LMO Discarga LMO Carga

Tempo (s) Potencial (V) Tempo (s) Potencial (V)

0 0.897 1.91E+04 0.649
1.2
19000.00 0.524 38000.00 1.04
431 0.881 1.96E+04 0.662
1
861 0.873 2.00E+04 0.67
1.29E+03 0.87 2.05E+04 0.684
0.8
1.72E+03 0.868 2.12E+04 0.692

Potencial (V)
2.15E+03 0.865 2.17E+04 0.7
0.6
2.51E+03 0.862 2.25E+04 0.708
2.87E+03 0.862 2.30E+04 0.714
0.4
3.37E+03 0.859 2.35E+04 0.722
3.73E+03 0.859 2.43E+04 0.727
0.2
4.09E+03 0.859 2.51E+04 0.735
4.52E+03 0.857 2.58E+04 0.743
0
4.88E+03 0.854 2.66E+04 0.757 0 5000
5.31E+03 0.854 2.73E+04 0.773
5.67E+03 0.851 2.81E+04 0.795
6.17E+03 0.846 2.89E+04 0.814
6.53E+03 0.843 2.95E+04 0.824
6.75E+03 0.838 3.02E+04 0.832
7.18E+03 0.83 3.11E+04 0.838
7.54E+03 0.822 3.18E+04 0.841
7.82E+03 0.814 3.25E+04 0.846
7.97E+03 0.808 3.32E+04 0.846
8.33E+03 0.797 3.39E+04 0.851
8.68E+03 0.786 3.47E+04 0.857
9.04E+03 0.776 3.54E+04 0.865
9.19E+03 0.77 3.61E+04 0.881
9.55E+03 0.762 3.69E+04 0.908
9.90E+03 0.754 3.76E+04 0.954
1.03E+04 0.749 3.78E+04 0.984
1.08E+04 0.743 3.80E+04 1.01
1.15E+04 0.741
1.22E+04 0.735
1.31E+04 0.73
1.37E+04 0.722
1.43E+04 0.719
1.50E+04 0.711
1.55E+04 0.703
1.60E+04 0.697
1.64E+04 0.689
1.69E+04 0.678
1.73E+04 0.67
1.77E+04 0.659
1.79E+04 0.651
1.82E+04 0.643
1.83E+04 0.635
1.84E+04 0.63
1.85E+04 0.619
1.87E+04 0.605
1.87E+04 0.6
1.88E+04 0.586
1.89E+04 0.573
1.89E+04 0.551
 Curva de Carga e Descarga
1.2

0.8
Potencial (V)

0.6 Desgarga
Carga

0.4

0.2

0
0 5000 10000 15000 20000 25000 30000 35000 40000
Tempo (s)
 Desintercalação do Li Intercalação do Li
Potencial (V) Corrente (A) Potencial (V) Corrente (A)
0.403 0.000138 0.403 -0.00184 0.02
0.449 0.00031 1.07 0.00074
0.495 0.000396 0.474 -0.00219 0.015
0.546 0.000568 0.531 -0.0027
0.01
0.597 0.00108 0.567 -0.00356

Corrente (A)
0.644 0.00263 0.582 -0.00425 0.005
0.623 0.00186 0.592 -0.00494
0
0.654 0.00349 0.603 -0.00563 0.4 0.5
0.664 0.00427 0.613 -0.00632 -0.005
0.674 0.00504 0.618 -0.00701
-0.01
0.685 0.00582 0.623 -0.00761
0.69 0.00659 0.633 -0.00855 -0.015
0.7 0.00737 0.644 -0.00933
0.705 0.00806 0.654 -0.01
0.715 0.00866 0.664 -0.0105
0.726 0.00935 0.685 -0.0105
0.731 0.00995 0.705 -0.0101
0.746 0.0106 0.715 -0.00976
0.756 0.00995 0.736 -0.00924
0.762 0.00943 0.746 -0.00916
0.762 0.00874 0.767 -0.00941
0.762 0.00814 0.782 -0.00959
0.767 0.00745 0.792 -0.00985
0.767 0.00668 0.808 -0.0101
0.772 0.0059 0.828 -0.01
0.782 0.00504 0.838 -0.00933
0.792 0.00444 0.844 -0.00881
0.813 0.00427 0.854 -0.00795
0.823 0.00453 0.859 -0.00761
0.833 0.00522 0.869 -0.00692
0.838 0.00599 0.879 -0.00632
0.844 0.00659 0.89 -0.00571
0.849 0.00754 0.9 -0.0052
0.849 0.00823 0.915 -0.00442
0.854 0.009 0.931 -0.00373
0.854 0.00969 0.946 -0.00305
0.859 0.0105 0.956 -0.00244
0.859 0.0113 0.972 -0.00176
0.864 0.0123 0.982 -0.000981
0.864 0.0132 1.01 -0.000379
0.864 0.014 1.03 0.000224
0.869 0.0148
0.874 0.0156
0.89 0.0148
 0.89 0.0141
0.89 0.0132
0.895 0.0124
0.895 0.0114
0.9 0.0106
0.9 0.00978
0.9 0.00909
0.9 0.00831
0.905 0.00762
0.905 0.00668
0.91 0.00608
0.915 0.00522
0.921 0.0047
0.931 0.00401
0.946 0.00349
0.967 0.00306
0.987 0.00272
1.02 0.0022
1.05 0.00186
1.09 0.00186
1.12 0.00238
 Curva de intercalação e desintercalação do Li
0.02

0.015

0.01
Corrente (A)

0.005 Desintercalação do Li
Intercalação do Li
0
0.4 0.5 0.6 0.7 0.8 0.9 1 1.1 1.2
-0.005

-0.01

-0.015
Potencial (V)
 Desintercalação do Li (0.5mV/s) Intercalação do Li (0,5mV/s) Desintercalação do Li (1.
Potencial (V) Corrente (A) Potencial (V) Corrente (A) Potencial (V)
0.458 0 0.475 -0.909 0.461
0.5 0.379 0.503 -1.14 0.492
0.527 0.53 0.532 -1.29 0.51
0.546 0.682 0.553 -1.36 0.527
0.563 0.758 0.569 -1.52 0.544
0.58 0.909 0.585 -1.82 0.564
0.597 1.14 0.598 -2.05 0.58
0.614 1.29 0.612 -2.5 0.597
0.631 1.52 0.625 -3.03 0.61
0.646 1.89 0.637 -3.71 0.629
0.663 2.42 0.644 -4.24 0.641
0.681 3.11 0.653 -4.85 0.651
0.7 4.02 0.659 -5.3 0.661
0.719 4.85 0.668 -5.76 0.671
0.737 5.53 0.675 -6.21 0.681
0.753 6.06 0.683 -6.67 0.695
0.768 6.14 0.69 -6.89 0.705
0.785 5.68 0.702 -7.12 0.715
0.795 5.23 0.714 -7.12 0.727
0.805 4.85 0.72 -6.74 0.737
0.817 4.47 0.727 -6.21 0.747
0.831 4.17 0.736 -5.61 0.756
0.842 4.17 0.746 -5 0.763
0.856 4.39 0.758 -4.7 0.773
0.868 4.85 0.771 -4.47 0.785
0.878 5.3 0.78 -4.55 0.795
0.886 5.91 0.79 -4.92 0.805
0.895 6.29 0.8 -5.3 0.81
0.903 6.52 0.807 -5.61 0.82
0.915 6.21 0.814 -5.91 0.834
0.92 5.91 0.82 -6.21 0.844
0.927 5.61 0.827 -6.36 0.854
0.934 5.23 0.839 -6.21 0.866
0.941 4.85 0.846 -5.76 0.876
0.947 4.55 0.853 -5.3 0.886
0.954 4.17 0.859 -4.77 0.895
0.963 3.79 0.869 -4.24 0.905
0.971 3.41 0.88 -3.79 0.919
0.98 3.11 0.89 -3.33 0.934
0.995 2.73 0.902 -2.88 0.947
1.01 2.42 0.915 -2.42 0.958
1.03 2.2 0.929 -2.12 0.966
1.04 2.12 0.942 -1.82 0.976
1.05 2.05 0.956 -1.67 0.986
1.06 1.89 0.971 -1.44 0.993
1.07 1.82 0.985 -1.21 1
1.09 1.82 0.998 -1.14 1.01
1.01 -1.14 1.02
1.02 -0.985 1.03
1.04 -0.833 1.04
1.06 -0.682 1.05
1.07 -0.53 1.06
1.07
1.09
ercalação do Li (1.0mV/s) Intercalação do Li (1.0mV/s)
Corrente (A) Potencial (V) Corrente (A)
0 0.442 -1.67
0.455 0.466 -1.97
0.682 0.483 -2.12
0.909 0.5 -2.27
1.14 0.517 -2.58 Cur
1.44 0.529 -2.8 15
1.74 0.542 -3.11
1.89 0.556 -3.48 10
2.2 0.566 -3.79
2.65 0.575 -4.24
5
3.11 0.58 -4.55

Corrente (A)
3.56 0.588 -5
0
4.17 0.595 -5.45 0.4 0.5 0.6
4.77 0.6 -5.91
5.45 0.605 -6.52 -5

6.29 0.61 -6.89

7.05 0.614 -7.35 -10
7.8 0.619 -7.88
8.56 0.622 -8.26 -15
9.24 0.624 -8.64
9.85 0.629 -9.02
10.4 0.632 -9.39
10.6 0.636 -9.92
10.8 0.641 -10.3
10.7 0.642 -10.7
10.4 0.646 -10.9
9.85 0.649 -11.3
9.62 0.656 -11.8
9.24 0.661 -12.1
8.71 0.666 -12.4
8.48 0.673 -12.7
8.41 0.678 -12.9
8.56 0.686 -12.9
8.86 0.697 -12.7
9.39 0.705 -12.3
9.85 0.712 -11.9
10.5 0.717 -11.4
10.8 0.722 -11
10.6 0.729 -10.5
10 0.736 -10.1
9.47 0.744 -9.7
9.02 0.754 -9.47
8.26 0.768 -9.55
7.8 0.778 -9.85
7.35 0.788 -10.2
6.89 0.792 -10.2
6.36 0.805 -10.5
5.91 0.815 -10.4
5.45 0.825 -10.2
5.23 0.831 -9.85
4.85 0.836 -9.39
4.55 0.841 -9.02
4.32 0.847 -8.48
4.09 0.853 -7.95
0.859 -7.58
0.864 -7.05
0.873 -6.52
0.881 -5.98
0.89 -5.53
0.9 -5
0.912 -4.47
0.922 -4.02
0.936 -3.64
0.946 -3.18
0.958 -2.95
0.971 -2.65
0.976 -2.5
0.988 -2.27
1 -2.05
1.02 -1.82
1.03 -1.52
1.05 -1.29
1.06 -1.06
1.07 -0.758
1.08 -0.379
 Curva de intercalação e desintercalação do Li
15

10

5
Desintercalação do Li (0.5mV/s)
Corrente (A)

Intercalação do Li (0,5mV/s)
0 Desintercalação do Li (1.0mV/s)
0.4 0.5 0.6 0.7 0.8 0.9 1 1.1 1.2
Intercalação do Li (1.0mV/s)
-5

-10

-15

Potencial (V)
 Desintercalação do Li Intercalação do Li
Potencial (V) Corrente (A) Potencial (V) Corrente (A)
0.454 -0.0306 0.451 -0.0306 Curva
0.467 -0.0131 0.457 -0.0394 1.5
0.481 -0.00437 0.47 -0.0569
0.494 0.00437 0.484 -0.0569 1
0.514 0.00437 0.496 -0.0656
0.536 0.0131 0.506 -0.0656 0.5

Corrente (A)
0.557 0.0219 0.517 -0.0656
0.58 0.0306 0.526 -0.0743 0
0.4 0.5
0.602 0.0394 0.541 -0.0743
0.626 0.0569 0.551 -0.0831 -0.5
0.641 0.0656 0.562 -0.0831
0.656 0.0831 0.572 -0.0831 -1
0.668 0.101 0.587 -0.0918
0.683 0.136 0.599 -0.0918 -1.5

0.695 0.162 0.611 -0.0918

0.704 0.197 0.623 -0.101
0.712 0.232 0.635 -0.109
0.721 0.284 0.643 -0.109
0.73 0.345 0.655 -0.136
0.739 0.407 0.664 -0.144
0.748 0.494 0.673 -0.162
0.76 0.59 0.677 -0.171
0.769 0.652 0.683 -0.197
0.773 0.704 0.688 -0.223
0.779 0.748 0.692 -0.241
0.784 0.8 0.697 -0.276
0.787 0.862 0.701 -0.302
0.79 0.923 0.706 -0.328
0.791 0.966 0.709 -0.363
0.793 1.01 0.712 -0.389
0.794 1.05 0.716 -0.433
0.796 1.09 0.718 -0.459
0.802 1.09 0.722 -0.52
0.803 1.05 0.725 -0.547
0.805 1.02 0.728 -0.582
0.806 0.966 0.731 -0.625
0.808 0.931 0.733 -0.652
0.808 0.897 0.736 -0.695
0.809 0.862 0.739 -0.748
0.811 0.818 0.74 -0.774
0.812 0.774 0.743 -0.8
0.812 0.73 0.745 -0.835
0.814 0.687 0.746 -0.862
0.815 0.652 0.748 -0.888
0.817 0.608 0.749 -0.931
0.818 0.573 0.751 -0.966
0.82 0.538 0.752 -0.984
0.821 0.494 0.754 -1.02
0.823 0.459 0.754 -1.05
0.826 0.415 0.755 -1.07
0.827 0.389 0.757 -1.1
0.832 0.354 0.758 -1.14
0.835 0.328 0.76 -1.17
0.842 0.284 0.766 -1.15
0.847 0.276 0.767 -1.1
0.853 0.258 0.767 -1.05
0.86 0.241 0.77 -1
0.868 0.232 0.77 -0.94
0.875 0.232 0.772 -0.905
0.884 0.249 0.773 -0.87
0.892 0.267 0.775 -0.835
0.901 0.328 0.775 -0.792
0.905 0.398 0.776 -0.739
0.908 0.442 0.779 -0.66
0.913 0.538 0.782 -0.617
0.914 0.608 0.784 -0.573
0.917 0.652 0.787 -0.52
0.919 0.713 0.788 -0.485
0.92 0.774 0.791 -0.45
0.922 0.835 0.794 -0.415
0.923 0.897 0.799 -0.389
0.926 0.949 0.802 -0.345
0.928 1 0.806 -0.319
0.929 1.05 0.811 -0.293
0.931 1.1 0.815 -0.284
0.934 1.15 0.827 -0.267
0.935 1.18 0.836 -0.284
0.941 1.17 0.842 -0.302
0.944 1.11 0.85 -0.345
0.946 1.06 0.853 -0.389
0.947 1.02 0.856 -0.433
0.95 0.966 0.859 -0.468
0.953 0.914 0.86 -0.512
0.953 0.862 0.862 -0.564
0.956 0.8 0.863 -0.617
0.959 0.748 0.863 -0.652
0.962 0.695 0.865 -0.695
0.965 0.634 0.865 -0.748
0.967 0.59 0.866 -0.792
0.971 0.547 0.868 -0.835
0.974 0.503 0.868 -0.87
0.977 0.477 0.869 -0.923
0.983 0.424 0.869 -0.966
0.988 0.398 0.871 -1
0.994 0.354 0.872 -1.05
1 0.328 0.874 -1.08
1.01 0.31 0.874 -1.12
1.01 0.284 0.875 -1.14
1.02 0.276 0.877 -1.18
1.03 0.249 0.884 -1.15
1.03 0.249 0.887 -1.1
1.04 0.232 0.889 -1.04
1.05 0.223 0.89 -0.984
0.893 -0.931
0.895 -0.879
0.898 -0.827
0.901 -0.774
0.902 -0.704
0.905 -0.669
0.908 -0.608
0.911 -0.555
0.914 -0.512
0.917 -0.468
0.92 -0.424
0.925 -0.38
0.929 -0.337
0.934 -0.293
0.94 -0.258
0.944 -0.232
0.95 -0.188
0.956 -0.162
0.962 -0.136
0.97 -0.109
0.977 -0.0831
0.982 -0.0656
0.994 -0.0219
0.988 -0.0481
1 0.00437
1.01 0.0131
1.02 0.0394
1.03 0.0743
1.04 0.109
1.04 0.136
1.05 0.171
1.05 0.214
 Curva de intercalação e desintercalação do Li
1.5

0.5
Corrente (A)

Desintercalação do Li
0 Intercalação do Li
0.4 0.5 0.6 0.7 0.8 0.9 1 1.1

-0.5

-1

-1.5
Potencial (V)