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    Ammonium Hydrogen Sulfite Water

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    Sidik Pamungkas
    Ammonium Hydrogen Sulfite Water is a permitted additive for use in grape wine and grape juice used for wine production at levels up to 0.2 g/L. It consists mainly of ammonium hydrogen sulfite and must contain at least 13.0% ammonium hydrogen sulfite. Specifications are provided for identification tests, purity limits for lead and arsenic, residue on ignition, and an assay method.

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    Ammonium Hydrogen Sulfite Water

    Uploaded by

    Sidik Pamungkas
    10 views2 pages
    Ammonium Hydrogen Sulfite Water is a permitted additive for use in grape wine and grape juice used for wine production at levels up to 0.2 g/L. It consists mainly of ammonium hydrogen sulfite and must contain at least 13.0% ammonium hydrogen sulfite. Specifications are provided for identification tests, purity limits for lead and arsenic, residue on ignition, and an assay method.

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    Ammonium Hydrogen Sulfite Water is a permitted additive for use in grape wine and grape juice used for wine production at levels up to 0.2 g/L. It consists mainly of ammonium hydrogen sulfite and must contain at least 13.0% ammonium hydrogen sulfite. Specifications are provided for identification tests, purity limits for lead and arsenic, residue on ignition, and an assay method.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    10 views2 pages

    Ammonium Hydrogen Sulfite Water

    Uploaded by

    Sidik Pamungkas
    Ammonium Hydrogen Sulfite Water is a permitted additive for use in grape wine and grape juice used for wine production at levels up to 0.2 g/L. It consists mainly of ammonium hydrogen sulfite and must contain at least 13.0% ammonium hydrogen sulfite. Specifications are provided for identification tests, purity limits for lead and arsenic, residue on ignition, and an assay method.

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    © All Rights Reserved
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    Ammonium Hydrogen Sulfite Water


    亜硫酸水素アンモニウム水

    Standards for Use

    Permitted for use in grape juice used for wine production and grape wine only.

    Shall be used at not more than 0.2 g/L in grape wine as ammonium hydrogen sulfite.
    When Ammonium Hydrogen Sulfite Water is used in grape juice used for wine production,
    this additive is considered to be used in grape wine.

    Shall not remain at a level not less than 0.35 g/kg as sulfur dioxide in grape wine
    (excluding squeezed grape juice used for wine production containing not less than 1 %
    (volume) of ethanol and the concentrate of such squeezed grape juice).

    Compositional Specifications

    Substance Name Ammonium Hydrogen Sulfite Water

    Definition
    Ammonium Hydrogen Sulfite Water is a solution consisting mainly of ammonium
    hydrogen sulfite.

    Content
    Ammonium Hydrogen Sulfite Water contains not less than 13.0% of ammonium
    hydrogen sulfite (NH4HSO3 = 99.11).

    Description Ammonium Hydrogen Sulfite Water occurs as a light yellow liquid.

    Identification
    (1) Ammonium Hydrogen Sulfite Water responds to the test for Ammonium Salt and
    all the tests for Sulfite and Bisulfite in the Qualitative Tests.
    (2) Ammonium Hydrogen Sulfite Water contains not less than 2.2 % as ammonia
    (NH3=17.03).
    Weigh accurately about 0.5 g of Ammonium Hydrogen Sulfite Water, add 25 mL of water
    to dissolve it, and add 10 mL of sodium hydroxide solution (2 in 5). Immediately connect
    the flask containing this solution to a previously assembled distillation apparatus. The
    apparatus is equipped with a condenser joined to a delivery tube with a spray trap and
    the lower end of the condenser is immersed in 30 mL of 0.1 mol/L sulfuric acid, exactly
    measured, in a receiver. Heat and distill ammonia into the sulfuric acid until about 25
    mL of the distillate is obtained. Titrate the excess sulfuric acid in the receiver with 0.2
    mol/L sodium hydroxide (indicator: 3 drops of methyl red TS). Determine the amount of
    ammonia by the formula.
    Each mL of 0.1 mol/L sulfuric acid = 3.406 mg of NH3

    Purity
    (1) Lead Not more than 5 μg/g of NH4HSO3 as Pb (an amount equivalent to 8.0 g of
    ammonium hydrogen sulfite (NH4HSO3), Method 5, Control Solution: Lead Standard
    Solution 4.0 mL, Flame Method).
    Sample Solution To the specified amount of Ammonium Hydrogen Sulfite Water,
    add 20mL of diluted hydrochloric acid (1 in 4), and boil gently for 5 minutes with a watch
    glass covering it. Allow to cool. Use this solution as the sample solution. If the sample
    does not dissolve completely, evaporate it to dryness, and add 20 mL of diluted
    hydrochloric acid (1 in 4) to the residue. Boil gently for 5 minutes, allow to cool, and use
    this solution as the sample solution.

    (2) Arsenic Not more than 3 μg/g of NH4HSO3 as As (an amount equivalent to 5.0 g
    of ammonium hydrogen sulfite (NH4HSO3), Standard Color: Arsenic Standard Solution
    3.0 mL, Apparatus B).
    Test Solution To the specified amount of Ammonium Hydrogen Sulfite Water, add
    water to make 50 mL. Measure 10 mL of this solution, add 2 mL of sulfuric acid, and
    heat on a water bath until sulfur dioxide is no longer evolved. Evaporate to about 2 mL,
    and add water to make 10 mL. Use 5 mL of this solution as the test solution.

    Residue on Ignition Not more than 0.2% per ammonium hydrogen sulfite (NH4HSO3)
    (10 g).

    Assay Weigh accurately about 0.3 g of Ammonium Hydrogen Sulfite Water, and
    proceed as directed under Sulfite Determination.
    Each mL of 0.05 mol/L iodine = 4.955 mg of NH4HSO3

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