Chapter 1 To 3 Profff
Chapter 1 To 3 Profff
Chapter 1 To 3 Profff
BY
TO
OGBOMOSO, NIGERIA.
IN CIVIL ENGINEERING.
NOVEMBER 2023.
i
CERTIFICATION
This thesis with the title “Effect of Indiscriminate Disposal of Solid Waste A Case
OJO, Tosin Isaiah and ADIKA, Emmanuel Adewunmi was carried out under my
——————————— ———————
Supervisor Date
Prof. S. O. OJOAWO
(B.Tech, Ph.D, COREN)
Civil Engineering Department,
Ladoke Akintola University of
Technology, Ogbomoso, Nigeria.
——————————— ———————
Ag. Head of Department Date
Dr. J.R. Oluremi
B.Tech, Ph.D,M.Sc)
Civil Engineering Department,
Ladoke Akintola University of
Technology, Ogbomoso, Nigeria.
DEDICATION
ii
We dedicate this work to the Almighty God for the successful commencement of this
program.
iii
ACKNOWLEDGMENTS
We wish to acknowledge Almighty God, who guided us from the beginning to the end
Special thanks to our supervisors in person of Prof. S. O. Ojoawo for the attention he
We also acknowledge the Head of Department (Dr. J.R. Oluremi) of Civil Engineering,
department of Civil Engineering, LAUTECH for their love and guidance at all times.
We also acknowledge the effort of our Parents for the unconditional love, support, and
iv
SUMMARY
The indiscriminate disposal of solid waste is a growing concern worldwide, with far-
reaching consequences for the environment. This study focuses on the effects of such
indiscriminate waste disposal practices in the Ogbomoso North region. The aim of this
research is to comprehensively assess the environmental, social, and health impacts of
improper waste management and to provide insights into potential mitigation
strategies.
The study will employ a mixed-methods approach, combining quantitative data
collection and qualitative analysis. Quantitative data was gathered through extensive
field surveys and sampling of waste disposal sites, water bodies, and ambient air
quality. Qualitative method shall involve in-depth interviews with local residents,
waste management authorities, and health professionals to gain a deeper
understanding of the perceptions, behaviors, and consequences of indiscriminate
waste disposal.
In Ogbomoso North LGA, there is presently leading to severe environmental
degradation. Open dumping and uncontrolled burning of waste contribute to soil and
water contamination, are posing risks to agricultural productivity and aquatic
ecosystems. The study will also identify the release of harmful gases and particulate
matters from burning waste, exacerbating air pollution and respiratory ailments
among the local population.
Finally, the spread of diseases linked to improper waste management practices
is a significant concern. The accumulation of stagnant water in waste piles becomes
breeding grounds for disease vectors, increasing the incidence of waterborne and
vector-borne diseases. The lack of proper waste containment and disposal
infrastructure further compounds these issues.
v
TABLE OF CONTENTS
Title page i
Certification ii
Dedication iii
Acknowledgments iv
Summary v
Table of contents vi
CHAPTER ONE: INTRODUCTION
1.1 Background of study 1
1.2 Problem statement 3
1.3 Aim and objectives 3
1.4 Scope of study 4
1.5 Justification of study 4
1.6 Definition of terms 4
3.3.1 Procedure 19
3.3.2 Methods 20
vi
3.4 Determination of water pollution around the dumpsite of the study area 20
REFERENCES 27
vii
LIST OF FIGURES
viii
CHAPTER ONE
INTRODUCTION
1
Nigeria and Ghana came to the same conclusions: that approximately 80% of solid
waste in African countries was disposed of through indiscriminate dumping
(Ogwueleka 2009; Aziale and Asafo-Adjei 2013). The prevalence of indiscriminate
dumping and its spread across African communities is therefore clear. However,
although indiscriminate dumping is more prevalent in developing countries,
developed countries are not an exception. Improper Solid Waste disposal and
management causes all types of pollution: air, soil, and water.
Indiscriminate dumping of wastes contaminates surface and ground water
supplies. In urban areas, Municipal solid wastes clogs drains, creating stagnant water
for insect breeding and floods during rainy seasons. Uncontrolled burning of solid
waste and improper incineration contributes significantly to urban air pollution.
Greenhouse gases are generated from the decomposition of organic wastes in
landfills, and untreated leachate pollutes surrounding soil and water bodies. Health
and safety issues also arise from improper Solid Waste Management. Insect and
rodent vectors are attracted to the waste and can spread diseases such as cholera and
dengue fever. Using water polluted by Solid Waste for bathing, food irrigation and
drinking water can also expose individuals to disease organisms and other
contaminants.
Several studies have shown that solid waste generation rate is average of 0.5kg
per person per day (Okpala, 1984). The generation rates for the African’s major cities
are estimated to range from 0.31 to 1.4kg per capital per day. This gives an average of
0.78kg (Achankang, 2003). According to world Bank study, urban per capital waste
management rate for most of the low-income countries will increase by approximately
0.2kg per day by 2025 because of relatively high annual growth rates of GNP and
urban population (Chakrabarti and Ssarkhal, 2003). Improper collection and disposal
leads to spread of communicable diseases, obnoxious conditions and spoils biosphere
as a whole; for instance, respiratory infections and diarrhea diseases have been
identified as the two major causes of death among the poorest 20% of the world
countries ranked by national GDP per capital (Gwatkin and Guillot, 1999). The
outbreak of these diseases has been attributed to area where solid waste is improperly
collected and disposed.
The poorest populations mostly resort to sporadic and indiscriminate dumping
of their waste into available plots of land, sidewalks, roadways, streams, channels and
2
drainage areas. More than 70 percent of the refuse generated in the city is disposed of
in this way. These refuse are good contaminants of streams, ground water especially
shallow wells and the entire environment. Therefore, this study aimed at assessing the
effect of indiscriminate solid waste disposal and the environmental issues in
Ogbomoso South and make necessary recommendations on waste disposal and
management practices to prevent further deterioration of the environment and the
negative effects on the human population in Ogbomoso South Local Government
Area.
In an ideal situation, the environment should be clean and free from waste so
as for the environment to be ultimately free from air, land and water pollution.
However, the reverse is the case in this area. Refuse are being dumped virtually
everywhere in the area, the level of the indiscriminate dumping of refuse is clearly
increasing all over the places, littering street and causing pollution, all of which
contribute to the untidiness of the environment. The conventional waste management
approach based on collection and disposal of wastes, such as provision of waste bins
in the area and monthly collection of wastes from each home by the Ogbomoso south
waste management authority has failed to provide efficient and effective results. And
these poses some environmental and human health risk. The prevalence of parasites,
tetanus, malaria, hookworm, cholera and diarrhea is attributed the unsanitary
condition of this area. The indiscriminate disposal of these wastes also provide
breeding ground for mosquitoes, rats, and other vermins, generating amongst others;
yellow fever, Lassa fever and trachoma mortality in the area. Therefore, this research
sets out to look at the environmental implication of the indiscriminate waste disposal
in Ogbmoso south local government area.
3
Objectives
1. To appraise the existing situation of solid waste disposal and identify the existing
waste management practices, infrastructure and policies in place in Ogbomoso
South Local Government.
2. To assess the impact of indiscriminate disposal of solid wastes on ground water,
soil and air in the area.
3. To identify the prevalence of water-borne and vector-borne diseases among
residents due to the poor waste disposal practices.
4. To proffer engineering solution to the menace.
4
H4: Indiscriminate dump of Solid waste causes damage to soil through deposits of
harmful chemicals and material
H5: Indiscriminate dump of Solid waste blocks drainages which can lead to flood in
the environment
2. Indiscriminate dump of Solid waste has no significant effect on Health of the
individuals H1: Indiscriminate dump of Solid Waste causes infectious diseases
among people
H2: Indiscriminate dump of Solid Waste pollutes the atmosphere which causes air-
borne diseases
H3: Indiscriminate dump of Solid Waste is a breeding place for diseases vectors which
transmit diseases
H4: Indiscriminate dump of Solid Waste results to contamination of food and water
H5: Indiscriminate dump of Solid Waste causes Cholera and Dysentery
3. Indiscriminate dump of solid waste has no significant relationship between people’s
attitude and practice. H1: Indiscriminate dump of Solid Waste arises because people
cannot pay for the waste
H2: Indiscriminate dump of Solid Waste is because of people’s laziness
H3: Indiscriminate dump of Solid Waste were dumped in abandoned lands
H4: Indiscriminate dump of Solid Waste results as a result of non-implemented
sanctions for violators
H5: Indiscriminate dump of Solid Waste dumped on the waterways
Here are definitions of some key terms related to the study of the
indiscriminate disposal of solid waste:
5
iii. Environment: The natural surroundings in which an organism, population, or
community exists. It encompasses both the living (biotic) and non-living (abiotic)
components of the Earth, including air, water, soil, and ecosystems.
iv. Contamination: The introduction of harmful substances or pollutants into the
environment, which can negatively affect the quality of air, water, soil, and other
natural resources.
v. Ecosystem: A complex network of living organisms (plants, animals,
microorganisms) and their physical environment (air, water, soil) that interact and
function as a unit within a specific geographical area.
vi. Vectors: These are organisms, such as mosquitoes and rodents, that can transmit
diseases to humans and animals. Vectors are capable of carrying and spreading
pathogens that cause illnesses.
vii. Air Pollution: The presence of harmful substances or pollutants in the air, often
resulting from human activities like burning fossil fuels, industrial processes, and
waste decomposition. It can have detrimental effects on human health and the
environment.
viii. Aesthetics: The visual or sensory qualities of a place or object that contribute to its
overall appearance and attractiveness.
ix. Waste Management: The systematic collection, transport, processing, recycling,
and disposal of waste materials, with the goal of minimizing its environmental
impact and promoting sustainability.
x. Leachate: This is a liquid that results from water passing through waste materials
and extracting soluble substances from them. In the context of waste disposal,
leachate is formed when rainwater or other liquid percolate through landfills or waste
dumps picking up contaminants from the decomposing waste. Leachate can be
highly polluted and poses a risk of contaminating ground water and surface water
bodies.
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CHAPTER TWO
LITERATURE REVIEW
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b) Solid Waste
Solid Wastes are non-liquid and non-gaseous wastes from houses, streets and
public places, shops, offices, and hospitals, industrial processes etc. We all produce
unwanted byproducts and residues in nearly everything we do. As man processes and
prepares food, waste is generated from the nonedible parts (i.e peels husk, fibres etc);
upon eating food, waste in the form of excreta is the final outcome; in clothing the
body, waste is generated from worn out fabrics; in meeting our desires to comfort
ourselves by acquiring varied material belongings, waste is generated when these are
worn out or become old; and in our technological advancement, waste, most of which
is dangerous to life, is generated. A lot of solid wastes are been created each day in
Nigeria from our household, farms, institutions, industries, business centres among
several others.
Solid wastes could be defined as non-liquid and nongaseous products of
human activities, regarded as being useless. It could take the forms of refuse, garbage
and sludge (Leton and Omotosho, 2004). Solid waste is a non-liquid, non-soluble
material ranging from municipal garbage to industrial waste that sometimes contains
complex and hazardous substances, it includes domestic waste, institutional waste,
catering and market waste and bio-medical waste. Solid waste disposal refers to the
management and final disposal of solid materials generated by various human
activities. It is an essential aspect of waste management and environmental
sustainability. Solid waste includes non-biodegradable materials like plastics, metals,
glass, and hazardous chemicals, as well as organic waste, such food scraps, yard waste
and papers.
c) Municipal Wastes
The main components of municipal waste are food wastes, rubbish, ashes and
residues, demolition and construction wastes, special wastes and treatment plant
wastes. Wastes such as street sweepings, roadside litter, catch basins debris, dead
animals and abandoned vehicles are classified as special wastes. The solid and semi-
solid wastes from water, waste water and industrial waste treatment facilities are
included in treatment plant wastes.
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d) Industrial Wastes
Industrial wastes are those wastes arising from industrial activities.
e) Hazardous wastes
These are wastes that pose a substantial danger immediately or over a period
of time to human, plant or animal life. A waste is classified as hazardous if it exhibits
any of the following characteristics: Ignitability, Corrosivity, Reactivity, and Toxicity
(Khitoliya, 2014).
f) Indiscriminate Dumping
Indiscriminate Dumping, Achi et al., (2012) opined that indiscriminate dumping
refers to unlawful disposal of waste in undesignated spaces such as open or vacant
land, sources of water and other areas. Indiscriminate dumping is a very common and
prevalent though risky practice, especially among developing countries.
9
waste, wastes from landscape and tree trimming, general wastes from parks and
recreational areas (Hoornweg et al., 1999).
v. Institutional Waste: These are wastes that are often generated from hospitals,
schools, dispensary, pharmacy, barracks which may be largely household types, but
hospitals (medical wastes/clinical wastes) dispose more dangerous materials such as
cotton wools, bandages, syringes, waste from operating theatres, discharged drugs and
cans (Hoornweg et al., 1999).
vi. Construction/Demolition Wastes: It includes waste generated from construction
and demolition of buildings, roads, bridges, etc. It consists of earth, stones, bricks,
wood, iron bars, concrete, etc.
vii. Hazardous Waste: According to Environmental Protection Agency (EPA),
hazardous wastes are wastes or combination of wastes that pose substantial threat to
human health or living organisms because: (a) Such wastes are non-degradable in
nature. (b) They can be biologically magnified. (c) They can be lethal. (d) They may
otherwise cause or tend to cause detrimental cumulative Effects (Hoornweg et al.,
1999).
Corrosiveness:
Corrosive waste refers to materials that can cause severe damage or deterioration to
metal containers, human tissues, and other materials when they come into contact.
Corrosive substances typically have a low or high pH, and they can be either acidic or
alkaline.
Examples of corrosive materials include strong acids like sulfuric acid and
hydrochloric acid and strong bases like sodium hydroxide.
10
Corrosive waste poses a threat to human health, infrastructure, and the environment.
When not properly managed, it can lead to leaks, spills, and the release of hazardous
fumes.
Ignitability:
Ignitable waste includes materials that can catch fire easily, even under standard
temperature and pressure conditions. These wastes are typically classified into four
categories: liquids with flashpoints below 60°C (140°F), non-liquids that can readily
ignite, ignitable compressed gases, and oxidizers.
Examples of ignitable materials include gasoline, acetone, and certain aerosol cans
containing flammable propellants.
Ignitable waste poses a risk of fire, which can lead to property damage, injuries, and
environmental contamination if not managed properly.
Reactivity:
Reactive waste refers to substances that are unstable and can react violently with
water, air, or other materials. They can also generate toxic gases, heat, or explosions
when subjected to certain conditions, such as temperature or pressure changes.
Examples of reactive materials include explosives, cyanides, and materials that can
release toxic gases upon contact with water.
Reactive waste requires careful handling and disposal to prevent accidents, fires, or
explosions, and it is crucial to store such waste away from incompatible materials to
avoid unexpected reactions.
Toxicity:
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Examples of toxic materials include heavy metals (e.g., lead, mercury, and cadmium),
certain organic compounds (e.g., pesticides, PCBs), and many industrial chemicals.
Toxic waste must be managed carefully to prevent contamination of soil and water,
exposure to humans and wildlife, and long-term health and environmental risks.
12
gasification process are a low-energy gas typically containing (by volume) 20%
CO, 15% H2, 10% CO2 and 2% CH4 USEPA, 2009.
E. Composting: Composting is the most responsible technical solution for many
developing countries especially, where the climate is arid and the soil is in serious
need of organic supplements. The composting process usually follows 2 basic
steps as shown in Fig. 2.13, which may be preceded or followed by pre- or
posttreatments (crushing, sorting, humidification, mixing with other waste, etc...)
USEPA, 2009.
Additionally, convenience plays a role, as people may opt for the easiest and quickest
disposal methods rather than the environmentally responsible ones. All of these
factors combined contribute to the widespread issue of indiscriminate solid waste
disposal, leading to pollution, health hazards, and ecological damage.
13
2. Health Hazards: Indiscriminate disposal attracts pests and disease vectors like
rats, mosquitoes, and flies, increasing the risk of diseases like malaria, dengue, and
cholera. People living near dumpsites are exposed to hazardous substances, leading to
respiratory problems and other health issues.
3. Habitat Destruction: Illegal dumping and improper waste disposal destroy natural
habitats, disrupting ecosystems and biodiversity. Waste accumulation can alter the
composition of soil and water, harming plant and animal life.
4. Aesthetic Degradation: Piles of garbage and waste strewn around public areas
negatively impact the visual appeal of communities, reducing overall quality of life
and affecting tourism potential.
7. Economic Loss: The cost of cleaning up and managing waste sites, as well as
treating the health issues caused by improper disposal, can place a heavy economic
burden on governments and communities.
8. Social Issues: Improper waste disposal can lead to social conflicts, as communities
near dumpsites may protest against their adverse living conditions. Waste scavenging
can also expose vulnerable populations, such as children and informal waste workers,
to health and safety risks.
10. Legal and Regulatory Issues: Governments may need to allocate resources for
stricter waste management regulations and enforcement measures, diverting resources
from other essential services.
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2.8 Solutions to indiscriminate disposal of solid wastes
1. Public Awareness and Education: Launch campaigns to educate people about the
importance of proper waste disposal, recycling, and the harmful effects of
indiscriminate dumping. Increasing awareness can encourage responsible behavior.
2. Waste Segregation: Promote the separation of waste at the source into categories
like organic, recyclable, and non-recyclable. This makes recycling and proper disposal
more efficient.
15
10. Stringent Enforcement: Enforce waste management regulations and impose
penalties for indiscriminate disposal. Regular monitoring can deter illegal dumping.
16
CHAPTER THREE
PROPOSED METHODOLOGY
3.1. THE STUDY AREA
Ogbomosho has about 257 surrounding villages and emerging towns which
amalgamated to the rulership of Soun. The major economy in the land is Agriculture
cashew plantations are widely distributed across the land, In addition, Mango
plantations are widely distributed too. Ogbomosho is one time the largest planter of
cassava across the globe.
The people of the land also engages in trading, rearing of domestic animals like
goats and sheep. Also, a very prominent veterinary hospital exist in Ogbomosho for
vaccination of livestock. The people are widely traveled.
The location of the town on terrain unattractive to manufacturers and investors, with
the road network being poor.
The present Ogbomoso North Local Government Area with its Administrative
Headquarters at Kinnira was carved out of the Old Ogbomoso Local Council on the
27th September, 1991, the Old Ogbomoso Local Council was however established on
1st of April,1973.
The Local Government being an semi-urban area is strategically located and serves as
link to Northern part of the country.
It covers total land mass of 207978 square kilometres and using the growth rate of
3.2% from 2006 census, the 2010 estimated population, the Local Government Area is
put at 225,408. The Local Government Area is bounded by Ogbomoso South, Orire
and Surulere Local Government Areas to the West and East respectively. It lies
between longitude 8.1335N and latitude 4.2538E
17
The map of study are shown below in figure 3.1a, 3.1b and 3.1c
18
Figure (B). Map of Oyo state showing Ogbomoso North
In other to put in place the existing solid wastes management practice in the study
area, an assessable method for data collection was acquired, which will consist of a
field/preliminary survey using questionnaires. The questionnaires was designed to
source various information relevant to study area.
19
This comprised:
a. General Information:
Here, the questionnaire was mandatory to prepare information on the method which
implies waste transportation and disposing off of solid waste
Below this section, the questioner was mandated to prepare information on the
situation of the air in the area whether it is clear most of the time or polluted and how
frequent and critical is it.
Here, the questioner was mandated to prepare information on the situation concerning
the groundwater in the area to know what major sources of water and how far is the
source of water to the waste disposal point.
Under this section, the questioner was required to provide information on the
condition on human health in the area to know if there is a regular ailment related to
water source and if human consumption from polluted water bodies can lead to
diseases like cholera, diarrhea and dysentery and so on.
3.3.1 Procedure
1. The Proper working condition of the gas monitor was used, calibration and the
proper functionality of its sensors was ensured.
2. Safety was prioritized by wearing appropriate personal protective equipment
3. The survey of the around the dumpsite was carried out to identify potential gas
emission point and as well the wind direction was noted.
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4. The gas monitor was calibrated using certified calibration gases for the gases to
be detected to ensure the accuracy of the measurements.
5. The gas monitor was hold close to point where gas emission is suspected, and
the readings were taken at multiple location to ensure a comprehensive
assessment.
6. The concentration of gases detected were recorded and location where high
concentration found was noted. This helped us to assess the extent of gas
emissions.
7. The result which we got was later compared in context to health and
environmental risks.
8. The result was documented and necessary recommendations was provided based
on the findings.
9. Lastly, the compliance of the activities with local regulations and safety standard
for working around hazardous sites was ensured.
3.3.2 Methods
This was carried out with the use of gas monitor or other gas detector sources to
determine the presence of gases in the environment( gases such as CO, CO2, NO,
Methane etc) to know the level at the air of the environment is polluted.
This was compared to the results with EPA standards and discuss the results
3.4 Determination of water pollution around the dumpsite of the study area
This was done by identifying the certain dumpsite closer to water source, identifying
another source that was served as control, some 20-25cm away from dumpsite. The
water sample was collected from the source of water
To determine the level at which the water is polluted in the water sources the
following procedures was followed:
i. Two different wells was identified and selected, one closer to the dumpsite,
when the others was about 20 to 30 metres away from the dumpsite. The well
further away from the dumpsite was assumed to be ideal while the other well
near the dumpsite was assumed to be polluted.
21
ii. Water samples was collected from both wells in a clean and sterile container
which had not been previously used for other substances.
iii. The sample information such as the date, time, location, well identification
and other necessary information was recorded.
iv. The temperature of the sample was measured using thermometer.
v. The water samples was now taken to the laboratory for further examinations,
the water samples obtained from both wells was now examined under,
Physical analysis, Chemical analysis and Biological analysis, to determine the
pollution level of the samples.
1. Density
When designing a solid waste management system, such as the design of sanitary
landfills, storage, types of collection, little sample and transport vehicles, etc., the
density of the garbage, or its mass per unit volume (kg/m3), is an important
consideration.
To put it simply, compaction of wastes to the ideal density was necessary for an
experimental test to operate efficiently.
In other words, as solid waste were travelled from its source to its disposal, its density
was fluctuated significantly due to manual scavenging, handling, weather-related
wetting and drying, and decomposition.
We calculated for density of solid waste dividing the net weight of the waste sample
(weight of loaded container minus weight of empty container) by the container's
volume and expressed as kg/m.
2. Moisture level
The weight of water (wet weight minus dry weight) divided by the total wet weight of
the waste, is known as the moisture content.
Moisture makes solid wastes heavier, which was raised to the cost of collection and
transportation. Additionally, moisture content is a key factor in determining whether
22
waste treatment by incineration is economically feasible, because wet waste requires
energy for the evaporation of water, and for raising the temperature of water vapour.
Wastes should be generally be protected from rain or other outside water.
Moisture content (%)= {Wet wt. – dry wt. / wet wt.} x 100
The usual moisture content range is 20 to 40%, which will reflects the extremes of
wastes in a dry climate, and during the wet season in an area with considerable
precipitation. Values above 40%, however, will not be unusual.
Aside from climatic factors, low-income areas typically have higher moisture content,
due to the greater percentage of food and yard waste.
Moisture content will also plays an important role in other processing methods such
as composting and anaerobic digestion.
Due to its significance in the design of mechanical separators, shredders, and waste
treatment processes, the size distribution of waste elements in the waste stream was
crucial. This varies greatly, hence it is important to properly analyse the waste
characteristics, while developing a system.
* 40 mL distilled water was added and stirred well with a glass rod.
* This was allowed to stand for half an hour with intermittent stirring.
23
Procedure for pH test
Calibration of electrode
b. Organic content:
A 10 gm portion of the dried ground sample was placed in a silica dish and
slowly heated in an electric furnace to 700 degree Celsius for 30 min. The residue was
weighed and the loss of weight represents the organic content and was expressed as
percent by weight. The knowledge of organic content helps assess the feasibility of
biological processing-composting and anaerobic digestion.
c. Toxicity:
* Ultimate analysis
* Proximate analysis
24
Toxicity test
1. Separation of liquid wastes: Liquids (containing less than 0.5% dry solid
material) were filtered through glass fiber to create a TCLP extract. Wastes
(containing 0.5% or greater dry matter) were separated and stored for later
analysis.
2. Particle size reduction: Using a standard 9.5 mm sieve, we filtered solid
material and prepared it for extraction by cutting, crushing or grinding to a
particle size of 1 cm or less.
3. Extraction of solid material: The solid material is then extracted for at least 18
hours with a slightly acidic fluid equal to 20 times its weight. The materials
were placed in a tumbler to simulate the leaching action of water seeping
through waste in the landfill.
4. Final separation: The liquid waste was separated from the solid waste through
a fiber glass filter. The solid material was discarded and the liquid components
were assessed. The initial liquid components may be added or may be
analyzed separately, depending on compatibility.
5. TCLP testing analysis: Lastly, we identify and quantify all inorganic and
organic materials using EPA-approved methods.
d. Proximate analysis
e. Ultimate analysis
25
compounds during combustion, the determination of halogens is often included in an
ultimate analysis. The results of the ultimate analysis were used to characterize the
chemical composition of the organic matter in MSW. They were also used to define
the proper mix of waste materials to achieve suitable C/N ratios for biological
conversion processes.
The fusing point of ash is defined as that temperature at which the ash
resulting from the burning of waste will form a solid (clinker) by fusion and
agglomeration. Typical fusing temperatures for the formation of clinker from solid
waste range from 2000 to 2200°F (1100 to 1200°C.
a. Biodegradability
A. Organic fraction often equated with the volatile solids (VS) content of the waste
BF = 0.83 - 0.028LC
Where:
0.028=empirical constant
26
i. Hydrogen sulfide, H2S (rotten eggs)
b. Production of Odors
Odors can develop when solid wastes are stored for long periods of time on-site
between collections, in transfer stations, and in landfills. The development of odors in
on-site storage facilities is more significant in warm climates. Typically, the formation
of odors results from the anaerobic decomposition of the readily decomposable
organic components found in MSW. For example, under anaerobic (reducing)
conditions, sulfate can be reduced to sulfide (S-2), which subsequently combines with
hydrogen to form H2S The formation of H2S can be illustrated by the following two
series of reactions.
27
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25. Top of Form
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