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Project 326 Calculations 2 (1) .XLSB

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Calculations around the mixer (AMT001)

Volume of the tank: 80 m^3


80000 L

Area of the tank 10 m

Radius 1.7841241162 m
Concentration of
H2SO4 in the inlet
stream (C_A) 1641.8041217 g H2SO4/ L solution
Concentration of
H2SO4 in the exit
stream (C_out) 25.5 g H2SO4/ L solution
Concentration of H2O
in the inlet stream
(C_out) 104.80 g H2O/ L solution
Concentration of H2O
in the exit stream
(C_out) 986.10 g H2O/ L solution
mass of H2SO4 2040000 g
2040 kg
2.04 ton
4497.4248 lb

density of H2SO4 1.834 g/cm^3


1834 kg/m^3
molar mass of H2SO4 98.079 g/mol kg/kmol lb/lb-mol
liters of H2SO6 1112322.7917 cm^3
1112.32 L

density of H2O 1 g/cm^3


1000 kg/m^3
liters of water in the
exit stream 78887.68 L
mass of water in the
exit stream 78887.68 kg
78887677.208 g
78.89 ton
173917.35 lb
Water in the inlet
stream of the acid
solution 130212.77 g
130.21 kg
0.13 ton
287.07 lb
130.21 L
Pure water in the inlet
stream 78757.46 kg
78757464.44 g
78.76 ton

total mass of the


solution exit stream 178414.78 lb
80927.68 kg
80.93 ton
80927677.208 g

For specific enthalpy the reference states are: Water ( 0°C, 1 atm, liquid)
Sulphuric acid (25°C, 1 atm, liquid)
mass fraction of
H2SO4 in theexit
solution 2.5% wt H2SO4

The specific enthalpy


of the acid solution of
2.5% wt H2SO4 at Btu/lb-m solution
75°C 121 H2SO4

reference used for this heat capacity


was liquid water at 1 atm with temp.
of 0 °C. Also water was going from 0°C
to 25°C

ΔH of the acid Heat capacity of the inlet water


solution (stream 10) 21588187.863 Btu (stream 8)
22757946303 J Molar mass of H2O
22757946.303 kJ
Energy of water
ΔH of the acid
solution (stream 10) -
energy of water= 19187700.662 kJ
Calculations around the mixer (AMT001)
Assumptions: Ideal gas behaviour
References: Water ( 0°C, 1 atm, liquid)
Sulphuric acid (25°C, 1 atm, liquid)

(25°C, Liquid, 1 atm) (250°C, Liquid, 10 atm)

ΔH_a

(100°C, Liquid, 1 atm) ΔH_d

ΔH_b

(100°C, Vapor, 1 atm) (250°C, Vapor, 1 atm)


ΔH_c

ΔH_total = ΔH_a + ΔH_b + ΔH_c + ΔH_d

ΔH_total = ∫24_25^100▒ 〖𝐶 _(𝑝(𝑙)) 𝑑𝑇 〗


+𝛥𝐻 ̂_𝑣+∫_100^250▒ 〖𝐶 _(𝑝(𝑣)) 𝑑𝑇+0 〗

= 48.40 kJ/mol

mass of water needed


to heat the acid
solution to 75°C
degrees 396450.33083 mol
molar mass of water
(steam) 18.016 g/mol
7142449.1602 g
7142.45 kg
7.14 ton
Mass concentration
of H2SO4 in the inlet 94%

Density of
the inlet
Density of the exit acid
acid solution 1011.60 kg/m^3 solution 1746.6 kg/m^3
Mass flow
Mass flow rate of the rate of the
exit stream 80927.68 kg/hr exit stream 2170.21 kg/hr

80.93 ton/hr 2.17 ton/hr

Volumetric
Volumetric flow rate 80 m^3/hr flow rate 1.24 m^3 H2SO4 solution/hr

F_w = 78.76 m^3/hr F_9 = 1.24


C_w = 1000 kg H2O/ m^3 C_9, A = 1641.80
T_w = 25 °C C_9, W = 104.80
T_9 = 25

F_10 = 7.14 m^3/hr

T= 250 °C

F_10 = 80 m^3 H2SO4 solution/hr


C_10, A = 25.50 kg H2SO4/ m^3 solution
C_10, W = 986.10 kg H2O/ m^3 solution
T_10 = 75 °C

The specific enthalpy


of the acid solution Btu/lb-m
of 94% wt H2SO4 at solution
25°C -50 H2SO4

ΔH of the
acid
solution
0.8365 kJ/mol (stream 9) -82090.20609 Btu
18.016 g/mol -86538273.34 J
0.046431 kJ/g -86538.27334 kJ
3656784 kJ
stream 6

Water (250°C, Vapour, 10 atm)

heat exchanger

Water (25°C, Liquid, 1 atm)

stream 3
m^3 H2SO4 solution/hr

m^3 H2SO4 solution/hr


kg H2SO4/ m^3 solution
kg H2O/ m^3 solution
°C

m^3 H2SO4 solution/hr


g H2SO4/ m^3 solution
g H2O/ m^3 solution
,

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