YASHSHREE ACADEMY, DHANGARWADI, AHEMNAGAR

ANNUAL EXAM 2020-21

CLASS–XI
Time: 3 HRs. SUB: CHEMISTRY MM.: 65

General Instructions:
(a) All questions are compulsory.
(b) Section A: Q. No. 1 to 20 are very short answer questions (objective type) and carry 1 mark each.
(c) Section B:Q. No. 21 to 27 are short answer questions and carry 2 marks each.
(d) Section C:Q. No. 28 to 34 are long answer questions and carry 3 marks each.
(e) Section D:Q. No. 35 to 36 are also long answer questions and carry 5 marks each.
(f) There is no overall choice. However, an internal choice has been provided in two questions of two marks, two
questions of three marks and all the three questions of five marks weightage. You have to attempt only one of the
choices in such questions.
SECTION A
Read the given passage and answer the questions 1 to 5 that follows:
Hydrocarbons are carbon and hydrogen containing compounds that burn to produce oxides of carbon.
Hydrocarbons are carcinogenic and their products are also major pollutants. Carbon monoxide (CO) is poisonous
in nature as it reacts with the haemoglobin of blood, which can even result in death. Though carbon dioxide
(CO2) is not toxic in nature, yet it contributes towards global warming by trapping the reflected IR rays. This
results in the heating up of the Earth's atmosphere, thereby leading to the melting of icebergs and glaciers.
1. Define environmental chemistry. 1
2. Carbon monoxide gas is more dangerous than carbon dioxide gas. Why? 1
3. How IR rays are harmful for atmosphere? 1
4. Write the name of the complex formed by the reaction of CO with haemoglobin. 1
5. What is the range of pH value for Acid rain? 1
Questions 6 to 10 are one word answers/one sentence:
6. Arrange the following set of compounds in order of their decreasing relative reactivity toward 1
selectorphilic (E+ ) attack
Chlorobenzene, 2,4-dinitrochlorobenzene, p-nitrochlorobenzene
7. For an isolated system, ΔU = 0, what will be ΔS? 1
8. Name a species that will be isoelectronic with Rb+ ion. 1
9. Calculate the amount of carbon dioxide (in mole) that could be produced when 1 mole of carbon is 1
burnt in air.
10. Name the method, which can be used to separate two compounds with difference of boiling 1
point(less than 200C) in a solvent.

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 Questions 11 to 15 are multiple choice questions 1
11.
The correct IUPAC names of the products obtained by the ozonolysis of Pent-2-ene.
(a) Ethanal and butanal (b) Propanal and Butanal
(c) Ethanal and Propanal (d) None of these

12. The equilibrium constant for a reaction is 10. What will be the value of ΔG0 1
(Given: R = 8.314 JK-1mol-1, T= 300K, log10= 1)
(a) -5.744 kJ mol-1
(b) -7.744 kJ mol-1
(c) + 5.744 kJ mol-1
(d) +7.744 kJ mol-1
13. Which of the following has the smallest number of molecules? 1
(a) 11.2 L of O2 at NTP
(b) 8.0 g of O2
(c) 0.1 mole of O2
(d)2.24X104 mL of O2
14. Which one of the following statements is incorrect in relation to ionization enthalpy? 1
(a) Ionization enthalpy increases for each successive electron.
(b) The greatest increase in ionization enthalpy is experienced on removal of electron from core
noble gas configuration.
(c) End of valence electrons is marked by a big jump in ionization enthalpy.
(d) Removal of electron from orbitals bearing lower ‘n’ value is easier than from orbital having
higher ‘n’ value.
15. The process of treating permanent hardness of water using synthetic resins is based on the 1
(a)exchange of cations only
(b)exchange of anions only
(c)exchange of both cations and anions
(d) No exchange of ions takes place

Questions 16 to 20
(a) Assertion and reason both are correct statements and reason is correct explanation for assertion.
(b) Assertion and reason both are correct statements but reason is not correct explanation for assertion.
(c) Assertion is correct statement but reason is wrong statement.
(d) Assertion and reason both are incorrect statements.
16. Assertion : Orbital is a region where the probability of finding e- is maximum. 1
Reason : At node maximum probability of finding e- is one.
17. Assertion : All isotopes of a given element show the same type of chemical behaviour. 1
Reason : The chemical properties of an atom are controlled by the number of electrons in the
atom.

18. Assertion : Under low pressure and high temperature real gases behave as an ideal gases. 1
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 Reason : The Size of the particle of gases and inter molecular attraction force become
negligible.
19. Assertion : Mixture of petrol and kerosene is separated by distillation method. 1
Reason : Distillation is used to separate volatile liquids from non-volatile impurities or a
mixture of those liquids that have sufficient difference in boiling points.
20. Assertion: Benzene undergo electrophilic substitution reactions easily and nucleophilic 1
substitution with difficulty?

Reason : Benzene is a planar molecule having delocalized electrons above and below the
plane of ring. Hence, it is electron rich. As a result, it is highly attractive to electron
deficient species

SECTION B (SA)

21. What is the energy in joules required to shift the electron of hydrogen atom from the first Bohr orbit 2
to the fifth Bohr orbit and what is the wavelength of the light emitted when the electron returns to
the ground state? (Given , The ground state electron energy is -2.18x10-11erg , 1 erg= 10-7 J)
OR
Electromagnetic radiation of wavelength 242 nm is just sufficient to ionize the sodium atom.
Calculate the ionization energy of sodium in kJmol-1.(Given h= 6.626X10-34Js)
22. The increasing order of reactivity among group 1 elements is Li < Na < K < Rb <Cs whereas that 2
among group 17 elements is F > CI > Br > I. Explain.

23. What is polar covalent bond and why CO2 has zero dipole moment? 1+1
24. For a reaction: 2A(g) + B(g) →2D(g) 2
∆Uo = -10.5kJ and ∆So= -44.1J Calculate ∆Goat 298 K for the reaction and predict whether the
reaction is spontaneous or not? (Given, R= 8.314x10-3 kJK-1mol-1)
OR
The reaction of NH2CN(s) with O2 was carried out in bomb calorimeter and ΔU was found to be
-742 KJ/mol at 298 K. Calculate the enthalpy change of reaction at 298 K.
25. Explain the following: 1+1
(a)If you pump air into cycle tyre, a slight warming effect is noticed at the valve stem.
(b) Entropy decreases in going from normal egg to hardboiled egg?
26. How does H2O2 behave as a bleaching agent? 2
27. Draw the structure of (i) BeCl2 (vapour) (ii) BeCl2 (solid). 1+1

SECTION C (LA-I)
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28. (a) What will be the mass of one 12C atom in g? 1+2
(b) Calculate the mass percent of different elements present in sodium sulphate(Na 2SO4).
(Atomic mass of Na=23,S=32,O=16u)
OR
(a) How many significant figures should be present in the answer of the calculation of 5 × 5.364
(b)Determine the molecular formula of an oxide of iron in which the mass per cent of iron and
Oxygen is 69.9 and 30.1 respectively. Given that the molar mass of the oxide is 159.69 g mol-1
(Atomic mass Fe=56,O=16u)
29. (a) Write the electronic configuration of 29Cu. 1+1+1
(b) Explain the Photo electric effect.
(c) State the Heisenberg’s uncertainty principle.

30. (a) Define hydrogen bond. Give an example of Intra-molecular hydrogen bonding. 1+1+1
(b) Give reasons:
(i)H2O has higher boiling point than HF.
(ii)Ice floats on the surface of water.

31. (a) Critical temperature for carbon dioxide and methane are 31.1 °C and -81.9 °C respectively. 1+2
Which of these has stronger intermolecular forces and why?
(b) Calculate the temperature of 4.0 mol of a gas occupying 5 dm3 at 3.32 bars.
(R = 0.083 bar dm3 K-1 mol-1).
OR
(a) What would be the SI unit for the quantity pV2T 2/n?
(b) A student forgot to add the reaction mixture to the round bottomed flask at 27 °C but instead
he/she placed the flask on the flame. After a lapse of time, he realized his mistake, and using a
pyrometer he found the temperature of the flask was 477 °C. What fraction of air would have
been expelled out?

32. (a) The compound AgF2 is an unstable compound. However, if formed, the compound acts as a very 1+2
strongoxidizing agent. Why?
(b)Identify the substance oxidized, reduced, oxidizing agent and reducing agent for each of the
Following reactions:
(i) 2AgBr (s) + C6H6O2(aq)→ 2Ag(s) + 2HBr (aq) + C6H4O2(aq)
(ii) HCHO(l) + 2[Ag (NH3)2]+(aq) + 3OH-(aq)→ 2Ag(s) + HCOO-(aq) + 4NH3(aq) + 2H2O(l)

ONLY FOR VISUALLY IMPAIRED

While sulphur dioxide and hydrogen peroxide can act as oxidising as well as reducing agents in
their reactions, nitric acid acts only as oxidants. Why?
33. (a) Why are lithium salts commonly hydrated and those of the other alkali metal ions usually 1+1+1
anhydrous?
(b) Why is LiF almost insoluble in water whereas LiCl soluble not only in water but also in
acetone?
(c) Describe two important uses of each of the following: (i) Caustic soda (ii) Sodium carbonate
34. (a) How will you convert Benzene into Acetophenone? 1+1+1
(b) Propanal and pentan-3-one are the ozonolysis products of an alkene? What is the structural
formula of that alkene?
(c) Benzene extra ordinarily stable though it contains three double bonds. Why?

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SECTION D (LA-II)
35. (a) A liquid is in equilibrium with its vapour in a sealed container at a fixed temperature. The 2+3
volume of the container is suddenly increased.
i) What is the initial effect of the change on vapour pressure?
ii) What happens when equilibrium is restored finally and what will be the final vapour pressure?
(b) What is Kc for the following equilibrium reaction
2SO2(g)+ O2(g)⇄ 2SO3(g)
when the equilibrium concentration of each substance is: [SO2]= 0.60 M, [O2] = 0.82 M and
[SO3] = 1.90 M ?

OR
(a) Explain why pure liquids and solids can be ignored while writing the equilibrium constant
expression?
(b) A sample of HI(g) is placed in flask at a pressure of 0.2 atm. At equilibrium the partial
pressure of HI(g) is 0.04 atm.
2HI(g)⇄H2(g) + I2(g)
Calculate the value of Kp for the given equilibrium?
36. (a)( i) Why does Aluminium trichloride behave as a Lewis acid? 2+3
(ii) Draw the shapes of BH4+.
(b) What happens when (Write reaction only)
(i) Borax is heated strongly.
(ii) Boric acid is added to water.
(iii)Aluminium is treated with dilute NaOH.
OR
(a) Give reasons:
(i)Diamond is used as an abrasive.
(ii) Aluminium alloys are used to make aircraft body.
(b) write&balance the following reactions:
(i) Silicon is heated with methyl chloride at high temperature in the presence of copper.
(ii) Silicon dioxide is treated with hydrogen fluoride.
(iii) CO is heated with ZnO.

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