DIVISION: JEE (MAIN+ADVANCED)

COURSE COURSE
CLASS XI VIKAAS JA
NAME CODE
PHASE 01JA,JAZA,02JA, TOTAL BATCH 01JA,JAZA,02JA,
16
CODE(S) IA,03JA PAGES CODE(S) IA,03JA

JEE (MAIN+ADVANCED) 2025

TEST TEST CODE &

TEST TYPE
PATTERN SEQUENCE 
JEE
PART TEST (PT) APT 02
(ADVANCED) 

15th July 2023 | Saturday

Paper-1 : 3 Hrs | 9:30 AM to 12:30 PM

Paper-2 : 3 Hrs | 2:30 PM to 5:30 PM

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 ANSWER KEY (AK)

PAPER-1
Q.No. 1 2 3 4 5 6 7 8 9 10

Ans. C A C A C A A B A B
PART-I : Q.No. 11 12 13 14 15 16 17 18 19 20
MATHEMATICS Ans. C D 06.00 05.00 52.00 37.50 35.00 03.50 CD AC
Q.No. 21 22
Ans. AD ABC
Q.No. 23 24 25 26 27 28 29 30 31 32
Ans. C B B A D B D D A C

PART-II : Q.No. 33 34 35 36 37 38 39 40 41 42
PHYSICS Ans. A B 15.00 06.00 02.00 09.00 08.00 05.00 A D
Q.No. 43 44
AC AC
Q.No. 45 46 47 48 49 50 51 52 53 54
Ans. B A A D C D A C B C

PART-III : Q.No. 55 56 57 58 59 60 61 62 63 64
CHEMISTRY Ans. D D 01.00 10.50 04.00 02.00 04.00 71.71 ABC ACD
Q.No. 65 66
AB AC
PAPER-2
Q.No. 1 2 3 4 5 6 7 8 9 10

PART-I : Ans. ABD ABC BCD AB AB ABD AD A D C

MATHEMATICS Q.No. 11 12 13 14 15 16 17 18
Ans. 07.00 24.00 05.00 01.00 50.00 04.00 15.00 05.00
Q.No. 19 20 21 22 23 24 25 26 27 28

PART-II : Ans. AB A BD AB ACD BC BD A D B

PHYSICS Q.No. 29 30 31 32 33 34 35 36
Ans. 15.00 02.00 08.00 20.00 02.00 02.00 20.00 20.00
Q.No. 37 38 39 40 41 42 43 44 45 46

PART-III : Ans. ABD BC AC BD BCD BCD ABCD B B C

CHEMISTRY Q.No. 47 48 49 50 51 52 53 54
Ans. 05.00 03.00 06.00 16.00 05.00 08.00 47.00 18.00

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 TEXT SOLUTIONS (TS)
9 3
PAPER-1   m  3  m  0
16 4
PART-I: MATHEMATICS 9 9 m
  0
1. Coeff. of x2 > 0  a > 2 16 4 4
x2 dk xq.kkad > 0  a > 2 m 45

D < 0  64 - 4 (a - 2) (a + 4) < 0 4 16
 (a - 4) (a + 6) > 0 45
 a   ,  6   4,  m<
4
 a  4,  CasefLFkfr-II

K
 9 
(A) Since   3xx
2
2.
 
10 3/4
K (i) D = 0  (m – 3)2 = 4m
 9 
x 2  x  3     0 m2 – 10m + 9 = 0
 10  m = 1,9
For real solution. Disc, of (1)  0 (ii) f(3/4) > 0  m > – 45/4
m–3 3
  9  
K
(iii) + >
 1  4 3      0 2 4
  10   4m – 12 > 6
K K 9
 9   9  m>
  11  4   0  11  4   0 2
 10   10  from (i) and (ii) and (iii)  m = 9
K (i), (ii) vkSj (iii) ls  m = 9
 9 
But 11  4   0K R
 10 
 given equation cannot have a real root.
4. 2
K
 9 
(A) pwfd   3xx –1
2
gy-
 10 
K
 9 
x 2  x  3     0 Clearly, f(–1) > 0, f(2) < 0
 10 
Now f(0) = – 4 < 0
okLrfod gy ds fy,, (1)  0  f(–1) = 1 – a – 4 > 0
 and f(2) = 4 + 2a – 4 < 0
 9  
K
 1  4 3      0  a < – 3 and a < 0
  10    a  (–, –3)
K K
 9   9  gy-
  11  4   0  11  4   0 2
 
10  10 
–1
K
 9 
ijUrq 11  4   0  K  R
 10 
 nh xbZ lehdj.k okLrfod ewy ugh j[krh gSA Li"Vr;k f(–1) > 0, f(2) < 0
vc f(0) = – 4 < 0
3   f(–1) = 1 – a – 4 > 0
3. x2 + x + 1 = t 
 4 ,   vkSj f(2) = 4 + 2a – 4 < 0
  a < – 3 vkSj a < 0
f(t)=t2 – (m-3)t+m=0   a  (–, –3)

5. The given equation is
3 (cos x – 1)(12 cos2x + 5 cos x + 9) = 0
Case fLFkfr-1 f    0
4  cos x = 1
x = 2n, n  Z
Hence It has infinite solution as n  Z
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gy- fn;k x;k lehdj.k gS blh izdkj, tan 9 – tan 3
(cos x – 1)(12 cos2x + 5 cos x + 9) = 0 sin2 2 sin3
 cos x = 1 = 
cos 3 cos  cos 9
x = 2nn, n  Z 2 sin9
vr% vuUr gy n  Z rFkk tan 27 – tan 9 
cos 27
 sin9 sin3 sin 
6. Use cot  – tan  = 2 cot 2  k1  2     2k 2
&solving we get  cos 27 cos 9 cos 3 
– 2ncot 2n =2n 2 2 2
 cot 2n = –1  p  1  q  1  r  1
10.      
   2   2   2 
  2n =  k   , nN
 4  (p + 1)2 + (q + 1)2 = (r + 1)2
p + 1 = 8, q + 1 = 6, r + 1 = 10
gy- cot  – tan  = 2 cot 2ls hence minimum (p + q + r) = 21
gy djus ij
1 1
– 2ncot 2n =2n 11. 2k cos 40º  
 cot 2n = –1 sin20º 3 cos 20º
  3 cos 20º  sin 20º
  2n =  k   , nN =
 4
3 sin 20º cos 20º
7. 16cos A . cos 2A . cos22 A . cos23 A 3 1
 2  cos 20º  sin20º
sin24   2 2 8 cos 40
 sin2 4 A  = 
= 16  4  =  15  3 3
 2 sin40º
 2 sin A  sin 4
15 3k2 = 16
32 so blfy, 18k 4  162k 2  369  1745
sin
= 15 = 1
2 2p  1
sin 12. S = [2(p2 + 1) + 2p] = (2p + 1)
15 2
(p2 + 1 + p) = 2p3 + 3p2 + 3p + 1
aba–b = 2a 2 = p3 + (p + 1)3
8. =
a2 – b2 a2 – b2 b2
1– 13. p( x)  x 6  x 5  x 4  x 2  x 4  x 3  x
a2
2 2 cos x  x 2 ( x 4  x 3  x 2  1)  x 4  x 3  x
= =
1 – tan2 x cos 2x p(a)  p(b)  p(c)  p(d)  (a 4
 a3  a)

9. We have, k1 = tan 27 – tan   (a  1 a) ( a  a

2 4 3
 a 2  1  0)
= (tan 27 – tan 9) + (tan 9 – tan 3) +  a  1  a
2

(tan 3 – tan )
  a  2 ab  4  1
2
Now, tan 3 – tan 
sin2 2 sin  1 2 (1)  4  1 = 6
= 
cos 3 cos  cos 3
14. cot  = 2p + 3, cot  = 2p + 1
Similarly, tan 9 – tan 3
Now vc cosec2 – cosec2 = 24
sin2 2 sin3
=   (1 + cot2) – (1 + cot2) = 24
cos 3 cos  cos 9
 (cot  + cot ) (cot  – cot ) = 24
2 sin9  2(4p + 4) = 24 
and tan 27 – tan 9 =  p + 1 = 3
cos 27 p = 2
 sin9 sin3 sin   cot  = 7, cot  = 5
 k1  2     2k 2
 cos 27 cos 9 cos 3  tan   tan 
Now vc, tan ( + ) =
gy- ;gk¡, k1 = tan 27 – tan  1  tan  tan 
= (tan 27 – tan 9) + (tan 9 – tan 3) + 1 1

(tan 3 – tan ) 12 / 35 6 m
= 7 5 = = =
sin2 2 sin 1 1 34 / 35 17 n
vc, tan 3 – tan  =  1 
cos 3 cos  cos 3 7 5

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15. Given fn;k gqvk gS (a + b) n   15  1

17. Sn  160  2   n  1 
 sin  cos  

4 4
2  7  7
  = 1

 a b  
 160 
n
n  29
b a 14
 sin4  + cos4  + sin4  +
a b   n2  29n  2240  0
cos4 = (sin2 + cos2 )2  (n – 35) (n + 64) = 0
 b   a
2

2
 n = 35
  sin2     cos2   – 2
  
 a   b  18. x3 – px2 + qx = 0 ...(1)
sin2  cos2  = 0 x(x2 – px + q) = 0
2
 b a  ; x = 0, x2 – px + q = 0
  sin2   cos2   = 0

 a b   0, ,  are the roots of equation (1)
b
sin2  
a
cos2  2 = p   = p/2 ...(2)

a b & 2 = q ...(3)
sin2  cos2  Since  is the root of the equation
  3x2 – 7ax + b = 0 also,  32 – 7a + b = 0
a b
7ap
sin4  cos4  3q – + b = 0 [using (2) & (3)]
  =  (sayekuk) 2
a2 b2 7 3q  b
Now from given condition vc nh xbZ 'krZ ds   7ap = 2(b + 3q)  =
2 ap
vuqlkj gy- x3 – px2 + qx = 0 ...(1)
 sin4    cos4   1 x(x2 – px + q) = 0 ; x = 0,
a  + b  
 ab
2 2
 a   b
x2 – px + q = 0
1
 a + b =
ab  vFkkZr~ 0, ,  nh x;h lehdj.k (1) ds ewy gSA
1 2 = p   = p/2 ...(2)
 =
(a  b)2 vkSj  2 = q ...(3)
sin8  cos8  pw¡fd '' lehdj.k 3x – 7ax + b = 0 dk ewy
2
Hkh
L.H.S. =  gSA
a3 b3
2 2   32 – 7a + b = 0
 sin4    cos4  
= a  + b  7ap
 a 
2
 b
2
 3q – +b=0 [(2) vkSj (3) ls]
2
= (a + b) 2 7 3q  b
2  7ap = 2(b + 3q)  =
 1  1 2 aq
= (a + b)  2 
=
 (a  b)  (a  b)
3

Sol.(19-20)
now put a = 3 & b = 4   = 7, n = 3
sin  + sin  = –a, sin  . sin  = b
  
 2 sin  cos   a …(i)
16. 1,6,11,.......  2   2 
T2019 = 1 + (2019 – 1) 5 = 10091 cos  + cos  = – c, cos  . cos  = d
9,16,23,.......
T2019 = 9 + (2019 – 1) 7 = 14135   
 2 cos  cos   c …(ii)
P : {1,6,11,......10091}  2   2 
Q : {9,16,23,......14135} Eq. (i) divided by eq (ii)
Common terms mHk;fu"B in : 16,51,86 (i) dks (ii) ls foHkkftr djus ij
Tk  10091  a
16 + (k – 1) 35  10091  tan 
 2  c
 35k  10110
 k  288.85
 n(P  Q) = n(P) + n(Q) – n (P  Q)
= 2019 + 2019 – 288
= 3750

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 
2 tan 
1. sin(  )   2 
 
1  tan2  
 2 
2a N2 = F2 + (mg)2
c 2ac
=  2 N = 10 2 N
a 2
a  c2
1 2
c 27. From perpendicular to incline
 2 urry ds yEcor ls
1  tan   1 a
2

2. cos ( + ) =  2 = c2 S = ut + 1 at 2
2     a2 2
1  tan   1 2
 2 
 
c
0 = 10T + 1 5 3 T2
c a2 2
2
=
c 2  a2 T=
4
sec
3
Sol.(21-22) From along the incline
 urry ds vuqfn'k ls
 f(x) = ax2 + bx + c = 0 1 2
S = ut + at
 2
2
 f(3) = 0  9a + 3b + c = 0 ......(1) R = 0 + 1  5   4 
and vkSj f(5) = –3f(2) 2  3
 25a + 5b + c = – 3(4a + 2b + c) R=
40
m
 37a + 11b + 4c = 0 ...... (2) 3
by (1) ls 36a + 12b + 4c = 0 ........(3) 28. Average velocity = 0 because net
(2) – (3) displacement of the body is zero.
 a–b=0  a=b vkSlr osx = 0 D;ksafd oLrq dk dqy foLFkkiu
b 'kwU; gSA
 +  = – = – 1 as a = b
a Average speed = Total dis tan ce cov ered 2 Hmax

Time of fight 2u / g
 ax + bx + c = a(x – 3)(x + 4)
2

put x = 1 j[kus ij dqy r; nwj h 2 Hmax

vkSlr osx = 
 a + b + c = a(–2)(5) dqy le; 2u / g
2u2 / 2g
--------------------------------------------------------------  v av   v av  u / 2
2u / g
Velocity of projection = v (given)
PART-II: PHYSICS iz{ksI; dk osx = v (given)
 vav = v/2
23. Acceleration = 4/2 = 2
mg  a 
T= kg-force.
g 29. (i)
24. Refer to answer key a=0

2v y 2  12 12
25. t =   sec N = F.
g 10 5
12
(ii)
15
2F F
a= =
4m 2m
9  ucos 
26. F.B.D. of block (CykWd dk FBD)
F – N = ma
 F  F
N=F– m   = .
 2m  2

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 bt 3
 s=  vo t
(iii) 6
3F
a=
4m 34. u=0 vmax
rest
A B C
F – N = ma From v2–u2=2as ls
N = F – ma 1 2
 3F  SBC  S AB  at
N=F– m   2
 4m   SAC = SAB + SBC = at2
F  Total time taken for motion
N=
4 between A and C = 2t
 A rFkk C ds chp xfr esa fy;k x;k dqy
le; = 2t
(iv) Now for the return journey from C to A (SAC
3F = at2)
a=
4m C ls A rd ykSVus ds nkSjku (SAC = at2)
1 2 1
S AC  ut  at  at 2  0  at12  t1  2t
2 2
Hence total time in which point returns to
initial point
 3F 
2F – N = ma N = 2F – m   bl izdkj d.k }kjk izkjfEHkd fLFkfr esa ykSVus esa
 4m 
fy;k x;k le;
5F
N=
4
. T  2t  2t  (2  2 )t

35. T1 – 60 = 6 × 2
(v) T2 – 40 = 4 × 2
3F F T1 3
a= = =
3m m T2 2
36. w.r.t. person O;fDr ds lkis{k
4  1t
± tan45º =
F 3
N + F = ma N+F= m  
m
N = 0.

30. Refer to answer key

31. Horizontal velocity {kSfrt osx v x = 20 m / s
Vertical velocity Å/okZ/kj osx vy = u + gt = 0 +
10 × 5 = 50 m/s
Net speed dqy pky
v v 2x  v 2y  (20)2  (50)2  54 m / s
32. Refer to answer key
33. Given, acceleration a = bt
fn;k x;k gS fd Roj.k a = bt 4  1t
= ±1
3
dv bt 2
  bt  v  c t = 1,7
dt 2 t = 7 – 1 = 6.
At t = 0 ij, v = v0  c = v0
bt 2 37. Refer to answer key
So, v =  vo
2
H tan 
ds bt 2 38. 
   vo R 4
dt 2
 = 45° & R = 36 m
H=9m
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 20 N

a0
39.
F 12 mg
a= = = 1 m/s2
M 84 --------------------------------------------------------------

PART-III: CHEMISTRY
 12 – NAB = 4(a) 2.(14x  2)  1.(14y)
45. M m ix. = = 20
 12 – NAB = 4(1) 3
NAB = 8N. 28x + 14y = 56 ...(1)
1.(14x 2) 2.(14y )
M m ix. = = 24
3
40. 14x + 28y = 70 ...(2)
N2 cos 60°
N1 cos 30° 1/ 2
N1 N2  150  150
46.  1 =     V1 = 2
30° 60°  V  1
N1 sin 30°
N2 sin 60° 150
 V1 = = 75 V
(1.41)2
2 1
60° 30° 150
and V2 = = 50 V
N1 sin 30° = N2 sin 60° (1.73)2
N1 cos 30° + N2 cos 60° = mg Hence potential should be dropped by25 V.
Solving above equation mijksDr lehdj.k dks (vr% foHko 25 V ls de fd;k tkuk pkfg,A)
47. Electron jumps from 2s to 3d state.
gy djus ij
Total number of radial nodes in 3d = (n – 
mg 10  10 – 1) = 3 – 2 – 1 = 0.
N2 =   50
2 2 gy % bysDVªkWu 2s ls 3d voLFkk esa tkrk gSA
3d esa dqy f=kT;h; uksM dh la[;k = (n –  – 1)
41. (41 to 42)
= 3 – 2 – 1 = 0.
VB,A  VB  VA =
 14 ˆ 14 ˆ   2 ˆ 2 ˆ 
 i j   i j
 2 2   2 2 
= 8 2 ˆi  6 2 ˆj
In 'A' frame. 'B' moves with constant
velocity as shown
'A' ds rU=k esa, 'B' n'kkZ;s vuqlkj vpj pky ls 48.
xfr djsxk

Electron finding probability at xy, xz & yz

planes and along z-axis.
3dz2 has zero radial (i.e. spherical) node
and two conical nodes, none of which is
planar.
bysDVªkWuks ds ik;s tkus dh izkf;drk xy, xz o yz
ry ij rFkk z-v{k ds vuqfn'k gksrh gSA
45 45  4 
dmin = sin 53º =   = 9 m. 3dz2 d{kd 'kwU; f=kT;h; ¼vFkkZr~ xksyh;½ uksM
4 4 5
rFkk nks dksfudy uksM j[krk gS] bues ls dksbZ Hkh
43. Weight of block CykWd dk Hkkj = m(g – a)
leryh; ugh gksrk gSA
= 1 (10 – 5) = 5N
44. ma0 = 20 – m(g) 49. C + O2  CO + CO2
a0 = 20 – 10 Apply POAC on C and O
= 10 m/s2 1 × nC = 1 × nCO + 1 × nCO2
2  nco  nco …(i)
2

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 2  nO2  1 nCO  2  nCO2 (b) II give +ve test with neutral FeCl3 due to
presence of phenolic –OH group, but (I)
2

2.5 = nCO  2nCO2

does not.
From equation (i) and (ii) (c) In (I) aromatic aldehyde does not give
nCO = 1.5, nCO2 = 0.5 Fehling test but (II) gives.
nCO 1.5 (d) In (I) and (II) acidic hydrogen atom is
So, ratio  3 present so both give +ve test with Na
nCO2 0.5
metal.
gy. C + O2  CO + CO2 gy % (a) nksuksa tyh; NaHCO3ds lkFk ijh{k.k ugha
C rFkk O ij POAC yxkus ij nsrs gSA
1 × nC = 1 × nCO + 1 × nCO2 (b) II mnklhu FeCl3 ds lkFk ijh{k.k nsrk gS
2  nco  nco …(i) D;ksafd blesa QhukWfyd –OH lewg mifLFkr gSA
2
(c) (I) esa ,SjksesfVd ,fYMgkbMª QSgfyax ijh{k.k
2  nO2  1 nCO  2  nCO2 2

ugha nsrk gS tcfd (II) nsrk gSA

2.5 = nCO  2nCO2
(d) (I) rFkk (II) nksuksa esa vEyh; gkbMªkstu
lehdj.k (i) rFkk (ii) ls mifLFkr gS blfy, nksuksa Na /kkrq ds lkFk
nCO = 1.5, nCO2 = 0.5
ijh{k.k nsrs gSA
vr% vuqikr nCO  1.5  3
nCO2 0.5 54. Acetaldehyde and Propyne can be
distinguish by tollen's reagent and Iodoform
50. Mn = 1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 5s2 test.
 In Mn4+ number of unpaired electrons = 3 ,slhVSfYMgkbM vkSj izksikbu dks VkWysu vfHkdeZd
So, Charge on Manganese ion = 4 + . vkSj vk;ksMksQkWeZ ijh{k.k }kjk foHksfnr fd;k tk
So, x = 4 ldrk gSA
gy- Mn = 1s2, 2s2, 2p6, 3s2, 3p6, 3d5, 5s2
  Mn4+ esa v;qfXer bysDVªkWuksa dh la[;k = 3 55. Refer to Answer Key
blfy,, eSaXuht vk;u ij vkos'k = 4 + . vr% ,
56. The block of an element corresponds to the
x=4
type of subshell which receives the last
CHO
O / Zn
electron : 28Ni–[Ar] 3d8 4s2.
51. 
3
 2HCHO + Group number = 8 + 2 = 10
H2O
CHO gy- ,d rRo dk CykWd ml midks'k ds çdkj ij
O3 / Zn
  HCHO + + fuHkZj djrk gS ftlesa vfUre bysDVªkWu Hkjk tkrk
H2O
gS 28Ni–[Ar] 3d8 4s2
CH3CHO oxZ la[;k = 8 + 2 = 10
O / Zn

3
 HCHO + h
H2O 57.  p. x  
4
H—C—C—C—H + CHO  2x = p (given) (fn;k x;k gS)
O O O CHO ( p)2 h
O / Zn
 

3
 O + CHO– 2 4
H2O
h
CHO + HCHO  m2 (v)2  {p = mv}
2
CH3–CH h
52. , groups gives v 
| 2m2 
OH
1 h 1
positive iodoform test.  v  or v 
m 2 m
gy % , CH3–CH lewg /kukRed
|
OH 58. Mn - 1s2 2s2 2p6 3s2 3p6 3d5 4s2
vkW;ksMksQkWeZ ijh{k.k nsrk gSA (I) n +  = 4 for 3p & 4s electrons. Hence,
total = 6 + 2 = 8
53. (a) Both does not give the test with aq. (II) m = 0 for all s-electron and two-p
NaHCO3. electron and one d-electron. Hence, total =
13.

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gy. Mn - 1s2 2s2 2p6 3s2 3p6 3d5 4s2 66. Monochloro products are 1-chlorohexane,
(I) 3p rFkk 4s bysDVªkWuksa ds fy, n +  = 4 A vr% 2-chlorohexane and 3-chlorohexane.
eksuksDyksjks mRikn 1-DyksjksgsDlsu, 2-DyksjksgsDlsu
dqy bysDVªkWu = 6 + 2 = 8
rFkk 3-Dyksjks gsDlsu gSA
(II) lHkh s-bysDVªkWu vkSj nks p-bysDVªkWu vkSj ,d
d-bysDVªkWu ds fy;s m = 0 gS blfy, budh dqy PAPER-2
la[;k 13 gSA
PART-I: MATHEMATICS
n(n  1)
59. =6 n=4
2 1. f ( x)  0
E = Separation energy
So D  0
22 13.6eV
= 13.6 eV × 2  64a2  16a  0
4 4
 I.E. (H-atom) = 13.6 eV  1
a  0, 
=4× 
 13.6eV   4
= 4 × E
 4 
n(n  1)
gy. =6 n=4
2 O
(B)  
E = i`FkDdj.k ÅtkZ = 13.6 eV ×
2
2 13.6eV
2
 f(0) = a < 0 so zero lies between  & 
4 4 f(0) = a < 0 vr% 'kwU;  rFkk ds e/; fLFkr
 I.E. (H-ijek.kq) = 13.6 eV = 4 ×
gSA
 13.6eV 
 = 4 × E
 4   
(C) f(0) > 0 & rFkk f(1) > 0 & rFkk
60. C5H8 , (Molecular O 1
Mass vkf.od nzO;eku = 68) D>0
4
a > 0 & rFkk a & rFkk a(4a – 1) > 0
61. CH3 – CH2 – CH2 – CH2 – NH2 , 7
 1 4
so blfy, a  , 
, 4 7
So (C) wrong vr% (C) vlR; gSA
(D) for f ( x )  0 mini a = 0
f ( x)  0 ds fy, U;wure a = 0
f(x) = 4x2
,
mini f(x) = 0 correct
U;wure f(x) = 0 lR; gSA
62. % of chlorine ¼Dyksjhu dh izfr'krrk gS½ 2. f(1) = 0 one root is x = 1
35 . 5 Mass of AgCl
=   100
143 . 5 Mass of substance
35 . 5 0 . 287
=   100  71 . 71 % .
143 . 5 0.099

63. Spin quantum number had to be introduced

to account for the splitting of spectral lines
f(0) < 0  r + p – 2q < 0  r p < 2…….
under the electric field (stark effect). q
pØ.k Dok.Ve la[;k oS|qr {kS=k ds vUrxZr (A)]
LisDVªe js[kkvksa ds foikVu dks le>kus ds fy, r  p – 2q
Product of roots = = 1  =
nh xbZ gSA ¼LVkWdZ izHkko½ p  q – 2r
64. Theory based rational (B)
Also (r + p) < 2q  (r + p)2 < 4q2
65. Alkenes are hex-2-ene and hex-1-ene. 4q2 – 4pr > (p – r)2  Roots of
,Ydhu gsDl-2-bZu rFkk gsDl-1-bZu gSaA px2 + 2qx + r = 0 are real and distinct
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gy- f(1) = 0 dsoy ,d ewy x = 1 gSA
6. tan A + tan B + tan C = tan A tan B tan C = 3 tan
B = 6 tan A
 3 tan A + tan C = 6 tan A
tan C = 3 tan A
 tan A + 2 tan A + 3 tan A = tan A . 2
tan A . 3 tan A i.e. vFkkZr~ tan A = tan3A
f(0) < 0  r + p – 2q < 0 i.e. vFkkZr~ tan2 A = 1 i.e. vFkkZr~
 r  p < 2……. (A)] tan A = 1  A

q 4
r  p – 2q  tan A tan B = 2 tan2A = 2
ewyksa dk xq.kuQy = = 1  =
p  q – 2r
7. Let four numbers in A.P. are a, a+x, a+2x &
ifjes; (B) a+3x respectively then
rFkk (r + p) < 2q  (r + p)2 < 4q2 2 (–x) + 4k x2 + 8x3 = 2 (–3x) + 4x2 + (–x)3
4q2 – 4pr > (p – r)2  px2 + 2qx + r = 0 9x3 + (4k – 4)x2 + 4x = 0
ds ewy okLrfod rFkk fHkUu fHkUu gSA x(9x2 + 4(k – 1) x + 4 = 0 (x  0 as a, b, c,
3. Given equation is d are distinct)
x2 + 2(a + 1)x + 9a – 5 = 0 9x2 + 4(k – 1) x + 4 = 0
D = 4(a + 1)2 – 4(9a – 5) = 4(a – 1) (a – 6) Now x  R as a, b, c, d are real.
 D  0  a  1 or a  6  roots are Hence 16(k – 1)2 – 16.9  0
real (k – 1)2  9
If a < 0, then 9a – 5 < 0. Hence, the k 1  3
products of roots is less than 0. So, the So the correct options are A & D
roots are of opposite sign. If a > 7, then gy- ekuk pkj la[;k,a a, a+x, a+2x vkSj a+3x
sum of roots is –2(a + 1) < 0. Product of
roots is greater than 0.
lekUrj Js.kh esa gS rc
gy- fn;k x;k lehdj.k 2 (–x) + 4k x2 + 8x3 = 2 (–3x) + 4x2 + (–x)3
9x3 + (4k – 4)x2 + 4x = 0
x2 + 2(a + 1)x + 9a – 5 = 0
x(9x2 + 4(k – 1) x + 4 = 0 (x  0, a, b, c, d
D = 4(a + 1)2 – 4(9a – 5) = 4(a – 1) (a – 6)
fHkUu fHkUu gSA)
 D  0  a  1 ;k a  6  nksuksa ewy
9x2 + 4(k – 1) x + 4 = 0
okLrfod gSA vc x  R as a, b, c, d okLrfod gS
;fn a < 0 rc 9a – 5 < 0 vr% ewyks dk vr% 16(k – 1)2 – 16.9  0
xq.kuQy 'kwU; ls de gS (k – 1)2  9
blfy, ewy foijhr fpUg ds gSA ;fn a > 7 rc k 1  3
ewyksa dk ;ksxQy –2(a + 1) < 0 ewyksa dk xq.ku
blfy, lgh fodYi A vkSj D gSA
'kwU; ls cMk gSA
Sol. (8 to 10)
4. cos 3 + sin 3 + 2 sin 2 sin  – 2 sin 2
cos  – 3 sin  + 3 cos  > 0 x2 – x  1
() y=
 cos 3 + sin 3 + cos  – cos 3 – sin 3 x2  x  1
– sin  – 3 sin + 3 cos  > 0 = (y –1)x2 + (y + 1)x + (y – 1) = 0
 4 (cos  – sin ) > 0  x  R, D  0
3   (y +1)2 – 4(y – 1)(y – 1)  0
 cos  > sin   (2n – , 2n )  y2 + 2y + 1 – 4(y2 – 2y + 1)  0
4 4
 –3y2 + 10y – 3  0
 3y2 – 10y + 3  0
 (3y – 1)(y – 3)  0
1 
y   ,3 
3 
least positive integral is 1
5. cos2+ cos2 (cos–2cos  U;wure /kukRed iw.kk±d 1 gSA
cos (+ cos (
number of positive integral is 3
 cos2+cos2(+cos2(–
/kukRed iw.kk±d ekuksa dh la[;k 3 gSA
(cos(– cos– –  cos(
= cos2cos2(cos
cos
 cos2cos2 (+(cos2(+– sin2
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 5 15. x2 + (20)1/4x + 51/2 = 0 , B + B = ?
() y=1+ =1+
x 
5
x  x 1
2
2 2
 5
2
 20x 2
 1 3
x  2  4
 
x4 + 5 + 2 5 x 2 = 20 x 2 = 2 5 x 2
 23 
so range is  1 ,  x 4  –5 

 3  
x  25 
8

 23 
blfy, ifjlj  1 ,  gSA  = 25 , 8 = 25
8
 3 
8 + 8 = 50
x2  2 1
() y= =1+
x 12
x 1 2  
16. cos2  cos x  s inx 
so range is (1, 2] 2 
blfy, ifjlj (1, 2] gSA 
 
= 1 + tan2  x  tan2 x 
11. f ( x)  9 sin x  16 cos x 
2 2
 4 
10(3 sinx  4 cos x) L.H.S  1 R.H.S  1
10(3 sin x  4 cos x )  100 so both side will be equal blfy, nksuksa rjQ
 25sin x  60sinx  84
2 leku gSA
 
 (5 sinx  6)2  48 cos2  cos x  s inx  = 1 and 1 +
The minimum value of f(x) occurs when sin 2 
x = 1.   
f(x) dk U;wure eku gksxk tc sin x = 1. tan2  x  tan2 x  =1 ........ (ii)
 4 
Therefore, the minimum value of f ( x ) is 7. 
(cos x + sin x) = n
f (x ) dk U;wure eku 7 gSA 2
cos x + sin x = 2n
3 cos x + sin x = 0
12. 4 sin3 x cos3x  4 cos3 x sin3x 
2 tan x = –1
or ;k 
x = n – [this satisfy equation (ii) also]
(3 sin x  sin 3x ) cos 3x  (3 cos x  cos 3x ) 4
3 
sin3x  x = n – [;g lehdj.k (ii) larq"V djrs gSA]
2 4
3 number of solution in (–2, 2] is 4
or ;k 3[sinx cos3x  cos x sin3x ]  (–2, 2] esa gyksa dh la[;k 4 gSA
2
1
or ;k sin4x 
2 17. tan x =  3
2 5
13. 12 sinx + 5 cosx  [–13, 13]  , x
3 3
& vkSj y2 – 4y + 17 = (y – 2)2 + 13  13
2 5
12 5   , 
So blfy, y = 2 & vkSj sin x  3 3
13 13
1
cosx = 1  cos x = 
sin(x  )  sin  / 2 2
2 4
tan   5/12  x= ,
3 3
xy
x    / 2  12cot 2 4
2   , 
3 3
= 12cot(  / 2  )  12tan   5
 
–= = K=3
14. LHS = (cos 24° – cos 84°) – (cos 12° – cos 3 K
48°)
2 sin 54° sin 30° – 2 sin 30° sin 18° 18. (a + 2d) = 4a  3a = 2d
sin 54° – sin 18° We have given that a + 5d = 17
cos 36° – sin 18°  a + 5  3a  = 17
5 1 5 1 1  2 
– = a=2 , d=3
4 4 2
so series 2 , 5 , 8 .......
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gy- (a + 2d) = 4a  3a = 2d 52 = Vx2 + Vy2 = Vx2 + 42
gesa fn;k x;k gS fd a + 5d = 17  Vx = ± 3m/s
 a + 5 
3a  Vx  ux
 = 17 a=2 , d=3
Vx = ux + axt  t =
 2  ax
vr% Js.kh 2 , 5 , 8 .......
34
t1 = = 2.5 s
-------------------------------------------------------------- 0.4
3  4
t2 = = 17.5 s]
PART-II: PHYSICS –0.4
23. v = u + at
= 10 m/s
 F  2F 1 2
19. In figure-1 (fp=k-1 esa) FBC = 2m    S= at = 40 m
 9m  9 2
 F  5F 1
FAB = 5m   S = ut + at2
 9m  9 2
In figure-2 (fp=k-2 esa) FBC = 1
– 40 = 10t + (– 10)t2
 F  7F  F  4F 2
7m   FAB = 4m 
 9m 
 t = 4.
 9m  9 9
24. u = 0, a = a0
20. Suppose of acceleration of wedge a1 v2 = u2 + 2a0x
towards right and acceleration of sphere a2  v = 2a0 x v x
downward
ekuk ost dk Roj.k a1 nka;h rjQ gS rFkk xksys v = u + at  v  t]
dk Roj.k a2 uhps dh rjQ gSA 25. Slope of A is greater than slope of B.
A <ky B ls vf/kd gSA  aA > aB
1 2
S= at ( u = 0)  SA > SB
2

26. vx = 40 cos60º = 20
v2 = v 2x + v 2y
2
 40  2
  = (20) + v y
2
mg – N cos = ma2 ...........(i)
 3 
N sin = ma1 ...........(ii)
20
vy =
3
20
vy 1
tan = = 3 =
vx 20 3
 = 30º
From wedge certain caf/kr xfr ls v 2y = u2y + 2aysy
a2 cos = a1sin ...........(iii) 160
sy = m
From (i),(ii) & (iii) ls 3
a2 = g sin2
27. Net velocity is equal to horizontal velocity,
= 5 m/s2 . hence particle is at highest point.
21. Refer to answer key
dqy osx {kSfrt osx ds cjkcj gS vr% d.k
vf/kdre ÅWapkbZ ij gksxkA
22. Since acceleration is in x direction only,
28. Particle will strike the ground with same
velocity in y-direction will not change.
initial velocity making same angle with the
When speed = 5 m/s
horizontal.
Roj.k dsoy x fn'kk esa gS vr% y- fn'kk dk osx d.k tehu ij leku izkjafHkd pky rFkk leku
ifjofrr ugh gksxkA izkjafHkd dks.k ds lkFk VDdjkrk gSA
tc pky 5 m/s gSA
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29. T1 – 60 = 6 × 2 T2 – 40 = 4 × 2 u 1
= u cos   cos =
T1 3 3 3
 =
T2 2 u2 sin 2 2u2 sin cos
R = =
a 2a g g
30. t 
u  u cos 60 u 2u2 2 2 1 4 2 u2
=   =
Displacement = a foLFkkiu = a g 3 3 9g
Distance = t × u = 2 a nwjh = t × u = 2 a --------------------------------------------------------------
31. Area under a–t graph = change in velocity PART-III: CHEMISTRY
a–t vkjs[k dk {ks=kQy = osx esa ifjorZu
 1/2(1 + 4) × 3 = v – 0.5 v = 8 m/s. 37. Refer to answer key

80 38. (A) 1s2, 2s2, 2p2x , 3s2, 3p2x and 3d1xy

32. y = 80x – 4x2, R = = 20
4 orbitals have ( + m) = 0. So no. of
33. Time of flight mMM;u dky, T electrons = 11
2usin  2u 1
= = tan  (C) |Total spin| = 5 × = 2.5
gcos  g 2
u (D) Spin states = spin multiplicity= 5 + 1= 6.

gy. (A) 1s2, 2s2, 2p2x , 3s2, 3p2x rFkk 3d1xy d{kd
( + m) = 0 bysDVªkWuksa dh la[;k = 11 j[krs gSA
1
 (C) |dqy pØ.k | = 5 × = 2.5
2
1 (D) pØ.k voLFkk = pØ.k cgqxq.kdrk=5+1=6.
 Range ijkl = u cos T + gsin.T2
2
2u2 gsin  4u2 39. (A) orbital is 3s.
= sin   . 2 tan2 
g 2 g
4r R (r)

2u2 2u2
2

= sin [1 + tan2] = tan. sec.

2

(B)
g g
Hence vr% n = 2.
r
34. Choose the floor of the elevator as (C) For radial nodes
reference. The observer is inside the  6  36 – 24 2r
=  =3± 3
elevator take the downward direction as 2 3a o
positive.
93 3
fy¶V ds Q'kZ dks funZs'k fLFkfr ds :i esa ysrs gSA r= ao
2
izs{kd fy¶V ds vUnj gS ,oa uhps dh vksj fn'kk dks
/kukRed ysrs gSA 9–3 3
first R.N. has r = ao
Acceleration of bolt relative to elevators is 2
fy¶V ds lkis{k cksYV dk Roj.k 93 3
2nd R.N. has r = ao
a' = g –(–a) = g + a 2
1 1 2h gy- (A) d{kd 3s gSA
h = a' t 2 = (g  a)t 2  t=
2 2 ga
4r R (r)

TC
2

(B)
2

TC TC r
35. = TA = TB. TB (C) f=kT; uksMks (radial nodes) ds fy,
2 2
 6  36 – 24
=
TA 2
36. At maximum height v = u cos  2r 93 3
=3± 3 r = ao
vf/kdre Å¡ p kbZ ij v = u cos 3a o 2

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 9–3 3 44. Refer to answer key
izFke R.N. ds fy, r = ao
2 45. Refer to answer key
93 3 46. Therory based
2nd R.N. ds fy, r =
ao
2 47. 5, Mn+2 (25) = 1s2 2s2 2p6
 y z y = 0 0 1
40. CxHyOz+  x    O2xCO2+ H2O
 4 2  2 M= 0 0 -1 0 1 0
3s2 3p6 3d5 4s0
134.4 108
1 mole 0 1 2
22.4 18 -1 0 1 -2, -1,0 +1, +2
= 6 mole = 6 mole
From stoichiometry, x = 6 and y = 12 Total number of electrons having m = -1 is 5
So, formula of organic compound m = -1 j[kus okys dqy bysDVªkWUl dh la[;k 5 gSA
= C6H12Oz. 48. (C), (D) and (F) are false
However, the value of z cannot be (C) EF is simplest whole number ratio of
predicted. So, possible formulae are atoms of various element in the compound.
C6H12O6 and C6H12O. (D) EF and MF can be same also.
 y z y (F) In 100 g Ca 16 O 8 …….
gy. CxHyOz+  x    O2xCO2+ H2O 40 16
 4 2 2
or Ca 2 O 1 ………..
134.4 108
1 eksy 5 2
22.4 18  In 1000 g Ca4O5……….
= 6 eksy = 6 eksy (C) (D) rFkk (F) vlR; gSA
jllehdj.kferh ls, x = 6 rFkk y = 12 (C) EF ;kSfxd esa fofHkUu rRoksa ds ijek.kqvksa dk
blfy,] dkcZfud ;kSfxd dk lw=k = C6H12Oz. ljyre iw.kkZad vuqikr gSA
;|fi] z dk eku ugha crk;k tk ldrk gS] (D) EF rFkk MF leku Hkh gks ldrs gSaA
blfy, lEHkkfor lw=k C6H12O6 rFkk C6H12O gSaA (F) 100 g esa Ca 16 O 8 …….
40 16
41. 1º and 2º amine can be differentiated by
vFkok Ca 2 O 1 ………..
Carbylamine test. 5 2
1º o 2º ,ehu dks dkchZy ,ehu ijh{k.k }kjk 1000 g esa Ca4O5……….
foHksn fd;k tk ldrk gSA
49. (b), (c), (d), (f), (g), (h).
42. (A) CH3–CH=C=CH–CH3 h 4h
(1) O

3  CH3–CH=O+O=C=O 50. x × p = or = 16 x
(2) Zn,H2O 4 P
(B) CH3–CH=CH–CH–CH=C(CH3)3 51. Refer to answer key
(1) O 6

3 
5 7
(2) Zn,H2O
CH3 52. 8
CH3–CH=O+CHO+O=C 4
2 1
CH3 3
CHO (Acetone) 53. Electronic configuration of an ion [ M+ ] is
¼,lhVksu½ [Ar] 3d10, so electronic configuration of M is
(C) [Ar] 3d10, 4s1. Atomic number of M is 29 so
(1) O atomic number of element which is just
(CH3)2C=C=CH2 
3 
(2) Zn,H2O below M in the periodic table is 47.
(CH3)2C=O+O=C=O+O=CH2 ,d vk;u [ M+ ] dk bysDVªkWfud vfHkfoU;kl [Ar]
3d10 gSA vr% M dk [Ar] vfHkfoU;kl 3d10, 4s1 gSA
(Acetone) (,lhVksu)
M dk ijek.kq Øekad 29 gS blfy, M ds uhps
okys rRo dk ijek.kq Øekad 47 gSaA
(D) CH3–C = C = C – CH3
CH3 CH3 54. Electronic configuration will be : 2, 8 , 8.
So, maximum atomic number of an
(1) O3
 
CH3–C = O + CO2
(2) Zn,H2O element = 2 + 8 + 8 = 18.
CH3 bySDVªkWfud foU;kl : 2, 8 , 8 gksxkA
(Acetone) blfy,, ,d rRo dk vf/kdre ijek.kq Øekad =
¼,lhVksu½ 2 + 8 + 8 = 18.
43. Refer to answer key ---- TEXT SOLUTIONS (TS) END ----
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