KaVo Spray 2112

Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 1 of 11

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

KaVo Spray 2112

Product code:
0.411.9630
0.411.9640
1.013.5234
0.411.9650
0.411.9660
Further trade names
KaVo Spray, KaVo Spray 2112 A
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture
The product is intended for professional use.
1.3. Details of the supplier of the safety data sheet
Company name: Kaltenbach & Voigt GmbH
Street: Bismarckring 39
Place: D-88400 Biberach
Telephone: +49 (0) 7351 56 0 Telefax: + 49 (0) 7351 56 1488
e-mail: sdb@kavo.com
e-mail (Contact person): support@gefahrstoff.com
Internet: http://www.kavo.com/
Responsible Department: Questions concerning SDB: PES-Ingenieurgesellschaft mbH
1.4. Emergency telephone +49 (0) 7351 56 4000 (24 h)
number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Regulation (EC) No. 1272/2008
Hazard categories:
Aerosol: Aerosol 1
Aspiration hazard: Asp. Tox. 1
Hazard Statements:
Extremely flammable aerosol.
Pressurised container: May burst if heated.
May be fatal if swallowed and enters airways.
2.2. Label elements
Regulation (EC) No. 1272/2008
Signal word: Danger

Revision No: 2,1 - Replaces version: 2 GB - EN

KaVo Spray 2112
Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 2 of 11

Pictograms:

Hazard statements
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Do not pierce or burn, even after use.
P410+P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
2.3. Other hazards
In case of insufficient ventilation and/or through use, explosive/highly flammable mixtures may develop.

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Hazardous components
CAS No Chemical name Quantity
EC No Index No REACH No
Classification according to Regulation (EC) No. 1272/2008 [CLP]
75-28-5 isobutane 50 - < 100 %
200-857-2 601-004-00-0
Flam. Gas 1, Liquefied gas; H220 H280
8042-47-5 White mineral oil (petroleum) 20 - < 25 %
232-455-8 01-2119487078-27
Asp. Tox. 1; H304
74-98-6 propane 5 - < 10 %
200-827-9 601-003-00-5 01-2119486944-21
Flam. Gas 1, Liquefied gas; H220 H280
106-97-8 butane 1-<3%
203-448-7 601-004-00-0 01-2119474691-32
Flam. Gas 1, Liquefied gas; H220 H280
Full text of H and EUH statements: see section 16.

SECTION 4: First aid measures

4.1. Description of first aid measures

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Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 3 of 11

After inhalation
Provide fresh air.
After contact with skin
Wash with plenty of water.
After contact with eyes
Rinse immediately carefully and thoroughly with eye-bath or water.
After ingestion
Observe risk of aspiration if vomiting occurs. Rinse mouth immediately and drink plenty of water.
4.2. Most important symptoms and effects, both acute and delayed
No information available.
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media
Carbon dioxide (CO2), Foam, Extinguishing powder.
Unsuitable extinguishing media
Full water jet
5.2. Special hazards arising from the substance or mixture
Extremely flammable. Vapours can form explosive mixtures with air.
5.3. Advice for firefighters
In case of fire: Wear self-contained breathing apparatus.
Additional information
Use water spray jet to protect personnel and to cool endangered containers. Collect contaminated fire
extinguishing water separately. Do not allow entering drains or surface water.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Remove all sources of ignition. Provide adequate ventilation.
6.2. Environmental precautions
Do not allow uncontrolled discharge of product into the environment. Danger of explosion.
6.3. Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Treat the recovered material as prescribed in the section on waste disposal .
6.4. Reference to other sections
Safe handling: see section 7
Personal protection equipment: see section 8
Disposal: see section 13

SECTION 7: Handling and storage

7.1. Precautions for safe handling

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KaVo Spray 2112
Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 4 of 11

Advice on safe handling

Do not pierce or burn, even after use.
Advice on protection against fire and explosion
Do not spray on naked flames or any incandescent material. Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/122 °F. Keep away from sources of ignition - No smoking. Vapours can form
explosive mixtures with air.
Further information on handling
Avoid contact with skin, eyes and clothes.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep container tightly closed. Keep in a cool, well-ventilated place. Keep away from heat, hot surfaces, sparks,
open flames and other ignition sources. No smoking.
Advice on storage compatibility
Do not store together with: Oxidising agent. Pyrophoric or self-heating substances.
Further information on storage conditions
Protect against direct sunlight. Protect against: Frost.
7.3. Specific end use(s)
The product is intended for professional use.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Exposure limits (EH40)

CAS No Substance ppm mg/m³ fibres/ml Category Origin

106-97-8 Butane 600 1450 TWA (8 h) WEL

750 1810 STEL (15 min) WEL

Additional advice on limit values

none
8.2. Exposure controls

Protective and hygiene measures

Wash hands before breaks and after work. When using do not eat or drink.
Eye/face protection
Wear eye protection/face protection.
Hand protection
When handling with chemical substances, protective gloves must be worn with the CE-label including the four
control digits. The quality of the protective gloves resistant to chemicals must be chosen as a function of the

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Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 5 of 11

specific working place concentration and quantity of hazardous substances. For special purposes, it is
recommended to check the resistance to chemicals of the protective gloves mentioned above together with the
supplier of these gloves.
Skin protection
Wear suitable protective clothing.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls
Avoid release to the environment.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state: Liquid (Aerosol)
Colour: light yellow
Odour: odourless
Test method
pH-Value: not determined DIN 19268
Changes in the physical state
Melting point: not determined
Initial boiling point and boiling range: -40 °C
Flash point: - 80 °C
Flammability
Solid: not applicable
Gas: not applicable
Explosive properties
Vapours can form explosive mixtures with air.
Lower explosion limits: 0,9 vol. %
Upper explosion limits: 9,4 vol. %
Ignition temperature: No information available.
Auto-ignition temperature
Solid: not applicable
Gas: not applicable
Decomposition temperature: not determined
Oxidizing properties
Not oxidising.
Vapour pressure: not determined
Density (at 20 °C): 0,853 g/cm³ DIN 51757
Water solubility: practically insoluble
Solubility in other solvents
not determined

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Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 6 of 11

Partition coefficient: not determined

Viscosity / dynamic: not determined
Viscosity / kinematic: 15,5 mm²/s
Vapour density: not determined
Evaporation rate: not determined
9.2. Other information
Odour threshold: not determined
Density: Data apply to the technically active substance.
pressure: - bar (20 °C )

SECTION 10: Stability and reactivity

10.1. Reactivity
Extremely flammable. Ignition hazard.
10.2. Chemical stability
The product is stable under storage at normal ambient temperatures.
10.3. Possibility of hazardous reactions
Vapours can form explosive mixtures with air.
Heating causes rise in pressure with risk of bursting.
10.4. Conditions to avoid
Keep away from sources of heat (e.g. hot surfaces), sparks and open flames.
10.5. Incompatible materials
No information available.
10.6. Hazardous decomposition products
No known hazardous decomposition products.
Further information
Do not mix with other chemicals.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity
Based on available data, the classification criteria are not met.

Revision No: 2,1 - Replaces version: 2 GB - EN

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Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 7 of 11

CAS No Chemical name

Exposure route Dose Species Source Method
8042-47-5 White mineral oil (petroleum)
oral LD50 > 5000 Rat Manufacturer
mg/kg
dermal LD50 > 2000 Rabbit Manufacturer
mg/kg
inhalative (4 h) aerosol LC50 > 5000 Rat Manufacturer
mg/l

Irritation and corrosivity

Based on available data, the classification criteria are not met.
Sensitising effects
Based on available data, the classification criteria are not met.
Carcinogenic/mutagenic/toxic effects for reproduction
Based on available data, the classification criteria are not met.
STOT-single exposure
Based on available data, the classification criteria are not met.
STOT-repeated exposure
Based on available data, the classification criteria are not met.
Aspiration hazard
Based on available data, the classification criteria are not met.
Additional information on tests
The mixture is classified as not hazardous according to regulation (EC) No 1272/2008 [CLP].

SECTION 12: Ecological information

12.1. Toxicity
The product is not: Ecotoxic.
CAS No Chemical name
Aquatic toxicity Dose [h] | [d] Species Source Method
8042-47-5 White mineral oil (petroleum)
Acute fish toxicity LC50 > 100 96 h Brachydanio rerio Manufacturer
mg/l (zebra-fish)
Acute algae toxicity ErC50 > 100 72 h Desmodesmus Manufacturer
mg/l subspicatus
Acute crustacea toxicity EC50 > 100 48 h Daphnia magna (Big Manufacturer
mg/l water flea)

12.2. Persistence and degradability

The product has not been tested.
12.3. Bioaccumulative potential
The product has not been tested.

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Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 8 of 11

Partition coefficient n-octanol/water

CAS No Chemical name Log Pow
75-28-5 isobutane 2,8
8042-47-5 White mineral oil (petroleum) > 3,5
74-98-6 propane 2,36
106-97-8 butane 2,89

12.4. Mobility in soil

The product has not been tested.
12.5. Results of PBT and vPvB assessment
The product has not been tested.
12.6. Other adverse effects
No information available.
Further information
Avoid release to the environment.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal
Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation.
Waste disposal number of waste from residues/unused products
160504 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and
discarded chemicals; gases in pressure containers (including halons) containing hazardous
substances; hazardous waste
Waste disposal number of used product
160504 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and
discarded chemicals; gases in pressure containers (including halons) containing hazardous
substances; hazardous waste
Waste disposal number of contaminated packaging
150104 WASTE PACKAGING; ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND
PROTECTIVE CLOTHING NOT OTHERWISE SPECIFIED; packaging (including separately
collected municipal packaging waste); metallic packaging
Contaminated packaging
Completely emptied packages can be recycled.

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: UN 1950
14.2. UN proper shipping name: AEROSOLS
14.3. Transport hazard class(es): 2
14.4. Packing group: -
Hazard label: 2.1

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KaVo Spray 2112
Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 9 of 11

Classification code: 5F
Special Provisions: 190 327 344 625
Limited quantity: 1L
Excepted quantity: E0
Transport category: 2
Tunnel restriction code: D
Inland waterways transport (ADN)
14.1. UN number: UN 1950
14.2. UN proper shipping name: AEROSOLS
14.3. Transport hazard class(es): 2
14.4. Packing group: -
Hazard label: 2.1

Classification code: 5F
Special Provisions: 190 327 344 625
Limited quantity: 1L
Excepted quantity: E0
Marine transport (IMDG)
14.1. UN number: UN 1950
14.2. UN proper shipping name: AEROSOLS
14.3. Transport hazard class(es): 2.1
14.4. Packing group: -
Hazard label: 2.1

Special Provisions: 63, 190, 277, 327, 344, 959

Limited quantity: 1000 mL
Excepted quantity: E0
EmS: F-D, S-U
Air transport (ICAO-TI/IATA-DGR)
14.1. UN number: UN 1950
14.2. UN proper shipping name: AEROSOLS, flammable
14.3. Transport hazard class(es): 2.1
14.4. Packing group: -
Hazard label: 2.1

Revision No: 2,1 - Replaces version: 2 GB - EN

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Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 10 of 11

Special Provisions: A145 A167 A802

Limited quantity Passenger: 30 kg G
Passenger LQ: Y203
Excepted quantity: E0
IATA-packing instructions - Passenger: 203
IATA-max. quantity - Passenger: 75 kg
IATA-packing instructions - Cargo: 203
IATA-max. quantity - Cargo: 150 kg
14.5. Environmental hazards
ENVIRONMENTALLY HAZARDOUS: no
14.6. Special precautions for user
Warning: Flammable gases.
14.7. Transport in bulk according to Annex II of Marpol and the IBC Code
not applicable

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulatory information
Restrictions on use (REACH, annex XVII):
Entry 3: White mineral oil (petroleum)
Entry 40: isobutane; propane; butane
2010/75/EU (VOC): No information available.
Information according to 2012/18/EU P3a FLAMMABLE AEROSOLS
(SEVESO III):
National regulatory information
Employment restrictions: Observe restrictions to employment for juvenils according to the 'juvenile
work protection guideline' (94/33/EC).
Water contaminating class (D): 1 - slightly water contaminating
15.2. Chemical safety assessment
Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Changes
This data sheet contains changes from the previous version in section(s): 2,3,4,5,7,8,9,11,13,15.
Abbreviations and acronyms
ADR: Accord européen sur le transport des marchandises dangereuses par Route
(European Agreement concerning the International Carriage of Dangerous Goods by Road )
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
Revision No: 2,1 - Replaces version: 2 GB - EN
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Safety Data Sheet

according to Regulation (EC) No 1907/2006 Page 11 of 11

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service
LC50: Lethal concentration, 50%
LD50: Lethal dose, 50%
Classification for mixtures and used evaluation method according to Regulation (EC) No. 1272/2008 [CLP]
Classification Classification procedure
Aerosol 1; H222-H229 On basis of test data
Asp. Tox. 1; H304 Calculation method

Relevant H and EUH statements (number and full text)

H220 Extremely flammable gas.
H222 Extremely flammable aerosol.
H229 Pressurised container: May burst if heated.
H280 Contains gas under pressure; may explode if heated.
H304 May be fatal if swallowed and enters airways.
Further Information
The above information describes exclusively the safety requirements of the product and is based on our
present-day knowledge. The information is intended to give you advice about the safe handling of the product
named in this safety data sheet, for storage, processing, transport and disposal. The information cannot be
transferred to other products. In the case of mixing the product with other products or in the case of
processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

Revision No: 2,1 - Replaces version: 2 GB - EN