Sec: OSR.

IIT_*CO-SC GTA-6(P1) Date: 18-04-24

Time: 3HRS 2021_P1 Max. Marks: 180
KEY SHEET
MATHEMATICS
1 A 2 B 3 B 4 C 5 2
6 8 7 5 8 6 9 24 10 40
11 BD 12 BC 13 ABC 14 AD 15 BD
16 AB 17 9 18 9 19 9

PHYSICS
5.66
20 C 21 D 22 B 23 B 24 OR
5.67
3905
25 5 26 1 27 TO 28 10 29 150
3915
30 ABCD 31 CD 32 ABD 33 BD 34 ABD

35 ABD 36 3 37 5 38 2

CHEMISTRY
39 D 40 A 41 B 42 B 43 7.40

44 0.02 45 3 46 4 47 4 48 16

49 CD 50 ABCD 51 ABD 52 BC 53 ABC

54 ACD 55 2 56 2 57 6
Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
SOLUTIONS
MATHS
1.

    4,   3
 7   7  4  6   6 
5  5
Sn   n   n
Sn  4 Sn 1  3 Sn  2  0
S7  4 S6  3 S5  0
1 a 1
2. Since an  2  1   1 n  , it
an  1 an  1 an  1
follows that
1
an  3  1   1   an  1  an ,
an  2
so is a periodic sequence with a period 3 . Since
1
a1  2, a2  , a3  1 , so P3  1 and
2
P2017   P3   P1  2
672

8
3. tan3  2tan6  4tan12 
tan24

tan3  2tan6  4tan12 


8 1  tan 212 

2tan12
4
tan3  2tan6 
tan12
 
 tan3  2tan6 

2 1  tan 2 6 
tan6
 cot3    3
4. Parametric equation of line through A  1,3
x 1 y  3
is  r
cos sin
 Any point on the line is
 rcos  1, rsin  3
 B  ABcos  1, ABsin  3 & C  ACcos  1, ACsin  3
lies on x  y  4 & y  x respectively.
 ABcos  1  ABsin  3  4
or AB  cos  sin   2
& ACcos  1  ACsin  3
 AC  cos  sin   4

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
But AB.AC  16
 1   2   16  cos2  sin2   8
or cos2  1/ 2
1
given tan  
3
2
 1 1 
 
3   3
2
 m  m2  3
 1  
 1  m1 m 2   1  1 
 3 

   ˆ
5. r  a ab
 
  r a
r a  a  2
a2
a
 a2
 ˆ
6. r 2  a 2  | a  b |2
 
 4  a 2  (a  b) 2  8  4cos
 rmax
2
8
x2 y2 z4
7. L1 :  
1 1 1

2 2
x  0 y 1 z  3
and L 2 :  
1 1 1
2
 ˆ ˆ ˆ
b1  b 2  n  2i  0 j k
Line will be R   1, 0, 2     2, 0,1
5
Distance from origin will be   5
5
8.

Using section formula and eliminating

we get w  2u  6
 locus of M  u, v, w  is 2 x  z  6
9. z  3  4i  4

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
( x  3) 2  ( y  4) 2  42
z will lie on circle
given in figure
amp  z   0  1
min

amp  z  max  2   2
2tan 24
tan2  
1  tan 
2
7
24
tan 1   2   tan  2     tan  2   
7
1
10. area of triangle formed by z, iz & z  iz is | z |2
2
2
x
11. Ellipse  y2  1
4

 b 
P   x1 , y1  A   x1 , y1 
 a 
 b 
Q   x 2 , y2  B   x 2 , y2 
 a 
 1   1 
A   x1 , y1  B   x 2 , y 2 
 2   2 
Mid point of AB   h1k 
x1  x 2 b  y1  y 2 
h k
2 a 2
 x  x 2 y1  y 2 
Mid point of PQ  1 ,    h, 2k 
 2 2 
Equation of PQ by mid point form & chord of contact & compare.
Circle x 2  y 2  4
xt  y  t  4   4 Chord of contact
hx  2ky  h 2  4k 2 Mid point chord
h 2k h 2  4k 2
Compare  
t t4 4
2k  h  h  4k
2 2

x 2  4y 2  2y  x  0
1 3
Ellipse with e  1  
4 2

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
12. Let equation be x  4y  c  0
Put in x 2  4xy  3y 2  5x  6y  3  0 & D  0
3x 2  x  C  x  
2
 C  x   C  x 
3   5x  6  3 0
 4   4 
D0
C  5, 8
Equation of T1 & T2 is x  4 y  5  0 & x  4 y  8  0 .
 2cosx  cos  2n  1 x  2cos  2nx   cos  2n  x  x  2
13. ln   dx
0 1  cos2 x
b b
 f  x  dx   f  a  b  x  dx
a a

 2cosx  cos  2n  1 x  2cos  2nx   cos  2n  1 x  2

ln   dx
0 1  cos2 x
 4 1  cos  2nx  
2In   dx
01  cos2 x
2
 sin nx
I n  2 dx
0 sin 2 x

f  x  f a  b  x
sin 2 nx
 /2
In  4 dx
0 sin 2 x
 / 2 sin  n  1 x  sin x
2 2

I n 1  I n  4 
0 sinx
 / 2 sin  2 n  1 x
I n 1  I n  4 dx
0 sinx
 / 2 sin  2 n  3  x
Similarly I n  2  I n 1  4  dx
0 sinx
(1)………….  2   0
I n 1  I n  I n  2  In 1
2In 1  I n  I n  2
I0 , I1 , I 2  are in A.P.
 /2 sin 2 x  /2 
I0  4 0dx  0 I1  4 dx  4
0 0 sin 2 x 2
A.P. will be I0  0, I1  2 , I 2  4
100
n0 I n  I 0  I1  I99  2 0  198   9900
99

I1011  2022
2x 2 / 3 8 / 3
14.  
 x  1 x  4   x  1 x  4
 2
x 1 e x 1    e x  4 8
e  3 3 3
  x  1 x  4  2 xdx    x  1   x  4  e dx

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
15. y  y  y  y 
d
y  y   y  y  y 
dx
dy
y  y 
dx
y  2y
2dy
dx 
y
x  2lny  C
x
C
y  e2
1
f 0 
e
1
1
f  x  e2
y  y i  y ii  y iii  y iv 
d
y  yi  yii   yii  yiii  
dx
d
y  y i  y ii   y  y i 
dx
y  y  y  y i  y ii
i ii

y  2 y ii
16.

f  x   1  cosx
3
g  x  x a
2
f   x   sinx
3
g  x   (x  0)
2
3
sinx 
2
 2
x ,
3 3
17. For two common tangents circles must be intersecting.
AC  16  9  n 2  BC

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL

2  25  n 2  8  0n 216
 n  0, 1, 2, 3, 4  9
18.
19. P  ABC   P  ABC   P  AB   1/ 7 .
P  AB   P  A   P  AB   1/ 7 .
P  AB  1  P  AB  4
P  A / B   
P  B 1  P  B 5

PHYSICS
20. Suppose that the two conductors carry free charge Q and Q . Consider a closed surface enclosing
the conductor with charge Q. Using ohm's and Gauss's Law,
     
I  ∮ J  dS  ∮  E  dS   ∮ E  dS
Q V Q
I   
 0 r R  0 r
Q  0 r
C 
V R
21.

V1 1   ΔT   V2 1  3 ΔT   V1
 V1 ΔT  V2  3 V2ΔT   0
V2
ΔT 
 V1  3 V2
22. Object at distance 2f produce real image of same size and inverted.
Object lying between f and 2f produce real inverted magnified image.
Object lying outside 2f produce real inverted diminished image.
dn 1 2
23.  , dn 
n 100 100
2
 n 1 
R  
 n 1

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
nR  2n  n  1  2n  n  1
1 2 2
dR  dn  dn
R n 1 n 1
2 2 2 2 16
    
1 100 3 100 300
dR 16
% %
R 3

24.
0 4i
25. B
2
4i 1
one turn of coil  
2 20
1 40 di
 induced emf  5  
20 2 dt
di
 2 2  107
dt
dsin 1000t 
 2 2  107  20
dt
3
 4 2  10 cos1000t
 Peak value of emf  4 2 m volt
 4 1.414
 5.656  5.66mV
For part -2
Induced emf
 dsin1000t d 
 2 2  107  20  5 sin  3000t  
 dt dt 
 2 2  103  2cos1000t  1.5cos3000t 
 2  4cos1000t  3cos3000t 
(4 2) 2  (3 2) 2
 e rms 
2
 16  9   5 mvolt
26.
27. Consider an element of liquid column

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
 gh
F x  0Td 1  cos53  .h d
2

1  3  4 103 10 2
1  h
2  5  2
2
 h2
400  5 104
1
h  1 mm
106
Now for equilibrium of cylinder
4
Fb  2 T    cy  g R 2 
5
  R2 
Fb   liq g  h  R   2 R   R  2 R     g
 2 
 cy  3909.82 kg / m
28.

x  v0 t
1 2
2 hy  gt
2
1
y  2 h  gt 2
2
x 2
v 2t 2
y  0
2h 2h
1 v2 t 2
2 h  gt 2  0
2 2h
v 0 t  4 h  ght 2
2 2 2

4 h2
t2 
v02  gh
2h
t
v02  gh
v 2  v0 2 g 2 t 2
4 h2 4 g2 h2
 v g  2
2
0
2
 v0  2
2

v0  gh v0  gh
K  minimum, v 2  minimum
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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
2
dv
0
dv02
4 g2 h 2
1 0
 
2
v02  gh

v 
2
2
0  gh  4 g2 h 2
v 02  gh  2gh
v0  gh
v0  gh  10  10  10 m / s
4  100  100
v 2  100   300 m / s
100  100
1
K   1 300  150 J
2
29.
2z1z 2
30. pt  pi
z1  z 2
Z  Z1
pr  2 pi
Z1  Z2
B
z  v 
v
31. 2P0 V0 T0 P0 V0 T0
2P0 VT V0 2P0 T
2P0 V0 P0 V0 2P0  V  V0 
 
T0 T0 T
V V0 V0 V 3 V0
   0 
T T T0 2 T0 2 T0
2P V 3 P V 3
Ui  0 0  RT0  0 0  RT0
RT0 2 RT0 2
2P  V0  V  3
Uf  0  RT  3P0  V0  V 
RT 2
ΔW  ΔU
9
2P0  V0  V   3P0  V0  V   P0 V0
2
4 V0  4 V  6 V0  6 V  9 V0
7 V0  10 V
7 V0
V
10
In (1)
7 V0 V0 3 V0
 
10 T T 2 T0
17 T0
T
15

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
32.

For resonance, I 2  I1sin

Vm Vm XL
 
XC R  XL
2 2
R 2  X L2
 R 2  X L2  X L  X C
L
 R 2   2 L2 
C
1 R2
 r  
LC L2
2
33. Δ  (angular width of central maximum).
a
2 2 2
  0.3 
a a a
    0.3  4200Å

2
In case (2) Δ 
a
2 2 2 1
  0.3   1   0.3
a a a 
   1.43
34.

q1 q1  q2
In loop ABGFA  E
C c
q q q
In loop ABCDGFA 1  2  2  E
C C c
q E
Vmn  2  2
 c n  3n  1

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35.

mv
r  A
qB
2 m
t1 
3qB
mv
AB  AO  2rcos30  r 3  3
qB
AB m
t2   3
v qB
 2 m 3 m
T  3  t1  t 2   3   
 3qB qB 


m
qB
 
2  3 3   B 

r R1

sin135 sin30


rsin30 1 r
R 
r  2 
sin135 2 2
r R2

sin15 sin150


rsin150 r 2 2 r 2
R2  
 
sin15 2 3 1 3 1
R1 B r 3  1 3 1
  
R 2 B V2 2 2
36.      1 A   2  1  6  6

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
If we rotate plane mirror by 3 in clock wise direction then reflected ray is rotated by 6 in


clockwise direction.
1 k
37. f0 
2 m
1 K b2
f  
2 m 4 m 2
2 K 4  K b2 
f0  f    
3 m 3  m 4m 2 
b2 1 K
2
   b 2  25  b  5
4m 4 m
38. ΔU  0
ΔU  ΔU lead  ΔU water
ΔQLead  ΔU Lead  m Lead  CP Lead  Tf  Ti 
0  0.6  CP   292.8  373.0   0.2  386  292.8  290.0 
0.5  4180  292.8  290.0 
Which in
CP  126 Jkgk 1

CHEMISTRY
39.
40.

41. In Haber's process iron oxide is used as a catalyst with small amounts of K 2 O & Al 2O3 to increase
the rate of attainment of equilibrium.
Process 
200 atm
N 2  3H 2 700k 2NH 3ΔH  46.1 kJ / mol

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
2
42. (i) If hybridisation is dsp then shape will be square planer.
(ii) In case of 2 lone pair &4 bond pair  sp3 d 2  shape will be square planer.
43. Na 2 CO3  HCl 
 NaHCO3  HCl
0.1M
 H    K a1 K a 2  16  1016  4 108
pH  8  log4  8  0.6  7.4
44. HCO3  H   CO32  , K a 2  8 1010
0.1M 4  108 M

8  1010 
 
4  10 8 CO32 
0.1
  CO3   2  103 M
2

45.

46.

47.

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
48. Let initial concentration of A   A0 
1 d A
Rate    k[A]n ;
3 dt
At 

At  d  A   3k t  [A] n 1 
 A0  [A]n  0 dt;   n  1   3kt
 A0 
 1 1 
     n  1 3kt;
 A  n 1
 0  
A
n 1
 t

1 1
  n  1 3kt 
 At   A0 
n 1 n 1

According to graph n  1  3, n  4 , slope  tan45

 1   n  1 3k, k  1/ 9
Rate  k
1 16
[A]4  (0.2)4  104 Mmin 1
9 9
16
P so 9P  16
9
49.
n
50.   2 a 0  
Z  
2
for He ion, n  2, Z  2, 2  2 a 0    X
2
 2 a 0  X
51.

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Narayana IIT Academy 18-04-24_OSR.IIT_*CO-SC_JEE-ADV_GTA-6(P1)_KEY&SOL
52. Compound(P) and Compound(Q) can be differentiated by NOT by aq.NaOH. Only compound(R)
gives foul smell of isocyanide with CHCl3  KOH
53. (d) is incorrect, Hg is not a transition elements.
54.
55. 3CH 3  CH 2  CH 2  OH  4HNO3 
3CH 3  CH 2  COOH  4NO  5H 2O
n HNO3 4

n Alcohol 3
4 180
n HNO3 ( Expected )   4
3 60
as % reaction yield is 80%
Hence
n HNO3 ( actual )  4  0.8  3.2
w HNO3  3.2  63  201.6
56. (2) & (6) are not used for softening of water
d
57.  2  0.02P
P
d M
at P  0  lim P0    2 
p RT
 M  2RT  60gm / mole

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