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2022 Chemistry Paper I (Theory) MJ CLUSTER

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EXAMINATION NO.

: ___________________________

MULANJE CLUSTER 2022 MSCE MOCK EXAMINATIONS

CHEMISTRY
Subject Number: M31/I

Tuesday, 31 May Time allowed: 2 hour


8:00 - 10am
PAPER I
(100 Marks)

Instructions Question Tick if Do not write


1. This paper contains 11 printed Number answered in these
pages. Please check. columns
2. Fill in your examination number at 1
the top of each page. 2
3. This paper contains two sections, A 3
and B. In section A there are ten
short answer questions while in 4
section B there are three restricted
essay questions. 5
6
4. Answer all the thirteen questions in
the spaces provided. 7
8
5. Use of electronic calculators is
allowed. 9

6. The maximum number of marks for 10


each answer is indicated against each
11
question.
12
7. In the table provided on this page,
tick against the question number you 13
have answered.

©2022MJ CLUSTER Turnover/


EXAMINATION No. _____________________________
Page 2 of 11 M038/I

Section A (70 marks)


Answer all the ten questions in this section
1. a. What is a molecule?
__________________________________________________________________
_________________________________________________________ (1 mark)
b. State one factor that affect solubility of a solute in a solvent.
__________________________________________________________________
________________________________________________________ (1 mark)
c. Write the formula of a compound formed between potassium ions,
𝑲+ and sulphate ions, 𝐒𝐎𝟐−
𝟒 .

_________________________________________________________ (1 mark)

d. Given 𝟕𝟒𝒀and 𝟖𝟒𝒀 as two isotopes of an element Y.


i. Suggest one chemical property of element Y
_______________________________________________________________
(1 mark)
ii. Write an ion formed when element Y loses its outermost electron(s).
_______________________________________________________________
(1 mark)
iii. Give a reason why the two isotopes react in the same way.
_______________________________________________________________
_______________________________________________________________
(1 mark)
2. a. Write a balanced chemical equation that describes reversible
reaction of hydrated copper sulphate (CuSO4*5H2O).

(3 marks)
EXAMINATION No. _____________________________
Page 3 of 11 M038/I

b. A hydrated Magnesium sulphate (MgSO4*nH2O) was heated to


become anhydrous, its mass dropped from 246.5g to 120.5g. Work
out the value of n. (RFM: MgSO4 = 120; and H2O = 18).

(3 marks)

c. Figure 1 is a structure of an element that is composed of four


atoms to make a molecule.

i. Identify the element with the structure above.


____________________________________________________________
(1 mark)

ii. State two allotropes of the element.


____________________________________________________________
__________________________________________________ (2 marks)

iii. Mention one agricultural importance of the element.


____________________________________________________________
___________________________________________________ (1 mark)

3. a. What is a reducing agent?


__________________________________________________________________
________________________________________________________ (1 mark)
EXAMINATION No. _____________________________
Page 4 of 11 M038/I

b. Silver nitrate solution react with zinc metal as shown in the


chemical equation.
AgNO3 (aq) + Zn (s) Zn(NO3)2 (aq) + Ag(s)
i. Identify the spectator ion in the reaction.
_____________________________________________________ (1 mark)
ii. Write a balanced oxidation half equation for the reaction.

____________________________________________________ (2 marks)
iii. Describe how Zinc nitrate salt produced from this reaction can
be obtained and purified.
_______________________________________________________________
_______________________________________________________________
____________________________________________________ (2 marks)
c. Give two apparatus suitable for conducting distillation method of
separating mixtures.
__________________________________________________________________
________________________________________________________ (2 marks)
4. a. Define molar gas volume.
__________________________________________________________________
________________________________________________________ (1 mark)
b. Calculate the volume occupied by 47.6g of ammonia gas (NH3) gas
at r.t.p.? (RAM, N = 14; H = 1 and Molar gas volume r.t.p is
22.4dm3).

(4 marks)
EXAMINATION No. _____________________________
Page 5 of 11 M038/I

c. Give two types of intermolecular forces.


________________________________________________________________
_______________________________________________________ (2 marks)

5. a. State the difference between saturated hydrocarbons and


unsaturated hydrocarbons.
__________________________________________________________________
_______________________________________________________ (2 marks)
b. Given below are below molecular formula of some organic
compounds represented by letters P, Q, R and S
P. C3H6
Q. C4H10
R. C4H9OH
S. CH3COOH

i. Identify the function group of compound S.


__________________________________________________ (1 mark)
ii. Give the name of compound R.
__________________________________________________ (1 mark)
iii. Draw the structural formula of compound P.

(1 mark)
iv. Write a chemical equation in which compound P undergo
addition reaction with chlorine molecule.

(2 marks)

v. Draw and name any two isomers of compound Q.

(4 marks)
EXAMINATION No. _____________________________
Page 6 of 11 M038/I

6. a. Give two properties which can be used to identify purity of a


substance.
__________________________________________________________________
______________________________________________________ (2 marks)

b. Figure 2 below shows a flow diagram of soap preparation.

Figure 2
i. Name the homologous series of substance A.
_________________________________________________________ (1 mark)

ii. Why is process B necessary in soap making process?


__________________________________________________________________
________________________________________________________ (1 mark)
iii. Give one reason why sodium chloride is added in the process?
__________________________________________________________________
________________________________________________________ (1 mark)

7. a. Figure 3 is a diagram for Plastics.

Figure 3
i. Name the type of plastic plastics labelled.
X.__________________________________________________ (1 mark)
Y.__________________________________________________ (1 mark)
EXAMINATION No. _____________________________
Page 7 of 11 M038/I

ii. State one difference between plastic X and plastic Y.


_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
(2 marks)

b. Mention two disadvantages of landfill as a waste treatment and


disposal method.
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
(2 marks)
c. Discuss one unwanted effects of alkanes.
__________________________________________________________________
__________________________________________________________________
(2 marks)
d. Explain the importance of the ozone layer.
__________________________________________________________________
__________________________________________________________________
__________________________________________________________________
(2 marks)
8. a. Give one chemical property of acidic oxide.
__________________________________________________________________
__________________________________________________________________
(1 mark)
b. Describe how the presence of a catalyst does increases rate of
reaction?
__________________________________________________________________
__________________________________________________________________
(2 marks)
EXAMINATION No. _____________________________
Page 8 of 11 M038/I

9. a. What does ∆𝐇𝐧𝐨 denotes?


__________________________________________________________________
__________________________________________________________________
(1 mark)
b. Nitrogen gas react with hydrogen gas to produce ammonia gas as
shown in the equation:
N2 +3H2 → 2NH3

Given the bond energy values as shown in table 2 below

Bond Energy (kjmol-1)


N-H 390
N≡N 942
H-H 435
Table 2
i. Calculate the overall energy changes for the reaction above.

(4 marks)
ii. Determine the type of heats of reaction for the reaction above.
__________________________________________________________________
(1 mark)
EXAMINATION No. _____________________________
Page 9 of 11 M038/I

10. a. Identify a general trends of the periodic table that makes atoms to
attract electrons from other atoms.
__________________________________________________________________
(1 mark)

b. Draw a dot and cross diagram for hydrogen chloride (HCl).

(3 marks)

Section B (30 marks)

Answer all the three questions in this section.

11. a. Describe how carbonate ions are used to remove lead ions (Pb2+)
in industrial effluents before releasing them into water bodies.
_________________________________________________________________
_________________________________________________________________
_________________________________________________________________
_________________________________________________________________
_________________________________________________________________
_________________________________________________________________
_________________________________________________________________
(4 marks)
EXAMINATION No. _____________________________
Page 10 of 11 M038/I

b. Discuss three benefits of recycling metals and plastics.


________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
________________________________________________________________
(6 marks)
12. a. Describe two industrial importance of water.
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
(4 marks)
b. With the aid of chemical equations, describe the process of
rusting.
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
_______________________________________________________________
(6 marks)
EXAMINATION No. _____________________________
Page 11 of 11 M038/I

13. With the aid of a well labelled diagram, describe the water cycle.

______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
______________________________________________________________________________
(10 marks)
END OF QUESTION PAPER
NB: This paper contains 11 printed pages.

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