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Solutions to JEE MAIN-2|JEE 2024

PHYSICS
SECTION-1
1.(C) For uniformly charged circular arc
2k 
E0 = sin  , where  is half angle it forms at centre
R
k
For 1,  =135 , E0 = 2
R
k
For 2,  = 45 , E0 = 2
R
2.(D) = E0 . Projected Area

= E0 (2r )
3.(B) Due to upper half and lower half ring potential will be equal but of opposite sign, while electric field will
be equal and in same direction.
  .3a
4.(D) R= ; x=
A 2a 2
 2a  a
y= 2 ; z=
3a 6a 2
2 R R
5.(A) RAB = . +
3 4 4
5
RAB = R
12

6.(B) As RA  RB
Before closing switch, i = const.
VA VB
After closing switch, VA =VB
As potential differecne across A decreases, Intensity decreases
7.(D) Charge stored in 5f = 0 due to short circuit
So energy = 0

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8.(C) Kx = Fe

q2 q2
Kx =  x=
2 A0 2 K 0 A
9.(C)
10.(B) By kirchhoff’s junction law
i1 = i2 + i3
50 −V V − 0 V − 30
= +
5 3 15
150 − 3V = 5V + V − 30
9V =180 ; V = 20V
30 20 10 − 30 2
i1 = = 6 A, i2 = A, i3 = = A
5 3 15 3
11.(D)

I
12.(A) J =  J A  J B (as I is same)
A
J = E  EA  EB (as  is same)

q
13.(B) = (1− cos53)
2 0

q  3
= 1 − 
20  5 
q
=
50

14.(D) Resistance of voltmeter is infinity. So current drawn from battery is zero.

V
 I=
2R
V
P.d across R = IR =
2

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15.(C)

2
 5 = 2V
2+3

 1V

2k 
16.(D) E0 = sin 
d
2k
=  sin 60
 
 
2 3
6k  6kq
= = 2

17.(B) Current through battery

1.5 + 1.5
i=  Current through 10 resistor;
 15 10 
 + 2 + 2r 
 15 + 10 
15 3 3 
i10 = i = i  voltage across 10 resistor =  i  10 = 2 (Given)
15 + 10 5 5 
3 3 10 90 1
  =2  (8 + 2r ) = =9  r= = 0.5
5 (6 + 2 + 2r ) 10 2
18.(B) VR =.e−t / RC
VC =[1− e−t / RC ]
At t =100 ms
1 100
VR =VC  e−t / RC = ; RC = 145.45 ms
2 ln(2)
19.(B) q flown = CV − (−2CV ) = 3CV
1
U f = C  (2V )2 = 2CV 2
2
1
U i = CV 2
2
1 3
U = 2CV 2 − CV 2 = CV 2
2 2
Wb = q flow 2V = + 3CV  2V = + 6CV 2
3 9
H =Wb − U = + 6CV 2 − CV 2 = CV 2
2 2
9
CV 2
H 2 9
Now, = 2
= = 2.25
U f 2CV 4

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20.(A) KCL at junction

2( x − 0) + 2( x − 4) + 2( x − 2) = 0
x=2
Va = 2,Vb = 2
Va −Vb = 0

SECTION-2
1.(110) dV = − Edx
V 5

 dV = −  (4 − 3x
2
)dx
5 2
V − 5 =105 ; V =110 volt
m m 9.110−31
2.(13)  = ; = = −8 −19 2
= 2 10−13 sec
ne 
2
ne 2 10  9 10  (1.6 10 )
2 27

3.(6) Qnet = 1200 pC

After connecting the charge will divide equally as capacitance are same
Q1 = Q2 = 600 pC
1 (1200 ) 1 ( 600 )
2 2
H= − 2 = 6000 pJ ; H = 6 nJ
2 60 2 60
k (q − Q) kq kq
4.(4) − + =0
3R 2R R
kq − Q kq
=−
3R 2R
3
q −Q = − q
2
5 2
q =Q ; q = Q
2 5
5.(3) I g  Rg = ( I − I g ) Rsh
0.05 50 = (5 − 0.05). Rsh
2.5
Rsh =
4.95
50
 =
A 99
5 10−7  50
−6
=
2.97 10 99
= 3m
50
6.(200) In steady state current through battery I = = 1A
23 + 3 +17 + 7
 Q10F = CV =10  20 = 200C

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7.(180) r = rp − r0 = 6iˆ − 8 ˆj

r = 62 + 82 =10m
q 200 10−6
V = k = = 9 109 
r 10
= 180 103 Volt ; =180 kV

8.(4) From Rt = R0 (1 + t )  5 = R0 (1 + 50 ) ... (i)

and 6 = R0 (1 + 100 ) ... (ii)
5 1 + 50 1
 = or  =
6 1 + 100 200
 1 
Putting the value of  in equation (i), we get: 5 = R0 1 + 50    R0 = 4
 200 
2 + 4 − 3 +1
9.(4) Applying loop rule I = = 1 amp
1+1+1+1

VAB = 4 + 2 −1 2 = 4 volts

40
10.(4) VAC = VAB = 10 = 4V
L 100
i.R = 4
5
R=4
1+ R
5R = 4 + 4 R
R = 4

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CHEMISTRY
SECTION-1
1. (B) For zero order reaction, same amount of reactant is consumed in equal time interval.
[X] X 0.75 X 0.50 X 0.25 X 0
Time 0 t 2t 3t 4t
p = t

Hence, q = 2t 
r = 3t 
q r
 t = p = =  6p = 3q = 2r
2 3
2. (C) Discharging tendency : Ag+ > Cu2+ > H+ > Na+
Electrolyte Product of electrolysis at cathode
CuSO 4 ( aq ) Cu(s)
AgNO3 ( aq ) Ag(s)
NaCl ( aq ) H2 ( g )
Na 2SO4 ( aq ) H2 ( g )
HCl ( aq ) H2 ( g )
3. (D) Facts related to colloids
1
4. (B) t1/2 
( a )n −1
[a = initial conc. of reactant]
[n = order w.r.t. reactant]
For A, t1/2  a [Given]
1
 t1/2 
( a )−1
Comparing, n –1 = –1 , n = 0
→ order w.r.t A = 0
For B, t1/2  a = k [Given]
k 1
t1/2 =  t1/2  1
a (a )
Comparing, n –1 = 1, n = 2
Order w.r.t. B = 2
Overall order of reaction = 0 + 2 = 2
5. (B) OH– has maximum ionic molar conductivity due to grotthus conductance.
For alkali metal cations,
Hydrated Radius : Li + ( aq )  Na + ( aq )  K + ( aq )  Rb+ ( aq )  Cs + ( aq )

Hydrated Radius  Ionic mobility   m 

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Rate of disappearance / Appearance

6. (D) Rate of reaction =
Stoichiometric coefficient
( ROD )A ( ROD )B ( ROA )C ( ROA )D
ROR = = = =
2 3 1 2
−1 d  A −1 d  B d C 1 d  D −2d  B 3d  D
= = = = ; =
2 dt 3 dt dt 2 dt dt dt
7. (B) Facts related to enzymes.
8. (C) Facts related to Tyndall effects
9. (D) Nernst Equation for above cell reaction is
  Mn 2+   Fe3+ 
5 
−0.059      
Ecell = Ecell log  8 5
5   MnO−4   H+   Fe2+  
     
pH  [H+]  Ecell 
  
10. (B) eq Ca 3 ( PO4 )2  = eq Ca 2+  + eq  PO43−  = x + y
   
  
M = eq  n − factor ; M = ( x + y )  6 = 6 ( x + y )

11. (A) Rate = k   A   B  C

2 1 0

Rate Mol L−1s −1

k= = = Mol−2 L2 s −1
 A   B ( Mol L )
2 1 −1 3

12. (B) Use, m x =n

m = No. of times a reactant concentration is made.
n = No. of times rate of reaction becomes
x = Order w.r.t. a reactant
For A For B
mx = n mx = n
x
1
2 x =4   = constant
2
2 x =2 2 ( 2 ) – x = ( 2 )0
x=2 x=0
Rate law expression is Rate = k  A   B
2 0

1
when volume is doubled, concentration of both the reactants is halved. Let new rate be R .
2 0
1  1 
R1 = k  A   B
2  2 
0
1 2 1
R = k    A       B
1 0
4 2
1 1
R1 =  k   A  B ; R1 = R
2 0
4 4

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13. (D) HClO2 + 2H + + 2e − ⎯⎯

→ HClO + H 2O ; (
 G1 = −2FE1 ) ...(i)

2HClO + 2H + + 2e− ⎯⎯
→ Cl2 + 2H 2O ; G 2 = −2FE2 ...(2)

2HClO2 + 6H+ + 6e− ⎯⎯

→ Cl2 + 4H2O ; G3 = −6FE3 ...(3)

  
 G3 = 2 G1 +  G 2  −6FE3 = −4FE1 − 2FE2  E3 =
( 2E + E ) = 1.659 V
1 2
3
14. (D)

i t
15. (B) Equivalents = . If same current is passed for same duration equivalents will be same. (1 : 1 : 1)
F
Equivalents = moles  n-factor.
1
If equivalent are same, moles  n-factor → Ag : Cu : Au = 1 : 2 : 3
n − factor
1 1 1
Moles → Ag : Cu : Au = : : = 6 : 3: 2
1 2 3
Moles deposited  conc. Of ions in soln. 
1
x
16.(A) = kp n Using n = 2
m
1
1
0.2 = k4 n
1
0.2 = k 42
0.5 = k25 n
1
2  4 n 0.2
=  =k k = 0.1
5  25  2
2
2  2 n
=  At 36 bar
5 5
1
x
= 0.1x 36 2
m
2 x
1= = 0.6
n m
n=2
0.6 6 3
Number of moles = = = = 0.02
28 28 10 140

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2.303 A 
17. (A) k = log  0 
t  At 
2.303  2  2.303  5  2.303 −1
k= log   ; k=  log   =  0.4 = 0.092 min
10  0.8  10 2 10

18. (C)

19. (B) Gold sol is negative sol. It contains negatively charged AuO−2 ions adsorbed on it.

20. (D) Fact

SECTION-2
1 1
1. (54) Conductance ( G ) = = S
R 20
Conductivity ( k ) = conductance ( G )  cell constant ( G *)
k 0.027 S cm−1
Cell constant ( G *) = = = 0.54 cm −1 = Z ; 100 Z = 54
G 1/ 20 S

2. (25) By definition of gold number, the amount of protective colloid required to prevent coagulation of 10 ml
gold sol against 1 ml 10% NaCl soln. = 50 mg
= 50 10−3 g
−3
For 10 ml gold sol, protective colloid required = = 50  10 g
−3
For 50 ml gold sol, protective colloid required = 5  50 10 g = 0.25 g
x = 0.25 g ; 100 x = 25

RT
3. (1) Ecell = Ecell − log Qc for concentration cell, Ecell = 0
nF
 2
0.06 1 ( 0.001) 
Ecell = 0.12 = 0 − log  2 
2
 ( )
 1 10− x 

−
 10 6
0.12 = −0.03  log  −2x 
10 
−2x
−4 = −6  log10 − ( −2x  log10 )
0.12
 − = log10−6 − log (10 ) 
0.03
 −4 = −6 + 2x  2x = 6 − 4 = 2  x = 1

0.693 0.693
4. (50) t1/2 = = = 10 min
K 0.0693
t3/4 = 2  t1/2 = 20 min
t 7/8 = 3  t1/2 = 30 min
t3/4 + t 7/8 = 50 min

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5. (67) Products of electrolysis of aq.Na 2SO4 are H 2 ( g ) and O 2 ( g )

Cathode  Anode
equivalents of H 2( g ) and O2( g ) produced will be same.
 Equivalent = Moles  n -factor
1
 Moles  [If equivalents are same]
n -factor
Moles ( H 2 ) n -factor ( O2 ) 4 2
 = = =
Moles ( O2 ) n -factor ( H 2 ) 2 1
3.36
Total moles of H2 ( g ) & O2 ( g ) = = 0.15
22.4
2
Moles of H2 =  0.15 = 0.1
2 +1
i  t % efficiency
Moles  n -factor =  [Applying Faradays law for H2 (g) ]
F 100
9.65  t 50
0.1 2 = 
96500 100
t = 4000 s = 66.67 min 67 min

6. (5) Pi = 10 atm
Pf = (10 − 50% of 10 ) atm = 5 atm
| p |= 5 atm
PV = nRT
At const. ‘V’ and ‘T’, P  n
 P  n
 P  V = nRT
1
 5  5 = n   300  n = 1
12
Now moles of gas adsorbed = 1
Mass of gas adsorbed = Moles  Molar Mass
= 1 30 = 30 g
Mass of gas adsorbed per unit gram of charcoal
30
( x / m) = = 0.5 = Z  10 Z = 5
60

−1 −1
7. (3) Unit of k = mol L s

Zero order reaction
 x = k t (x – Conc. Of product at time t)
 0.6 = k 10  60
0.6
 k = Mol L−1 s−1 = 0.001 mol L−1 s −1
600
k = 0.001 = 110−3 = 110−x
x=3

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
→ Ag + + e−
8. (83) Ag ⎯⎯  G1 = −1 F  ( −0.80 )

AgI + e− ⎯⎯
→ Ag + I −  G 2 = −1 F  x
  
→ Ag + + I−
AgI ⎯⎯  G 3 =  G1 +  G 2

 G3 = −2.303 RT log KSP = F ( 0.80 − x )
2.303 RT
 −  log KSP = 0.80 − x
F
 (
−0.06  log 8 10−17 = 0.80 − x )
 0.966 = 0.80 − x
1000 x
 x = −0.166  = 83
2

9. (24)
( Flocculation value ) x + =
46
( Flocculation value ) y4+ 16
100
 = 4096
Z 10−3
100000
 Z= = 24.414
4096
Rounding off → Z = 24

  
10. (12) f H Reaction =  f H( Pr od ) −  f H( React )

( )
= 2  f H A( g ) − 1  f H A 2( g )

( )
= 2  40 − 1 20 kJ mol−1
= 60 kJ mol−1
f HReaction = ( Ea )f − ( Ea )b
 60 = Ea f − 60
 Ea f = 120 kJ mol−1
x = 120
x /10 = 12

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MATHEMATICS
SECTION-1
1 x  x2 − 4
1.(A) y+ =x  y= , y  1,  )
y 2
x + x2 − 4
 y=
2

2.(B) The fundamental period of sin x + cos x is
2
 1 + cos x 
3.(B) lim   a = finite only if a = 0
x →− /2  cos x 

 e− cos x − 2c   1
f  =b  b=a =0 ; lim = f  =0 c=
2 +
x → /2  2 2
x−
2
4.(A) Given, f ( x) = x + x
2 x, x  0
 f ( x) =  
 0, x  0

It is clear from the graph of f ( x) is continuous for every value of x

Alternate
Since, x and | x | is continuous for every value of x, so their sum is also continous for every value of x
1 1 1
5.(B) In domain is (−, 0)  1,  ) So, lim = lim = −1
[ x] −
x → 0 [ x] x → 0 [ x]

(1 + x)(1 + x2 )....(1 + x16 )(1 − x)

6.(C) y=
(1 − x)
1 − x32
y=  y − yx = 1 − x32
1− x
 y − y − xy = −32 x31
xy + y − y = 32 x31
xy + y + y − y = 32  31x30
Put x = −1  2( y − y) = 32  31
 y − y = 496

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7.(C) Let f ( x) = x & g ( x) = − | x |  Non-differentiable at x = 0

Then f + g = 0  Differentiable at x = 0
2
f .g = − x  differentiable at x = 0

2
sin  
2  x=2
8.(C) lim x sin   = lim
x→  x  x→ 1  2 
 
2 x
1
9.(B) x→
x
 
1 1
2 f   − f ( x) = x +
 x x
1  1
Adding both  f ( x) + f   = 2  x + 
 x  x
1
f ( x) + f  
  x =2
1
x+
x

10.(C)
x + 1 − 1 = 1 − 1 , 1 +  x  1, 2 ) 
1

1
1
1 +  x 1 +  x 2 1 +  x
1 1
 0  1− 
1 + {x} 2
 1
 Range  0, 
 2

11.(B)
 (
f ( x) = sin  log x + x 2 + 1  ;
 )
 
( ) 
2
  x2 +1 − x2     
 (  )
f (− x) = sin  log − x + x 2 + 1  = sin  log 
  x +1 + x
2
  = sin  log 
   
1 

  x + x +1  
2
  
  

 (  )
= sin  − log x + x 2 + 1  = − f ( x) [ sin(–x) = –sin(x)]  f (x) is an odd function

 63  63 1
12.(A) Let sin −1 
 8  =   sin  =
8
 cos  =
8
 
1 32
 sec ( 2 ) = =−
2cos  − 1
2 31

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13.(C)

It is clear from the graph that f ( x) is continuous everywhere also it is differentiable everywhere except
at x = 2 .

14.(C) Let tan −1 a = , tan −1 b = 


  + =  (1 + tan ) (1 + tan ) = 2
4
 (1 + a) (1 + b) = 2  (a, b) lies on a hyperbola

15.(B) 1  (sin x + cos x)  2

 cot −1 (1)  cot −1(sin x + cos x)  cot −1 ( 2)
 
f ( x)  cot −1 2, 
 4

 2 1
 x sin   x  0
16.(B) Let f ( x) =   x , f ( x) is differentiable
 x=0
 0
at x = 0 but f ( x) is not continuous at x = 0

eax − ebx aeax − bebx

17.(B) lim = lim = a −b
x→0 x x→0 1

r +1
−1  2 − 2r  n
( ) ( )
n
18.(A) S =  tan  r +1 

=  tan −1 2r +1 − tan −1 2r telescopic series gives
 1+ 2  2  r = 0
r
r=0

( )
S = tan −1 2n+1 −

4

19.(A) Take log & differentiate both sides

Put x = 2024

−1 −1 −1
20.(B) tan ( x + 1) + tan ( x + 2) = − tan x
( x + 1) + ( x + 2)
Apply tan  = −x
1 − ( x + 1)( x + 2)
Solving we get x = 1,3 , but x = 3,1 doesn’t satisfy the original equation.
Hence only solution is x = −1

Solutions | Page 14 JEE Main-2 | JEE 2024

 Vidyamandir Classes: Innovating For Your Success

SECTION-2
1.(2) x − 3 sin x − 3 = ( x − 3) sin( x − 3)
cos ( x − 3 ) x 2 − 6 x + 5 = cos( x − 3) ( x − 5)( x − 1)
f ( x) = ( x − 3)sin( x − 3) + cos( x − 3) ( x − 5)( x − 1)
Only N.D at x = 5 & x = 1

2.(2) Since, lim f ( x) = f (0)

x→0

1 − cos x − ( − sin x )
 lim = k  lim =k [using L ‘Hospital’s rule]
x→0 x2 x→0 2x
 =  =
→

3.(7) 2 log3/16 sin x  1 − 2 log3/16 cos x

3 3
2 log3/16 sin x cos x  1  sin x cos x   sin 2 x 
4 2
     2 5 
x [ p, q]  [r , s] ; x   ,    , 
6 3  3 6 
 1
4.(4) y = −2 x 2 + 2 x  Range of g ( x) =  −, 
 2 
Range of g ( x)  domain of f ( x)
 1
  −,  − −2
 2
 1
Now, Range of f ( x) for x   −,  − −2 will be the range of fog ( x) .

2 
1+ x 2 y −1
y = f ( x) =  2 y + xy = x + 1  x=
2+ x 1− y
1 2 y −1 1  3
C-I: x     y   −,   (1,  )
2 1− y 2  5
2 y −1
C-II: x  −2   −2  y  R
1− y
 (C − I )  (C − II )
 3
 Range of fog ( x) =  −,   (1,  )
 5
5.(0) We have f ( x ) = sin   x + sin  − x = sin 3x + sin ( −4 ) x = sin 3x − sin 4 x
 f (  ) = sin 3 − sin 4 = 0
1 1
  1 1  3   1 1  3  1  1 1 
6.(4) lim n3 1 − − 3  + n +  = n 1 −  + 3   + n +  = n 1 −  + 3  + n + 
n→  n n    n n   3  n n 
 1 1 1 
 n −  + n +  = 0   = −1,  =  3  − (−1)  = 4
 3 3 3 

Solutions | Page 15 JEE Main-2 | JEE 2024

 Vidyamandir Classes: Innovating For Your Success

6 x2 + 5x + 1 2 x 2 − 3x + 4
7.(4)  0 & −1  1
2x −1 3x − 5
(2 x + 1)(3x + 1) 2 x 2 − 3x + 4 2 x 2 − 3x + 4
 0 &  −1 & 1
2x −1 3x − 5 3x − 5
 −1 −1   1  2 x2 − 1 2 x2 − 6 x + 9
 x  ,   ,  & 0 & 0
 2 3  2  3x − 5 3x − 4
 −1 −1   1   −1 1   5   5
 x  ,    ,   x ,    ,0  & x   −, 
 2 3  2   2 2 3   3
 −1 −1   1 1 
 x  ,    , 
 2 3  2 2
18 2 2 2 2
 ( +  +  +  ) = 4
5
8.(1) We have x = sin −1 (a 6 + 1) + cos −1 (a 4 + 1) + tan −1 (a 2 + 1)
It is possible only when a = 0
Thus, x = sin −1 (1) + cos −1 + (1) + tan −1 (1)
  3
= +0+ =
2 4 4
   
Therefore, sin  x +  − cos  x + 
 4  4
 3    3  
= sin  +  − cos  +  = 1
 4 4  4 4
9.(3) Since sum of the roots is –ve and product of the root is positive, both roots are negative. Thus m is a
negative root.
1
Now, tan −1 (m) + tan −1  
m

(
= tan −1 ( m ) −  + cot −1(m) = − + tan −1 (m) + cot −1 (m) = − + ) 
2
=−

2
Clearly, k = −1 Hence, the value of (k + 4) is 3.
10.(0) We have,
3 
 x , x0
3
f ( x) = x = 
− x , x  0
3

f ( x) − f (0) x3
 (LHD at x = 0) = lim = lim =0
x → 0− x−0 x→0 x
and,
f ( x) − f (0) x3
 (RHD at x = 0) = lim = lim =0
x → 0+ x−0 x→0 x
Clearly, (LHD at x = 0) = (RHD at x = 0)
Hence, f ( x) is differentiable at x = 0 and its derivative at x = 0 is 0.

Solutions | Page 16 JEE Main-2 | JEE 2024