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Extraction of Aluminium

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EXTRACTION OF

ALUMINIUM
Aluminium is extracted by electrolysis, commonly from bauxite ore using the Hall-
Heroult process

Bauxite Ore Alumina

Alumina is mixed with calcium


Bauxite ore is a mixture fluoride or cryolite to lower its
of hydrated aluminium high melting point of around
oxide that contains 2,000 degrees celsius to 900-
950 degrees celsius. Cryolite
ferric oxide and silica,
also acts as a solvent which
which are impurities.
melts the alumina to increase
Therefore, as part of the its conductivity. This reduces
extraction process, the energy cost of the
bauxite is purified to extraction, as the ions can still
produce Alumina. move freely at low
temperatures.

Reactions at the Reactions at the


Cathode Anode

2Al2O3 + 3C → 4Al + 3CO2


At the anode: Oxide ions are oxidised to form
oxygen molecules. (2O2– →O2 + 4e–)
At the cathode: aluminium ions receive The oxygen molecules from the aluminium
electrons and are reduced to atoms. oxide react with the carbon from the graphite
(Al3+ + 3e– → Al) anode and forms carbon dioxide. As this is a
The aluminium, now in a molten state, sinks to combustion reaction, the anodes gradually burn
the bottom of the tank as it is heavier than the away, and therefore need to be replaced
cryolite solution. regularly.

(C (s) + 2O2- CO2 (g) + 4e–)

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