,~'~lay Materials Used in

Construction
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REEVES, G. M, SIMS, I. & CRIPPS, J. C. (eds) 2006. Clay Materials Used in Construction. Geological Society,
London, En~ineerin~ Geology Special Publication, 21.
LIEOLO(JlCAL SOCIETY ENGINEERING GEOLOGY SPECIAL PUBLICATION NO. 2 "

Clay Materials Used in Construction

EDITED BY

G.M. R E E V E S
UHI Millennium Institute, Thurso, UK

I. S I M S
STATS Limited, St Albans, UK

and

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University of Sheffield, UK

2006
Published by
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Dedicated to Professor Sir Alec Skempton, F.R.S., F.R.Eng.
1914-2001
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Mangla Dam, West Pakistan, 1963

Alec Skempton (right) and Peter Fookes (left)
 Contents

Foreword . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxi
Editors' note . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxii
M e m b e r s o f the W o r k i n g Party . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxiii
Acknowledgements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxiii
Preface . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxiv
List o f symbols and units . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xxv

Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1.1. Clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
1.2. Definitions o f clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
1.2.1. Definitions o f clay and clay minerals b y the A I P E A Nomenclature and C M S
Nomenclature Committees . . . . . . . . . . . . . . . . . . . . . . 2
1.2.2. Civil engineering definitions o f clay in British practice . . . . . . . . . . . 4
1.2.3. International Civil Engineering Soil Classification b y particle size distribution
(grading) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
1.3. Some British clay production statistics . . . . . . . . . . . . . . . . . . . . . 5
1.4. Geographical and stratigraphical distribution . . . . . . . . . . . . . . . . . . 5
1.5. The W o r k i n g Party . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
1.5.1. The report . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10

. The composition of clay materials . . . . . . . . . . . . . . . . . . . . . . . . . 13

2.1. C l a y minerals . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
2.1.1. The kaolin and serpentine groups . . . . . . . . . . . . . . . . . . . 15
2.1.2. The i l l i t e - m i c a group . . . . . . . . . . . . . . . . . . . . . . . . 15
2.1.3. Smectites . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
2.1.4. Vermiculite . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
2.1.5. Chlorite . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
2.1.6. M i x e d layer clay minerals . . . . . . . . . . . . . . . . . . . . . . 19
2.1.7. Sepiolite and palygorskite . . . . . . . . . . . . . . . . . . . . . . 20
2.1.8. Swelling properties o f clay minerals . . . . . . . . . . . . . . . . . . 20
2.1.9. Ion exchange properties o f clay minerals . . . . . . . . . . . . . . . . . 21
2.2. Non-clay mineralogy . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
2.2.1. Quartz and chert . . . . . . . . . . . . . . . . . . . . . . . . . . 23
2.2.2. Feldspars . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
2.2.3. Carbonates . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
2.2.4. Iron sulphides . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
2.2.5. Oxides and h y d r o x i d e s . . . . . . . . . . . . . . . . . . . . . . . 24
2.2.5.1. Iron oxides and hydroxides . . . . . . . . . . . . . . . . . . 24
2.2.5.2. A l u m i n i u m oxides and hydroxides . . . . . . . . . . . . . . . 24
2.2.5.3. Ion exchange in oxides and hydroxides . . . . . . . . . . . . . 24
2.2.6. Sulphates . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
2.2.6.1. Ettringite group . . . . . . . . . . . . . . . . . . . . . . 24
2.2.7. Zeolites . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
2.2.8. Phosphates . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
2.2.9. Halides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
2.3. Organic matter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 25
2.3.1. Organic-clay complexes and interactions . . . . . . . . . . . . . . . . . 26
viii CONTENTS

2.4. Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 26
2.5. Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27

F o r m a t i o n and alteration of clay ma t e r i a l s . . . . . . . . . . . . . . . . . . . . . 29

3.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
3.1.1. The clay cycle . . . . . . . . . . . . . . . . . . . . . . . . . . 29
3.1.2. Clay materials and plate tectonics . . . . . . . . . . . . . . . . . . . 29
3.1.3. Origins o f clay minerals by n e o f o r m a t i o n inheritance and transformation . . . . 30
3.2. Weathering environment and soils . . . . . . . . . . . . . . . . . . . . . . 32
3.2.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . 32
3.2.2. Controls on clay mineral formation during weathering and soil formation . . . . 33
3.2.2.1. Climate . . . . . . . . . . . . . . . . . . . . . . . . . 33
3.2.2.2. Drainage and topography . . . . . . . . . . . . . . . . . . 34
3.2.2.3. Parent rock type . . . . . . . . . . . . . . . . . . . . . 34
3.2.2.4. Time . . . . . . . . . . . . . . . . . . . . . . . . . . 35
3.3. Sedimentary environment . . . . . . . . . . . . . . . . . . . . . . . . . . 36
3.3.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
3.3.2. Origin o f clay minerals in sediments . . . . . . . . . . . . . . . . . . 37
3.3.3. Source and supply o f m u d . . . . . . . . . . . . . . . . . . . . . . 38
3.3.4. Erosion, transport, and deposition o f m u d . . . . . . . . . . . . . . . . 38
3.3.5. Erosion, transport and deposition by water . . . . . . . . . . . . . . . . 39
3.3.5.1. Transport by rivers . . . . . . . . . . . . . . . . . . . . . 39
3.3.5.2. Chemical composition o f river suspended sediment . . . . . . . . 39
3.3.5.3. Transport in the sea and ocean . . . . . . . . . . . . . . . . 39
3.3.5.4. Deposition by settling and flocculation . . . . . . . . . . . . . 41
3.3.5.5. Fabric and microstructures . . . . . . . . . . . . . . . . . . 42
3.3.6. Erosion transport and deposition by ice . . . . . . . . . . . . . . . . . 43
3.3.7. Erosion transport and deposition by wind . . . . . . . . . . . . . . . . 44
3.3.8. Sedimentary n e o f o r m e d clays . . . . . . . . . . . . . . . . . . . . . 45
3.4. Diagenetic to low grade metamorphic environment . . . . . . . . . . . . . . . . 48
3.4.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . 48
3.4.2. Early diagenetic processes . . . . . . . . . . . . . . . . . . . . . . 48
3.4.3. Main pathways and reactions o f clay mineral diagenesis . . . . . . . . . . . 49
3.4.3.1. Smectite-to-illite reaction and illitization . . . . . . . . . . . . . 50
3.4.3.2. Illite ' c r y s t a l l i n i t y ' . . . . . . . . . . . . . . . . . . . . . 51
3.4.3.3. Formation o f chlorite . . . . . . . . . . . . . . . . . . . . 53
3.4.3.4. Diagenesis o f kaolin . . . . . . . . . . . . . . . . . . . . 53
3.4.4. Burial diagenetic reactions o f non-clay phases in mudrocks . . . . . . . . . 53
3.4.5. Compaction, porosity and permeability . . . . . . . . . . . . . . . . . 54
3.5. Hydrothermal environment . . . . . . . . . . . . . . . . . . . . . . . . . 55
3.5.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . 55
3.5.2. Hydrothermal clay mineral formation . . . . . . . . . . . . . . . . . . 56
3.6. Clay materials: products o f weathering, sedimentary, diagenetic/low grade metamorphic,
and hydrothermal processes . . . . . . . . . . . . . . . . . . . . . . . . . 57
3.6.1. Clay rich soils . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
3.6.2. Residual kaolin deposits . . . . . . . . . . . . . . . . . . . . . . . 59
3.6.3. Vermiculite . . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
3.6.4. Terrigenous clays, mudstones and shales . . . . . . . . . . . . . . . . . 59
3.6.5. Sedimentary or secondary kaolins . . . . . . . . . . . . . . . . . . . 63
 CONTENTS ix

3.6.6. Sedimentary bentonites and tonsteins . . . . . . . . . . . . . . . . . . 64

3.6.7. Chemical perimarine and lacustrine clay deposits . . . . . . . . . . . . . 65
3.6.8. Deep sea clays . . . . . . . . . . . . . . . . . . . . . . . . . . 65
3.6.9. H y d r o t h e r m a l kaolin deposits . . . . . . . . . . . . . . . . . . . . . 66
3.6.10. Other hydrothermal clay deposits . . . . . . . . . . . . . . . . . . . 67
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67

. P r o p e r t i e s of clay materials, soils and m u d r o c k s . . . . . . . . . . . . . . . . . . . 73

4.1. Composition, classification and description o f clay materials . . . . . . . . . . . . 74
4.1.1. Mineralogy . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
4.1.2. Classification o f clays . . . . . . . . . . . . . . . . . . . . . . . . 75
4.1.2.1. Geological classification . . . . . . . . . . . . . . . . . . 75
4.1.2.2. Engineering classification . . . . . . . . . . . . . . . . . . 76
4.1.2.3. Pedological classification . . . . . . . . . . . . . . . . . . 78
4.1.3. Particle size and grading o f clays . . . . . . . . . . . . . . . . . . . 78
4.1.4. Description o f clays . . . . . . . . . . . . . . . . . . . . . . . . 80
4.1.5. Classification o f mudrocks . . . . . . . . . . . . . . . . . . . . . . 81
4.1.6. B r e a k d o w n o f mudrocks . . . . . . . . . . . . . . . . . . . . . . . 82
4.1.7. Durability o f mudrocks . . . . . . . . . . . . . . . . . . . . . . . 83
4.1.8. Description o f mudrocks . . . . . . . . . . . . . . . . . . . . . . . 84
4.1.9. Classification o f weathering in mudrocks . . . . . . . . . . . . . . . . 85
4.2. F r a m e w o r k for clay material behaviour . . . . . . . . . . . . . . . . . . . . . 85
4.2.1. Moisture content, density and saturation . . . . . . . . . . . . . . . . . 87
4.2.2. Flow and r h e o l o g y . . . . . . . . . . . . . . . . . . . . . . . . . 87
4.2.3. Plasticity o f clays: Atterberg limits . . . . . . . . . . . . . . . . . . . 89
4.2.4. Permeability and diffusion . . . . . . . . . . . . . . . . . . . . . . 94
4.2.5. Stresses in the ground: pore pressures and effective stress . . . . . . . . . . 95
4.2.6. Unsaturated clays and suction . . . . . . . . . . . . . . . . . . . . . 96
4.2.7. Clays for ceramic applications . . . . . . . . . . . . . . . . . . . . . 98
4.2.8. Thermal properties o f clays . . . . . . . . . . . . . . . . . . . . . . 99
4.2.9. C o m p a c t i o n o f clays . . . . . . . . . . . . . . . . . . . . . . . . 100
4.3. Geotechnical parameters: strength and stiffness o f clay materials . . . . . . . . . . . 101
4.3.1. Deformation . . . . . . . . . . . . . . . . . . . . . . . . . . . 102
4.3.2. Strength parameters . . . . . . . . . . . . . . . . . . . . . . . . 103
4.3.3. Compression . . . . . . . . . . . . . . . . . . . . . . . . . . . 104
4.3.4. O n e - d i m e n s i o n a l compression and swelling . . . . . . . . . . . . . . . 107
4.3.5. Critical state strength . . . . . . . . . . . . . . . . . . . . . . . . 109
4.3.6. Shear strength parameters . . . . . . . . . . . . . . . . . . . . . . 109
4.3.7. U n d r a i n e d shear strength parameters . . . . . . . . . . . . . . . . . . 110
4.3.8. Effects o f structure . . . . . . . . . . . . . . . . . . . . . . . . . 111
4.3.9. Modulus o f rupture . . . . . . . . . . . . . . . . . . . . . . . . . 111
4.3.10. Strength and deformation o f m u d r o c k s . . . . . . . . . . . . . . . . . 111
4.4. Potentially troublesome clay materials . . . . . . . . . . . . . . . . . . . . . 112
4.4.1. Shrink and swell . . . . . . . . . . . . . . . . . . . . . . . . . . 112
4.4.2. Dispersive soils . . . . . . . . . . . . . . . . . . . . . . . . . . 114
4.4.3. Collapsible soils . . . . . . . . . . . . . . . . . . . . . . . . . . 114
4.4.4. Quick clays . . . . . . . . . . . . . . . . . . . . . . . . . . . . 115
4.4.5. Tropical residual soils . . . . . . . . . . . . . . . . . . . . . . . . 115
4.4.5.1. R e d tropical soils . . . . . . . . . . . . . . . . . . . . . 116
4.4.5.2. Other tropical soils . . . . . . . . . . . . . . . . . . . . . 117
X CON 1 LNI'S

4.5. Properties o f some British clays and mudrocks . . . . . . . . . . . . . . . . . . 117

4.5.1. Recent and Quaternary deposits . . . . . . . . . . . . . . . . . . . . 119
4.5.1.1. Tills . . . . . . . . . . . . . . . . . . . . . . . . . . 119
4.5.1.2. V a r v e d and laminated clays . . . . . . . . . . . . . . . . . 120
4.5.1.3. Alluvial and Marine clays . . . . . . . . . . . . . . . . . . 120
4.5.2. Tertiary clays . . . . . . . . . . . . . . . . . . . . . . . . . . . 121
4.5.2.1. Ball C l a y . . . . . . . . . . . . . . . . . . . . . . . . 121
4.5.2.2. London Clay . . . . . . . . . . . . . . . . . . . . . . . 121
4.5.2.3. L o n d o n Clay---density and moisture content . . . . . . . . . . . 121
4.5.2.4. L o n d o n C l a y - - p a r t i c l e size and consistency limits . . . . . . . . . 121
4.5.2.5. L o n d o n C l a y - - s t r e n g t h and stiffness . . . . . . . . . . . . . . 123
4.5.2.6. L o n d o n C l a y - - c o m p a c t i o n , consolidation and permeability . . . . . 124
4.5.3. Cretaceous clays . . . . . . . . . . . . . . . . . . . . . . . . . . 124
4.5.3.1. Gault C l a y . . . . . . . . . . . . . . . . . . . . . . . . 124
4.5.3.2. Gault C l a y ~ d e n s i t y and moisture content . . . . . . . . . . . . 124
4.5.3.3. Gault C l a y - - p a r t i c l e size and consistency limits . . . . . . . . . . 125
4.5.3.4. Gault C l a y - - s t r e n g t h . . . . . . . . . . . . . . . . . . . . 125
4.5.3.5. Gault C l a y - - c o m p r e s s i b i l i t y and permeability . . . . . . . . . . 125
4.5.4. Jurassic clays . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
4.5.4.1. Lias C l a y . . . . . . . . . . . . . . . . . . . . . . . . 126
4.5.4.2. Lias C l a y - - m o i s t u r e content and density . . . . . . . . . . . . 126
4.5.4.3. Lias C l a y - - p a r t i c l e size and consistency limits . . . . . . . . . . 127
4.5.4.4. Lias C l a y - - s t r e n g t h and stiffness . . . . . . . . . . . . . . . 127
4.5.5. Permo-Triassic mudrocks . . . . . . . . . . . . . . . . . . . . . . 127
4.5.5.1. Mercia M u d s t o n e . . . . . . . . . . . . . . . . . . . . . 127
4.5.5.2. Mercia M u d s t o n e - - d e n s i t y and moisture content . . . . . . . . . 128
4.5.5.3. Mercia M u d s t o n e - - p a r t i c l e size and consistency limits . . . . . . . t28
4.5.5.4. Mercia M u d s t o n e - - s t r e n g t h and deformation . . . . . . . . . . . 128
4.5.5.5. Mercia M u d s t o n e - - c o n s o l i d a t i o n and permeability . . . . . . . . . 129
4.5.5.6. Mercia M u d s t o n e - - c o m p a c t i o n . . . . . . . . . . . . . . . . 129
4.5.6. Carboniferous mudrocks . . . . . . . . . . . . . . . . . . . . . . . 129
4.5.6.1. Coal Measures mudrocks . . . . . . . . . . . . . . . . . . 129
4.5.6.2. Coal Measures m u d r o c k s - - m o i s t u r e content and plasticity . . . . . . 13C
4.5.6.3. Coal Measures m u d r o c k s - - s t r e n g t h . . . . . . . . . . . . . . 130
4.5.6.4. Coal Measures m u d r o c k s - - c o n s o l i d a t i o n and deformation parameters . 130
4.5.6.5. Coal Measures m u d r o c k s - - d u r a b i l i t y . . . . . . . . . . . . . . 130
4.6. Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131
4.6.1. Variation in U K clays and mudrocks with geological age . . . . . . . . . . 132
4.6.2. Degradation o f over-consolidated clays and indurated m u d r o c k s . . . . . . . 133
4.6.3. Controls on properties . . . . . . . . . . . . . . . . . . . . . . . 134
References 134

. W o r l d and E u r o p e a n clay deposits . . . . . . . . . . . . . . . . . . . . . . . . . 139

5.1. The character o f clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
5.1.1. General . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
5.1.2. Climate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
5.1.3. Time . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
5.2. Environments o f clay formation . . . . . . . . . . . . . . . . . . . . . . . . 140
5.2.1. Residual clays o f tropical regions . . . . . . . . . . . . . . . . . . . . 140
5.2.2. H y d r o t h e r m a l clays . . . . . . . . . . . . . . . . . . . . . . . . 140
 CONTENTS xi

5.2.3. Transported clays . . . . . . . . . . . . . . . . . . . . . . . . . 141

5.2.4. Clays o f glacial origin . . . . . . . . . . . . . . . . . . . . . . . 141
5.3. P a l a e o g e o g r a p h y and clay depositions . . . . . . . . . . . . . . . . . . . . . 141
5.3.1. The Palaeozoic . . . . . . . . . . . . . . . . . . . . . . . . . . 141
5.3.1.1. Cambrian . . . . . . . . . . . . . . . . . . . . . . . . 141
5.3.1.2. Ordovician . . . . . . . . . . . . . . . . . . . . . . . . 142
5.3.1.3. Silurian and D e v o n i a n . . . . . . . . . . . . . . . . . . . . 143
5.3.1.4. Carboniferous and Permo-Triassic . . . . . . . . . . . . . . . 143
5.3.2. The M e z o z o i c . . . . . . . . . . . . . . . . . . . . . . . . . . 144
5.3.2.1. Jurassic . . . . . . . . . . . . . . . . . . . . . . . . . 144
5.3.2.2. Cretaceous . . . . . . . . . . . . . . . . . . . . . . . . 145
5.3.3. The C e n o z o i c . . . . . . . . . . . . . . . . . . . . . . . . . . . 146
5.4. Climatic changes in the Quaternary . . . . . . . . . . . . . . . . . . . . . . 147
5.5. W o r l d clay deposits . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147
5.5.1. ' C o m m o n ' clay . . . . . . . . . . . . . . . . . . . . . . . . . . 147
5.5.2. Kaolin clays . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
5.5.3. Smectite clays . . . . . . . . . . . . . . . . . . . . . . . . . . 150
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150

. British clay stratigraphy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153

6.1. Pre-Carboniferous . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156
6.1.1. Silurian shales . . . . . . . . . . . . . . . . . . . . . . . . . . 157
6.2. Carboniferous . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 157
6.2.1. B o w l a n d Shale F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . 158
6.2.2. W a r w i c k s h i r e Group . . . . . . . . . . . . . . . . . . . . . . . . 158
6.3. P e r m i a n and Triassic . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159
6.3.1. Mercia M u d s t o n e Group . . . . . . . . . . . . . . . . . . . . . . . 159
6.3.2. Penarth Group . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
6.4. Jurassic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
6.4.1. Lias Group . . . . . . . . . . . . . . . . . . . . . . . . . . . . 162
6.4.2. U p p e r and L o w e r Fuller's Earth and F r o m e Clay Formations . . . . . . . . . 164
6.4.3. Blisworth Clay & Forest Marble Formations . . . . . . . . . . . . . . . 164
6.4.4. Oxford Clay F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . . 164
6.4.5. W e s t W a l t o n Formation . . . . . . . . . . . . . . . . . . . . . . . 165
6.4.6. A m p t h i l l Clay F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . 165
6.4.7 K i m m e r i d g e Clay F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . 165
6.5. Cretaceous . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 166
6.5.1. Wadhurst Clay F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . 166
6.5.2. W e a l d Clay F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . . 166
6.5.3. Atherfield Clay F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . 166
6.5.4. Speeton Clay Formation . . . . . . . . . . . . . . . . . . . . . . . 166
6.5.5. Gault F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . . . . . 167
6.6. Tertiary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167
6.6.1. O r m e s b y Clay F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . 168
6.6.2. L a m b e t h Group . . . . . . . . . . . . . . . . . . . . . . . . . . 168
6.6.3. L o n d o n Clay F o r m a t i o n . . . . . . . . . . . . . . . . . . . . . . . 169
6.7. Quaternary deposits . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17C
6.8. Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 173
xii CONTENTS

7. Exploration . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177
7.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 177
7.1.1. The exploration cycle . . . . . . . . . . . . . . . . . . . . . . . . 178
7.1.2. Standards relevant to exploration . . . . . . . . . . . . . . . . . . . 178
7.1.3. Personnel . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178
7.2. Non-intrusive exploration . . . . . . . . . . . . . . . . . . . . . . . . . . 179
7.2.1. Desk studies . . . . . . . . . . . . . . . . . . . . . . . . . . . 179
7.2.2. W a l k - o v e r surveys . . . . . . . . . . . . . . . . . . . . . . . . . 181
7.2.3. Field m a p p i n g . . . . . . . . . . . . . . . . . . . . . . . . . . 183
7.2.4. Preliminary assessment report . . . . . . . . . . . . . . . . . . . . 185
7.3. Geophysical investigations . . . . . . . . . . . . . . . . . . . . . . . . . 185
7.3.1. Geophysical m a p p i n g . . . . . . . . . . . . . . . . . . . . . . . . 185
7.3.2. Borehole geophysical logging . . . . . . . . . . . . . . . . . . . . . 187
7.4. Sampling p r o g r a m m e s . . . . . . . . . . . . . . . . . . . . . . . . . . . 188
7.4.1 A i m s o f sampling . . . . . . . . . . . . . . . . . . . . . . . . . 188
7.4.2 Sampling strategies and grids . . . . . . . . . . . . . . . . . . . . . 188
7.4.3 Sample numbers . . . . . . . . . . . . . . . . . . . . . . . . . . 189
7.5. Intrusive exploration methods . . . . . . . . . . . . . . . . . . . . . . . . 189
7.5.1. Trial pitting and trenching . . . . . . . . . . . . . . . . . . . . . . 189
7.5.2. D y n a m i c probing and w i n d o w sampling . . . . . . . . . . . . . . . . . 191
7.5.3. Boring and drilling . . . . . . . . . . . . . . . . . . . . . . . . . 191
7.5.4. Cone penetration testing . . . . . . . . . . . . . . . . . . . . . . . 192
7.5.5. L o g g i n g and description . . . . . . . . . . . . . . . . . . . . . . . 193
7.5.6. Groundwater m e a s u r e m e n t . . . . . . . . . . . . . . . . . . . . . . 193
7.6. Soil samples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
7.6.1. Sample quality . . . . . . . . . . . . . . . . . . . . . . . . . . 194
7.6.2. Sample types . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
7.6.3. Sample preservation and storage . . . . . . . . . . . . . . . . . . . . 196
References 196

Compositional and textural analysis of clay material . . . . . . . . . . . . . . . . . 199

8.1. Mineralogical analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
8.1.1. X-ray p o w d e r diffraction analysis . . . . . . . . . . . . . . . . . . . 199
8.1.1.1. Mineral identification . . . . . . . . . . . . . . . . . . . . 201
8.1.1.2. Crystallinity indices o f i l l i t e / m i c a . . . . . . . . . . . . . . . 203
8.1.1.3. Peak decomposition techniques . . . . . . . . . . . . . . . . 204
8.1.1.4. Quantitative mineralogical analysis . . . . . . . . . . . . . . 204
8.1.2. Infra-red spectral analysis . . . . . . . . . . . . . . . . . . . . . . 206
8.1.3. Thermal analysis . . . . . . . . . . . . . . . . . . . . . . . . . . 207
8.1.3.1. Differential thermal analysis . . . . . . . . . . . . . . . . . 207
8.1.3.2. Thermal gravimetric analysis . . . . . . . . . . . . . . . . . 208
8.1.3.3. E v o l v e d gas detection and analysis . . . . . . . . . . . . . . . 209
8.2. Petrographic analysis . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
8.2.1. Optical m i n e r a l o g y . . . . . . . . . . . . . . . . . . . . . . . . . 209
8.2.2. Electron m i c r o s c o p y . . . . . . . . . . . . . . . . . . . . . . . . 209
8.2.2.1. Scanning electron m i c r o s c o p y . . . . . . . . . . . . . . . . 209
8.2.2.2. Transmission electron m i c r o s c o p y (TEM) . . . . . . . . . . . . 212
8.2.3. Image analysis techniques . . . . . . . . . . . . . . . . . . . . . . 212
8.2.4. X-ray goniometry . . . . . . . . . . . . . . . . . . . . . . . . . 213
8.2.5. Specific surface area . . . . . . . . . . . . . . . . . . . . . . . . 213
 CONTENTS xii'

8.3. Inorganic g e o c h e m i c a l analysis . . . . . . . . . . . . . . . . . . . . . . . . 214

8.3.1. B u l k compositions and selective leach techniques . . . . . . . . . . . . . 214
8.3.1.1. X-ray fluorescence spectrometry . . . . . . . . . . . . . . . . 214
8.3.1.2. ICP-AES analysis . . . . . . . . . . . . . . . . . . . . . 215
8.3.1.3. Carbonate determination . . . . . . . . . . . . . . . . . . . 215
8.3.1.4. Sulphur species . . . . . . . . . . . . . . . . . . . . . . 216
8.3.1.5. Selective leaching techniques . . . . . . . . . . . . . . . . . 216
8.3.1.6. Interstitial water analysis . . . . . . . . . . . . . . . . . . 216
8.3.2. Electron microprobe analysis ( E M P A ) . . . . . . . . . . . . . . . . . . 216
8.3.3. Ion exchange . . . . . . . . . . . . . . . . . . . . . . . . . . . 217
8.3.3.1 Cation e x c h a n g e capacity . . . . . . . . . . . . . . . . . . 217
8.3.3.2 A n i o n e x c h a n g e capacity . . . . . . . . . . . . . . . . . . 218
8.4. Organic matter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 218
8.4.1 Total organic carbon (TOC) analyses . . . . . . . . . . . . . . . . . . 218
8.4.2 R o c k - E v a l pyrolysis . . . . . . . . . . . . . . . . . . . . . . . . 218
8.4.3 Organic petrography . . . . . . . . . . . . . . . . . . . . . . . . 219
8.4.4. Biological assays . . . . . . . . . . . . . . . . . . . . . . . . . 220
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 220

. L a b o r a t o r y testing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223
9.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 223
9.2. Sample preparation and conduct o f testing . . . . . . . . . . . . . . . . . . . 223
9.2.1. Sample preparation . . . . . . . . . . . . . . . . . . . . . . . . . 224
9.2.1.1. Disturbed specimens . . . . . . . . . . . . . . . . . . . . 224
9.2.1.2. Undisturbed specimens. . . . . . . . . . . . . . . . . . . . 224
9.2.1.3. R e c o m p a c t e d specimens . . . . . . . . . . . . . . . . . . . 225
9.2.1.4. Remoulded specimens . . . . . . . . . . . . . . . . . . . . 225
9.2.2. Laboratory e n v i r o n m e n t . . . . . . . . . . . . . . . . . . . . . . . 225
9.2.3. Calibration o f e q u i p m e n t . . . . . . . . . . . . . . . . . . . . . . . 225
9.2.4. Precision o f data . . . . . . . . . . . . . . . . . . . . . . . . . . 226
9.3. Classification tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227
9.3.1. Scope . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227
9.3.2. Moisture content . . . . . . . . . . . . . . . . . . . . . . . . . 227
9.3.3. Liquid and plastic limits . . . . . . . . . . . . . . . . . . . . 228
9.3.3.1. Liquid limit . . . . . . . . . . . . . . . . . . . . . . . 228
9.3.3.2. Plastic limit . . . . . . . . . . . . . . . . . . . . . . . 229
9.3.4. Shrinkage tests . . . . . . . . . . . . . . . . . . . . . . . . . . 230
9.3.4.1. Shrinkage l i m i t - - d e f i n i t i v e m e t h o d . . . . . . . . . . . . . . 230
9.3.4.2. Shrinkage l i m i t - - A S T M m e t h o d . . . . . . . . . . . . . . . 231
9.3.4.3. Linear shrinkage . . . . . . . . . . . . . . . . . . . . . . 231
9.3.5. D e n s i t y tests . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
9.3.5.1. Linear m e a s u r e m e n t . . . . . . . . . . . . . . . . . . . . 232
9.3.5.2. I m m e r s i o n in water . . . . . . . . . . . . . . . . . . . . 232
9.3.5.3. Water d i s p l a c e m e n t . . . . . . . . . . . . . . . . . . . . 232
9.3.6. Particle density . . . . . . . . . . . . . . . . . . . . . . . . . . 233
9.3.6.1. Small p y k n o m e t e r m e t h o d . . . . . . . . . . . . . . . . . . 233
9.3.6.2. M e t h o d s for clays containing coarse particles . . . . . . . . . . . 233
9.3.7. Particle size . . . . . . . . . . . . . . . . . . . . . . . . . . . 233
9.3.7.1. H y d r o m e t e r test . . . . . . . . . . . . . . . . . . . . . . 234
9.3.8. Clay suction . . . . . . . . . . . . . . . . . . . . . . . . . . . 234
xiv CONTENTS

9.4. C h e m i c a l tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235

9.5. C o m p a c t i o n related tests . . . . . . . . . . . . . . . . . . . . . . . . . . 236
9.5.1. C o m p a c t i o n tests (moisture c o n t e n t - - d e n s i t y relationship) . . . . . . . . . . 236
9.5.1.1. B.S. 'light c o m p a c t i o n ' test . . . . . . . . . . . . . . . . . 239
9.5.1.2. B.S. ' h e a v y c o m p a c t i o n ' test . . . . . . . . . . . . . . . . . 239
9.5.1.3. C o m p a c t i o n in C B R m o u l d . . . . . . . . . . . . . . . . . 240
9.5.2. Moisture condition value . . . . . . . . . . . . . . . . . . . . . . . 240
9.5.3. California bearing ratio . . . . . . . . . . . . . . . . . . . . . . . 242
9.6. Dispersibility and durability tests . . . . . . . . . . . . . . . . . . . . . . . 242
9.6.1. Pinhole m e t h o d . . . . . . . . . . . . . . . . . . . . . . . . . . 243
9.6.2. Crumb and cylinder tests . . . . . . . . . . . . . . . . . . . . . . 243
9.6.3. Dispersion m e t h o d . . . . . . . . . . . . . . . . . . . . . . . . . 243
9.7. Consolidation tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243
9.7.1. O n e - d i m e n s i o n a l consolidation in an o e d o m e t e r . . . . . . . . . . . . . . 245
9.7.1.1. Procedure . . . . . . . . . . . . . . . . . . . . . . . . 245
9.7.2. Constant, or controlled, rate o f strain o e d o m e t e r consolidation . . . . . . . . . 247
9.7.3. Consolidation in a hydraulic consolidation cell . . . . . . . . . . . . . . 249
9.7.3.1. Test procedures . . . . . . . . . . . . . . . . . . . . . . 252
9.7.4. Isotropic consolidation in a triaxial cell . . . . . . . . . . . . . . . . . 253
9.7.4.1. E q u i p m e n t and test procedure . . . . . . . . . . . . . . . . 253
9.7.5. Continuous-loading consolidation tests . . . . . . . . . . . . . . . . . 254
9.7.5.1. Constant rate o f loading . . . . . . . . . . . . . . . . . . . 254
9.7.5.2. Constant pore pressure gradient . . . . . . . . . . . . . . . . 254
9.7.5.3. Constant pressure ratio . . . . . . . . . . . . . . . . . . . 255
9.7.5.4. Consolidation with restricted flow . . . . . . . . . . . . . . . 255
9.7.5.5. B a c k pressure control . . . . . . . . . . . . . . . . . . . . 255
9.8. Permeability tests . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 255
9.8.1. Falling head test . . . . . . . . . . . . . . . . . . . . . . . . . . 255
9.8.2. Permeability in a hydraulic consolidation cell . . . . . . . . . . . . . . . 256
9.8.2.1. Scope . . . . . . . . . . . . . . . . . . . . . . . . . . 256
9.8.2.2. Procedure and calculations . . . . . . . . . . . . . . . . . . 257
9.8.3. Permeability in a triaxial cell . . . . . . . . . . . . . . . . . . . . . 257
9.8.3.1. Procedure and calculations . . . . . . . . . . . . . . . . . 257
9.9. Shear strength tests: total stress . . . . . . . . . . . . . . . . . . . . . . . . 258
9.9.1. V a n e shear test . . . . . . . . . . . . . . . . . . . . . . . . . . 258
9.9.2. U n c o n f i n e d c o m p r e s s i o n test . . . . . . . . . . . . . . . . . . . . . 259
9.9.2.1. Portable autographic apparatus . . . . . . . . . . . . . . . . 259
9.9.2.2. L o a d frame . . . . . . . . . . . . . . . . . . . . . . . . 259
9.9.3. U n d r a i n e d triaxial c o m p r e s s i o n test . . . . . . . . . . . . . . . . . . . 259
9.9.4. Direct shear test . . . . . . . . . . . . . . . . . . . . . . . . . . 260
9.9.4.1. Consolidation stage . . . . . . . . . . . . . . . . . . . . 261
9.9.4.2. Shearing stage . . . . . . . . . . . . . . . . . . . . . . 261
9.9.5. Direct shear test for residual strength . . . . . . . . . . . . . . . . . . 262
9.9.6. Ring shear test for residual shear strength . . . . . . . . . . . . . . . . 262
9.10. Effective stress shear strength tests . . . . . . . . . . . . . . . . . . . . . . 263
9.10.1. Principles . . . . . . . . . . . . . . . . . . . . . . . . . . . . 264
9.10.2. Samples and e q u i p m e n t . . . . . . . . . . . . . . . . . . . . . . . 264
9.10.3. Saturation and consolidation stages . . . . . . . . . . . . . . . . . . . 265
9.10.4. Consolidated u n d r a i n e d c o m p r e s s i o n (CU) test . . . . . . . . . . . . . . 266
9.10.5. Consolidated drained c o m p r e s s i o n (CD) test . . . . . . . . . . . . . . . 267
 CON I E N T S XV

9.11. ' A d v a n c e d ' tests 268

9.11.1. Measuring devices . . . . . . . . . . . . . . . . . . . . . . . . . 27C
9.11.2. Stress path testing . . . . . . . . . . . . . . . . . . . . . . . . . 27C
9.11.3. B-bar test . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271
9.11.4. Other ' a d v a n c e d ' test procedures . . . . . . . . . . . . . . . . . . . 271
9.11.4.1. Initial effective stress . . . . . . . . . . . . . . . . . . . 272
9.11.4.2. Triaxial extension . . . . . . . . . . . . . . . . . . . . . 272
9.11.4.3. Stress ratio Ko . . . . . . . . . . . . . . . . . . . . . . 272
9.11.4.4. Anisotropic consolidation . . . . . . . . . . . . . . . . . . 272
9.11.4.5. Resonant c o l u m n . . . . . . . . . . . . . . . . . . . . . 272
9.11.4.6. Simple shear . . . . . . . . . . . . . . . . . . . . . . . 273
9.11.4.7. Cyclic triaxial . . . . . . . . . . . . . . . . . . . . . . 273
References 273

10. Earthworks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 275

10.1. Types o f e n g i n e e r e d fill . . . . . . . . . . . . . . . . . . . . . . . . . . . 276
10.1.1. Infrastructure e m b a n k m e n t s . . . . . . . . . . . . . . . . . . . . . . 276
10.1.2. Earth dams . . . . . . . . . . . . . . . . . . . . . . . . . . . . 279
10.1.3. E n v i r o n m e n t a l mitigation structures . . . . . . . . . . . . . . . . . . 284
10.1.4. Substructure fills . . . . . . . . . . . . . . . . . . . . . . . . . . 285
10.1.5. Quarry tips . . . . . . . . . . . . . . . . . . . . . . . . . . . . 285
10.2. Planning requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . 286
10.2.1. Planning considerations . . . . . . . . . . . . . . . . . . . . . . . 286
10.2.2. E n v i r o n m e n t a l and safety considerations . . . . . . . . . . . . . . . . 287
10.2.2.1. Visual intrusion . . . . . . . . . . . . . . . . . . . . . . 287
10.2.2.2. Stability o f slopes . . . . . . . . . . . . . . . . . . . . . 287
10.2.2.3. Waste disposal . . . . . . . . . . . . . . . . . . . . . . 287
10.2.2.4. V e h i c u l a r traffic . . . . . . . . . . . . . . . . . . . . . . 288
10.2.2.5. Noise . . . . . . . . . . . . . . . . . . . . . . . . . . 288
10.2.2.6. Dust . . . . . . . . . . . . . . . . . . . . . . . . . . 288
10.2.2.7. G r o u n d and surface waters . . . . . . . . . . . . . . . . . . 288
10.2.2.8. Flora and fauna . . . . . . . . . . . . . . . . . . . . . . 289
10.2.2.9. A m e n i t y . . . . . . . . . . . . . . . . . . . . . . . . . 289
10.2.2.10. A r c h a e o l o g y . . . . . . . . . . . . . . . . . . . . . . . 289
10.2.2.11. Restoration . . . . . . . . . . . . . . . . . . . . . . . . 289
10.2.3. Parties to the d e v e l o p m e n t . . . . . . . . . . . . . . . . . . . . . . 290
10.3. Material characteristics o f n e w fills . . . . . . . . . . . . . . . . . . . . . . 290
10.3.1. E a r t h m o v i n g in clay . . . . . . . . . . . . . . . . . . . . . . . . 290
10.3.2. Fill characteristics . . . . . . . . . . . . . . . . . . . . . . . . . 291
10.3.3. D e s i g n . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293
10.3.3.1. Shear strength . . . . . . . . . . . . . . . . . . . . . . . 293
10.3.3.2. C o m p a c t i o n . . . . . . . . . . . . . . . . . . . . . . . 293
10.3.3.3. End-product c o m p a c t i o n specifications . . . . . . . . . . . . . 293
10.3.3.4. M e t h o d c o m p a c t i o n specifications . . . . . . . . . . . . . . . 294
10.3.3.5. Slope stability . . . . . . . . . . . . . . . . . . . . . . 294
10.3.3.6. Setting moisture content limits for the construction o f fills . . . . . . 294
10.3.3.7. Sub grade properties for infrastructure e m b a n k m e n t s and substructure
fills . . . . . . . . . . . . . . . . . . . . . . . . . . 295
10.3.3.8. M a k i n g m a x i m u m use o f clay in construction . . . . . . . . . . . 296
10.3.4. Deleterious chemical effects . . . . . . . . . . . . . . . . . . . . . 996
xvi CONTENTS

10.4. L o n g - t e r m material characteristics and maintenance . . . . . . . . . . . . . . . . 297

10.4.1. C l a y degradation . . . . . . . . . . . . . . . . . . . . . . . . . 297
10.4.2. Types and effect o f maintenance . . . . . . . . . . . . . . . . . . . . 299
10.4.3. L o n g - t e r m requirements o f clay fills . . . . . . . . . . . . . . . . . . 299
10.4.3.1. Operational safety . . . . . . . . . . . . . . . . . . . . . ' 300
10.4.3.2. S y n e r g y w i t h other assets . . . . . . . . . . . . . . . . . . 300
10.4.3.3. Costs o f repair . . . . . . . . . . . . . . . . . . . . . . 300
10.4.3.4. Disruption and customer satisfaction . . . . . . . . . . . . . . 300
10.4.3.5. Costs o f failure . . . . . . . . . . . . . . . . . . . . . . 300
10.4.4 Remedial and preventative measures . . . . . . . . . . . . . . . . . . 301
10.5. I m p r o v e d clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 301
10.5.1. Mechanical i m p r o v e m e n t . . . . . . . . . . . . . . . . . . . . . . 302
10.5.2. C h e m i c a l treatment . . . . . . . . . . . . . . . . . . . . . . . . . 304
10.5.2.1. Lime . . . . . . . . . . . . . . . . . . . . . . . . . . 304
10.5.2.2. Lime i m p r o v e m e n t . . . . . . . . . . . . . . . . . . . . . 305
10.5.2.3. Lime stabilization . . . . . . . . . . . . . . . . . . . . . 305
10.5.2.4. Lime and cement stabilization . . . . . . . . . . . . . . . . 306
10.5.2.5. Stabilizing material for use in h i g h w a y s and substructure capping . . . 306
10.5.2.6. Treating materials for use in bulk fill . . . . . . . . . . . . . . 306
10.5.2.7. Materials characteristics . . . . . . . . . . . . . . . . . . . 307
10.5.2.8. Lime piles and lime-stabilized clay columns . . . . . . . . . . . 307
10.5.2.9. Safety and the environment . . . . . . . . . . . . . . . . . 307
10.6. Case histories . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 308
10.6.1. A34 N e w b u r y Bypass . . . . . . . . . . . . . . . . . . . . . . . . 308
10.6.2. Orville D a m . . . . . . . . . . . . . . . . . . . . . . . . . . . 310
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 311

11. E a r t h m o v i n g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 315
11.1. E a r t h m o v i n g practice . . . . . . . . . . . . . . . . . . . . . . . . . . . 315
11.1.1. Preparation works for earthworks in construction and for mineral deposits . . . . 316
11.1.2. Bulk earthmoving for construction . . . . . . . . . . . . . . . . . . . 317
11.1.3. Bulk earthmoving in quarries and other mineral workings . . . . . . . . . . 317
11.2. M e t h o d s o f earthmoving . . . . . . . . . . . . . . . . . . . . . . . . . . 320
11.2.1. M a n u a l work . . . . . . . . . . . . . . . . . . . . . . . . . . . 32C
11.2.2. Plant that can only excavate . . . . . . . . . . . . . . . . . . . . . 32C
11.2.3. Plant that can excavate and load materials . . . . . . . . . . . . . . . . 321
11.2.4. Plant that hauls and deposits . . . . . . . . . . . . . . . . . . . . . 322
11.2.5. Plant that can excavate, load, haul and deposit materials . . . . . . . . . . . 323
11.2.6. Plant that can compact materials . . . . . . . . . . . . . . . . . . . . 324
11.2.7. Specialist earthworks plant . . . . . . . . . . . . . . . . . . . . . . 326
11.2.8. Plant used in excavation and spoil removal in tunnelling . . . . . . . . . . . 326
11.2.9. Plant teams . . . . . . . . . . . . . . . . . . . . . . . . . . . 327
11.3. Selection o f earthmoving and compaction plant . . . . . . . . . . . . . . . . . 328
11.3.1. Material factors . . . . . . . . . . . . . . . . . . . . . . . . . . 329
11.3.2. Quantities . . . . . . . . . . . . . . . . . . . . . . . . . . . . 334
11.3.3. Spatial factors . . . . . . . . . . . . . . . . . . . . . . . . . . . 335
11.3.4. Surface water and groundwater . . . . . . . . . . . . . . . . . . . . 335
11.3.5. Plant and other f~ctors . . . . . . . . . . . . . . . . . . . . . . . 336
 CONTENTS xvii

11.4. The control o f earthworks . . . . . . . . . . . . . . . . . . . . . . . 336

11.4.1. Acceptability criteria for earthworks materials . . . . . . . . . . . . . . 336
11.4.2. Control during earthmoving . . . . . . . . . . . . . . . . . . . . . 337
11.4.3. Behaviour o f clays during earthmoving . . . . . . . . . . . . . . . . . 339
11.5. Examples o f earthmoving schemes . . . . . . . . . . . . . . . . . . . . . . 340
11.5.1. C l a y and sand quarry . . . . . . . . . . . . . . . . . . . . . . . . 340
11.5.2. L e i g h t o n - L i n s l a d e Bypass . . . . . . . . . . . . . . . . . . . . . . 340
11.6. Safety on earthmoving sites . . . . . . . . . . . . . . . . . . . . . . . . . 343
11.6.1. Safety o f earthworks . . . . . . . . . . . . . . . . . . . . . . . . 343
11.6.2. Safely related to earthmoving plant . . . . . . . . . . . . . . . . . . 343
References 344

12. Specialized applications . . . . . . . . . . . . . . . . . . . . . . . . . . . . 347

12.1. Principles . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 347
12.1.1. Scope o f chapter . . . . . . . . . . . . . . . . . . . . . . . . . . 347
12.1.2. Bentonite . . . . . . . . . . . . . . . . . . . . . . . . . . . . 347
12.1.3. Interaction o f slurries and natural ground . . . . . . . . . . . . . . . . 349
12.1.4. Test procedures . . . . . . . . . . . . . . . . . . . . . . . . . . 350
12.2. C l a y slurries . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 352
12.2.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . 352
12.2.2. Applications . . . . . . . . . . . . . . . . . . . . . . . . . . . 352
12.2.2.1. D i a p h r a g m walls and piles . . . . . . . . . . . . . . . . . . 352
12.2.2.2. Slurry tunnelling . . . . . . . . . . . . . . . . . . . . . 355
12.2.2.3. Pipe j a c k i n g and microtunnelling; shaft sinking . . . . . . . . . . 358
12.2.2.4. Soil conditioning in earth-pressure-balance tunnelling . . . . . . . 358
12.2.2.5. Vertical and horizontal (directional) drilling . . . . . . . . . . . 358
12.2.3. Re-use and disposal o f slurries . . . . . . . . . . . . . . . . . . . . 361
12.3. Plastic clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 362
12.3.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . 362
12.3.2. Waste disposal facilities . . . . . . . . . . . . . . . . . . . . . . . 362
12.3.2.1. Landfill liners and covers . . . . . . . . . . . . . . . . . . 362
12.3.2.2. Geosynthetic clay liners . . . . . . . . . . . . . . . . . . 367
12.3.3. Radioactive waste storage and disposal . . . . . . . . . . . . . . . . . 368
12.3.3.1. Introduction and b a c k g r o u n d . . . . . . . . . . . . . . . . . 368
12.3.3.2. Functions and materials for disposal vaults . . . . . . . . . . . . 369
12.3.3.3. Buffer materials . . . . . . . . . . . . . . . . . . . . . . 370
12.3.3.4. R o o m and tunnel backfills . . . . . . . . . . . . . . . . . . 372
12.3.3.5. Bulkheads, plugs and grout . . . . . . . . . . . . . . . . . 372
12.3.3.6. Shaft seals . . . . . . . . . . . . . . . . . . . . . . . . 373
12.3.3.7. Exploration borehole completions . . . . . . . . . . . . . . . 373
12.3.4. Bentonite-cement and grouts . . . . . . . . . . . . . . . . . . . . . 373
12.3.4.1. Bentonite-cement soft piles and c u t - o f f w a l l s . . . . . . . . . . . 373
12.3.4.2. Grouting . . . . . . . . . . . . . . . . . . . . . . . . 375
12.3.4.3. Treatment o f contained land . . . . . . . . . . . . . . . . . 377
12.3.5. Puddle clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . 377
12.3.5.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . 377
12.3.5.2. Puddle clay and the ' P e n n i n e s ' e m b a n k m e n t dam . . . . . . . . . 377
12.3.5.3. Puddle clay: nature and characteristics . . . . . . . . . . . . . 378
12.3.5.4. Puddle clay cores: construction practice and specification . . . . . . 37 C
12.3.5.5. Puddle clay in cores: characteristics . . . . . . . . . . . . . . 37 c
XVnl CONTENTS

12.3.5.6. Consistency . . . . . . . . . . . . . . . . . . . . . . . 379

12.3.5.7. Shear strength . . . . . . . . . . . . . . . . . . . . . . 380
12.3.5.8. In situ permeability . . . . . . . . . . . . . . . . . . . . 38C
12.3.5.9. Compressibility . . . . . . . . . . . . . . . . . . . . . . 381
12.3.5.10. Erodibility and dispersivity . . . . . . . . . . . . . . . . . 381
12.3.5.11. Puddle clay service performance . . . . . . . . . . . . . . . 381
12.3.6. Other applications . . . . . . . . . . . . . . . . . . . . . . . . . 381
12.3.6.1. Sealing o f lagoons, ponds and reservoirs . . . . . . . . . . . . 381
12.3.6.2. T a n k i n g systems . . . . . . . . . . . . . . . . . . . . . 381
12.3.6.3. Borehole sealing . . . . . . . . . . . . . . . . . . . . . 381
A p p e n d i x 12.1 Bentonite slurry for diaphragm walling . . . . . . . . . . . . . . . . . 382
A p p e n d i x 12.2 British W a t e r w a y s : Technical S e r v i c e s - - S t a n d a r d Specification for Puddle Clay. . 382
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 383

13. E a r t h e n architecture . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 387

13.1. The use o f earth as a global building material . . . . . . . . . . . . . . . . . . 387
13.2. Applications o f earth in building construction . . . . . . . . . . . . . . . . . . 389
13.3. Characterization o f earth for building . . . . . . . . . . . . . . . . . . . . . 391
13.4. The performance o f earth in building . . . . . . . . . . . . . . . . . . . . . 392
13.4.1. Structural performance . . . . . . . . . . . . . . . . . . . . . . . 392
13.4.2. Durability . . . . . . . . . . . . . . . . . . . . . . . . . . . . 392
13.4.3. Thermal performance . . . . . . . . . . . . . . . . . . . . . . . . 392
13.4.4. Fire resistance . . . . . . . . . . . . . . . . . . . . . . . . . . . 392
13.5. Engineered earth . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 392
13.6. Specification and practice . . . . . . . . . . . . . . . . . . . . . . . . . . 393
13.7. The tradition o f earth building in the U K . . . . . . . . . . . . . . . . . . . . 393
13.8. N e w earth building in the U K . . . . . . . . . . . . . . . . . . . . . . . . 396
13.9. Advantages o f earth as a contemporary building material . . . . . . . . . . . . . . 398
13.10. Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 399
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 399

14. Brick and other ceramic products . . . . . . . . . . . . . . . . . . . . . . . . . 401

14.1. Historical utilization o f clay in structural and fine ceramics . . . . . . . . . . . . . 401
14.2. Ceramic product range . . . . . . . . . . . . . . . . . . . . . . . . . . . 402
14.2.1. Ceramic bodies . . . . . . . . . . . . . . . . . . . . . . . . . . 402
14.3. C l a y minerals in ceramic products . . . . . . . . . . . . . . . . . . . . . . . 404
14.3.1. Kaolinite . . . . . . . . . . . . . . . . . . . . . . . . . . . . 404
14.3.2. Illite . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 405
14.3.3. Halloysite . . . . . . . . . . . . . . . . . . . . . . . . . . . . 405
14.3.4. Montmorillonite (smectite) . . . . . . . . . . . . . . . . . . . . . . 405
14.3.5. Chorite . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 405
14.4. Structural or h e a v y clay products . . . . . . . . . . . . . . . . . . . . . . . 405
14.4.1. Bricks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 406
14.4.2. Pipes . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 406
14.4.3. Tiles and other applications . . . . . . . . . . . . . . . . . . . . . 406
14.5 Clays utilize in structural ceramic products . . . . . . . . . . . . . . . . . . . 407
14.5.1. C o m m o n clay and shale . . . . . . . . . . . . . . . . . . . . . . . 407
14.5.2. Fireclay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 407
14.5.3. Ball clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 408
 CONTENTS xix

14.6. Structural or clay extraction, processing and manufacture . . . . . . . . . . . . . . 408

14.6.1. Extraction . . . . . . . . . . . . . . . . . . . . . . . . . . . . 408
14.6.2. Pre-treatment and preparation . . . . . . . . . . . . . . . . . . . . . 408
14.6.3. F o r m i n g . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 409
14.6.4. Drying . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41C
14.6.5. Firing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41C
14.7. E n g i n e e r i n g properties o f bricks . . . . . . . . . . . . . . . . . . . . . . . 411
14.7.1. Porosity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 411
14.7.2. Strength . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 412
14.8. Fine ceramic or w h i t e w a r e products . . . . . . . . . . . . . . . . . . . . . . 412
14.8.1. Wall tiles . . . . . . . . . . . . . . . . . . . . . . . . . . . . 412
14.8.2. Floor tiles . . . . . . . . . . . . . . . . . . . . . . . . . . . . 412
14.8.3. Tableware and electrical porcelain . . . . . . . . . . . . . . . . . . . 413
14.8.4. Sanitaryware . . . . . . . . . . . . . . . . . . . . . . . . . . . 413
14.9. Clay raw materials for fine ceramic products . . . . . . . . . . . . . . . . . . . 413
14.9.1. Ball clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 413
14.9.2. Kaolin (china clay) . . . . . . . . . . . . . . . . . . . . . . . . . 417
14.9.3. Flint clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 418
14.10. Fine ceramic clay production and refining . . . . . . . . . . . . . . . . . . . . 418
14.10.1. Ball clay . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 418
14.10.2. Kaolin . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 420
14.11. Fine ceramic manufacturing processes . . . . . . . . . . . . . . . . . . . . . 422
14.11.1. Ceramic b o d y preparation . . . . . . . . . . . . . . . . . . . . . . 422
14.11.2. Ceramic article f o r m i n g . . . . . . . . . . . . . . . . . . . . . . . 422
14.11.3. Drying and firing . . . . . . . . . . . . . . . . . . . . . . . . . 423
14.12. Future trends in ceramics . . . . . . . . . . . . . . . . . . . . . . . . . . 424
14.12.1. General trends . . . . . . . . . . . . . . . . . . . . . . . . . . 424
14.12.2. Processes and materials . . . . . . . . . . . . . . . . . . . . . . . 424
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 425

15. C e m e n t and related products . . . . . . . . . . . . . . . . . . . . . . . . . . . 427

15.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 427
15.1.1. W h a t is c e m e n t ? . . . . . . . . . . . . . . . . . . . . . . . . . . 427
15.1.2. History and d e v e l o p m e n t o f m o d e r n c e m e n t . . . . . . . . . . . . . . . 428
15.2. Portland c e m e n t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 429
15.2.1. Types o f clay u s e d in the manufacture o f Portland c e m e n t . . . . . . . . . . 429
15.2.2. Role o f clays in the manufacture o f Portland c e m e n t . . . . . . . . . . . . 43C
15.2.3. C o m p o s i t i o n and hydration reactions o f Portland c e m e n t . . . . . . . . . . 431
15.2.4. W h i t e Portland c e m e n t . . . . . . . . . . . . . . . . . . . . . . . 432
15.2.5. P o r t l a n d - P o z z o l a n a c e m e n t . . . . . . . . . . . . . . . . . . . . . . 433
15.2.6. Calcined clays as Portland c e m e n t additions . . . . . . . . . . . . . . . 434
15.3. L i m e and hydraulic lime c e m e n t s . . . . . . . . . . . . . . . . . . . . . . . 435
15.3.1. Natural hydraulic lime c e m e n t s . . . . . . . . . . . . . . . . . . . . 435
15.3.2. L i m e mortars . . . . . . . . . . . . . . . . . . . . . . . . . . . 435
15.4. Other types o f c e m e n t . . . . . . . . . . . . . . . . . . . . . . . . . . . 436
15.4.1. 'Inorganic p o l y m e r c e m e n t s ' or chemical c e m e n t s . . . . . . . . . . . . . 436
15.4.1.1. G e o p o l y m e r c e m e n t . . . . . . . . . . . . . . . . . . . . 436
15.4.1.2. P y r a m e n t concrete . . . . . . . . . . . . . . . . . . . . . 436
15.4.1.3. Tectoaluminate c e m e n t . . . . . . . . . . . . . . . . . . . 437
15.4.1.4. Earth ceramics and calci~m silicate briO . . . . . . . . . . . . . . . 437
XX C O N ' I E N I'S

15.4.2. Clays in calcium aluminate cements . . . . . . . . . . . . . . . . . . 437

15.4.3. G y p s u m - P o r t l a n d - p o z z o l a n a cements . . . . . . . . . . . . . . . . . 438
15.5. Use o f clay in specialist applications . . . . . . . . . . . . . . . . . . . . . . 439
15.5.1. Lightweight aggregates . . . . . . . . . . . . . . . . . . . . . . . 439
15.5.2. R h e o l o g y control . . . . . . . . . . . . . . . . . . . . . . . . . 439
15.5.2.1. Ready mixed concrete . . . . . . . . . . . . . . . . . . . 439
15.5.2.2. Cement grouts . . . . . . . . . . . . . . . . . . . . . . 439
15.5.3. Immobilization o f toxic waste . . . . . . . . . . . . . . . . . . . . . 440
15.6. Recycled clays in concrete . . . . . . . . . . . . . . . . . . . . . . . . . 441
15.6.1. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . 441
15.6.2. Ash from municipal solid waste (MSW) . . . . . . . . . . . . . . . . . 441
15.6.3. Ash from industrial processes . . . . . . . . . . . . . . . . . . . . . 441
15.6.4. Waste bricks . . . . . . . . . . . . . . . . . . . . . . . . . . . 442
15.6.5. Waste cracking catalyst . . . . . . . . . . . . . . . . . . . . . . . 443
15.6.6. Building rubble as recycled aggregate . . . . . . . . . . . . . . . . . 443
15.6.7. Dredging spoils . . . . . . . . . . . . . . . . . . . . . . . . . . 444
15.6.8. Other waste materials . . . . . . . . . . . . . . . . . . . . . . . . 444
15.7. Deleterious effects o f clays in concrete . . . . . . . . . . . . . . . . . . . . . 444
References 445

A p p e n d i x A Mineralogical and chemical data . . . . . . . . . . . . . . . . . . . . . . 449

A p p e n d i x B Properties data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 461

A p p e n d i x C Some Wo r l d, E u r o p e a n and U K clay deposits . . . . . . . . . . . . . . . . . 475

A p p e n d i x D Test methods for clay materials . . . . . . . . . . . . . . . . . . . . . . . 481

Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 485

Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 513

CAUTION
Use of Formation-specific Data for Clay Deposits

In this Working Party report, various example data and 'typical values' of properties are included for particu-
lar types of material and named geological formations. These are given strictly for guidance purposes. As the
performance of clay materials and clay deposits is likely to be highly variable and dependent not only on
material properties, but on mass-specific and site- or source-specific conditions, great care must be taken in
using these values. Assessments of particular clay materials should be based on property data obtained for
representative samples from actual sites or sources and must not rely on the example data or 'typical values'
given in this report.
 Foreword

Lord Oxburgh of Liverpool, Chairman of Shell plc and former President of the Geological Society (2000-2002).

Clay is one of the most abundant constituents of the Earth's surface. It covers most of the floors of the oceans and is
common on land. Since ancient times it has provided human beings with a very useful material from which they could
fashion objects in an astonishing range of sizes and with an astonishing range of properties, from fine brooches to great
dams, from paper to building bricks, not to mention its medicinal uses.
Yet for all its value and importance, clay has been an elusive material to understand. The reason, of course, is the
very nature of clay--the fact that it is composed of grains too fine for the eye to see and only thousandths ofa millimetre
across. Furthermore, it has few characteristics to excite the imagination of traditional field geologists, except that it was
the medium in which fossils could often be near-perfectly preserved.
It had been known for many centuries that there were different kinds of clay. Some were suitable for cement making,
some for fine china, some for making bricks, etc. Although the optical microscope provided the first clues to the fine
structure of clays, it was the development of the electron microscope and X-ray structural methods that revealed the
fine details and secrets of the differences between different clays, and between the different clay minerals.
It is the interaction of the minute clay grains with water that gives clays some of their unique properties both in bulk
and in detail. Water can lie along the boundaries of the grains in clays and its concentration can profoundly affect the
bulk physical properties - from a creamy slurry to the heavy digging ground, unbeloved of gardeners, to the geologist's
solid mudstone. Water molecules can also lie loosely within the structures of some of the clay minerals or they can be
an integral and tightly bound part of the mineral structure. Paradoxically, perhaps, these properties mean that in bulk,
clays are among the least permeable of rocks; their very low porosity makes them excellent containment for aquifers or
hydrocarbon reservoirs.
The combination of fine grain size and water has another unique and important consequence--chemical reactivity.
Water along grain boundaries provides an excellent medium for the diffusion of chemical species on the local scale, and
the fine grain size means that the surface area/volume ratio is very favourable to chemical reactionss. These reactions
may take place at ambient temperatures such as in the setting of cement, or at high temperatures in the potter's kiln, and
result in a profound change in mineralogy and in bulk physical properties.
I hope that even the most sceptical readers will be convinced that clays are both important and interesting and that at
the very least they should dip into this volume. If they do, I have no doubt that they will be amply rewarded. To my
mind the book succeeds in meeting most, if not all, of the requirements of a professional reference work with a wide
range of information important to clay professionals and to the civil engineer, general geologist, or for that matter
archaeologists, alike. Even those with a lay interest in clays and their historical and practical importance will find a
great deal to interest them.
The Geological Society is doing a great service by publishing this unique volume that represents a number of years
of hard work on the part of the Clay Working Party of the Engineering Group. Each of the fifteen chapters was written
by a small team of experts in their fields and the Working Party has brought together information from an enormous
range and diversity of sources, reinforced and collated in the light of the experience of professionals in many areas. It
will become a standard reference for those whose work involves dealing with clay and a source of pleasure and infor-
mation for those who choose to dip into it at random. Both the Society and the Working Party are to be congratulated.

Ron Oxburgh
29 August 2004
 Editors' note

During a distinguished career over more than 50 years, the Chairman of the Clay Working Party, Professor Peter G
Fookes, F.R.Eng., has been a tireless supporter of the Engineering Group of the Geological Society, including the
initiation and chairmanship of many working parties that have generated influential, often milestone, reports. This
important work has included the unique trilogy of major reports on geological materials in construction of which this
current volume forms the concluding part. Peter has said that, in retirement, he should make way for others to undertake
the chairmanship of any future working parties. The editors of this valedictory report therefore wish to record their
appreciation, on behalf of engineering geologists throughout the profession, for the monumental contribution to their
discipline made by Peter Fookes, both personally and also by encouraging or helping others. Peter has always explained
that 'his work is his hobby', so it must be hoped that his wisdom and experience will continue to be available, as a
consultant and teacher, for many years to come, even as he enjoys a well-earned retirement.

The photograph was taken by Ken Head somewhere in the Salt Range in West Pakistan in March 1965, when a
young Peter Fookes (looking at the camera) had characteristically organised a weekend geological field trip.
 Members of the Working V'arty
Professor Peter G. Fookes Chairman--Consultant, Winchester SC & 1998-2004
Dr Ian Sims Secretary & Editor (2)--STATS Limited, St Albans SC & 1998-2004
Mr John H. Charman Consultant, Dorchester SC & 1998-2004
Dr John C. Cripps Editor (3)--University of Sheffield 1998-2004
Mr Kenneth H. Head Retired soil engineers, Cobham (Surrey) 2003-2004
Dr Stephen Hillier Macaulay Institute, Aberdeen 1999-2004
Mr Peter Hobbs British Geological Survey, Nottingham 1999-2004
Mr Philip C. Homer Consultant, Luton SC & 1998-2004
Dr Thomas R. Jones ImerysMinerals Limited, formerly ECC International plc (retired) 1999-2004
Mr John R. Masters Geolabs Limited, Warlord 1999-2003
Dr George W. E. Milligan Geotechnical Consulting Group, London SC & 1998-2004
Mr David R. Norbury CL Associates, Wokingham 1999-2004
Dr John Perry Mott MacDonald Group, Croydon SC & 1998-2004
Dr Alan Poole University of London, Queen Mary College (retired) 2003-2004
Dr George M. Reeves Editor (1)--University of Newcastle (now at the Decommissioning & Environmental
Remediation Centre, UHI Millennium Institute, Thurso) 1998-2004
Dr Harry F. Shaw University of London, Imperial College (Department of Earth Science & Engineering)
SC & 1998-2004
Dr Michael R. Smith Advisor--The Institute of Quarrying, Nottingham SC & 1998-2000
Ms Linda Watson University of Plymouth (School of Architecture) 1999-2004
Dr Graham West Geological Society Engineering Group Representative--Retired engineering geologist,
Wokingham SC & 1998-2004
Mr Gordon J. Witte WBB Minerals Limited, Sandbach SC & 1998-2004
The Working Party was inauguratedin 1998 and completedits work in 2004.
SC, Served on Steering Committee, 1998

Acknowledgements
The Working Party has been most grateful to receive considerable help from numerous individuals, organizations and
companies who have contributed in various ways by providing advice, information and illustrations or by acting as
:eviewers for particular chapters. We give thanks to all these people and organisations. In addition, with apologies to
anyone who might have been inadvertently omitted, those to whom specific appreciation is due include the following:
Prof. John M. Adams, Ms Ruth E. Allington (Geoffrey Walton Practice), Association of Geotechnical &
Geoenviroumental Specialists (AGS: Ms Dianne Jennings), Prof. John H. Atkinson (City University, London), Dr
Maxwell E. Barton (University of Southampton), Prof. Frederick G. Bell, Mr Andrew Bloodworth (British Geological
Survey), Mr Michael Cambridge (Knight Piesold), Dr Andrew Charles (Building Research Establishment, retired), Mr
Rodney Chartres (Bullen Consultants), Mr Adam Czarnecki (Cory Environmental (Central) Limited), Dr Maurice A.
Czerewko (University of Sheffield), Mr William Darbyshire (Environment Agency), Mr Anthony B. Di Stefano
(Knight Piesold), Dr Mark Dyer (University of Durham), Dr Eric Farrell (University of Dublin, Trinity College),
Mr John Ferguson (Balfour Beatty Limited), Mrs Margaret Ford (University of Plymouth), Dr David A. Greenwood,
Dr John Greenwood (Nottingham Trent University), Dr W. J. Rex Harries, Mr Arthur Harrisson (Rugby Cement plc),
Mr Ian Higginbottom (Wimpey Laboratories, retired), Mr Graham Holland (British Waterways), Dr Jennifer Huggett
(Petroclays), Prof. Richard Jardine (University of London, Imperial College), Prof. Stephan A. Jefferis (University of
Surrey), Dr Ian Jefferson (Nottingham Trent University), Mr G. Peter Keeton (Soil Mechanics Limited), Miss Sign
Kitchen (STATS Limited), Prof. David Manning (University of Newcastle), Dr Richard J Merriman (British Geologi-
cal Survey), Mr A. Iain Moffat (University of Newcastle), Dr Dewey Moore (University of New Mexico, USA), Mr
Timothy Murdoch (Allott & Lomax), Dr Paul Nathanail (University of Nottingham), Dr Philip J. Nixon (Building
Research Establishment Limited), Dr Myriam Olivier, Dr Kevin Privett (SRK Consulting), Mr Nicholas Ramsey
(Fugro Limited), Mr David Richardson (The Banks Group), Mr Peter Shotton (Cementation Foundations Skanska),
Dr Alan Smallwood (W. S. Atkins Consultants Limited), Dr Andrew S. Smith (Hanson Brick Limited), Dr Douglas
I. Stewart (University of Leeds), Mr Michael G. Sumbler (Rockvision Consulting), Dr Mark Tyrer (University of
London, Imperial College), Dr Peter N. W. Verhoef (University of Delft, Netherlands), Dr Paul Wignall (University of
Leeds), Dr J. Michael Woodfine.
The very significant contribution made by private individuals and employers whose staff were afforded the time and
permission to be members of the Working Party cannot be overstated and we offer grateful thanks to those companies
and in,'titution,'.
 Preface

This book is about clay, as seen through the eyes of construction and production engineers and geoscientists. So, what
is clay and why do we need a new book on it? The answer to the first question cannot be given here in the Preface, since
the word has different meanings, depending on the situation and context, and its occurrence and uses are ubiquitous
and diverse. Definitions of clay, from various viewpoints are given in Chapter 1, although these are by no means
exhaustive, and further references for the interested reader are also to be found in that chapter.
In the following chapters, clay is generally used in the commonly understood sense of being a fine-grained, natural,
earthy material which, at certain moisture contents, displays plasticity. Where, within a chapter, usage differs from this
general meaning, the appropriate definition for the particular context is given.
This book, which is a Working Party Report of the Engineering Group of the Geological Society, considers most
aspects of clay, including its identification and evaluation; occurrence and distribution; extraction; various forms of
processing; use in man-made products; and engineering uses, for example in embankments, but excluding the engineer-
ing aspects of clay in situ. The latter topic was considered by the Engineering Group Committee to be such a large
subject that inclusion would have distorted the intention and thrust of the book. With so many applications in various
industries, it was considered a book was needed to present and explain, in a coherent format, the very wide range of
geological information about clay. In this way information known within one discipline can be disseminated to the
benefit of other applications.
The Report is an addition to the group of several important Working Party Reports and other documents published by
the Engineering Group in the past four decades or so, which focus, from a geological viewpoint, on the help that applied
geology can provide to practitioners in the diverse industries related to the subject matter. This particular Report is the
final part of a trilogy of such books on geological materials in construction:
9 Aggregates. First edition, 1985; second edition, 1993; third edition, 2001.
9 Stone: Building Stone, Rockfill and A rmourstone in Construction. First edition, 1999.

These first two members of the trilogy have proved most successful and it is hoped that Clay Materials used in
Construction will also prove to be so.
The membership of this Working Party, like its predecessors, was drawn widely from industrial, academic and
institutional concems. Every member of the Working Party worked long and hard and members gave freely of their
time or their employers' time, for which I am most grateful. Any credit should be attributed equally to every member of
the Working Party.
This book, also like its predecessors, is the combined work of the whole Working Party membership. Each chapter
was initially drafted by one or more members of the working party, combined with many day-long meetings. It was
subsequently edited and cross-checked by all the members as an iterative process and commented upon by correspond-
ing members. This book, like its predecessors, therefore carries the collective authority of the whole Working Party.
Appendices were handled in a similar way and particular effort was made to make the book as comprehensive as
possible and, again despite being drafted by a committee, to achieve reasonable continuity of style and uniformity in
technical level and mode of presentation.
I conclude with two personal sentiments. Firstly, a very warm and special thank you to Dr lan Sims who for the past
twenty-five years of the forty or so years I have been Chairman of various Working Parties, has been the Secretary. As
Secretary, he has done an absolutely superb job in the face of many difficulties, with consistently sound advice,
immaculate meeting minutes, endless correspondence and telephone calls, with virtually no complaint about any chore
with which he was saddled. It therefore gave me, and the Working Party, great pleasure to see that he was chosen to
receive the Engineering Group Award for 2003. Congratulations, lan.
My second is the dedication of this Working Party Report to the memory of Professor Sir Alec Skempton, F.R.S.,
F.R.Eng. I had the enormous privilege of working with him on the Mangla, Jari and Sukian Dams in West Pakistan in
the 1960s, when I was a young man on site and he was the visiting consultant. His visits were inspirational and I learnt
much from him that has stood me in good stead for the rest of my career. I came to regard him with tremendous respect
and awe. These views I still hold today. 'Skem' worked in many engineering soils, even rock on occasion, but his
principal medium was clay. He was always more than willing to pass on his knowledge to others, and this book has
been written in the same spirit. The Working Party thus has no hesitation in dedicating our book to him. This has also
given me much pleasure.

Peter Fookes
Chairman of the Working Party

Winchester
May 2002 and 2004
 List of s y m b o l s and units

Below are listed units and symbols referred to in this book. Further symbols and explanation of those below are
presented in the relevant chapters.

Basic units
~ , g m , ram, m , distance Angstrom unit ( 10 - 10m), nanometre (10 - 9 m), microns (10 - 6 m), millimetre
km (10 -3 m), metre, kilometre (103 m)
m2 area square metres
s, min, h, a, Ma time second, minute, hour, year (annum), millenia (106 a)
gg, mg, g, kg, mass microgram (10-6 g), milligram (10-3 g ) , gram, kilogram (103 g), megagram (106 g),
Mg, T tonne (106 g)
g acceleration 9.81 m/s 2
due to
gravity
N, kN, MN, GN weight, force newton, kilonewton (103 N), meganewton (106 N), giganewton (109 N)
[1 N = 1 kg x g = 1 kg x 9.81 rn/s 2]
Pa, kPa, MPa, pressure; stress pascal, kilopascal, megapascal, gigapascal; newton, kilonewton,
GPa; N/m 2 meganewton and giganewton per square metre [ 1 Pa = 1 N/m 2]
k N / m 2 M N / m 2,
GN/m 2
m/s, km/h velocity metres per second, kilometres per hour
~ temperature degrees Celsius, centigrade
ml, m 3, M m 3 volume millilitres, cubic metres, mega cubic metres (103 m 3)
kW, MW power kilowatt, megawatt
thermal capacity

Soil characteristics
e voids ratio [e = volume of voids/volume of soil grains]
v specific volume [total volume of soil/volume of soil grains]
n % porosity [n = volume of voids/total volume of soil]
w % moisture content [mass of water x 100/mass of dry soil]
Wopt 0~ optimum moisture content
WL, Wp, Ws % liquid, plastic and shrinkage limits for soils
MCV moisture condition value
I, % plasticity index [Ip = wL - Wp]
A activity [A =/p/weight % clay size]
G~ density of soil particles [Gs = weight of soil particles/volume of soil particles]
Y kN/m 3 unit weight [y = weight of soil/volume of soil]
7w kN/m 3 unit weight of water [% = 9.81 kN/m 3]
%, 7d kN/m 3 bulk (wet) and dry unit weight of soil
7dmax kN/m 3 maximum dry unit weight
P Mg/m 3tonne/m 3 density [p = mass of soil/volume of soil]
Pb' Pd Mg/m 3 T/m 3 bulk (wet) and dry density of soil
Pdmax Mg/m 3 maximum dry density
Sr Saturation ratio [Sr = volume of water/total volume of voids]
A % air voids percentage [A = volume of voids x 100/total volume]
Ar aggregation ratio [At = % clay mineral/% clay size]
U coefficient of uniformity (of soil grading)
C coefficient of curvature (of soil grading)
K m/s hydraulic conductivity, coefficient of (field) permeability
ki m 2, darcy intrinsic permeability

Soil and rock properties

kPa, kN/m 2 normal stress in terms of total and effective stress (compression positive)
Cyv,c~' kPa, k N / m 2 vertical or overburden total and effective stresses
cy~,,(Yh' kPa, kN/m 2 horizontal or lateral total and effective stresses
(~1, (~2, (~3 kPa, kN/m 2 major, intermediate and minor principal total stresses
(~It,(~2 t, (~3 I kPa, kN/m 2 major, intermediate and minor principal effective stresses
kPa, kN/m 2 shear stress
P,p' kPa, kN/m 2 mean principal total and effective stresses respectively
U kPa, kN/m 2 pore (water) pressure
s kPa, pF pore (water) suction
8s shear strain
El, ~2, ~3 major, intermediate and minor strains
8vol volumetric strain
Y engineering shear strain
vK specific volume of over-consolidated soil atp' = 1.0 kPa
Np specific volume of isotropically normally consolidated soil atp' = 1.0 kPa
slope of isotropic normal compression line (v versus lnp')
K slope of isotropic normal swelling line (v versus lnp')
Rp one dimensional over-consolidation ratio (ratio of maximum effective over burden
stress to the present value)
K0 coefficient of earth pressure at rest (O'nt/O'v t)
KoCo compression index (slope of e-log effective consolidation pressure for compression)
Cs swelling index (slope of e-log effective consolidation pressure for swelling)
mv mZ/MN one-dimensional coefficient of compressibility
Cv mZ/s, m2/yr coefficient of consolidation
E' o kN/m 2 one-dimensional stiffness modulus
Cu, C' kPa, kN/m 2 cohesion intercept in terms of total stresses and effective stresses respectively
r degrees angle of friction in terms of total stresses and effective stresses respectively
Ccritt , Cp t, Crt kPa, kN/m 2 cohesion intercept in terms of effective stresses respectively for critical, peak
and residual conditions
~,.i,', ~,p', *r' degrees angle of friction in terms of effective stress respectively for critical, peak and
residual conditions
Ca, (Da kPa, degrees apparent cohesion intercept and angle of friction
Su kPa, kN/m 2 undrained shear strength
(7 c MPa uniaxial (unconfined) compressive strength (UCS)
m,s empirical strength parameters for rocks
E,K,G MPa, GPa deformation moduli in terms of linear, volumetric and shear strain respectively
for total stresses
E',K',G' MPa, GPa deformation moduli in terms of linear, volumetric and shear strain respectively
for effective stresses
Ei, Esoc, Etan MPa, GPa deformation moduli in terms of linear strain respectively in terms of total stresses
Ki, Ksoc, Ktan measured respectively at the initial part of the stress-strain curve, total
Gi, G .... Gta~ stress/total strain at a particular strain on stress-strain curve and as the slope of
Eit, Esect, Etan ' the stress-strain curve at a particular strain. May also be expressed in terms of
Ki',Ksoo',Ktan' effective stresses. Similar moduli in terms of volumetric and shear strain may also
Gi', Gse~', Gta n' by defined, as shown
v Poisson's ratio
% slake durability index (n = number of cycles)