Revision date: 19/12/2018 Revision: 4 Supersedes date: 01/02/2018

SAFETY DATA SHEET

Mr Muscle All Purpose Cleaner

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name Mr Muscle All Purpose Cleaner

Product number MMAP5LTR

1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Detergent. For full details regarding recommended uses please refer to the product label.

1.3. Details of the supplier of the safety data sheet

Supplier SC Johnson Professional Ltd
Denby Hall Way
Denby
Derbyshire
DE5 8JZ
+44 (0) 1773 855100
sdsuk@scj.com

1.4. Emergency telephone number

Emergency telephone National Poisons Information Service (UK) 0344 8920111 (Health Professionals only)
National Poisons Information Centre (Eire) 01-8092566/8379964

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification (EC 1272/2008)
Physical hazards Not Classified

Health hazards Eye Dam. 1 - H318

Environmental hazards Not Classified

Environmental The product does not meet the requirement for classification as an environmental hazard in
accordance with directive 1999/45/EEC

2.2. Label elements

Hazard pictograms

Signal word Danger

Hazard statements H318 Causes serious eye damage.

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Precautionary statements P280 Wear protective gloves/ protective clothing/ eye protection/ face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P313 Get medical advice/ attention.
P302+P352 IF ON SKIN: Wash with plenty of water.
P332+P313 If skin irritation occurs: Get medical advice/ attention.
P501 Dispose of contents/ container in accordance with local regulations.

Contains C9-C11 ALCOHOL ETHOXYLATE ( 6MEO), 3-C12-14-(even numbered)-alkylamido-N,N-

dimethylpropan-1-amino oxide

Detergent labelling < 5% amphoteric surfactants, < 5% non-ionic surfactants

2.3. Other hazards

This product does not contain any substances classified as PBT or vPvB.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

C9-C11 ALCOHOL ETHOXYLATE ( 6MEO) 1-10%

CAS number: 68439-46-3

Classification
Acute Tox. 4 - H302
Eye Dam. 1 - H318

3-C12-14-(EVEN NUMBERED)-ALKYLAMIDO-N,N- 1-10%

DIMETHYLPROPAN-1-AMINO OXIDE
CAS number: — EC number: 939-581-9 REACH registration number: 01-
2119978229-22-XXXX
M factor (Acute) = 1

Classification
Acute Tox. 4 - H302
Skin Irrit. 2 - H315
Eye Dam. 1 - H318
Aquatic Acute 1 - H400
Aquatic Chronic 3 - H412

SODIUM HYDROXIDE <1%

CAS number: 1310-73-2 EC number: 215-185-5 REACH registration number: 01-
2119457892-27-XXXX

Classification
Met. Corr. 1 - H290
Skin Corr. 1A - H314
Eye Dam. 1 - H318

The full text for all hazard statements is displayed in Section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

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Inhalation Not relevant. Unlikely route of exposure as the product does not contain volatile substances.

Ingestion Rinse mouth thoroughly with water. Get medical attention if any discomfort continues.

Skin contact Wash skin thoroughly with soap and water.

Eye contact Remove any contact lenses and open eyelids wide apart. Important! Immediately rinse with
water for at least 15 minutes. Get medical attention if any discomfort continues.

4.2. Most important symptoms and effects, both acute and delayed
Inhalation No specific symptoms known.

Ingestion No specific symptoms known.

Skin contact Prolonged and frequent contact may cause redness and irritation.

Eye contact Irritation of eyes and mucous membranes.

4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor No specific recommendations.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media The product is not flammable. Use fire-extinguishing media suitable for the surrounding fire.

5.2. Special hazards arising from the substance or mixture

Hazardous combustion No known hazardous decomposition products.
products

5.3. Advice for firefighters

Protective actions during No specific firefighting precautions known.
firefighting

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions Wear protective clothing as described in Section 8 of this safety data sheet. Avoid contact with
eyes.

6.2. Environmental precautions

Environmental precautions Not considered to be a significant hazard due to the small quantities used.

6.3. Methods and material for containment and cleaning up

Methods for cleaning up Flush away spillage with plenty of water. Avoid contamination of ponds or watercourses with
washing down water. Absorb spillage with non-combustible, absorbent material. Do not
discharge into drains or watercourses or onto the ground.

6.4. Reference to other sections

Reference to other sections For waste disposal, see Section 13.

SECTION 7: Handling and storage

7.1. Precautions for safe handling

Usage precautions Avoid contact with eyes.

7.2. Conditions for safe storage, including any incompatibilities

Storage precautions Store in closed original container at temperatures between 0°C and 30°C.

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7.3. Specific end use(s)

Specific end use(s) The identified uses for this product are detailed in Section 1.2.

SECTION 8: Exposure controls/Personal protection

8.1. Control parameters

Occupational exposure limits
SODIUM HYDROXIDE
Short-term exposure limit (15-minute): WEL 2 mg/m³
WEL = Workplace Exposure Limit

Ingredient comments None.

3-C12-14-(EVEN NUMBERED)-ALKYLAMIDO-N,N-DIMETHYLPROPAN-1-AMINO OXIDE

DNEL Workers - Inhalation; Long term systemic effects: 3.52 mg/m³

Workers - Dermal; Long term systemic effects: 5 mg/kg/day
Workers - Dermal; Long term local effects: 0.27 %
General population - Inhalation; Long term systemic effects: 0.87 mg/m³
General population - Dermal; Long term systemic effects: 2.5 mg/kg/day
General population - Dermal; Long term local effects: 0.27 %
General population - Oral; Long term systemic effects: 0.25 mg/kg/day

PNEC - Fresh water; 30.3 µg/L

- marine water; 3.04 µg/L
- Intermittent release; 3.4 µg/L
- STP; 9.7 mg/l
- Sediment (Freshwater); 0.214 mg/kg
- Sediment (Marinewater); 0.021 mg/kg
- Soil; 0.025 µg/kg

REACTION PRODUCTS OF C12-18-(EVEN NUMBERED)-ALKYLAMINES & ACRYLIC ACID & SODIUM

HYDROXIDE

DNEL Professional - Dermal; Long term systemic effects: 5.3 mg/kg/day

Professional - Inhalation; Long term systemic effects: 3.8 mg/m³
Consumer - Dermal; Long term systemic effects: 2.7 mg/kg/day
Consumer - Inhalation; Long term systemic effects: 0.9 mg/m³
Consumer - Oral; Long term systemic effects: 0.3 mg/kg/day

PNEC - marine water; 0.0003 mg/l

- Soil; 0.0041 mg/kg
- Fresh water; 0.03 mg/l
- Sediment (Freshwater); 0.108 mg/kg
- Intermittent release; 0.042 mg/l
- STP; 9.9 mg/l
- Sediment (Marinewater); 0.0108 mg/kg

SODIUM HYDROXIDE (CAS: 1310-73-2)

DNEL Industry - Inhalation; Long term local effects: 1 mg/m³

Consumer - Inhalation; Long term local effects: 1 mg/m³

8.2. Exposure controls

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Protective equipment

Appropriate engineering Not relevant.

controls

Eye/face protection Wear eye protection.

Hand protection The most suitable glove should be chosen in consultation with the glove
supplier/manufacturer, who can provide information about the breakthrough time of the glove
material. To protect hands from chemicals, gloves should comply with European Standard
EN374. The selected gloves should have a breakthrough time of at least 8 hours.

Hygiene measures Wash hands after contact.

Respiratory protection Not relevant.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Appearance Liquid

Colour Green.

Odour Perfume.

Odour threshold Not determined.

pH pH (concentrated solution): 10.3-11.3

Melting point Not determined.

Initial boiling point and range Not determined.

Flash point Not determined.

Evaporation rate Not determined.

Upper/lower flammability or Scientifically unjustified.

explosive limits

Vapour pressure Not determined.

Vapour density Not determined.

Relative density Not determined.

Partition coefficient Data lacking.

Auto-ignition temperature Scientifically unjustified.

Decomposition Temperature Not determined.

Viscosity Not determined.

Explosive properties Scientifically unjustified.

Oxidising properties Does not meet the criteria for classification as oxidising.

9.2. Other information

Other information No information required.

SECTION 10: Stability and reactivity

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10.1. Reactivity
Reactivity There are no known reactivity hazards associated with this product.

10.2. Chemical stability

Stability Stable at normal ambient temperatures and when used as recommended.

10.3. Possibility of hazardous reactions

Possibility of hazardous Not known.
reactions

10.4. Conditions to avoid

Conditions to avoid There are no known conditions that are likely to result in a hazardous situation.

10.5. Incompatible materials

Materials to avoid No specific material or group of materials is likely to react with the product to produce a
hazardous situation.

10.6. Hazardous decomposition products

Hazardous decomposition No known hazardous decomposition products.
products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity - oral
Notes (oral LD₅₀) Based on available data the classification criteria are not met.

ATE oral (mg/kg) 14,084.51

Acute toxicity - dermal

Notes (dermal LD₅₀) Based on available data the classification criteria are not met.

Acute toxicity - inhalation

Notes (inhalation LC₅₀) Based on available data the classification criteria are not met.

Skin corrosion/irritation
Animal data Moderately irritating.

Serious eye damage/irritation

Serious eye damage/irritation Risk of serious damage to eyes.

Respiratory sensitisation
Respiratory sensitisation Based on available data the classification criteria are not met.

Skin sensitisation
Skin sensitisation Based on available data the classification criteria are not met.

Germ cell mutagenicity

Genotoxicity - in vivo Does not contain any substances known to be mutagenic.

Carcinogenicity
Carcinogenicity Does not contain any substances known to be carcinogenic.

Reproductive toxicity
Reproductive toxicity - Does not contain any substances known to be toxic to reproduction.
development

Specific target organ toxicity - single exposure

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STOT - single exposure No information available.

Specific target organ toxicity - repeated exposure

STOT - repeated exposure No information available.

Aspiration hazard
Aspiration hazard Based on available data the classification criteria are not met.

Inhalation No specific health hazards known.

Ingestion May cause discomfort if swallowed.

Skin contact Skin irritation should not occur when used as recommended.

Eye contact Causes serious eye damage.

SECTION 12: Ecological information

Ecotoxicity Not regarded as dangerous for the environment.

12.1. Toxicity
Toxicity The product is not expected to be hazardous to the environment.

12.2. Persistence and degradability

Persistence and degradability The surfactant(s) contained in this product complies(comply) with the biodegradability criteria
as laid down in Regulation (EC) No. 648/2004 on detergents. Data to support this assertion
are held at the disposal of the competent authorities of the Member States and will be made
available to them at their direct request, or at the request of a detergent manufacturer.

12.3. Bioaccumulative potential

Bioaccumulative potential No data available on bioaccumulation.

Partition coefficient Data lacking.

12.4. Mobility in soil

Mobility The product is soluble in water.

12.5. Results of PBT and vPvB assessment

Results of PBT and vPvB This product does not contain any substances classified as PBT or vPvB.
assessment

12.6. Other adverse effects

Other adverse effects None known.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

General information When handling waste, the safety precautions applying to handling of the product should be
considered.

Disposal methods Dispose of waste to licensed waste disposal site in accordance with the requirements of the
local Waste Disposal Authority. No specific disposal method required. Reuse or recycle
products wherever possible.

SECTION 14: Transport information

General The product is not covered by international regulations on the transport of dangerous goods
(IMDG, IATA, ADR/RID).

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14.1. UN number
Not applicable.

14.2. UN proper shipping name

Not applicable.

14.3. Transport hazard class(es)

No transport warning sign required.

14.4. Packing group

Not applicable.

14.5. Environmental hazards

Environmentally hazardous substance/marine pollutant

No.

14.6. Special precautions for user

Not applicable.

14.7. Transport in bulk according to Annex II of MARPOL and the IBC Code
Transport in bulk according to Not applicable.
Annex II of MARPOL 73/78
and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18
December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of
Chemicals (REACH) (as amended).
Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16
December 2008 on classification, labelling and packaging of substances and mixtures (as
amended).

15.2. Chemical safety assessment

No chemical safety assessment has been carried out.

SECTION 16: Other information

Key literature references and Where Exposure Scenarios for the substances listed in Section 3 are available they have
sources for data been assessed for the uses identified in this data sheet or on the product label and the
appropriate relevant information is incorporated into this Safety Data Sheet.

Revision comments This is the first issue.

Revision date 19/12/2018

Revision 4

Supersedes date 01/02/2018

SDS number 21644

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Hazard statements in full H290 May be corrosive to metals.

H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H318 Causes serious eye damage.
H373 May cause damage to organs (Kidneys) through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.

Notes for Hazard Statements The full text for Hazard Statements in section 16 relates to the reference numbers in sections
in Full 2 and 3 and not necessarily the finished product classification.

This information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate
and reliable as of the date indicated. However, no warranty, guarantee or representation is made to its accuracy, reliability or
completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.

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