wwwleadtocss.com FEDERAL PUBLIC SERVICE COMMISSION (COMPETITIVE EXAMINATION FOR Roll Number RECRUITMENT TO POSTS IN BS-17 UNDER THE FEDERAL GOVERNMENT, 2020 CHEMISTRY, PAPER] TIME ALLOWED: [(PART-1 MCOs) 30 MINUTES MAXIMUM MARKS: 20 THREE HOURS __[ (PART-II) 2 HOURS & 30 MINUTES, MAXIMUM MARKS: 80 NOTE: (i) Candidate must write Q.No. in the Answer Book in accordance with in the Q.Paper. ‘Attempt ONLY FOUR gucstions from PART-I. All questions carry EQUAL marks. Use of simple calculator is allowed. Periodic Table is on page-2. Extra attempt of any question or any part of the attempted question will not be considered. PART-II Q.2. (a) Write two equations of state for real gases and compare them high lighting their (10) important features. (©) @ Explain Heisenberg’s uncertainty principle. (os) ii) Discuss Born’s interpretation of wave function. (05) (10) @0) Q.3. (a) Explain the Kohlrausch law. Why do the real solution should deviate from the (10) law? (b) Compare Langmuir’s and Freundlich’s adsorption isothenns. 10) @oy Q.4. (@ Explain the Arrhenius equation. Also high Light its applications and limitations. (10) (®) Explain various acid-base theories. What are hard and soft acids and bases? (10) (20) Q.5. (a) Make a comparison of column chromatography and thin layer chromatography (10) (TLC) by highlighting merits and demerits of the both, (®) Explain Wemer’s theory of coordination complexes. Give examples from (10) (20) d-block transition metals. Q.6. (a) Give a comprehensive classification of various chromatographic techniques. (10) Also mention potential application of each, (®)—@_Whatis Hydrogen bonding. Explain. @s) (i) Deseribe Hybidization in p-block elements 5) (10) @0) Q.7. (a) Explain erystal Field Theory (CFT) for d-block elements, «oy (db) Write an extensive essay on types of chemical bonding giving examples, (10) Gay Q.8. Write short nates on the following: (Seach) 20) (Liquid junction potential (i) Potentiometry (ii) Collision theory of Chemical reactions. (iv) Transition state theory,wwwleadtocss.com FEDERAL PUBLIC SERVICE COMMISSION (COMPETITIVE EXAMINATION FOR Roll Number RECRUITMENT TO POSTS IN BS-17 UNDER THE FEDERAL GOVERNMENT, 2020 CHEMISTRY, PAPER-II TIME ALLOWED: [(PART-1 MCOs) 30 MINUTES MAXIMUM MARKS: 20 THREE HOURS __[ (PART-II) 2 HOURS & 30 MINUTES, MAXIMUM MARKS: 80 NOTE: (i Candidate must write Q.No. in the Answer Book in accordance with Q.No. in the Q.Paper. ‘Attempt ONLY FOUR gucstions from PART-I. All questions carry EQUAL marks. Use of simple calculator is allowed. Periodic Table is on page-2. Extra attempt of any question or any part of the attempted question will not be considered. PART-II Q.N0.2, Explain the difference between: (Seach) 20) @) Inductive and Field effects (i) Inductive and Resonance effects (ii) Localized and Delocalized bonding (ix) Conjugation and Hyperconjugation Q.No0.3. (a) “The resonance effect has an appreciable influence on physical characteristics and (10) the chemical reactivity of ergante molecules". Elaborate the statement with the help of examples, (@) Cutline the EAS mechanism (Llectrophilic Aromatic Substitution) through which (5) aromatic compounds react with electiophiles. (e) Discuss factors which favour an climinstion reaction oceurring over a substitution (5) (20) QNo.4. How would you carry out the following conversions? Account for your answer with (4 exch) (20) mechunism in each case. @) (CHS sCCH=CH: + (CHL) :C(OMCH(CH)2 Gi) (CHycer-cH: = (CH ;ccHEOMCH, Gi) (CH) ,CoH=C =) (CH) CCH.CH.OH fy (CHACe=CH | (CH CCOEH, () (CHy),Cc= = (Cy sCCH.CHO Q.No.5. The following reactions can be used for the preparation of alkunes or eycloalkanes. (Sen Elaborate them with the help of reaction mechanistes. (@) Corey House reaction (it) Wurtz reaction Gi) Kolbe reaction Gv) Simmons - Smith Reaction QNo.6. How would you convert cyclohexanone into the following compounds? Write (4 each) 20) down the mechanisms of the reactions (@) Ceprolactone (b) Caprolactam —_ (C)__Cyeloheptanone (d) Cyclohexa-12-dione (1) Cyclohexane QNo. 7. (a) How can a racemic mixture be separated ito its components? Describe different methods. (16) ()_(O-Lactic seid has a specific rotation of — 3.8°, What will be the specific rotation ofa (4) @0) solution containing 7.5g of (-)-lactic acid and 2.S g of (+)-lactic acid? QNo. 8. (4) Starch, glycogen and cellulose sre polymers of glucose. How will you differentiate among (12) these three both structurally and functionally. () Explain precisely the following terms. (8) 20) () Glycolysis i) Glycogenolysis Gui) Glycouenesis_ (iv) gluconeogenesis: