbit 12800 mg/kg -
LD50 Oral Rat 5000 mg/kg -
bisphenol A LD50 Oral Rat 1200 mg/kg -
2,4,6-tris LD50 Dermal Rat 1280 mg/kg -
(dimethylaminomethyl)phenol
LD50 Oral Rat 1200 mg/kg -
4-nonylphenol, branched LD50 Oral Rat 1300 mg/kg -
benzyldimethylamine LD50 Dermal Rabbit 1660 mg/kg -
LD50 Oral Rat 265 mg/kg -
3,6, LD50 Oral Rat 3990 mg/kg -
9-triazaundecamethylenediamine

Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
toluene Eyes - Mild irritant Rabbit - 0.5 minutes -
100
milligrams
Eyes - Mild irritant Rabbit - 870 -
Micrograms
Eyes - Severe irritant Rabbit - 24 hours 2 -
milligrams
Skin - Mild irritant Pig - 24 hours 250 -
microliters
Skin - Mild irritant Rabbit - 435 -
milligrams
Skin - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Moderate irritant Rabbit - 500 -
milligrams
benzyl alcohol Skin - Mild irritant Man - 48 hours 16 -
milligrams
Skin - Moderate irritant Pig - 100 Percent -
Skin - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Methyl isobutyl ketone Eyes - Moderate irritant Rabbit - 24 hours 100 -
microliters
Eyes - Severe irritant Rabbit - 40 milligrams -
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
N-(3-(trimethoxysilyl)propyl) Eyes - Severe irritant Rabbit - 15 milligrams -
ethylenediamine
Skin - Mild irritant Rabbit - 500 -

For additional information call Akzo Nobel at (847) 625-4200


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Section 11. Toxicological information


milligrams
2-piperazin-1-ylethylamine Eyes - Moderate irritant Rabbit - 24 hours 20 -
milligrams
Skin - Severe irritant Rabbit - 24 hours 5 -
milligrams
Isopropyl alcohol Eyes - Moderate irritant Rabbit - 24 hours 100 -
milligrams
Eyes - Moderate irritant Rabbit - 10 milligrams -
Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Mild irritant Rabbit - 500 -
milligrams
bisphenol A Eyes - Severe irritant Rabbit - 24 hours 250 -
Micrograms
Skin - Mild irritant Rabbit - 24 hours 500 -
milligrams
Skin - Mild irritant Rabbit - 250 -
milligrams
2,4,6-tris Eyes - Severe irritant Rabbit - 24 hours 50 -
(dimethylaminomethyl)phenol Micrograms
Skin - Mild irritant Rat - 0.025 -
Mililiters
Skin - Severe irritant Rat - 0.25 Mililiters -
Skin - Severe irritant Rabbit - 24 hours 2 -
milligrams
4-nonylphenol, branched Eyes - Severe irritant Rabbit - 100 -
milligrams
Skin - Severe irritant Rabbit - 24 hours 500 -
milligrams
benzyldimethylamine Eyes - Severe irritant Rabbit - 5 milligrams -
Skin - Severe irritant Rabbit - 4 hours 500 -
milligrams
3,6, Eyes - Moderate irritant Rabbit - 24 hours 100 -
9-triazaundecamethylenediamine milligrams
Eyes - Moderate irritant Rabbit - 5 milligrams -
Skin - Severe irritant Rabbit - 24 hours 5 -
milligrams
Skin - Severe irritant Rabbit - 495 -
milligrams
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Classification

For additional information call Akzo Nobel at (847) 625-4200


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Section 11. Toxicological information


Product/ingredient name OSHA IARC NTP
toluene - 3 -
Methyl isobutyl ketone - 2B -
Isopropyl alcohol - 3 -
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Not available.
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

Information on the likely : Not available.


routes of exposure
Potential acute health effects
Eye contact : Causes serious eye irritation.
Inhalation : No known significant effects or critical hazards.
Skin contact : Causes skin irritation.
Ingestion : Harmful if swallowed.

Symptoms related to the physical, chemical and toxicological characteristics


Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : No specific data.
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects

For additional information call Akzo Nobel at (847) 625-4200


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Section 11. Toxicological information


Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : Suspected of causing cancer. Risk of cancer depends on duration and level of
exposure.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity


Acute toxicity estimates
Route ATE value
Oral 1160.1 mg/kg
Dermal 6681.6 mg/kg

Section 12. Ecological information


Toxicity
Product/ingredient name Result Species Exposure
benzyl alcohol Acute LC50 10000 µg/l Fresh water Fish - Lepomis macrochirus 96 hours
Methyl isobutyl ketone Acute LC50 505000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days
Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - 33 days
Embryo
2-piperazin-1-ylethylamine Acute LC50 2190000 µg/l Fresh water Fish - Pimephales promelas 96 hours
Isopropyl alcohol Acute EC50 10100 mg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 1400000 to 1950000 µg/l Crustaceans - Crangon crangon 48 hours
Marine water
Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours
bisphenol A Acute EC50 1000 µg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 1.506 mg/l Marine water Algae - Prorocentrum minimum - 72 hours
Exponential growth phase
Acute EC50 7.75 mg/l Fresh water Daphnia - Daphnia magna - 48 hours
Neonate
Acute LC50 1.34 mg/l Marine water Crustaceans - Americamysis 48 hours
bahia - Larvae
Acute LC50 3.5 mg/l Marine water Fish - Rivulus marmoratus - 96 hours
Embryo
Chronic NOEC 2 mg/l Fresh water Algae - Chlorolobion braunii - 4 days
Exponential growth phase
Chronic NOEC 10 µg/l Marine water Crustaceans - Tigriopus 21 days
japonicus - Nauplii
Chronic NOEC 30 µg/l Fresh water Daphnia - Daphnia magna - 21 days
Neonate

For additional information call Akzo Nobel at (847) 625-4200


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Section 12. Ecological information


Chronic NOEC 0.2 µg/l Fresh water Fish - Carassius auratus - Adult 90 days
4-nonylphenol, branched Acute EC50 0.03 mg/l Marine water Algae - Skeletonema costatum 72 hours
Acute EC50 0.027 mg/l Marine water Algae - Skeletonema costatum 96 hours
Acute EC50 137 to 160 µg/l Marine water Crustaceans - Eohaustorius 48 hours
estuarius - Adult
Acute LC50 17 µg/l Marine water Fish - Pleuronectes americanus - 96 hours
Larvae
Chronic EC10 0.012 mg/l Marine water Algae - Skeletonema costatum 96 hours
Chronic NOEC 5 µg/l Fresh water Crustaceans - Gammarus 21 days
fossarum - Adult
Chronic NOEC 7.4 µg/l Fresh water Fish - Pimephales promelas - 33 days
Embryo
benzyldimethylamine Acute LC50 37800 to 39900 µg/l Fresh Fish - Pimephales promelas 96 hours
water

Persistence and degradability


Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
toluene 2.73 90 low
benzyl alcohol 0.87 - low
Methyl isobutyl ketone 1.9 - low
2-piperazin-1-ylethylamine -1.48 - low
Isopropyl alcohol 0.05 - low
bisphenol A 3.4 20 to 67 low
2,4,6-tris 0.219 - low
(dimethylaminomethyl)phenol
4-nonylphenol, branched 5.4 740 high
benzyldimethylamine 1.98 6.2 to 22 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations


Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere

For additional information call Akzo Nobel at (847) 625-4200


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Section 13. Disposal considerations


inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.

Section 14. Transport information

Special precautions for user : Please Note: The information provided in section 14 is based on a bulk package
shipment via ground transport in North America. All shippers are responsible for
ensuring the proper transportation classification and package/container requirements
are followed for the relevant mode of transport.
Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

DOT TDG Mexico IMDG IATA


Classification Classification Classification
UN number UN3469 UN3469 UN3469 UN3469 UN3469

UN proper PAINT PAINT PAINT PAINT PAINT


shipping name RELATED RELATED RELATED RELATED RELATED
MATERIAL, MATERIAL, MATERIAL, MATERIAL, MATERIAL,
FLAMMABLE, FLAMMABLE, FLAMMABLE, FLAMMABLE, FLAMMABLE,
CORROSIVE CORROSIVE CORROSIVE CORROSIVE CORROSIVE
Transport 3 (8) 3 (8) 3 (8) 3 (8) 3 (8)
hazard class(es)

Packing group II II II II II
Environmental No. Yes. No. Yes. No.
hazards

Section 15. Regulatory information


U.S. Federal regulations

United States inventory (TSCA 8b): All components are listed or exempted.

SARA 311/312

For additional information call Akzo Nobel at (847) 625-4200


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Section 15. Regulatory information


Classification : Fire hazard
Immediate (acute) health hazard
Delayed (chronic) health hazard
SARA 313
Product name CAS number %
Form R - Reporting toluene 108-88-3 15 - 20
requirements Methyl isobutyl ketone 108-10-1 10 - 15
bisphenol A 80-05-7 5 - 10
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.

California Prop. 65
WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other
reproductive harm.
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
toluene No. Yes. No. 7000 µg/day
(ingestion)
Methyl isobutyl ketone Yes. No. No. No.
bisphenol A No. Yes. No. Yes.

International lists
National inventory
Australia : At least one component is not listed.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Europe : All components are listed or exempted.
Japan : Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): At least one component is not listed.
Malaysia : At least one component is not listed.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Republic of Korea : All components are listed or exempted.
Taiwan : All components are listed or exempted.
Turkey : At least one component is not listed.

For additional information call Akzo Nobel at (847) 625-4200


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Section 16. Other information


Hazardous Material Information System (U.S.A.)
Health * 3

Flammability 3
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on SDSs or
products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS® ratings are to be
used with a fully implemented HMIS® program. HMIS® is a registered trademark and service mark of the American
Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS® Personal
Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.

National Fire Protection Association (U.S.A.)

3 Flammability
Health 3 0 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response
Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete
and official position of the National Fire Protection Association, on the referenced subject which is represented only by
the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be
interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals.
The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325,
which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704
systems to classify chemicals does so at their own risk.

History
Date of issue/Date of revision : 7 July 2021
Version : 5.12
MSDS # : 004669 0005 002FBE4A40
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as
modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
Notice to reader

For additional information call Akzo Nobel at (847) 625-4200


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Section 16. Other information


To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier,
nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information
contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that
these are the only hazards that exist.

For additional information call Akzo Nobel at (847) 625-4200


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