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Assignment 2 Chemical Equilibrium

This document provides a chemical equilibrium worksheet with several problems involving calculation of equilibrium constants and concentrations. It asks the student to: 1) Write equilibrium constant expressions for several reactions and determine the equilibrium constant given initial concentrations. 2) Analyze how changes in conditions would shift equilibrium or change concentrations for two reactions. 3) Calculate equilibrium concentrations given initial amounts and equilibrium constants for two reactions. 4) Determine an equilibrium constant given initial amounts and amounts at equilibrium for one reaction.

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vegamaharajfaith02
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79 views

Assignment 2 Chemical Equilibrium

This document provides a chemical equilibrium worksheet with several problems involving calculation of equilibrium constants and concentrations. It asks the student to: 1) Write equilibrium constant expressions for several reactions and determine the equilibrium constant given initial concentrations. 2) Analyze how changes in conditions would shift equilibrium or change concentrations for two reactions. 3) Calculate equilibrium concentrations given initial amounts and equilibrium constants for two reactions. 4) Determine an equilibrium constant given initial amounts and amounts at equilibrium for one reaction.

Uploaded by

vegamaharajfaith02
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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CHEMICAL EQUILIBRIUM WORKSHEET

1. What is the equilibrium constant expression for the following reactions:


a. Fe (s) + H2O (g) ⇌ Fe3O4 (s) + H2 (g)
b. Fe (s) + NO2 (g) ⇌ NO (g) FeO (s)
c. NH4Cl (s) ⇌ NH3 (g) + HCl (g)
d. As4O6 (s) + C (s) ⇌ As4 (g) + CO (g)

2. For the following reaction, write how each of the changes will affect the indicated quantity,
assuming a container of fixed size. For the shift, write either “left”, “right”, or “none”. For a
change in concentration, write how it would respond AFTER the change (choices are
“increase”, “decrease”, or “no change”.)

H2 (g) + Br2 (g) ⇌ HBr (g) ΔH > 0


Change Shift [H2] [Br2] [HBr]
1. Some H2 added -----
2. Some HBr added ----
3. Some H2 removed ----
4. Some Br2 removed ----
5. Temperature is increased
6. Temperature is decreased
7. Pressure is increased, and the
container volume decreased

CO (g) + H2 (g) ⇌ CH4 (g) + H2O (g) ΔH < 0


Change Shift [CO] [H2] [CH4] [H2O]
1. Some H2O removed ----
2. Some CH4 added ----
3. Some CO removed ----
4. Some H2 added ----
5. Temperature is increased
6. Temperature is
decreased
7. Pressure is decreased,
and the container volume
increased

3. For the following examples, write the equilibrium constant expressions and determine K for
the reaction given the equilibrium concentrations.
a. N2 (g) + H2 (g) ⇌ NH3 (g)
[NH3] = 0.0100 M, [N2] = 0.0200 M, [H2] = 0.0200 M
b. KClO3 (s) ⇌ KCl (s) + O2 (g)
[O2] = 0.0500 M, [KCl] = 0.00250 M, [KClO3] = 2.00 M
c. CO (g) + O2 (g) ⇌ CO2 (g)
[CO] = 2.0 M, [O2] = 1.5 M, [CO2] = 3.0 M
d. H2O (l) ⇌ H+ (aq) OH- (aq)
[H+] = 1x10-8 M, [OH-] = 1x10-6 M, [H2O] = 1x10-14 M
4. 0.200 mol of H2, 0.200 mol of I2 and 0.200 mol of HI were placed in a 1.00 L flask and
allowed to come to equilibrium. The value of Kc at this temperature is 49.5. Determine the
equilibrium concentrations of all the species. (Ans: [H2] = [I2] = 0.05 M, [HI] = 0.30 M)
H2 (g) + I2 (g) ↔ HI (g)
5. Calculate the equilibrium concentrations of all species in the following equation if 3.000
moles of H2 and 6.000 moles of F2 are placed in a 3.000 L container.
H2 (g) + F2 (g) ↔ HF (g) Kc = 1.15 x 102
-2
(Ans: [H2] = 3.2 x 10 M; [F2] = 1.032 M; [HF] = 1.936 M)
6. A mixture of 3.31 moles of A, 4.33 moles of B, and 5.95 moles of C is placed in a 1-L
container at a certain temperature. The reaction was then allowed to reach equilibrium. At
equilibrium, the number of moles of B is 6.16. Calculate the equilibrium constant Kc for the
reaction. (Ans: 4.5 x 103)
A ↔ 3B + 2C

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