MSDS

QATAR PEST CONTROL COMPANY W.L.
L
Professionals at your Service
MATERIAL SAFETY DATA SHEET

Meenakshi Agro Chemicals
Office:3-5-823, C7, Hyderabad Business Centre, Hyderguda,
HYDERABAD-500029, Telangana, INDIA,Off:009140
23231010, 66667440 Fax:0091 40 23240465,
email:macagrochemicals@yahoo.com
website: www.macagrochemicals.com
Factory: Survey no-500, Koyyalagudem (Village),
Choutuppal (Mandal), Yadadri Bhuaangiri (Dist), Telangana ,
INDIA PIN-508252, Phone: 0091 86942 00566

CRUNCH 5.0 % SC w/w
Table of contents
1. Identification of the substance / 9. Physical and chemical properties

Preparation and of the company 10. Stability and reactivity
Undertaking 11. Toxicological information
2. Composition/information on
ingredients 12. Ecological information
3. Hazards identification 13. Disposal considerations
4. First aid measures 14. Transport information
5. Fire-fighting measures 15. Regulatory information
6. Accidental release measures 16. Other information
7. Handling and storage
8. Exposure controls and personal protection
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING
Xn Product Name: fipronil 5% SC w/w

Supplier: Meenakshi Agro Chemicals
Survey no-500,Koyyalagudem(Vill),
Choutuppal (Mandal), Yadadri Bhuvanagiri ( Dist),
Telangana -INDIA
Pin-508252
Emergency 0091 40 23231010.
Telephone No. 0091 8694 200566.
Harmful
2. COMPOSITION/ INFORMATION ON INGREDIENTS
ACTIVE INGREDIENT
CAS Name 5-amino-1-(2,6-dichloro-4(trifluoromethyl)phenyl)-4-
((1,R,S)-(trifluoromethyl)sulfinyl)-1- H-pyrazole-3-
carbonitrile
ISO Name Fipronil

CAS No 120068-37-3
EC NO. 424-610-5
CIPAC No. 581
BIS No. IS 16145
Molecular Weight 437.15
Empirical Formula C12H4Cl2 F6 N4OS
Chemical Name HS Code CAS# Percent or content

Fipronil 38089910 120068-37-3 5%
Material Use Insecticide

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INDIA PIN-508252, Phone: 0091 86942 00566
3. HAZARDS IDENTIFICATION
Emergency overview
CAUTION:
HARMFUL IF SWALLOWED.
HARMFUL IF ABSORBED THROUGH SKIN.
HARMFUL IF INHALED.
Causes eye irritation.
Do not get in eyes, on skin, or on clothing.
Do not breathe vapours/mists.
Wash thoroughly after handling.
State of matter: liquid

Color: White to off white
Odour: characteristic
Potential health effects

Primary routes of exposure:
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of
entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified
gases.
Acute toxicity:
Slightly toxic after single ingestion. Slightly toxic after short-term skin contact. Slightly toxic after
short-terminhalation.
Irritation / corrosion:
May cause slight irritation to the skin. May cause moderate but temporary irritation to the eyes.
Sensitization:
Skin sensitizing effects were not observed in animal studies.
Medical conditions aggravated by overexposure:

Individuals with pre-existing diseases of the respiratory system, skin or eyes may have increased
susceptibilityto excessive exposures.
Signs and symptoms of overexposure:

CNS stimulation, tremors, convulsions
All injection injuries must be treated as potential threats to the future viability of the hand, foot, or
limb. Injection wounds containing dirt, leather, product or other infectious detritus should be
considered dangerous to the viability of the hand, foot or limb. Surgical exploration and debridement
may be required.
Potential environmental effects

Aquatic toxicity:
Very toxic (acute effect) to aquatic organisms.
23231010, 66667440 Fax:0091 40 23240465,
INDIA PIN-508252, Phone: 0091 86942 00566
Terrestrial toxicity:
With high probability not acutely harmful to terrestrial organisms.
4. FIRST AID MEASURES
General advice:
First aid providers should wear personal protective equipment to prevent exposure. Remove
contaminated clothing. Move person to fresh air. If person is not breathing, call 911 or ambulance,
then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or
physician for treatment advice. Have the product container or label with you when calling a poison
control center or doctor or going for treatment.
If inhaled:
Remove the affected individual into fresh air and keep the person calm.
If on skin:
Rinse skin immediately with plenty of water for 15 - 20 minutes.
If in eyes:
Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. Remove contact lenses, if
present, after first 5 minutes, then continue rinsing.
If swallowed:
Never induce vomiting or give anything by mouth if the victim is unconscious or having convulsions.
Do not induce vomiting. Have person sip a glass of water if able to swallow.
Note to physician
Antidote: No known specific antidote.
Treatment: Treat symptomatically. Anticonvulsant therapy as routinely administered to humans.

Based on animal studies diazepam and phenobarbital prevented convulsions. Due to the slow
elimination of the active compound and its metabolites, the treatment must be continued for several
days, gradually decreasing the dose of anticonvulsant based on the clinical response.
5. FIRE – FIGHTING MEASURES
Flash point: > 206.96 °F

Autoignition: Information applies to the solvent. Not applicable Lower explosion limit: As a
result of our experience with this product and our knowledge of its composition
we do not expect any hazard as long as the product is used appropriately and in
accordance with the intended use.
Upper explosion limit: As a result of our experience with this product and our knowledge of its
Composition we do not expect any hazard as long as the product is used
appropriately and in accordance with the intended use.
Self-ignition temperature: not self-igniting
Suitable extinguishing media: foam, dry powder, carbon dioxide, water spray
23231010, 66667440 Fax:0091 40 23240465,
INDIA PIN-508252, Phone: 0091 86942 00566
Hazards during fire-fighting:

carbon monoxide, carbon dioxide, hydrogen fluoride, Hydrogen chloride, nitrogen oxides, sulfur oxides,
acidhalides
If product is heated above decomposition temperature, toxic vapours will be released. The
substances/groups of substances mentioned can be released if the product is involved in a fire.
Protective equipment for fire-fighting:

Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if
exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage or
effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with
official regulations.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions:
Take appropriate protective measures. Clear area. Shut off source of leak only under safe conditions.
Extinguish sources of ignition nearby and downwind. Ensure adequate ventilation. Wear suitable
personal protective clothing and equipment.
Environmental precautions:
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.
Contain contaminated water/firefighting water.
Cleanup:
Dike spillage. Pick up with suitable absorbent material. Place into suitable containers for reuse or
disposal in a licensed facility. Spilled substance/product should be recovered and applied according
to label rates whenever possible. If application of spilled substance/product is not possible, then spills
should be contained, solidified, and placed in suitable containers for disposal. After decontamination,
spill area can be washed with water. Collect wash water for approved disposal.
7 HANDLING AND STORAGE

Handling
Ensure adequate ventilation. Provide good ventilation of working area (local exhaust ventilation if
necessary). Keep away from sources of ignition - No smoking. Keep container tightly sealed. Protect
contents from the effects of light. Protect against heat. Protect from air. Handle and open container
with care. Do not open until ready to use. Once container is opened, content should be used as soon
as possible. Avoid aerosol formation. Avoid dust formation. Provide means for controlling leaks and
spills. Do not return residues to the storage containers. Follow label warnings even after container is
emptied. The substance/ product may be handled only by appropriately trained personnel. Avoid all
direct contact with the substance/product. Avoid contact with the skin, eyes and clothing. Avoid
inhalation of dusts/mists/vapours. Wear suitable personal protective clothing and equipment.
Protection against fire and explosion:

The relevant fire protection measures should be noted. Fire extinguishers should be kept handy. Avoid
all sources of ignition: heat, sparks, open flame. Sources of ignition should be kept well clear. Avoid
extreme heat. Keep away from oxidizable substances. Electrical equipment should conform to national
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INDIA PIN-508252, Phone: 0091 86942 00566
electric code. Ground all transfer equipment properly to prevent electrostatic discharge. Electrostatic
discharge may cause ignition.
Storage
General advice:
Keep only in the original container in a cool, dry, well-ventilated place away from ignition sources, heat
or flame. Protect containers from physical damage. Protect against contamination. The authority
permits and storage regulations must be observed.
Storage incompatibility:
General advice: Segregate from incompatible substances. Segregate from foods and animal feeds.
Segregate from textiles and similar materials.
Temperature tolerance
Protect from temperatures below: 0 °C
Changes in the properties of the product may occur if substance/product is stored below indicated
temperature for extended periods of time.
Protect from temperatures above: 40 °C
Changes in the properties of the product may occur if substance/product is stored above indicated
temperature for extended periods of time
8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Users of a pesticidal product should refer to the product label for personal protective equipment
requirements.
Advice on system design:

Whenever possible, engineering controls should be used to minimize the need for personal protective
equipment.
Personal protective equipment

RECOMMENDATIONS FOR MANUFACTURING, COMMERCIAL BLENDING, AND PACKAGING
WORKERS:
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent) organic
vapour/particulate respirator. For situations where the airborne concentrations may exceed the level
for which an air purifying respirator is effective, or where the levels are unknown or Immediately
Dangerous to Life or Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained
breathing apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with
escape provisions.
Hand protection:
Chemical resistant protective gloves, Protective glove selection must be based on the user's assessment
of the workplace hazards.
Eye protection:
Safety glasses with side-shields. Tightly fitting safety goggles (chemical goggles). Wear face shield if
splashing hazard exists.
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INDIA PIN-508252, Phone: 0091 86942 00566
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. head protection,
apron, protective boots, chemical-protection suit.
General safety and hygiene measures:

Wear long sleeved work shirt and long work pants in addition to other stated personal protective
equipment. Work place should be equipped with a shower and an eye wash. Handle in accordance
with good industrial hygiene and safety practice. Personal protective equipment should be
decontaminated prior to reuse. Gloves must be inspected regularly and prior to each use. Replace if
necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Store work clothing
separately. Hands and/or face should be washed before breaks and at the end of the shift. No eating,
drinking, smoking or tobacco use at the place of work. Keep away from food, drink and animal feeding
stuffs.
9. PHYSICAL AND CHEMICAL PROPERTIES
Form: suspension
Odour: characteristic
Colour: Whtie to Off white
pH value: 7.2 ( 10 g/l)
onset of boiling: approx. 100 °C ( 1,013 hPa) Information applies to the
solvent.
Vapour pressure: approx. 23.3 hPa ( 20 °C) Information applies to the solvent.
Density: 1.03 g/cm3 ( 20 °C)
Vapour density: not determined
Partitioning coefficient n-octanol/
water (log Pow): not applicable
Viscosity, dynamic: approx. 1,600 - ( 21.6 °C)
1,850 mPa.s
Solubility in water: dispersible
Molar mass: 437.15 g/mol
10 STABILITY AND REACTIVITY
Conditions to avoid:
Avoid all sources of ignition: heat, sparks, open flame. Avoid prolonged storage. Avoid electro-static
discharge. Avoid contamination. Avoid prolonged exposure to extreme heat. Avoid extreme
temperatures.
Substances to avoid:
strong oxidizing agents
Hazardous reactions:
The product is chemically stable.
Hazardous polymerization will not occur. No hazardous reactions if stored and handled as
prescribed/indicated.
Decomposition products:
Hazardous decomposition products: No hazardous decomposition products if stored and handled as
prescribed/indicated., Prolonged thermal loading can result in products of degradation being given off.
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Thermal decomposition:
Possible thermal decomposition products:
carbon monoxide, carbon dioxide, nitrogen oxide, Hydrogen chloride, hydrogen fluoride, Sulphur
dioxide Stable at ambient temperature. If product is heated above decomposition temperature toxic
vapours may be released. If product is heated above decomposition temperature hazardous fumes may
be released.
Corrosion to metals:
Corrosive effects to metal are not anticipated.
Oxidizing properties:
Not an oxidizer.
not fire-propagating
11 TOXICOLOGICAL INFORMATION
Acute toxicity
Oral:
Type of value: LD50
Species: rat
Value: 1,999 mg/kg
Inhalation:
Type of value: LC50
Species: rat
Value: > 1.7 mg/l
Exposure time: 4 h
Type of value: LC50

Species: rat
Value: 6.8 mg/l (calculated)
Exposure time: 1 h
Dermal:
Type of value: LD50
Species: rat
Value: > 2,000 mg/kg
Irritation / corrosion
Skin:
Species: rabbit
Result: Slightly irritating.
Eye:
Species: rabbit
Result: Slightly irritating.
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Sensitization:
Species: guinea pig
Skin sensitizing effects were not observed in animal studies.
Genetic toxicity
Information on: fipronil
Results from a number of mutagenicity studies with microorganisms, mammalian cell culture and
mammals are available. Taking into account all of the information, there is no indication that the
substance is mutagenic.
----------------------------------
Carcinogenicity
In long-term studies in rats the substance induced thyroid tumors. In long-term studies in rodents
exposed to high doses, a tumorigenic effect was found; however, these results are thought to be due to a
rodent-specific liver effect that is not relevant to humans.
----------------------------------
Reproductive toxicity
Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the
parental animals.
----------------------------------
----------------------------------
12. ECOLOGICAL INFORMATION

Fish
Acute:
Brachydanio rerio/LC50 (96 h): 3.89 mg/l
Aquatic invertebrates
Acute:
Daphnia pulex/EC50 (48 h): 0.2 mg/l
Aquatic plants
Toxicity to aquatic plants:
green algae/EC50 (96 h): 0.068 mg/l
Common duckweed/EC50 (336 h): > 0.160 mg/l
green algae/EC50 (120 h): > 0.140 mg/l
Algae/EC50 (120 h): > 0.170 mg/l
Algae/EC50 (120 h): > 0.120 mg/l
----------------------------------
Non-Mammals
Other terrestrial non-mammals:
Honey bee/LD50 (48 d): 0,00593 ug/bee (contact)
Honey bee/LD50 (48 d): 0,00417 ug/bee (oral)
----------------------------------
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Degradability / Persistence
Biological / Abiological Degradation
Evaluation: Not readily biodegradable (by OECD criteria).
Other adverse effects:

The ecological data given are those of the active ingredient. Do not release untreated into natural
waters.
13 DISPOSAL CONSIDERATIONS
Waste disposal of substance:
Pesticide wastes are regulated. Improper disposal of excess pesticide, spray mix or rinsate is a violation
of federal law. If pesticide wastes cannot be disposed of according to label instructions, contact the
State Pesticide or Environmental Control Agency or the Hazardous Waste representative at the nearest
EPA Regional Office for guidance.
Container disposal:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner as
the substance/product. Rinse thoroughly at least three times (triple rinse) in accordance with EPA
recommendations. Consult state or local disposal authorities for approved alternative procedures
such as container recycling. Recommend crushing, puncturing or other means to prevent
unauthorized use of used containers.
RCRA:
This product is not regulated by RCRA.
14 TRANSPORT INFORMATION
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Marine pollutant: YES
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains FIPRONIL 5%)
Air transport
IATA/ICAO
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
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INDIA PIN-508252, Phone: 0091 86942 00566
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

(contains FIPRONIL 5%
15. REGULATORY INFORMATION
Federal Regulations
Registration status:
Chemical TSCA, US blocked / not listed
Crop Protection TSCA, US released / exempt
OSHA hazard category: Acute target organ effects reported; Chronic target organ effects reported
EPCRA 311/312 (Hazard categories): Acute; Chronic
16 OTHER INFORMATION
This material should only be used by persons who are made aware of its hazardous properties
and have been instructed in the required safety precautions.
Emergency Telephone Number (0091) –40-23231010(H.O.,Meenakshi Agro chemicals HYD.

(0091) –86942-00566-. Factory, Address: Survey no
500,Koyyalagudem(Vill),Choutuppal (Mandal), Yadadri Bhuvanagiri ( Dist),Telangana -INDIA,Pin-508252,
Address:
Head Office : MEENAKSHI AGRO CHEMICALS.
3-5-823,C7, Hyderabad Bussiness Centre
Hyderguda, HYDERABAD-5000029 Telangana, INDIA
Off: 0091 40 23231010,66667440
Factory Address : Survey no-500,Koyyalagudem(Vill),

Choutuppal (Mandal), Yadadri Bhuvanagiri ( Dist),
Telangana -INDIA,
Pin-508252,
Ph no-0091 86942 00566.
Date of preparation : 11.10.2021
The information presented herein is believed to be accurate and reliable, but is presented without any
warranty, express nor implied, on the part of Meenakshi Agro Chemicals.
MSDS
BITUMODE QATAR WATERPROOFING FACTORY

NEW INDUSTRIAL ZONE, DOHA, QATAR
BITUMODE QATAR WATERPROOFING FACTORY Code: QC-34
Implementation Date Page: 1
04-04-2023
MSDS MEMBRANE
Edition: 4
Bituminous Membrane and Protection Board

This Safety Data Sheet contains information concerning the potential risks to those involved in handling, transporting and
working with the material, as well as describing potential risks to the consumer and the environment. This information must
be made available to those who may come into contact with the material or are responsible for the use of the material. This
Safety Data Sheet is prepared in accordance with formatting described in the REACH Regulation (EC) No 1907/2006 and
described in CLP Regulation (EC) No 1272/2008.
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier

Bituminous Membrane Products Bitumode P APP, Bitumode Flex SBS, Bitumode Protection Board,
Bitumode P APP Anti Root, Bitumode Flex SBS Anti Root Membranes and BITUSELF 1.6, 2.0 and 3.0MM XL.
1.2 Relevant identified uses of the substance or mixture and uses advised against
Roofing and underground and wet area applications membranes.
1.3 Details of the supplier of the safety data sheet
BITUMODE QATAR WATERPROOFING FACTORY

P.O. Box 39199, Doha-Qatar
Email: info@bitumodeqatar.com
www.bitumodeqatar.com
1.4 Emergency telephone number
(974) 44442717
SECTION 2: Hazards Identification
2.1 Classification of the substance or mixture
Classification in accordance with the Dangerous Preparations Directive 1999/45/EC

The product is an article; therefore, no classification is required.
Classification in accordance with the Classification Labelling and Packaging Regulation EC (no) 1272/2008
The product is an article; therefore, no classification is required.
2.2 Label elements
Labelling in accordance with the Classification Labelling and Packaging Regulation EC (no) 1272/2008
None required.
2.3 Other hazards

Under normal conditions of use, this product is not expected to create any unusual emergency hazards. Due to
product form, exposure to dusts and fumes is not expected to occur.
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MSDS MEMBRANE
Edition: 4
SECTION 3: Composition / Information on Ingredients
3.1 Substances
Not applicable, product is an article.
3.2 Mixtures
The products are not mixtures under the CLP Regulation (EC) No 1272/2008, but are considered to be articles. The
products in the range consist of a reinforcing base material coated with bitumen and a surface finish. The base
materials include polyester, glass/polyester and glass fibers in sheet form, some used in conjunction with aluminum
foil. The bitumen coating may contain mineral filler and/or synthetic polymers. The fire performance cap sheets have
an inert graphite coating on the upper surface of the base carrier and the fire performance vapor control layers have
a fire-retardant modified bitumen coating. The surface finish may be sand, talc, mineral granules or polymeric film.
SECTION 4: First Aid Measures
4.1 Description of first aid measures

EYE CONTACT: For contact with cold material, e.g. small particles, wash thoroughly with water and obtain
medical attention if signs of discomfort persist.
In case of contact with hot material, flood eye with copious quantities of cold water for 10-
15 minutes. Do not try to remove material adhering to the eye. Cover the burn area loosely
with a sterile dressing, if available. Seek immediate medical attention.
SKIN CONTACT: For contact with hot material, cool the affected area under cold running water for at least 10
minutes. Do not attempt to remove anything from the burn area or apply burn creams or
ointments. Material adhering to skin will form a sterile barrier which will fall off after a few
days. Cover the burn area loosely with a sterile dressing, if available. Seek immediate
medical attention.
INHALATION: In case of inhalation of fumes, remove from exposure. If breathing becomes difficult seek
medical assistance.
INGESTION: If swallowed, rinse mouth with water.
4.2 Most important symptoms and effects, both acute and delayed.
Eyes: Particulates produced from cutting, grinding or drilling of the product may cause
Mechanical irritation of the eye. Hot melt products may cause thermal burns.
Skin: This product may produce skin abrasions. Mechanical rubbing may increase skin
Irritation. Hot melt products may cause thermal burns.
Ingestion: Not a likely route of entry.
Inhalation: Inhalation of dusts produced during cutting, grinding or sanding of this product or
Fumes from hot melt products may cause irritation of the mouth and nose and
Coughing.
4.3 Indication of any immediate medical attention and special treatments needed.
Symptomatic treatment as required.
SECTION 5: Firefighting Measures
5.1 Extinguishing media

Use any media suitable for the surrounding fires. Water, spray, fog, carbon dioxide (CO2), dry chemical, foam.
5.2 Special hazards arising from the substance or mixture.

Standard bitumen-based roofing membranes are combustible and release dense black smoke when they burn. Fire
performance membranes such as Ultra prevent, Mach One and Safe stick cap sheets have an inert graphite coating
on the upper surface of the base carrier, which when installed produces a significant reduction in the capacity of the
product to burn and reduces smoke emission in a fire situation.
04-04-2023
MSDS MEMBRANE
Edition: 4
5.3 Advice for fire fighters

Firefighters should wear full-face, self-contained breathing apparatus and impervious protective clothing. Firefighters
should avoid inhaling any combustion products. Do not release chemically contaminated water into drains, soil or
surface water.
SECTION 6: Accidental Release Measures
6.1 Personal precautions, protective equipment and emergency procedures

None usually necessary. If there are significant quantities of dust/shavings wear safety glasses with side-shields or
safety goggles and gloves.
6.2 Environmental precautions

None usually necessary
6.3 Methods and materials for containment and clearing up

Sweep up or gather material and place in appropriate container for disposal.
6.4 References to other sections

See sections 8 and 13 for further advice on protective clothing and disposal.
SECTION 7: Handling and Storage
7.1 Precautions for safe handling

Customary personal hygiene measures, such as washing hands after working with these products are
recommended. If dusts or fumes of this product are generated, avoid inhalation, skin and eye contact.
7.2 Conditions for safe storage, including any incompatibilities

Room temperature - normal conditions. Warehouse storage should be in accordance with package directions.
Material should be kept dry, and protected from the elements.
7.3 Specific end uses(s)

No special requirements.
SECTION 8. Exposure Controls/Personal Protection
8.1 Control parameters

No specific exposure limits available.
If process generated dusts or fumes are likely, follow workplace regulatory exposure limits for relevant hazards (e.g.
total dust, respirable dust, silica, talc, asphalt fumes). See Annex 1 for further information.
8.2 Exposure controls
Engineering Controls: No special protective measures are necessary for use of this product in that it is an article,
and under normal conditions of use is not expected to release, or otherwise result in exposure to a hazardous
chemical. If cutting, grinding, drilling, etc. ensure that there is adequate ventilation to keep dust levels within required
limits.
Personal Protective Equipment:
Eyes/Face: Where there is a risk of damage to the eyes/face from splashing of hot product or impact, wear
eye/face protection to EN166.
Skin: The use of heavy duty gloves to protect against skin abrasion and burns through contact with hot
bitumen or flame of gas torch during installation is recommended.
Respiratory: Not required under normal conditions of use. If dust or fumes are generated, wear appropriate
respiratory protection.
Environmental Exposure Controls: Not usually required.

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MSDS MEMBRANE
Edition: 4
SECTION 9: Physical and Chemical Properties
9.1 Information on basic physical and chemical properties

Appearance: Grey – black toned solid material. A variety of colored slate finishes are
Available on top layer felts.
Odour: None
Odour threshold: Not Applicable
pH: Not Applicable
Boiling Point: Not Applicable

Melting Point: Not applicable
Flash Point: Not Applicable
Evaporation rate: Not Applicable
Flammability (gas, solids): Standard bitumen-based roofing membranes are combustible. Fire
performance membranes have a significantly reduced Capacity to burn.
Upper/lower flammability limits: Not Applicable
Vapour Pressure: Not Applicable
Vapour Density: Not Applicable
Specific Gravity: Not applicable
Solubility (H2O): Not soluble
Solubility in other solvents: Not Applicable
Auto Ignition Temp.: No data
Decomposition temperature: No data
Viscosity: Not Applicable
Explosive properties: Not classified as explosive
Oxidizing properties: Not classified as oxidizing
9.2 Other information

None
SECTION 10: Chemical Stability and Reactivity
10.1 Reactivity
Not considered a reactive material.
10.2 Chemical stability

Stable under normal conditions.
10.3 Possibility of hazardous reactions

None expected.
10.4 Conditions to avoid.

None identified.
10.5 Incompatible materials

None identified.
10.6 Hazardous decomposition products

Bitumen fumes and dense black smoke if heated to excessive temperatures.
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MSDS MEMBRANE
Edition: 4
SECTION 11: Toxicological Information
11.1 Information on toxicological effects
This product has not been tested. Judgements on the expected toxicity of this product have been made based upon
consideration of its major components.
(a) Acute toxicity not expected to present an acute toxicity hazard. Inhalation of fumes may result in
irritation, especially if the product is overheated above recommended
temperatures
(b) Skin corrosion/irritation Mechanical abrasion may occur in contact with skin. Thermal burns when
handled at elevated temperatures.
(c) Serious eye damage/irritation not expected to present a hazard to the eyes. Mechanical irritation may
occur in contact with particles. Thermal burns when handled at elevated
temperatures.
(d) respiratory/skin sensitization Not considered to be a skin or respiratory sensitizer
(e) Germ cell mutagenicity contains no components known to be mutagenic.
(f) Carcinogenicity Bitumen may contain substances including polyaromatic hydrocarbons (PAHs), some
types of which have been associated with cancer. However, long-term studies of
bitumen and asphalt workers have not demonstrated any increased cancer risk from
the use of these products, and bitumen has been classified by IARC as Group 3, not
classifiable as to its carcinogenicity to humans.
(g) Reproductive toxicity contains no components known to be hazardous to reproduction.
(h) STOT-single exposure For Torch-on grades, inhalation of fumes may result in irritation,
Especially if the product is overheated above recommended temperatures.
(i) STOT-repeated exposure No chronic health effects are expected from the normal use of this
Product.
(j) Aspiration hazard not relevant.
SECTION 12: Ecological Information
This product has not been tested. Judgments on the expected toxicity of this product have been made based upon
consideration of its major components.
12.1 Toxicity
Not expected to be toxic to the environment.
12.2 Persistence and degradability

Not expected to be biodegradable.
12.3 Bio accumulative potential

Not expected to bio accumulate.
12.4 Mobility in soil

Not expected to be mobile in the environment.
12.5 Results of PBT and vPvB assessment

Not applicable.
12.6 Other adverse effects

None known.
SECTION 13: Disposal Considerations
13.1 Waste treatment methods

Dispose of in accordance with local regulations.
04-04-2023
MSDS MEMBRANE
Edition: 4
SECTION 14: Transport Information
Not considered to be dangerous goods for transport.
SECTION 15: Regulatory Information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
All components are listed as existing substances in Europe
15.2 Chemical Safety Assessment

A Chemical Safety Assessment has not been carried out for this product.
SECTION 16: Other Information
Other information:
This safety data sheet is prepared in accordance with the formatting described in Commission Regulation (EU) No
453/2010.
List of Abbreviations used in this SDS:
CAS Chemical Abstracts Service

CLP Classification, Labelling and Packaging Regulation (EC) no 1272/2008
DSD Dangerous Substances Directive 67/548/EEC
DPD Dangerous Preparations Directive 1999/45/EC
EC European Community/Commission
PBT Persistent, Bio accumulative and Toxic
REACH Registration, Evaluation, Authorization and Restriction of Chemicals Regulation (EC) no 1907/2006 vPvB
very Persistent, very Bio accumulative
Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose. Any product
purchased is sold on the assumption the purchaser will make his own tests to determine the quality and
suitability of the product. Supplier expressly disclaims any and all liability for incidental and/or consequential
property damage arising out of the use of this product. No information provided shall be deemed to be a
recommendation to use any product in conflict with any existing patent rights. Read the Material Safety Data
Sheet before handling product.
Legal disclaimer:
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a
guide. This company shall not be held liable for any damage resulting from handling or from contact with the
above product.
End of MSDS
Implementation Page: 1
Date
04-04-2023
MSDS BITUMODE PRIMER SB
Edition: 6

Name of Product : BITUMODE PRIMER SB
1. CHEMICAL PRODUCT AND COMPANY INFORMATION

Product name BITUMODE PRIMER SB
Manufacturer BITUMODE QATAR WATERPROOFING FACTORY
Address P.O. Box 39199, Doha-Qatar
Emergency Telephone (+974) 44442717
Product use Solvent based primer.
Date April 2023

2. COMPOSITION / INFORMATION ON INGREDIENTS
Type of component CAS # Percentage
Bitumen (Asphalt). 8052-42-4 60 - 65
Petroleum Solvents 8052-41-3 35 - 40
Water Not Available 0
3. HAZARDS IDENTIFICATION
Hazard information Petroleum asphalts or similar materials have been shown to cause
cancer in laboratory animals (Flammable Liquid and Vapour H226
Hazard Category 3)
Primary route of exposure Skin
Effects of acute / chronic
exposure
Skin contact Prolonged and repeated contact may cause irritation to the skin H315
(Hazard category 2)
Eye contact Contact may cause irritation H319.
Inhalation May cause headache, nausea, vomiting or dizziness.
Ingestion Nothing found to suggest toxicity. However, gastrointestinal distress

may occur. (H411)
4. FIRST AID MEASURES

Skin contact Wash with soap and water. If irritation persists, seek immediate
medical attention.
Eye contact Flush out for 15 minutes and if irritation persists, seek medical
assistance.
Inhalation Remove to fresh air. Administer oxygen as indicated. Seek medical
attention.
Ingestion Call a physician or the local Poison Control Centre immediately.
Date
04-04-2023
Edition: 6
5. FIRE FIGHTING MEASURES

Conditions of flammability Keep drums cool to prevent pressure build-up and possible bursting of
drums.
Means of extinction None, not combustible under expected conditions of use
Flash point & means of
determination None
Upper flammable limit N.A.
Lower flammable limit N.A.
Auto-ignition temperature N.A.
Hazardous combustion
products None
Explosion data
Sensitivity to
mechanical impact None
Sensitivity to
static discharge None
6. ACCIDENTAL RELEASE MEASURES

Return to container and sweep up residue with sand and place in a
landfill.
7. HANDLING AND STORAGE
Keep from freezing and do not store in excessive heat. Material can
dry out if drum leaks air.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure controls All chemicals are to be handled in such a manner so as to prevent eye
contact and excessive or prolonged skin contact. Use of appropriate
eye and skin protection gear is advised. Excessive inhalation of dust
and vapors is also to be avoided.
Personal protection
Ventilation Adequate fresh air.
Respirator Not required under normal use conditions.
Eye protection Yes, glasses. Do not wear contact lenses without proper eye
protection.
Protective gear Rubberized gloves
Other -
Date
04-04-2023
Edition: 6
9. PHYSICAL AND CHEMICAL PROPERTIES

Physical state Liquid
Odour and appearance Slight oil / Black liquid
Odour threshold N.A.
Specific gravity 1.00 – 1.02
Vapour pressure 6mm at 41.1°C
Vapour density (Air=1) 4.8
Evaporation rate N.A.
Boiling point 93.3°C – 101.6°C
Freezing point N.A.
Melting point N.A.
pH N.A.
Coefficient of water/oil
distribution N.A.
VOC Content 305.8 g/L
Flash Point > 400 C

10. STABILITY AND REACTIVITY
Conditions causing
instability None known.
Incompatible materials Oxidisers
Conditions of reactivity -
Hazardous decomposition
products Carbon dioxide, carbon monoxide, and Sulphur dioxides
11. TOXICOLOGICAL INFORMATION
Toxicology information
Skin contact Prolonged and repeated contact may cause irritation to the skin.
Eye contact Contact may cause irritation.
Inhalation May cause headache, nausea, vomiting or dizziness.
Ingestion Nothing found to suggest toxicity. However, gastrointestinal distress

may occur.
Date
04-04-2023
Edition: 6
12. ECOLOGICAL INFORMATION
Ecological information N.A.
13. DISPOSAL CONSIDERATIONS

Waste disposal Dispose of in a landfill as per EPA requirements.
14. TRANSPORT INFORMATION

DOT shipping name Asphalt [Cutback]
Technical shipping
name N.E.
DOT hazard
classification
Primary N.E.
Secondary N.E.
Freight classification Class 55
UN number None
IMO hazard class N.A.
DOT labels None
EPA/DOT hazardous
substance N.A.
15. REGULATORY INFORMATION
16. OTHER INFORMATION

Contact person/point Technical Department: (+974) 44442717
History MSDS Creation: Feb 2023
. . . End of MSDS. . .

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QATAR PEST CONTROL COMPANY W.L.

MATERIAL SAFETY DATA SHEET

MATERIAL SAFETY DATA SHEET

1. Identification of the substance / 9. Physical and chemical properties

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

Xn Product Name: fipronil 5% SC w/w

2. COMPOSITION/ INFORMATION ON INGREDIENTS

ISO Name Fipronil

Chemical Name HS Code CAS# Percent or content

Material Use Insecticide

State of matter: liquid

Potential health effects

Medical conditions aggravated by overexposure:

Signs and symptoms of overexposure:

Potential environmental effects

4. FIRST AID MEASURES

Treatment: Treat symptomatically. Anticonvulsant therapy as routinely administered to humans.

5. FIRE – FIGHTING MEASURES

Flash point: > 206.96 °F

Self-ignition temperature: not self-igniting

Hazards during fire-fighting:

Protective equipment for fire-fighting:

6. ACCIDENTAL RELEASE MEASURES

7 HANDLING AND STORAGE

Protection against fire and explosion:

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Advice on system design:

Personal protective equipment

General safety and hygiene measures:

9. PHYSICAL AND CHEMICAL PROPERTIES

10 STABILITY AND REACTIVITY

Type of value: LC50

12. ECOLOGICAL INFORMATION

Evaluation: Not readily biodegradable (by OECD criteria).

Other adverse effects:

Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.

15. REGULATORY INFORMATION

Emergency Telephone Number (0091) –40-23231010(H.O.,Meenakshi Agro chemicals HYD.

Factory Address : Survey no-500,Koyyalagudem(Vill),

Date of preparation : 11.10.2021

BITUMODE QATAR WATERPROOFING FACTORY

MATERIAL SAFETY DATA SHEET

Bituminous Membrane and Protection Board

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

1.3 Details of the supplier of the safety data sheet

BITUMODE QATAR WATERPROOFING FACTORY

1.4 Emergency telephone number

SECTION 2: Hazards Identification

2.1 Classification of the substance or mixture

Classification in accordance with the Dangerous Preparations Directive 1999/45/EC

2.2 Label elements

2.3 Other hazards

SECTION 3: Composition / Information on Ingredients

SECTION 4: First Aid Measures

4.1 Description of first aid measures

SECTION 5: Firefighting Measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture.

5.3 Advice for fire fighters