Glufosinate-Ammonium+SL+120C. 000000000030692706 SDS CPA US en 6-0
Glufosinate-Ammonium+SL+120C. 000000000030692706 SDS CPA US en 6-0
Glufosinate-Ammonium+SL+120C. 000000000030692706 SDS CPA US en 6-0
Glufosinate-Ammonium SL 120C
Revision date : 2024/01/25 Page: 1/14
Version: 6.0 (30692706/SDS_CPA_US/EN)
1. Identification
Glufosinate-Ammonium SL 120C
Recommended use of the chemical and restriction on use
* The “Recommended use” identified for this product is provided solely to comply with a Federal requirement and is not part of
the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or
implied, including by incorporation into or reference in the seller's sales agreement.
Company:
BASF CORPORATION
100 Park Avenue
Florham Park, NJ 07932, USA
2. Hazards Identification
According to Regulation 2012 OSHA Hazard Communication Standard; 29 CFR Part 1910.1200
Label elements
Pictogram:
Signal Word:
Danger
Hazard Statement:
H318 Causes serious eye damage.
H315 Causes skin irritation.
H360 May damage fertility. Suspected of damaging the unborn child.
H370 Causes damage to organs (Nervous system).
H373 May cause damage to organs (Nervous system) through prolonged or
repeated exposure.
H401 Toxic to aquatic life.
H411 Toxic to aquatic life with long lasting effects.
1-methoxypropan-2-ol
CAS Number: 107-98-2
Content (W/W): >= 7.0 - < 15.0%
Synonym: 1-Methoxy-2-propanol; Propylene glycol monomethyl ether
Alcohols, C10-16, ethoxylated, sulfates, sodium salts (> 1 < 2.5 mol EO)
CAS Number: 68585-34-2
Content (W/W): >= 10.0 - < 15.0%
Synonym: No data available.
4. First-Aid Measures
General advice:
First aid personnel should pay attention to their own safety. If the patient is likely to become
unconscious, place and transport in stable sideways position (recovery position). Immediately
remove contaminated clothing. Symptoms of poisoning may occur even after several hours, continue
medical observation for at least 48 hours after the accident.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
If on skin:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
If in eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
If swallowed:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention. Do not induce
vomiting due to aspiration hazard.
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11., vomiting, diarrhea, abdominal cramps, tremors, hypotension (low blood pressure),
weakness, unconsciousness, coma, convulsions, respiratory arrest, nausea, tachycardia, Symptoms
may be delayed for several hours.
Safety Data Sheet
Glufosinate-Ammonium SL 120C
Revision date: 2024/01/25 Page: 4/14
Version: 6.0 (30692706/SDS_CPA_US/EN)
Hazards: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11. (Further) symptoms and / or effects are not known so far
Note to physician
Treatment: Treat according to symptoms (decontamination, vital functions), no
known specific antidote. Administer activated charcoal. If necessary,
give oxygen. Monitor respiratory, cardiac and central nervous system.
Medical monitoring for at least 24-48 hours.
5. Fire-Fighting Measures
Extinguishing media
Further information:
Keep containers cool by spraying with water if exposed to fire. In case of fire and/or explosion do not
breathe fumes. Collect contaminated extinguishing water separately, do not allow to reach sewage
or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with
official regulations.
Environmental precautions
Do not discharge into the subsoil/soil. Do not discharge into drains/surface waters/groundwater.
Further information on storage conditions: Keep away from heat. Protect from direct sunlight.
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Wear a NIOSH-certified (or equivalent)
TC23C Chemical/Mechanical type filter system to remove a combination of particles, gas and
vapours. For situations where the airborne concentrations may exceed the level for which an air
purifying respirator is effective, or where the levels are unknown or Immediately Dangerous to Life or
Health (IDLH), use NIOSH-certified full facepiece pressure demand self-contained breathing
Safety Data Sheet
Glufosinate-Ammonium SL 120C
Revision date: 2024/01/25 Page: 6/14
Version: 6.0 (30692706/SDS_CPA_US/EN)
apparatus (SCBA) or a full facepiece pressure demand supplied-air respirator (SAR) with escape
provisions.
Hand protection:
Chemical resistant protective gloves, Protective glove selection must be based on the user's
assessment of the workplace hazards.
Eye protection:
Safety glasses with side-shields. Wear face shield or tightly fitting safety goggles (chemical goggles)
if splashing hazard exists.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. head protection,
apron, protective boots, chemical-protection suit.
Form: liquid
Odour: pungent
Odour threshold: Not determined due to potential health hazard by inhalation.
Colour: blue
pH value: approx. 5 - 8
(approx. 23 °C)
(undiluted)
Melting point: approx. 0 °C
Information applies to the solvent.
Boiling point: approx. 100 °C
Information applies to the solvent.
Flash point: No flash point - Measurement made
up to the boiling point.
Flammability: not applicable
Lower explosion limit: As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Upper explosion limit: As a result of our experience with this
product and our knowledge of its
composition we do not expect any
hazard as long as the product is used
appropriately and in accordance with
the intended use.
Autoignition: Based on the water content the
product does not ignite.
Vapour pressure: approx. 23 hPa
( 20 °C)
Information applies to the solvent.
Safety Data Sheet
Glufosinate-Ammonium SL 120C
Revision date: 2024/01/25 Page: 7/14
Version: 6.0 (30692706/SDS_CPA_US/EN)
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Oxidizing properties:
Based on its structural properties the product is not classified as oxidizing.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Conditions to avoid
See SDS section 7 - Handling and storage.
Incompatible materials
strong acids, strong bases, strong oxidizing agents
Decomposition products:
Hazardous decomposition products: ammonia
Thermal decomposition:
No decomposition if stored and handled as prescribed/indicated.
Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin
contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route
of entry for liquefied gases.
Acute Toxicity/Effects
Safety Data Sheet
Glufosinate-Ammonium SL 120C
Revision date: 2024/01/25 Page: 8/14
Version: 6.0 (30692706/SDS_CPA_US/EN)
Acute toxicity
Assessment of acute toxicity: Of low toxicity after short-term inhalation. Virtually nontoxic after a
single ingestion. Virtually nontoxic after a single skin contact. The product has not been tested. The
statement has been derived from the properties of the individual components.
Oral
Inhalation
Dermal
Irritation / corrosion
Assessment of irritating effects: Skin contact causes irritation. May cause severe damage to the
eyes. The product has not been tested. The statement has been derived from the properties of the
individual components.
Skin
Information on: Alcohols, C12-14, ethoxylated, sulfates, sodium salts (> 1 < 2.5 mol EO)
Species: In vitro assay
Result: Irritant.
Method: OECD Guideline 439
Safety Data Sheet
Glufosinate-Ammonium SL 120C
Revision date: 2024/01/25 Page: 9/14
Version: 6.0 (30692706/SDS_CPA_US/EN)
Species: rabbit
Result: Irritant.
Method: OECD Guideline 404
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Eye
Information on: Alcohols, C12-14, ethoxylated, sulfates, sodium salts (> 1 < 2.5 mol EO)
Species: In vitro assay
Result: Non corrosive.
Method: BCOP
Species: rabbit
Result: Risk of serious damage to eyes.
Method: OECD Guideline 405
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Sensitization
Assessment of sensitization: No sensitizing effect. The product has not been tested. The statement
has been derived from the properties of the individual components.
Aspiration Hazard
Some authorities consider isobutyl alcohol, n-primary alcohols and ketones with C3-C13 as "May be
harmful if swallowed and enters airways" The product has not been tested. The statement has been
derived from the properties of the individual components.
Chronic Toxicity/Effects
Genetic toxicity
Safety Data Sheet
Glufosinate-Ammonium SL 120C
Revision date: 2024/01/25 Page: 10/14
Version: 6.0 (30692706/SDS_CPA_US/EN)
Assessment of mutagenicity: The product has not been tested. The statement has been derived from
the properties of the individual components. Mutagenicity tests revealed no genotoxic potential.
Carcinogenicity
Assessment of carcinogenicity: The product has not been tested. The statement has been derived
from the properties of the individual components. The results of various animal studies gave no
indication of a carcinogenic effect.
Reproductive toxicity
Assessment of reproduction toxicity: The product has not been tested. The statement has been
derived from the properties of the individual components.
Teratogenicity
Assessment of teratogenicity: The product has not been tested. The statement has been derived
from the properties of the individual components.
Other Information
Misuse can be harmful to health.
Toxicity
Aquatic toxicity
Assessment of aquatic toxicity:
Toxic to aquatic life with long lasting effects.
The product has not been tested. The statement has been derived from the properties of the
individual components.
Toxicity to fish
Aquatic invertebrates
Aquatic plants
----------------------------------
Bioaccumulative potential
Bioaccumulation potential
Mobility in soil
Following exposure to soil, the product trickles away and can - dependant on degradation - be
transported to deeper soil areas with larger water loads.
----------------------------------
Additional information
Container disposal:
Rinse thoroughly at least three times (triple rinse) in accordance with EPA recommendations.
Consult state or local disposal authorities for approved alternative procedures such as container
recycling. Recommend crushing, puncturing or other means to prevent unauthorized use of used
containers.
Land transport
USDOT
Not classified as a dangerous good under transport regulations
Sea transport
IMDG
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Marine pollutant: YES
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains GLUFOSINATE AMMONIUM)
Air transport
IATA/ICAO
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (contains GLUFOSINATE AMMONIUM)
Further information
Product may be shipped as non-hazardous in suitable packages containing a net quantity of 5 L or
less under the provisions of various regulatory agencies: ADR, RID, ADN: Special Provision 375;
IMDG: 2.10.2.7; IATA: A197; TDG: Special Provision 99(2); 49CFR: §171.4 (c) (2) and also the
Special Provision 375 in Appendix B which is regulated in China "Regulations Concerning Road
Transportation of Dangerous Goods Part 3: Index of dangerous goods name and transportation
requirements" (JT/T 617.3)
DOT: This product is regulated if the amount in a single receptacle exceeds the Reportable Quantity
(RQ). Please refer to Section 15 of this SDS for the RQ for this product.
Federal Regulations
Registration status:
Crop Protection TSCA, US released / exempt
EPCRA 311/312 (Hazard categories): Refer to SDS section 2 for GHS hazard classes applicable
for this product.
Safety Data Sheet
Glufosinate-Ammonium SL 120C
Revision date: 2024/01/25 Page: 13/14
Version: 6.0 (30692706/SDS_CPA_US/EN)
State regulations
State RTK CAS Number Chemical name
NJ 107-98-2 1-methoxypropan-2-ol
PA 107-98-2 1-methoxypropan-2-ol
Based on an evaluation of the product's composition and the use(s), this product does not require a
California Proposition 65 Warning.
This chemical is a pesticide product regulated by the Environmental Protection Agency and is
subject to certain labeling requirements under federal pesticide law. These requirements differ from
the classification criteria and hazard information required for safety data sheets, and workplace
labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide
label.
WARNING:
KEEP OUT OF REACH OF CHILDREN.
Hazards to humans and domestic animals.
Causes substantial but temporary eye injury.
HARMFUL IF SWALLOWED.
HARMFUL IF INHALED.
HARMFUL IF ABSORBED THROUGH SKIN.
Avoid contact with the skin, eyes and clothing.
Avoid inhalation of mists/vapours.
We support worldwide Responsible Care® initiatives. We value the health and safety of our
employees, customers, suppliers and neighbors, and the protection of the environment. Our
commitment to Responsible Care is integral to conducting our business and operating our facilities in
a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring
the safe and environmentally sound handling of our products, and minimizing the impact of our
operations on society and the environment during production, storage, transport, use and disposal of
our products.