Revision date: 24/01/2018 Revision: 5

SAFETY DATA SHEET

Silicone Spray

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Silicone Spray

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses PC24 Lubricants, greases, release products

1.3. Details of the supplier of the safety data sheet

Supplier Aztec Aerosols
Gateway
Crewe
Cheshire
CW1 6FA
T+44 (0) 1270 656380
F+44 (0) 1270 656381
info@aztecaerosols.com

1.4. Emergency telephone number

Emergency telephone +44 (0)1270 656380 (Monday to Friday, 9am to 5pm)

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Aerosol 1 - H222, H229

Health hazards Skin Irrit. 2 - H315

Environmental hazards Aquatic Chronic 3 - H412

Human health Gas or vapour is harmful on prolonged exposure or in high concentrations. In high
concentrations, vapours and aerosol mists have a narcotic effect and may cause headache,
fatigue, dizziness and nausea. Deliberately concentrating and inhaling the contents of this
container is dangerous and can be fatal.

Environmental The product contains a substance which is toxic to aquatic organisms and which may cause
long-term adverse effects in the aquatic environment.

Physicochemical Aerosol containers can explode when heated, due to excessive pressure build-up. The
product is extremely flammable. When sprayed on a naked flame or any incandescent
material the aerosol vapours can be ignited.

2.2. Label elements

Pictogram

Signal word Danger

Hazard statements H222 Extremely flammable aerosol.

H229 Pressurised container: may burst if heated.
H315 Causes skin irritation.
H412 Harmful to aquatic life with long lasting effects.

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Precautionary statements P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
P102 Keep out of reach of children.
P260 Do not breathe vapour/ spray.
P271 Use only outdoors or in a well-ventilated area.
P501 Dispose of contents/ container in accordance with local regulations.

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

PETROLEUM GASES, LIQUEFIED; PETROLEUM GAS 60-100%

CAS number: 68476-85-7 EC number: 270-704-2

Classification
Flam. Gas 1 - H220
Press. Gas (Liq.) - H280

HYDROCARBONS, C6-C7, n-alkanes, isoalkanes, cyclics, 10-30%

<5% n-hexane
CAS number: — EC number: 921-024-6 REACH registration number: 01-
2119475514-35

Classification
Flam. Liq. 2 - H225
Skin Irrit. 2 - H315
STOT SE 3 - H336
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411

WHITE MINERAL OIL 1-5%

CAS number: 8042-47-5 EC number: 232-455-8 REACH registration number: 01-
2119487078-27-XXXX

Classification
Asp. Tox. 1 - H304

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HEXANE-norm <1%
CAS number: 110-54-3 EC number: 203-777-6 REACH registration number: 01-
2119480412-44

Classification
Flam. Liq. 2 - H225
Skin Irrit. 2 - H315
Repr. 2 - H361f
STOT SE 3 - H336
STOT RE 2 - H373
Asp. Tox. 1 - H304
Aquatic Chronic 2 - H411

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

General information Move affected person to fresh air at once.

Inhalation If spray/mist has been inhaled, proceed as follows. Move affected person to fresh air and
keep warm and at rest in a position comfortable for breathing. If breathing stops, provide
artificial respiration. Keep affected person warm and at rest. Get medical attention
immediately.

Ingestion Rinse mouth thoroughly with water. Do not induce vomiting. Get medical attention.

Skin contact Remove contaminated clothing immediately and wash skin with soap and water.

Eye contact Rinse immediately with plenty of water. Remove any contact lenses and open eyelids wide
apart. Continue to rinse for at least 15 minutes and get medical attention.

4.2. Most important symptoms and effects, both acute and delayed
General information The severity of the symptoms described will vary dependent on the concentration and the
length of exposure.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog.

5.2. Special hazards arising from the substance or mixture

Specific hazards Containers can burst violently or explode when heated, due to excessive pressure build-up.
Vapours are heavier than air and may spread near ground and travel a considerable distance
to a source of ignition and flash back. Extremely flammable. Forms explosive mixtures with
air.

5.3. Advice for firefighters

Protective actions during Cool containers exposed to heat with water spray and remove them from the fire area if it can
firefighting be done without risk. Warn firefighters that aerosols are involved. Use water to keep fire
exposed containers cool and disperse vapours.

SECTION 6: Accidental release measures

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6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Provide adequate ventilation. Use suitable respiratory protection if ventilation is inadequate.
Avoid inhalation of vapours.

6.2. Environmental precautions

Environmental precautions Avoid the spillage or runoff entering drains, sewers or watercourses. Contain spillage with
sand, earth or other suitable non-combustible material.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Eliminate all sources of ignition. No smoking, sparks, flames or other sources of ignition near
spillage. Provide adequate ventilation. Absorb spillage with non-combustible, absorbent
material. Leave small quantities to evaporate, if safe to do so. Do not allow material to enter
confined spaces, due to the risk of explosion.

6.4. Reference to other sections

Reference to other sections For personal protection, see Section 8. For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Read and follow manufacturer's recommendations. Keep away from heat, sparks and open
flame. Do not spray on a naked flame or any incandescent material. Eliminate all sources of
ignition.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Keep away from heat, sparks and open flame. Store at moderate temperatures in dry, well
ventilated area. Pressurized container: protect from sunlight and do not expose to
temperatures exceeding 50°C. Do not pierce or burn, even after use.

7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure Controls/personal protection

8.1. Control parameters

Occupational exposure limits
PETROLEUM GASES, LIQUEFIED; PETROLEUM GAS
Long-term exposure limit (8-hour TWA): WEL 1000 ppm 1750 mg/m³
Short-term exposure limit (15-minute): WEL 1250 ppm 2180 mg/m³
HYDROCARBONS, C6-C7, n-alkanes, isoalkanes, cyclics, <5% n-hexane
Long-term exposure limit (8-hour TWA): WEL 1200 mg/m³
WHITE MINERAL OIL
Long-term exposure limit (8-hour TWA): SUP 600 mg/m³
HEXANE-norm
Long-term exposure limit (8-hour TWA): WEL 20 ppm 72 mg/m³
WEL = Workplace Exposure Limit

Ingredient comments WEL = Workplace Exposure Limits

8.2. Exposure controls

Appropriate engineering Provide adequate ventilation. Avoid inhalation of vapours and spray/mists. Observe any
controls occupational exposure limits for the product or ingredients.

Personal protection Do not eat, drink or smoke when using this product.

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Eye/face protection Eyewear complying with an approved standard should be worn if a risk assessment indicates
eye contact is possible. The following protection should be worn: Chemical splash goggles.

Hand protection Due to the packaging form, aerosol, risk of skin contact is small. Chemical-resistant,
impervious gloves complying with an approved standard should be worn if a risk assessment
indicates skin contact is possible. It is recommended that gloves are made of the following
material: Nitrile rubber. Polyvinyl alcohol (PVA). Viton rubber (fluoro rubber). The most
suitable glove should be chosen in consultation with the glove supplier/manufacturer, who can
provide information about the breakthrough time of the glove material.

Hygiene measures Wash hands after handling. Wash at the end of each work shift and before eating, smoking
and using the toilet. Use appropriate hand lotion to prevent defatting and cracking of skin.

Respiratory protection If ventilation is inadequate, suitable respiratory protection must be worn.

SECTION 9: Physical and Chemical Properties

9.1. Information on basic physical and chemical properties

Appearance Aerosol.

Colour Clear.

Odour Organic solvents.

Initial boiling point and range -40 to -2°C @ 1013 hPa

Flash point <-40°C

Upper/lower flammability or Lower flammable/explosive limit: 1.8% Upper flammable/explosive limit: 9.5%
explosive limits

Vapour pressure ca. 590 to 1760 kPa @ 45°C

Vapour density ca. 1.5 at 15°C

Auto-ignition temperature 410-580°C

Comments Information given is applicable to the major ingredient.

9.2. Other information

Other information Not available.

Volatile organic compound This product contains a maximum VOC content of 560 g/l.

SECTION 10: Stability and reactivity

10.1. Reactivity
Reactivity Stable at normal ambient temperatures and when used as recommended.

10.2. Chemical stability

Stability Avoid the following conditions: Heat, sparks, flames.

10.3. Possibility of hazardous reactions

Possibility of hazardous Does not decompose when used and stored as recommended.
reactions

10.4. Conditions to avoid

Conditions to avoid Avoid heat, flames and other sources of ignition. Avoid exposing aerosol containers to high
temperatures or direct sunlight.

10.5. Incompatible materials

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Materials to avoid Keep away from oxidising materials, heat and flames.

10.6. Hazardous decomposition products

Hazardous decomposition Does not decompose when used and stored as recommended. Thermal decomposition or
products combustion products may include the following substances: Toxic and corrosive gases or
vapours.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

General information Deliberately concentrating and inhaling the contents of this container is dangerous and can be
fatal.

Inhalation In high concentrations, vapours and aerosol mists have a narcotic effect and may cause
headache, fatigue, dizziness and nausea. Unconsciousness, possibly death.

Skin contact Irritating to skin.

Eye contact Vapour or spray in the eyes may cause irritation and smarting.

Acute and chronic health Arrhythmia (deviation from normal heart beat). Irritating to skin. In high concentrations,
hazards vapours and aerosol mists have a narcotic effect and may cause headache, fatigue, dizziness
and nausea.

Route of exposure Inhalation

Target organs Central nervous system Respiratory system, lungs

Medical symptoms Skin irritation. Arrhythmia (deviation from normal heart beat). Narcotic effect. Vapours may
cause drowsiness and dizziness.

Toxicological information on ingredients.

HEXANE-norm

Acute toxicity - dermal

Acute toxicity dermal (LD₅₀ 3,000.0

mg/kg)

Species Rabbit

Acute toxicity - inhalation

Acute toxicity inhalation 48,000.0

(LC₅₀ gases ppmV)

Species Rat

ATE inhalation (gases 48,000.0

ppm)

Serious eye damage/irritation

Serious eye This product may cause skin and eye irritation.
damage/irritation

Skin sensitisation

Skin sensitisation Not sensitising.

Carcinogenicity

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Carcinogenicity Dose level: 0.043, 900, 3000, 9016 ppm, , Rat Dose level: 0.039, 900, 3000, 9018
ppm, , Mouse Based on available data the classification criteria are not met.

Reproductive toxicity

Reproductive toxicity - Fertility - 5000 ppm, , Rat Permanent testicular damage characterised by loss of
fertility germ-cell line.

Reproductive toxicity - Teratogenicity: - Dose level:: 200, 1000, 5000 ppm, , Rat, Mouse Teratogenicity:,
development Maternal toxicity: - NOAEL: 200 - 1000 ppm, ,

Specific target organ toxicity - repeated exposure

STOT - repeated exposure LOAEL 3000 ppm, Inhalation, Rat

SECTION 12: Ecological Information

Ecotoxicity This product has not been tested but contains ingredients which are toxic or very toxic to
aquatic organisms and may cause long term adverse effects in the aquatic environment.
During normal use the volatility of the components and the packaging form, pressurised
container, make entry into the aquatic environment unlikely, however, do not empty or
discharge into drains or watercourses. Ensure container is empty before disposal to prevent
contents entering watercourses.

12.1. Toxicity
Toxicity Not available.

Ecological information on ingredients.

HEXANE-norm

Toxicity Not available.

Acute aquatic toxicity

Acute toxicity - fish LL₅₀, 96 hours: 12.51 mg/l, Oncorhynchus mykiss (Rainbow trout)
LC₅₀, 96 hours: 2.1 -2.98 mg/l, Pimephales promelas (Fat-head Minnow)

Acute toxicity - aquatic LL₅₀, 48 hours: 21.85 mg/l, Daphnia magna

invertebrates

Acute toxicity - aquatic LL₅₀, 72 hours: 9.29 mg/l, Pseudokirchneriella subcapitata

plants

12.2. Persistence and degradability

Persistence and degradability Not available.

Ecological information on ingredients.

HEXANE-norm

Persistence and Not available.

degradability

12.3. Bioaccumulative potential

Bioaccumulative potential Not available.

Ecological information on ingredients.

HEXANE-norm

Bioaccumulative potential BCF: 501, Bioaccumulation is unlikely.

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12.4. Mobility in soil

Mobility Not known.

Ecological information on ingredients.

HEXANE-norm

Mobility Not known.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB Not available.
assessment

Ecological information on ingredients.

HEXANE-norm

Results of PBT and vPvB This substance is not classified as PBT or vPvB according to current EU criteria.
assessment

12.6. Other adverse effects

Other adverse effects Not available.

Ecological information on ingredients.

HEXANE-norm

Other adverse effects Not available.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information Do not puncture or incinerate, even when empty.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. Containers should be thoroughly emptied before disposal
because of the risk of an explosion. Empty containers must not be punctured or incinerated
because of the risk of an explosion.

SECTION 14: Transport information

General This product is packed in accordance with the Limited Quantity Provisions of CDGCPL2, ADR
and IMDG. These provisions allow transport of aerosols of less than 1 litre packed in cartons
of less than 30kg gross weight to be exempt from control providing that they are labelled in
accordance with the requirements of these regulations to show that they are being transported
as Limited Quantities. Aerosols not so packed and labelled must show the following.

14.1. UN number
UN No. (ADR/RID) 1950

UN No. (IMDG) 1950

UN No. (ICAO) 1950

UN No. (ADN) 1950

14.2. UN proper shipping name

Proper shipping name AEROSOLS
(ADR/RID)

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Proper shipping name (IMDG) AEROSOLS

Proper shipping name (ICAO) AEROSOLS

Proper shipping name (ADN) AEROSOLS

14.3. Transport hazard class(es)

ADR/RID class 2.1

ADR/RID classification code 5F

ADR/RID label 2.1

IMDG class 2.1

ICAO class/division 2.1

ADN class 2.1

Transport labels

14.4. Packing group

ADR/RID packing group None

IMDG packing group None

ADN packing group None

ICAO packing group None

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

EmS F-D, S-U

ADR transport category 2

Tunnel restriction code (D)

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations EH40/2005 Workplace exposure limits.
The Aerosol Dispensers Regulations 2009 (SI 2009 No. 2824).
The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (SI 2009 No. 1348) (as amended) ["CDG 2009"].

EU legislation Commission Regulation (EU) No 453/2010 of 20 May 2010.

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Guidance Workplace Exposure Limits EH40.

Safety Data Sheets for Substances and Preparations.
Approved Classification and Labelling Guide (Sixth edition) L131.
British Aerosol Manufacturers Code of Practice 7th. Edition 1999

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Revision comments Supplemental information added.

Revision date 24/01/2018

Revision 5

SDS number 10782

SDS status Approved.

Hazard statements in full H220 Extremely flammable gas.

H222 Extremely flammable aerosol.
H225 Highly flammable liquid and vapour.
H229 Pressurised container: may burst if heated.
H280 Contains gas under pressure; may explode if heated.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H361f Suspected of damaging fertility.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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