CLASS X CHEMISTRY Solution-985617
CLASS X CHEMISTRY Solution-985617
CLASS X CHEMISTRY Solution-985617
Class 10 - Science
1. Reactions which produce energy are called exothermic reaction. On the other hand, reactions which absorb energy are called
endothermic reaction.
For example
N2 (g) + 3H2 (g) → 2NH3 (g) + heat
2. Combination reaction is reaction in which two elements or compounds combine to form a single compound. Example:
CaO(s) + H2O(l) ⟶ Ca(OH)2(aq) (Heat)
In the above reaction, heat energy is released. Therefore, it is an exothermic reaction also.
3. Exothermic reaction: A chemical reaction in which heat is given out is known as exothermic reaction. For example
C(s) + O2 (g) → CO2(g) + Heat energy
NaOH (aq) + HCl(aq) → NaCl(aq) + H2O(l) + Heat energy
Endothermic reaction: A chemical reaction in which heat energy is absorbed is known as endothermic reaction. For example
Heat
ii. Evolution of gas - When zinc metal reacts with dilute hydrochloric acid then hydrogen gas is evolved.
Zn (s) + 2HC l (aq) → ZnC l2 (s) + H2 (g) ↑
iii. Change in temperature - When quick lime reacts with water it produces slaked lime with the evolution of heat and the vessel
becomes hot.
C aO(s) + H O(l) → C a(OH ) (aq) +Heat
2 2
6. When oily food is exposed to air; the oil is oxidised by oxygen which results in a bad smell and bad taste of oily food. This
phenomenon is called rancidity. Some of the methods to prevent rancidity is:
i. By adding anti-oxidants
ii. Vacuum Packing
7. i. 2Mg (s) + O2 (g) → 2MgO (s) + Heat (Combination reaction)
Electricity
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2. Water acting as a reducing agent
2F2 + 2H2O → 4HF + O2
10. An ionic equation may be defined as An equation which shows only the atoms and ions that actually take part in the chemical
reaction.
For example,
1. Zn + 2H+ ⟶ Zn2+ + H2
2. Sodium chloride(aq) + silver nitrate(aq) ⟶ silver chloride(s) + sodium nitrate(aq)
Step 1: Write the equation and balance it if necessary
NaCl(aq) + AgNO3(aq) → AgCl(s) + NaNO3(aq)
Step 2: Split the ions. (Only compounds that are aqueous are split into ions.)
Na+(aq) + Cl-(aq) + Ag+(aq) + NO3-(aq) → AgCl(s) + Na+(aq) + NO3-
Step 3: Cancel out spectator ions. (Spectator ions are ions that remain the same in their original states before and after a chemical
reaction.)
ii. Electrolytic decomposition or electrolysis: Decomposition takes place by electricity. Example, electrolysis of aluminium
oxide.
2Al2 O3 ⟶ 4Al + 3O2
Aluminium oxide Aluminium Oxygen
ii.
iii. Slaked lime is formed with hissing sound and lot of heat is evolved.
Heat
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4) Precipitate formed : If a precipitate is formed in the reaction, it is denoted by a downward arrow
AgNO3(aq) + NaCl(aq) →AgCl(s) ↓+ NaNO3(aq)
15. Carbon dioxide (CO2) gas turns lime water milky when passed through it due to the formation of insoluble calcium carbonate.
C a(OH) 2 + C O2 → C aC O3 + H2 O
Limewater Carbon Calcium
diox ide C arbonate
16. Reactions in which ions are exchanged between two reactants forming new compounds are called double displacement reactions.
AB + CD → AC + BD
These are the reactions in which two different atoms or groups of atoms are displaced by another atoms/groups of atoms.
Example :
i. BaCl2(aq) + Na2SO4(aq) → BaSO4 (s)¯ + 2NaCl (aq)
ii. AgNO3 (aq) + NaCl (aq) → AgCl(s)¯ + NaNO3 (aq)
Such reactions usually occur in ionic compound and are very fast reactions.
17. i. The metal ‘X’ is copper and the process is called corrosion.
ii. Green coating formed is of basic copper carbonate (CuCO3. Cu(OH)2)
iii. To prevent the corrosion process painting and galvanization can be done.
18. i. In white washing, following reaction occurs:
CaO + H2O ⟶ Ca(OH)2 + Heat
In the above reaction, calcium oxide (quick lime) reacts with water to form calcium hydroxide (slaked lime) and large amount
of energy is released.
ii. In black and white photography, photolysis of silver bromide takes place. Silver bromide decomposes in the presence of
sunlight to give silver and bromine.
Sunlight
19. Precipitation reaction: When two reactants react and product formed remains insoluble and settles as a solid it is called a
precipitate. Such reactions in which precipitate is formed are called precipitation reactions. Precipitation reaction produce
insoluble salts which settle down as precipitate.
AgNO3(aq) + NaCl(aq) → AgCl(s)↓ + NaNO3(aq)
BaCl2(aq) + NaSO4(aq)→ BaSO4↓ + 2NaCl(aq)
Heat
Heat
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CH4 + 4O → CO2 + 2H2O
5. The equation is balanced but it is not molecular. To do so write 4O as 2O2 which means that oxygen is in molecular form.
CH4 + 2O2 → CO2 + 2H2O This is the balanced chemical equation.
In the above example, Cu2+ oxidizes Zn to Zn2+ and itself gets reduced to Cu. Cu2+ is an oxidizing agent.
33. (i) 2HN O + C a(OH) → C a(N O ) + 2H
3 2 3 2 2
S2 →
S + 2e (oxidation)
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b. Substance reduced, SO2 is getting reduced to S.
S4+ + 4e →
S (reduction)
35. Sodium hydroxide (NaOH) reacts with acetic acid (CH3COOH) to form sodium acetate (CH3COONa) and water (H2O).
NaOH (aq) + CH3COOH(l) ⟶ CH3COONa(aq) + H2O(l)
It is a double displacement reaction as both the reactants exchange ions to form new products.
Also, it is a neutralization reaction between a strong base and weak acid as the base (NaOH) reacts with an acid (CH3COOH) to
form a salt (CH3COONa) and water (H2O).
2
× 0.35 = 0.70 mole
38. :
i. AgBr → Ag + Br2 [Unbalanced Chemical Equation]
Sunlight
hydroxide
39. i. CaCO3 (s) + 2HCl (aq) ⟶ CaCl2 (s) + H2O (l) + CO2 (g)
ii. 2Al (s) + 6HCl (aq) ⟶ 2AlCl3 (aq) + 3H2
iii. MnO2 + 4HCl ⟶ MnCl2 + H2O (l) + Cl2 (g)
Heat
Calcium hydroxide is alkaline in nature and hence turns red litmus blue.
42. Those reactions in which oxidation and reduction takes place simultaneously are called redox reactions.
i. PbO is getting reduced and C is getting oxidised.
ii. MnO2 is getting reduced and HCl is getting oxidised.
When hydrogen gas is passed over the hot copper oxide, it reacts with hydrogen gas to form elemental copper and water will be
produced in the liquid state.
CuO(s) + H2(g) → Cu(s) + H2O(l)
45. i. In first step, oxidation takes place whereas in second step, redox reaction takes place.
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ii. Metal initially taken in the powder form is copper.
2Cu(s) + O2(g) ⟶ 2CuO(s)
Heat
46. Al + H+ →
Al3 + H2 is not balanced equation. The equation has to be balanced in terms of atoms and also the charges. The
different steps for the balancing of the equation are :
1. The number of Al atoms in reactants and products are the same (one) and are balanced.
2. The number of hydrogen atoms in the products is 2 and in the reactants is 1. Therefore multiply the number of H atoms in the
reactants by 2.
Al + 2H+ →
Al3+ + H2
3. The equation is balanced in terms of atoms. But it is not balanced in terms of charges. There are two positive charges (in 2H+)
and three positive charges (in Al3+).
To equate them multiply 2H+ by 3 on the reactant side and Al3+ + H2
4. Now, the equation is balanced in terms of charges but not in terms of atoms. There are two Al atoms on the product side and
one Al atom on the reactant side. Therefore, multiply the Al atom on the reactant side by 2. Similarly, there are six H atoms on
the reactant side and two on the produce side. Therefore, multiply H2 molecule by three.
2Al + 6H+ →
2Al3 + 3H2
The equation is now completely balanced.
47. Aluminium metal replaces iron from ferric oxide giving aluminium oxide and iron.
Aluminium + Ferric oxide → Aluminium oxide + Iron
The steps for balancing the chemical equation are as follows :
1. The skeleton equation for the chemical reaction is :
Al + Fe2O3 → Al2O3 + Fe
2. In Fe2O3 (reactant), the number of atoms of Fe is two but it is one on the product side. Therefore, multiply symbol of Fe by
two.
Al + Fe2O3 → Al2O3 + 2Fe
3. In Al2O3 (product), the number of atoms of Al is two but it is one on the product side. Therefore, multiply the symbol of Al
with two.
2Al + Fe2O3 → Al2O3 + 2Fe
4. The number of oxygen atoms on both sides of the equation is the same (three). Therefore, these are not to be balanced. The
above chemical equation is in balanced form.
48. Barium chloride + Potassium sulphate →
Barium sulphate + Potassium chloride.
BaCl2 + K2SO4 →
BaSO4 + 2KCl
Barium chloride react with potassium sulphate to produce barium sulphate and potassium chloride.
49. i. a. Double displacement reaction and precipitation reaction
b. Combination reaction and exothermic reaction .
c. Thermal decomposition reaction
ii. Reaction (a) is a precipitation reaction, as a white precipitate of AgCl is formed. Due to the formation of precipitate this
reaction is also called precipitation reaction.
50. Ferrous sulphate crystals contain water molecules (FeSO4. 7H2O). On heating, ferrous sulphate crystals lose water and anhydrous
ferrous sulphate (FeSO4) is formed. So their colour changes from light green to white.On further heating, anhydrous ferrous
sulphate decomposes to form ferric oxide (Fe2O3), sulphur dioxide (SO2) and sulphur trioxide (SO3). So, the gas emitted smells
like burning sulphur.
51. The given reaction can be written in the form of two separate reactions:
Reduction
2PbO(s) 2Pb(s)
Loss of oxygen
Oxidation
C(s) CO2 (g)
Gain of oxygen
Therefore, according to above reactions, statements i & ii are incorrect and statements iii & iv are correct.
52. a. i. HCl is oxidized
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ii. MnO2 is reduced
b. Oxidation: Gaining of Oxygen or removal of Hydrogen, is called oxidation. Oxidation is the loss of electrons
Reduction: Gaining of Hydrogen or removal of Oxygen, is called reduction. Reduction is the gain of electrons.
53. Balance equation: Ba(OH)2 (aq) + 2HBr(aq) →
BaBr2(aq) + 2H2O (l)
54. The Change observed is that the lower end of the test tube becomes slightly warm because of the following reaction.
2Al + 3F eSO4 → Al2 (SO4 )3 + 3F e
When evolved gas is passed through lime water, it becomes milky due to the formation of insoluble calcium carbonate.
C a(OH )2 + C O2 (g) → C aC O3 (s) + H2 O(l)
But when excess CO2 gas is passed through lime water then the milky color(due to the formation of calcium carbonate)
disappears.
C aC O3 (s) + C O2 (g) + H2 O(l) → C a(HC O3 ) (aq)
2
Heat
Ag+ + e →
Ag (reduction)
Ag+ is getting reduced to Ag.
62. i. Zinc is more reactive than copper,it will displace copper from CuS04 So,this reaction will occur.
ii. Iron is less reactive than zinc, so it cannot displace zinc from zinc sulphate solution, Hence, the reaction will not take place.
iii. Zinc is more reactive than iron, it will displace iron from FeSO4 solution. So the reaction will take place.
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63. 1. MnO2 + Al → Mn + Al2O3 (Unbalanced )
△
i. Take 2g of C uSO ⋅ 5H O in a boiling tube fitted in a clamp stand. Observe its colour.
4 2
ii. Fit it with cork and delivery tube bent at two right angles which dips into a test tube.
iii. Heat crystals in a boiling tube.
iv. Observe vapours being condensed in test tube.
v. Cool the crystals and add few drops of water into it.
vi. Water vapours get condensed in a test tube and colour of blue crystals changes into white. On adding water to anhydrous
copper sulphate it changes into blue again.
66. i. Pb3O4 + HNO3 ⟶ Pb(NO3)2 + PbO2 + H2O [unbalanced]
Pb3O4(s) + 4HNO3(aq) ⟶ 2Pb(NO3)2(aq) + PbO2(s) + 2H2O(l) [balanced]
ii. C2H5OH + O2 ⟶ CO2 + H2O + Heat [Unbalanced]
C2H5OH(l) + 3O2(g) ⟶ 2CO2(g) + 3H2O(l) + Heat [balanced]
iii. Pb3O4 + HCI ⟶ PbCl2 + Cl2 + H2O [unbalanced]
Pb3O4(s) + 8HCI(aq) ⟶ 3PbCl2(aq) + Cl2(g) + 4H2O(l) [balanced]
67. i. The substance ‘X’ which is used in white washing is calcium oxide or quick lime and its formula is CaO.
ii. The reaction involve is: CaO(s) + H2O(l) →
Ca(OH)2 (aq)
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ii. A large amount of heat is released when calcium oxide is dissolved in water.
Dissolution
73. i. Zinc reacts with NaOH to form a coordination compound called sodium zincate with evolution of Hydrogen gas.
Zn + 2NaOH → Na2ZnO2 + H2
ii. Test:- When a burning splinter is brought near the gas, it burns with a Pop Sound.
iii. Hydrogen (H2) gas is evolved when Zn react with acid.
6
× 0.076 = 0.025 mole
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