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    Tutorial 4, 5 & 6 CHM361

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    2021819542
    This document contains a tutorial on inorganic chemistry concepts related to transition metals. It covers: 1) Condensed electron configurations, atomic size trends, oxidation states, and common oxidation states like +2 for transition elements. 2) Coordination numbers, molecular geometries, ligand donor atoms, and determining oxidation numbers and coordination numbers from complex ion formulas. 3) Types of isomerism in complex ions, ligand isomers, and determining if optical isomers exist. 4) Crystal field theory, orbital splitting diagrams, spectrochemical series, and effects of ligands on absorption spectra and color.

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    Tutorial 4, 5 & 6 CHM361

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    2021819542
    62 views4 pages
    This document contains a tutorial on inorganic chemistry concepts related to transition metals. It covers: 1) Condensed electron configurations, atomic size trends, oxidation states, and common oxidation states like +2 for transition elements. 2) Coordination numbers, molecular geometries, ligand donor atoms, and determining oxidation numbers and coordination numbers from complex ion formulas. 3) Types of isomerism in complex ions, ligand isomers, and determining if optical isomers exist. 4) Crystal field theory, orbital splitting diagrams, spectrochemical series, and effects of ligands on absorption spectra and color.

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    This document contains a tutorial on inorganic chemistry concepts related to transition metals. It covers: 1) Condensed electron configurations, atomic size trends, oxidation states, and common oxidation states like +2 for transition elements. 2) Coordination numbers, molecular geometries, ligand donor atoms, and determining oxidation numbers and coordination numbers from complex ion formulas. 3) Types of isomerism in complex ions, ligand isomers, and determining if optical isomers exist. 4) Crystal field theory, orbital splitting diagrams, spectrochemical series, and effects of ligands on absorption spectra and color.

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    62 views4 pages

    Tutorial 4, 5 & 6 CHM361

    Uploaded by

    2021819542
    This document contains a tutorial on inorganic chemistry concepts related to transition metals. It covers: 1) Condensed electron configurations, atomic size trends, oxidation states, and common oxidation states like +2 for transition elements. 2) Coordination numbers, molecular geometries, ligand donor atoms, and determining oxidation numbers and coordination numbers from complex ion formulas. 3) Types of isomerism in complex ions, ligand isomers, and determining if optical isomers exist. 4) Crystal field theory, orbital splitting diagrams, spectrochemical series, and effects of ligands on absorption spectra and color.

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    © All Rights Reserved
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    Download as docx, pdf, or txt
    of 4

    TUTORIAL 4 & 5

    1. Write the condensed subshell electron configuration for:


    a. Zr
    b. V3+
    c. Mo3+

    2. “Atomic sizes decreases at first, then becomes relatively constant.” This


    statement is true for trends across a period in transition metals. Explain why this
    is so.

    3. Explain the major difference between the numbers of oxidation states in


    transition elements with the main group elements.

    4. State why the oxidation state +2 is the most common among transition elements.

    5. Find the oxidation numbers of the transition metal in the following compounds:
    a. FeCO3
    b. MnO2
    c. CuCl2
    d. Cu2(OH)3Cl

    Chm361| Inorganic chemistry


    TUTORIAL 5 & 6

    Subtopic 6.1

    1. What is the meaning of coordination number for a metal ion in a complex ion?
    How does it differ from oxidation number?

    2. Name the molecular geometries associated with coordination numbers of 2, 4


    and 6.

    3. For each of the following ligands, determine the number and type of donor atoms
    in the ligand:

    a. ethylenediamine (en)
    b. oxalate ion (C2O42-)
    c. [EDTA]4-

    4. Determine the coordination numbers of the metal ion in the following complexes:
    a. [Au(CN)4]-
    b. [Co(NH3)4(H2O)2]Cl3
    c. [Au(en)2]Cl3
    d. [Cu(NH3)4]SO4
    e. K2[Ni(CN)4]

    5. Determine the oxidation numbers of the metal ion in the following complexes:
    a. [Cr(C2O4)3]3-
    b. [Mo(en)3]3+
    c. K3[Cr(CN)6]
    d. [PtCl4]2-
    e. [Fe(H2O)5(OH)]2+

    6. State the systematic name for the following compounds:


    a. K3[FeF6]
    b. Na2[CdCl4]
    c. [Co(NH3)4(H2O)Br]Br2
    d. [Pt(en)2Br2](ClO4)2

    7. Give formulas based on the following names:


    a. Tetraamminezinc sulfate
    b. Pentaamminechlorochromium(III) chloride
    c. Dibromobis(ethylenediamine)cobalt(III) sulfate
    Chm361| Inorganic chemistry
    d. Potassium hexacyanoferrate(II)

    Subtopic 6.2

    1. For any of the following that can exist as isomers, state the type of isomerism
    and draw the structures:
    a. [Pt(CH3NH2)2Br2]
    b. [Zn(H2O)(NH3)FCl]
    c. [Pd(CN)2(OH)2]2-
    d. [Cr(NH3)5(NO2)]2+
    e. [Pt(NH3)4I2]2+

    2. Determine the ligands that can form linkage isomers and explain with Lewis
    structures:
    a. SCN-
    b. S2O32-
    c. HS-

    3. Sketch mirror images of each of the following. From these sketches, determine
    whether optical isomers exist and note this fact on the drawings.
    a. [Rh(en)3]3+
    b. cis-[Cr(NH3)2(SCN)4]-

    Subtopic 6.3

    1. According to VB theory, what set of orbitals is used by a Period 4 metal ion in


    forming:
    a. a square planar complex
    b. a tetrahedral complex

    2. A metal ion uses d2sp3 orbitals when forming a complex. State its coordination
    number and shape.

    3. Define crystal field theory.

    4. What is crystal field splitting energy? Explain how it arises for octahedral
    complexes.

    5. Which of these ions cannot form both high spin and low spin octahedral
    complexes:
    a. Ti3+
    Chm361| Inorganic chemistry
    b. Co2+
    c. Fe2+
    d. Cu2+

    6. Draw orbital energy splitting diagram and use the spectrochemical series to show
    the orbital occupancy for each of the following:
    a. [Cr(H2O)6]3+
    b. [FeF6]3-
    c. [Rh(CO)6]3+
    d. [Co(OH)6]4-

    7. Rank the following in the order of increasing Δ and energy of light absorbed:
    [Cr(NH3)6]3+, [Cr(H2O)6]3+, [Cr(NO2)6]3-

    8. [Cr(H2O)6]2+ is violet. Another CrL6 complex is green. Can the ligand be CN-? Can
    it be Cl-? Explain.

    9. The tetraaquazinc(II) ion, [Zn(H2O)4]2+, is colourless. Explain why this might be


    expected.

    Chm361| Inorganic chemistry

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