Biomolecules ChemiStudious Notes
Biomolecules ChemiStudious Notes
Biomolecules ChemiStudious Notes
BImelcules
BL9meloculor ae tne ouaMiL LOmpoiinüL pHezont
UmdipeALNtcoll hete aHe uOyhLg M Aize_
HOH eM Lakbehydnates, miumeDd, pHatrime
emymes, nutteicacids, uitomins, houmonwe.
coubehudare icaubhehyduates aue theMaiunally
ocCLia SKgmicLompaird uhichaneamajoy
AouMLa omooyio'oui hody-Sm plont
Cowboyduater aie.poumed by+hepunteLs np
Phatasymtheuik
uC0tyHDhDOByS
Aumlight
CHgody tD2-
Cavbonydate
Thechomtalpaumuula op coukolhydnatrsugget
theseaue hyduato.op.coubom hutLatenon i~uwas
poumd +hattmotal cauhohyduates aua hyduateg
O Laubm 2Net+all the hydHntLIngcanbon
auhehyduate. b
cauhehiduatu could ka atategai iho polyhydxaxy
ompouos uuhith He.optncally actie Lwham
hyduolyscd)
ClouigicaiensoLLaLheh1yduotez
rOkbehiydHater aka.inauuh a acthauide! Sachaidoe
mon AuLgau Ln Latm
(al Based pm hotetiulausiza_3 tyhs
MMoneAaLChouidee : simnloztcaubphyduattluuhh
Omt be hyduolyaed unio smalle pu2duch
i) inaLthoades(oisarchouidedaxhohypduatot hunlyai
2-10 moleadlo op mbnDAacth0Hiderupinhyiniau.
rOaLthauidocoueshduatar uhiihgie lakgene:og
LOTiacchauides (moue-thaniD) upm hyduolyn
Lb)Bntod om Talte
) AugaL Caubchydunlu that hauo. suDet Lute
Sa. nu mono ard olig osarhayuideg
Cm.pgm iugaHL nubohujduatg uilhout IuuLsh lnle,
Paluaithnnidu.
lc)Bouod om natwL
i)ReduimAugau (Obohydsunts Aht
heducoTaiame oagemt Fehlinq solulion
gluosp pruutole
lii)ionHeducingsupau- hát dond-eduze
cutho AHe theie Eg>suNOL2
Memasntchnuidos
simpli caHhohyduate that canna behyduclyy
Lnte moHD ALmplan LompoLurds
HLtalline sodlide ALeetADluhie in uuatos
Bolubilituy i due to AtLon2 44-hordir bJuD
H04-DHqelyps pHesont Lin.thresa wnpoumd.
(a) AldneR :momoachanidu thatcontaim
aldeyde -cHD)quoup 2tupuient Ot cat
H2o ed ag C-häm ey:C
EN glucoie laldohamoink C-6 wmbourdi.
b) KotasosMomoAaLchàidd hat Lontaim
Hete uoup (c=0) Hhe.Hato guouip atled
Cnula bemyuhet enopl-althoaind ombon.
emerally heto JuoLp iipHLLOMIQtC2
Hlucose-LDntunse, quape.3uga)
wa 2uCOSeis A naHiHollF OLtLIHiÝ OganicconaLu
ADLHL2HLIpe GUADaL,honey,thamyfsuuetpuiti,
humanblocd
4 dedue Hatatey in matune
9+iadiiahauide.
(o) EuMm LLcHOAe (tmd sLDaA :
Ci2 H220tH20 CHI2 O6tC6Hi206
ULUtHh dl:H oH
(By boluMq aq dolutiom OQ AuCAOLL
di: H2SOy).
b EHgm AtakhpolysaLchanmde. when itu boled vn
Leme oLaud at 393 K 2-3 am pwiame,
glucose is obstauncd
(CgHio Og) +mHz0 H
393 k2-3atm
m GgH26
Physical Pnpouilies demhoo.
Luhite LHIL tallime solid. soluble.inuuater Totatouy
Aueet mtüute edugsugaH
AUriUUOog gluucpse ktutunalpokmula
gluunse i CHolCHOH) y CH20H
TP Aegtthmidue ta=DHAHOLID
1) ctyLation
CHO CHO
LCHOH)Y+ 5lCHaCo),0>(cHOCOCH3)4+SCH3OH
CH20H Cactic CH206OCH
LLquuco1e) anhydud) pemt-a aLeklgluuase
i1) Rlatiomsuitth mehyL_alLohiL
CHolCHOHs CH2OHtCH20H-> HOl CHOH)UCH,0 Ha +H0
(meHuyt glycoide)
Ronctiera dueto l-cHolGunp
iReduztign
CHOLCHDHs CLH0HLAt 2HI2CH20HlCHDH)YCH20H
AOHbitl
eyde qynyAAA asaLLAlaelkaEHP
CHQCHopettoE
to alcoholuLgup
ne alehuyde quoup i Hedured
Hedl> cHaltt2CH,Ü42 CH2 H
CHO CCHDH)r H2DH +HI
-hMmL
uith oniansi
(i)uidatiom tiluuete is omidied
agemts Lik bnomuma uLatA
CoOH lCHDH)YCH2OH
>
chocHOHDuCH20HCO LlucomiLALid
HNO
CHolCHOH) y H20HC
CDOH(CHOH)y co0H
AALLhautAcd
t) Aentign uithHCN OH
CH2DH (CHOH)s CHD-+HONCH0H(cHDHy CH
Lyluae tymahydsin CN
CH NNH C6H
NNH CLH
CCHOHD3
Lyicosaze u2OH
CenpigukAtiom apeLuLDAL
(omLguHatien qo guucose has beam guuem by Eiuthty om
He haiu ofti hemica pHonoktis. Cbmkigunation
hasbeam nomed au Dl+)qlucoe DHhLeLemts
COmiguatien op 4 E) imnies Motaten ap elme
olaHized ight to the Lught
CHO
H OH na.comyumd gycoHaLdohyde.enistr
HO -H Un 2 ematusmaL RORMng. he
H- -OH
H OH
enantiommeuiuith Hatem n Lstz
OH QHaup om iGht called
CHOH D-Lomiguunakion & Hhe atu:u
called LONLLguUtion:
haompiguudtem op.tHoie MEMDLALthaudehat
hasngiouvuaLiomaimilLay to D-glyanaldehyde,
HhatCmmtiomuu is (Qlled LonLguHatien D
Lce=UOHLA.
PAGE N0
Lyclicstucuuep0L DLt)guLose
ToLlem gaue a yclii stmciue LQllLd
hemiauefaistAuctuke mL suung poHmec
i a sin membtked sung Colled S-0Aide MIg
m 244elic hemiatetal s+uLuus
diywu in ne comfigusiaten op 0Hg0up
Hatom at C0nly d heLeaHe"calid
K d p pokmsog D(+) qluLoe
H OH HC HO H
H OH H24 OH H OH
HD H O Ho3
HO H HO H6-
H OH H -DH H OH
H H OH
CHOH CHzOH H-
CH20H
-D+gluLnie onenchaim AtkuchuMa -Dtgluunse
CHOHL 6 CH2 0H
H H OH
H
H OH H
2 OH OH 3 H
-DEqlucopuHmOIe_ BDOluuabyuOmote
MIuta-Ratatien
Le mol that LBp0m oe D+)lucose
haup Motatin op 120 19 uiham bofh th
kuystallunegonmoane diuolued im uatethe
ataten op phem chomgc £a4ea ZAYmtime!
he HalLon foH boh {om becomag 2qual to
524 hil Cenditiom ú called muuta Hatatien
&-0(+gluLoLe B-D+)gluLDLe
1120 524 19
Euctnse (Lacuiulosa),CguigDg_uiLsugaH
0 monosdichaHulle, Hetohemose huepauid
by hyduolysit op AuCHOse
CaH22O+H20 Cgti2Dg CGHi2D% Umda
.
PAGE NO:
LaLtpee os_miLkAugauCC42H2204
tose l puesemtim hiuk oR. Mmmaluepatd
cheee
by-PLodut tn puepaintion oR
ommiuk mulsM
C12H220+ H20 6H2%tC6H2 Dg
B-D guose
galocoLL
CH2OH CHOH
O OH
HO H
OH
H 0H H OH
B-D-galactose A-D uLDLL
H OH H
Branch at C
CHOH CH CH,OH
H 15 -0
H H H H H H
OH
-oN HLoNOH HLoN OH
o-}
HLo.
H OH H OH OH
a-Link a-Link
Amylopectin
(ii Cellulose: Cellulose occurs exclusively in plants and it is the most
abundant organic substance in plant kingdom. It is a predominant
constituent of cell wall of plant cells. Cellulose is a straight chain
HOH,C
O
OH
HOH,C
-O OH
OH
HOHC
OH
B-links
OH
OH
Cellulosse
polysaccharide composed only. of p-D-glucose units which are
joined by glycosidic linkage between Cl of one glucose unit and
C4 of the next glucose unit.
(i) Glycogen: The carbohydrates are stored in animal body as glycoger.
Itis also known as arnimal starch becauseitsstructure is similar to
amylopectin and is rather more highlybranched. It is present in liver,
muscles and brain. When the body needs gucose, enzymes break the
glycogen down toglucose. Glycogen is also found in yeast and fungi.
ImpDtanco og caubohyduatDe
SouLLO op emoug4 (LMapt colluloO)
rDuH body cmnot digeat calluloeeond geremungy
asouH b0dy clocsnot haue emume Leluuloië.
tgdtgut ut. But in mony othui Quagu9
anmal lcou), it ii nuezemt R hemLe ihy
Cn digeit celiuloAe A get emegy puDm it..
fhima Auidi
tmuno auid hauLD. (=NH2) lamino guaup) ard
Hhouyl(-CoDH) guoup 0d ane.clauiedas
, y , S omd to no on thhe pasitióm lbasitofJ
R -Caubon
HhN-C COOH
H
PAGENO.
-Auna Acid
N m euomtialmime aide : 4he ammumo aat
that cam be syntthuized by thebod4 Ex 9
9uyme,alanime, etu
E Eucotialamime atide:the amuno autl Hat
Cmt be.Syntheized by the.hody
Ex valme,
Lysume, elt
Heuenmtial omimo aLid u t betahin puem
CutlLcle puom poad Al theye imp0Hmt-po1
0LeuLHof bodu
wnittem as nly md Alonine alHla adsom
lyycine
#laupiratomop_ AmimgAuds
9m tHe bALil op n9 0p. amume 4 LAbylQuOLp
PHLCM HuyHe tauiyiod al audi hkit 2
neubua
buidit ne oA LAHbeuyl quDLLp L MOHe
HgNH-oHLA-N-dh--oHSt,N-CH-
L y=ALa
C-touminal AlmuNL-
Numiamal lanine 2
H O _H _
O
HhN-ch-ë-NN-LH2 -2
HyN-d TOHER-N-CHa-CroH (ALa-y)
minal lyuina
N-Huminol Alanuin -tu
#dauipiLotion co uitmuine
LAuatiHLOLublë iuitamim-BcomplenM BL,B2,Bg, Br2)-
(B) atH GYnAnlublo/fatgaluble:AD,EAK wtm0C
DNA RNA
1PemtoLa AugaHPIeNA 1:PemtoiLALLgaH PHeLM
unRA iL`-uihosei DAVA iD-S-deayaiboiz
2- DVA Lomtaimi pKNA COmtaumiujuOine
ghosine AHhmmunacmad HOLil aspyaimdune
apimidme bashazu d quonirdo
gimmmpLadeninaladimined1 puuine baeg
alpilino bases
2:9ttm HeplicaT |tinpomid by DNA
a LamoHeplicate dau
u9tHLspomLible EiHLnontible poy
HOtrmjei n aHotLmAymhheit
gemetiLtaite
A6Huah_paelondaa louLmolesulàu miX 201
eeLugaL