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14-10-2023 SR - Super60 Nucleus & Sterling BT Jee-Main-Rptm-11 Q.paper

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Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI


A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_NUCLEUS&STERLING_BT JEE-MAIN Date: 14-10-2023
Time: 09.00Am to 12.00Pm RPTM-11 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point Pen
only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on the
Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.
4. The Test Booklet consists of 90 questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Physics, Chemistry and Mathematics having
30 questions in each subject and subject having two sections.
(I) Section –I contains 20 multiple choice questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
(II) Section‐II contains 10 Numerical Value Type questions. Attempt any 5 questions only, if more than 5
questions attempted, First 5 attempted questions will be considered.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer
value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and
less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use of pencil is
strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone any electron
device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in the Hall.
However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:
Candidate’s Signature:________________ Invigilator’s Signature: ________________
SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
14‐10‐23_Sr.Super60_ NUCLEUS & STERLING_BT _ Jee‐Main_RPTM‐11_Test Syllabus
PHYSICS : SHM : Forced and damped oscillation (in one dimension),
resonance, Linear and angular simple harmonic motions, SHM in
rigid body systems.
RPTM‐11(15Q‐RPTM.11 SYLLABUS+15Q CUMULATIVE SYLLABUS)
CHEMISTRY : 1.d‐block elements: Introduction; Electronic confugurations;
oxidation states and their stability; standard electrode potentials ;
interstitial compounds ; alloys; Catalytic properties; Ionization
enthalpy; atomic radii; colour; magnetic properties; complex
formation; and applications of d‐block metals and their compounds
2.Compounds of Cr and Mn: Preparation,Structure and reactions of
oxoanions of Chromium and manganese
3.Coordination compounds: Introduction, Definition of important
terms related to co‐ordination compound,types of ligands,IUPAC
Nomenclature, Isomerism (structural),Isomerism
(stereo)(complexes containing ligands with chiral centres not to be
tested),Bonding in coordination compounds ,Werner theory,
Sidgwick theory(EAN concept, 18 electron rule)V.B. theory,Basic
concepts of crystal field theory(J T distortion‐basic idea) ,Bonding in
metal carbonyls, Stability of co‐ordination compounds, Importance
and applications of coordination compounds
RPTM‐11(15Q‐RPTM.11 SYLLABUS+15Q CUMULATIVE SYLLABUS)
MATHEMATICS : Complete Circle & Parabola
RPTM‐11(15Q‐RPTM.11 SYLLABUS+15Q CUMULATIVE SYLLABUS)

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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. A 21.2 kg objected oscillates at the end of a vertical spring that has a spring constant 20500

Nm 1 .The effect of air resistance is represented by the damping coefficient b  4 Nsm 1 .


Find the time interval that elapses while the energy of the system drops to 10% of its initial
value (Given, ln 10=2.302)
1)34.4 s 2)12.2 s 3)24.4 s 4)8.9 s

2. For the damped oscillation shown in the figure, m  250 g , k  340 Nm 1 and b  70 g s 1
(Given ln 2  0.693 ).The period of motion is

1)0.14 s 2)0.17 s 3) 0.54 s 4) 0.74 s


3. Find the limiting values of amplitude of a forced damped oscillator, when
 i  d  0 and  ii  d  0
F F 2F F
1) , 2) ,
m02 b
2 m02 b
2
md d2    2md d2   
m m
F F F F
3) , 4) ,
2m02  2 2m02 b
2
2 b 2md d2   
md 2 d    
  m   m

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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
4. A uniform disc of mass m and radius R is pivoted smoothly at P. If a uniform thin ring of
mass m and radius R is welded at the lowest point of the disc, find the period of SHM of the
system (disc+ ring)
p

m R

m
R

23R 23R  23R 23R


1)  2) 2 3) 4) 2
2g g 2 2g 2g

5. In the arrangement shown spring, pulleys, strings are ideal. The natural frequency of the
system for vertical oscillations is

1 8k 2 k 1 2k 2 2k
1) 2) 3) 4)
2 m  m 2 m  m
6. A screw gauge having 100 equal divisions and a pitch of length 1 mm is used to measure the
diameter of a wire of length 5.6cm.The main scale reading is 1 mm and 47th circular division
coincides with the main scale. The curved surface area of the wire to the approximate
significant figures is

1) 2.6cm2 2) 2.587cm2 3) 2.58cm2 4) 2.5872cm2


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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
7. Among the following, the figure which represents damped harmonic motion is

1) i and ii 2)iii and iv 3) i, ii,iii and iv 4) i and iv


8. A uniform semicircular ring having mass m and radius r is having at one of its ends freely as
shown in the given figure. The ring is slightly disturbed so that it oscillates in its own plane.
The time period of oscillation of the ring is

r r r 2r
1) 2 2) 2 3) 2 4) 2
 1  1 1 1
g 1    4 2  2 2  4 2
 2  g 1  2  g 1  2  g 1  2 
        
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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
9. A solid uniform cylinder of mass m performs small oscillations in horizontal plane. If
slightly displaced from its mean position shown in the figure. Initially springs are in natural
lengths and cylinder does not slip on ground during oscillations due to friction between
ground and cylinder. Force constant of each spring is k .The time period of oscillations are

k k

3m  3m  3m m
1)  2) 3) 4) 2
k 4 k 2 k 2k
10. An air chamber of volume V, has a long neck of cross-sectional area A.A ball of mass m is
fitted smoothly in the neck. The bulk modulus of air is B. If the ball is pressed down slightly
and released, the time period of its oscillation is
mV 2mV mV  m
1) 2 2)  3) 2 4)
2 BA2 BA2 BA2 2 BA2
11. Statement-I: If a hole were drilled through the centre of earth, i.e along the diameter and a
ball is dropped into the hole at one end, it will not get out of the other end of the hole.
Statement-II: It will execute SHM and will be seen at the other end after 43.2 min from the
time it is dropped
1) Both statement-I and statement II are correct and statement II is the correct explanation of
statement I
2) Both Statement- I and statement II are correct but statement II is not the correct
explanation of statement I
3) Statement I is correct but statement II is incorrect
4) Statement II is correct but statement I is incorrect

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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
12. Statement-I: The bob of a simple pendulum is a hollow ball full of water. If a fine hole is
made at the bottom of the ball, then the time period will vary till the ball gets empty and then
becomes constant
Statement-II: The time period of simple pendulum does not depend on the mass of the bob.
1) Both statement-I and statement II are correct and statement II is the correct explanation of
statement I
2) Both statement-I and statement II are correct but statement II is not the correct
explanation of statement I
3) Statement I is correct but statement II is incorrect
4) Statement II is correct but statement I is incorrect
13. Block A is released on the circular track of bigger block B from rest from the position as
shown in figure.Friction in absent everywhere. Choose the correct statement

1) Acceleration of center of mass of A and B is zero initially


2) When A reaches Q acceleration of centre of mass of A and B is zero
3) Normal force of the ground on the wedge is greater than combined weight of A and B.
when A reaches at point Q
4) Acceleration of B is maximum when A reaches Q
14. A U-shaped wire has a semicircular bending between A and B as shown in figure. A bead of
mass m moving with uniform speed v through a wire enters the semicircular bend at A and
leaves at B with velocity v/2 after time T. The average force exerted by the bead on the part
AB of the wire is

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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
v

A
d
B

3mv 3mv mv
1)0 2) 3) 4)
2T T T
15. In an experiment with a beam balance, an unknown mass m is balanced by two known
masses of 16 kg and 4 kg as shown in figure. The value of the unknown mass m is___
l1 l2 l1 l2

m m
32kg 8kg

1)10 kg 2)6 kg 3)16 kg 4)12kg


16. A uniform triangular plate ABC of mass m and moment of inertia I(about an axis passing
through A and perpendicular to plane of the plate) can rotate freely in the vertical plane
about point ‘A’ as shown in figure. The plate is released from the position shown in the
figure. Line AB is horizontal. The acceleration of centre of mass just after the release of
plane is
A a B

a a

mga 2 mga 2 mga 2 mga 2


1) 2) 3) 4)
3I 4I 2 3I 3I
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17. A disc of mass M and radius R rolls without slipping on a horizontal surface. If the velocity
of its centre is v0 , then the total angular momentum of the disc about a fixed point P at a
height 3/2R above the centre C
P

(3/2)R

v2

1) increases continuously as the disc moves away


2) decreases continuously as the disc moves away
3) is equal to 2MRv0
4) is equal to MRv0
18. Statement-I: The phase difference of two light waves change if they travel through different
media having same thickness, but different indices of refraction.
Statement-2: The wavelengths of waves are different in different media
In the light of the above statements, choose the most appropriate answer from the options
given below.
1) Both statement-I and statement II are correct and statement II is the correct explanation of
statement I
2) Both statement- I and statement II are correct but statement II is not the correct
explanation of statement I
3) Statement I is correct but statement II is incorrect
4) Statement II is correct but statement I is incorrect

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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
19. Eight identical droplets, each falling under gravity in the earth’s atmosphere with terminal
velocity v, combine to form a single drop. The terminal velocity of single drop and drag
force on it are calculated. Find the correct statement from the following.
a) Final terminal velocity is 4v
b) Final terminal velocity is 8v
c) Drag force is increased to four times.
d) Drag force is increased to eight times
1) a,d are correct 2) a,c are correct
3) b, d are correct 4) b,c are correct
20. Choose the correct statement(s):
a) All quantities may be represented dimensionally in terms of the base quantities.
b) A base quantity cannot be represented dimensionally in terms of the rest of the base
quantities.
c) The dimension of a base quantity in other base quantities is always zero.
d) The dimension of a derived quantity is never zero in any base quantity.
1) a, d are correct 2) a, b, c are correct
3) a,b,c, d are correct 4) b,c are correct
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. A cylindrical container having area of cross-section equal to 4A contains a non- viscous
liquid of density 2  .A cylindrical block of wood having cross sectional area A and length L
has density  , held vertically with its lower surface touching the liquid. Now it is released
from this position. Assume that the depth of the container is sufficient and the cylinder does
not touch the bottom.

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3L
The amplitude of oscillation of the wooden cylinder is .Then n is____
n
22. A mass of 4 kg oscillates on a spring with force constant 100 N/m. By what percent does the
frequency of oscillation decrease when a damping force with constant b=24 is introduced?

23. A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1m and
its cross-sectional area is 4.9  107 m 2 .If the mass is pulled a little in the vertically
downward direction and released, it performs simple harmonic motion of angular frequency
210 rad s 1 .If the Young’s modules of the material of the wire is n  109 Nm2 , the value of
n is_____
24. A load of 10 kN is supported from a pulley which in turn is supported by a rope of cross-

sectional area103 mm2 and modulus of elasticity103 Nmm2 ,as shown in figure. Neglecting
the friction at the pulley, Then deflection of the load in millimeter___

1200mm

800mm

10kN

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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
25. A space 2.5 cm wide between two large plane surfaces is filled with oil. Force required to
drag a very thin plate of area 0.5 m2 just midway the surface at a speed of 0.5 ms 1 is
1N.Find the coefficient of viscosity of oil (in 103 kg  m 1s 1 )

26. In the figure shown, the heavy cylinder(radius R) resting on a smooth surface separates two
x
liquids of densities 2  and 3 .The height ‘h’ for the equilibrium of cylinder is R. Then
2
x is_____

27. A 16 cm long capillary cube dipped in water. The water rises up to 8 cm. If the entire
arrangement is put in a freely falling elevator, the length of the water column in the capillary
tube will be in cm____
28. The radius of curvature of each surface of a convex lens having refractive index 1.6 to 20
cm. The lens is now immersed in a liquid of refractive index1.5.The ratio of power of lens in
air to its power in the liquid will be x:1. The value of x is_______
29. For a specific wavelength 700nm of light coming from a galaxy moving with velocity v, the
observed wavelength is 700.7 nm. The value of v is in x  105 m / s then x is___
30. The displacement of a damped harmonic oscillator is given by x  t   e 0.1t cos 10 t   
.here t is in seconds. The time taken in seconds for its amplitude of vibration to drop to 1/4th
of its initial value is close to____( ln 2  0.693 )

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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
Na / liq NH3 cold AlK KMnO4
31. CH 3  C  C  CH 3   X  Y . X & Y respectively are.
1) X: Cis 2-Butene Y: meso 2, 3-Butanediol
2) X: Cis 2-Butene Y: Recimic mixture of 2, 3-Butanediol
3) X: Trans – 2- Butene : Y: Meso 2, 3-Butanediol
4) X: Trans – 2 Butene : Y: Recimic mixture of 2, 3- Butanediol
32.
O

CH 3  C  Cl / AlCl3
(1eq)
B(Aromatic compound)
2) Zn-Hg / HCl
3) KMnO4 / H 
1) Compound B gives positive tollen’s test.
2) Compound B gives CO2 gas with Aq NaHCO3
3) Compound B gives ceric ammonium nitrate test
4) Compound B converts red litmus to blue
33. Assertion (A): Cyanide ion is a ambident nucleophile
Reason (R): Structure of Cyanide group is a resonance hybrid of two contributing structures
  
C  N : C  N 
 
1) Assertion and Reason are correct and Reason is correct explanation of Assertion
2) Assertion is wrong & Reason is correct
3) Assertion & Reason wrong
4) Assertion is correct & Reason is wrong
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Br2 in A + B
Anisole
34. ethanoic acid major minor
1) A: p- Bromoanisole 2) A: o- Bromoanisole
3) A: m –Bromoanisole 4) B: p –Bromoanisole
CH 3 O
NaOH Cl
CH 3  CH  C  C  CH 3 
2
A B
35.
B can be used in Reimer – Tiemann reaction then A is
OH Cl O
CH 3  CH  C  C  O Na  CH 3 O

CH 3 CH 3  CH  C  C  O Na 
1) 2)
Cl Cl O Cl OH O

CH 3  CH  C  C  O Na  CH 3  CH  C  C  O Na 

CH 3 CH 3
3) 4)
O
R  C  O Na   H O 
Electrolysis
R  R  CO  H  NaOH
36. Assertion(A): 2 2 2

Reason(R): Carbocation is the intermediate in Kolbe’s electrolysis


1) Assertion and Reason are correct and Reason is correct explanation of Assertion
2) Assertion is wrong & Reason is correct
3) Assertion & Reason wrong
4) Assertion is correct & Reason is wrong
37. Arrange the following labelled hydrogens in decreasing order of acidity
(I)
NO2
OH

COOH (III)
OH
(II)

1) I > II > III 2) II > III > I 3) III > II > I 4) I > III > II
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38. Assertion(A): Sucrose is a disaccharide and a non reducing sugar
Reason (R): In Sucrose molecule glycosidic linkage is present between C1 of  - fructose
and C2 of  – Glucose
1) Assertion and Reason are correct and Reason is the correct explanation of Assertion
2) Assertion is wrong & Reason is correct
3) Assertion & Reason wrong
4) Assertion is correct & Reason is wrong
39. Statement I: Permanent hardness is due to presence of MgCl2 , CaCl2 , MgSO4 & CaSO4 in
water
Statement II: Permanent hardness is removed by boiling of water
1) Statement I & Statement II both are correct
2) Statement I is correct & Statement II is wrong
3) Statement I is wrong & Statement II is correct
4) Statement I & Statement II both are wrong
40. Which of the following statements is incorrect regarding the importance of coordination
compounds in biological systems?
1) Vitamin B12 used to prevent anaemia is a complex compound of zinc
2) Haemoglobin is the red pigment of blood and contains iron.
3) Chlorophyll is the green pigment of plants and contains magnesium
4) All are correct
41. Which of the following ion(s) is/are act(s) as good oxidant(s).?


i) V 2 E 
M 2 / M
 1.18volts  
ii) Mn3 E 
M 3 / M 2 
 1.57volts 

iii) Cr 2 E 
M 2 / M
 0.91volts 
1) i and iii 2) only ii 3) ii and iii 4) only iii

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42. Match the columns
Column – I Column – II
(Ion)  (Magnetic moment)

a) Ti 2 p) 2.84B.M

b) Zn 2 q) 5.92B.M

c) Mn 2 r) 0B.M

d) Cr 2 s) 4.90 B.M
1) a – (s), b – (p), c – (q), d – (r). 2) a – (r), b – (p), c – (q), d – (s).
3) a – (p), b – (r), c – (q), d – (s) 4) a – (p), b – (s), c – (q), d – (r).
43. Assertion(A): Transition metals are good catalysts
Reason(R): V2O5 or Pt is used in the preparation of H 2 SO4 by contact process
1) Assertion is correct, Reason is correct; reason is a correct explanation for Assertion
2) Assertion is correct, Reason is correct; reason is not a correct explanation for Assertion
3) Assertion is correct, Reason is incorrect
4) Assertion is incorrect, Reason is correct
44. Why is HCl not used to make the medium acidic in oxidation reactions of KMnO4 in acidic
medium?
1) Both HCl and KMnO4 act as oxidizing agents
2) KMnO4 oxidises HCl into Cl2 which is also an oxidizing agent
3) KMnO4 is a weaker oxidizing agent than HCl
4) KMnO4 acts as a reducing agent in the presence of HCl

45. In Cr2O72  structure number of Cr  O  Cr bonds ….?


1) 1 2) 2 3) 4 4) 0

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46. Assertion(A): Tetrahedral complexes having two different types of unidentate ligands
(without consideration of stereo center in ligands) coordinated with central metal ion will
show geometrical isomerism.
Reason (R): Geometrical isomerism arises in homoleptic complexes due to different
possible geometric arrangement of the ligands.
1) Assertion and Reason are correct and Reason is the correct explanation of Assertion
2) Assertion is wrong & Reason is correct
3) Assertion & Reason wrong
4) Assertion is correct & Reason is wrong

47. Cr  H 2O   Cl3  at no.of Cr = 24  has a magnetic moment of 3.83 B.M. The correct
 6

distribution of 3d electrons in the chromium present in the complex is


1) 3d xy ,3d yz ,3d zx 2) 3d xy ,3d yz ,3d 2
z
3) 3d
 x2  y2  ,3d z 2 ,3d xz 4) 3d xy ,3d
 x2  y2  ,3d yz
48. The colour of the coordination compounds depends on the crystal filed splitting. What will
be correct order of absorption of wavelength of light in the visible region, for the complexes,
3 3 3
Co  NH 3   , Co  CN 6  , Co  H 2O 6  ?
 6
3 3 3
1) Co  CN 6   Co  NH 3 6   Co  H 2O 6 
3 3 3
2) Co  NH 3 6   Co  H 2O 6   Co  CN 6 
3 3 3
3) Co  H 2O 6   Co  NH 3 6   Co  CN 6 
3 3 3
4) Co  NH 3 6   Co  CN 6   Co  H 2O 6 

49. IUPAC name of  Pt  NH 3 2 Cl  NO2   is

1) platinumdiamminechloronitrate
2) chloronitrito – N- ammineplatinum (II)
3) diamminechloridonitrito – N- platinum (II)
4) diamminechloronitrate – N – palatinate (II)
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50. Among the following molecules/ions C22 , N 22 , O22 , O2 which is diamagnetic and has
shortest bond length.

1) C22  2) N 22  3) O2 4) O22 
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.

51. The EAN of Fe in K 4  Fe  CN 6  is ____


52. The number of unpaired electrons present in central metal atom of
Ni  CO 4 complex is ____
3
53.  Fe  CN   should be an inner orbital complex Ignoring the pairing energy, the value of
 6
crystal field stabilization energy for this complex is (-) ________  0 .(Nearest integer)
54. Total number of acidic oxides among the given ones are
N 2O3 , NO2 , N 2O, Cl2O7 , SO2 , CaO, Na2O & NO
55. How many following are obtained in thermal decomposition of LiNO3
Li2O, N 2 , O2 , LiNO2 , NO2
56. How many of the following polymers are polyesters.
Dacron, nylon 6.6,Nylon – 6, Glyptal, PHBV, Bakelite
57. Which of the following oxo acids of halogens do not exist?
HOCl , HOBr , HFO2 , HClO2 , HBrO2 , HIO2 , HFO3 , HClO3.
58. In pyrophosphoric acid
Number of P – OH bonds – x
Number of P = O bonds – y
Number of P – O – P bonds – z
Then x + y + z = ?
59. In Co2  CO 8 number of bridged CO ligands …..?

60. Acidified potassium dichromate reacts with potassium iodide and oxides it to I2. The
oxidation state of Chromium in the products of the reaction is _____

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MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
f b 
61. If f  x  is monotonic and differentiable function, then   
2 x b  f 1  x  dx 
f a

 
b b
1)  f 2
 x  dx 2)  f 2  x   f 2  a  dx
a a

   
b b
3)  f 2  x   f 2  b  dx 4)  f 2  x   f 2  b  dx
a a
62. Through the point P  3,4  a pair of perpendicular lines are drawn which meet x-axis at the
points A and B. The locus of incentre of triangle PAB is
1) x 2  y 2  6 x  8 y  25  0 2) x 2  y 2  6 x  8 y  25  0
3) x 2  y 2  6 x  8 y  25  0 4) x 2  y 2  6 x  8 y  25  0

63. If A is skew-symmetric matrix of order 2 and B,C are matrices 12 94  ,  92 14 respectively,
   

   
then A3  BC   A5 B 2C 2  A7 B3C 3  ...... A2n 1 B nC n , is  
1) a symmetric matrix 2) a skew-symmetric matrix
3) an identity matrix 4) idempotent matrix
64. Statement-I: The shortest distance between the lines x  y  z and
1
2 x  y  z  1  0  3 x  y  2 z  2 is
2
x2 y 1 z
Statement-II: Perpendiculars are drawn from points on the line   to the plane
2 1 3
x  4 y  13 z  12
x  y  z  3 .The feet of perpendiculars lie on the line  
4 14 10
1) S-1 false, S-II is true 2)S-I true, S-II true
3)S-I true, S-II is false 4)S-I false, S-II false

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65. If two circles x  y  6 x  6 y  13  0 and x 2  y 2  8 y  9  0 intersects at A and B. The focus of
2 2

the parabola whose directrix is line AB and vertex at (0,0) is__

1)  ,  2)  ,   3)   ,   4)   , 
3 1 3 1 3 1 3 1
 5 5  5 5  5 5  5 5

66. The point P on the parabola y 2  16 x for which PR  PQ is maximum, where

R   4,0  , Q   0,4  is ___

1)  4,8 2)  4, 8  3) 16,16  4) 16, 16 

67. The tangent to the circle x 2  y 2  4 at a point P intersect the parabola y 2  4 x at point Q
and R. Tangents to the parabola at Q and R intersect at S. If Q lies in the first quadrant such
that PQ=1 unit, then 16(area of SQR ) is
1) 21 2) 49 3) 63 4) 343

68. TP and TQ are tangents to parabola y 2  8 x and normal at P and Q intersect at a point R on
the parabola. The locus of circumcentre of TPQ is a parabola whose

1) Vertex is  2,1
7 
2) Foot of perpendicular from focus on the directrix is  ,0 
4 
3) Length of latus rectum is 4
9 
4) Focus is  ,0 
2 

69. Let P and Q be distinct points on the parabola y 2  2 x such that a circle with PQ as
diameter passes through the vertex O of the parabola. If P lies in the first quadrant and the
area of triangle OPQ is 3 2 , then P can be___


1) 4,2 2  
2) 9,3 2  1 1 
3)  ,
4 2
 4)  2,2 

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70.  
If the function f  x   x3  3  a  7  x 2  3 a 2  9 x  1 has a point of maximum at positive
value of x then
 29 
1) a   ,  2) a   ,7 
 7 
 29 
3) a   , 3   3,  4) a   3,     , 3
 7 
71. If 2 p 2  3q 2  4 pq  p  0 and a variable line px  qy  1 always touches a parabola whose
axis is parallel to X-axis, then equation of the parabola is____
2 2
1)  y  4   24  x  2  2)  y  3  12  x  1
2 2
3)  y  4   12  x  2  4)  y  2   24  x  4 
72. Let P be the plane 3 x  2 y  3 z  16 and let
 7
S   iˆ   ˆj   kˆ; 2   2   2  1and the distanceof  ,  ,   from the plane P is  .Let
 2
        
u , v and be three distinct vectors in S such that u  v  v      u .Let V be the
  
volume of the parallelopiped determined by vectors u , v and  .Then the value of V is_____
9 3 9 3 3 3
1) 2) 3) 4)
16 16 16 16
dx 2
73. Let f  x    ,x .If f  0   0 then f 1  ____
3  4 x2  4  3x 2 3

1  3  1  3 
1) tan 1    2) tan 1   
5 3  5  10 3 5 3  5  10 3
1  3  1 1  3  
3) tan 1    4) tan   
2 3  2  10 3 2 3  2  10 3
74. Let four circles having radii r1  5 units , r2  5 , r3  8 units and r4 units are mutually,
touching each other externally, then r4 
9 8 7 8
1) 2) 3) 4)
8 7 8 9
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75. The base BC of ABC passes through the point P(1,1) and its sides AB and AC are bisected
at right angles by x  y  0 and x  2 y  0 .The locus of vertex A is a circle with radius r then
5
 ____
r
1) 3 2)4 3)5 4)6
76.  
Statement-1: The sum of algebraic distances from the points n, n2 , where
n  1, 2,3,......2023 to a variable straight line is zero and if such a line always passes through
the point  ,   then     1366200
Statement-2: If sum of algebraic distances from the points  xi , yi   i  1,2,3........n to a
 n n 
variable straight line is zero then that the line passes through the point   xi ,  yi 
 
 i 1 i 1 
1) Statement 1 is correct and statement 2 is incorrect
2) Statement 1 is incorrect and statement 2 is correct
3) Statement 1 is incorrect and statement 2 is incorrect
4) Statement 1 is correct and statement 2 is correct
  1  cos 2  3 x    sin 3  4 x   
77. Statement-I: lim      is equal to 18
x 0   cos3  4 x    log  2 x  15  
  e 
Statement-II: Let k and m be positive real numbers such that the function
 2 f ' 8 309
f  x   3 x 2  k 2 x  1, 0  x  1 is differentiable for all x>0.Then is equal to
mx  k , x 1 1 8
f ' 
8
1) S-1 false, S-II is true 2) S-I true, S-II true
3) S-I true, S-II is false 4) S-I false, S-II false

78. The circle lying in the first quadrant whose centre lies on the curve y  2 x 2  27 is tangent to
4 x  3 y  0 and the y-axis then the diameter of the circle is____
1)6 2) 7 3) 8 4)9

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79. Let A  4, 2  and B  0,1 be two points on the parabola, normals at which intersect at the
 16 7 
point P(2,2) then equation of directrix is y  k  0 and focus of parabola is  ,  .then
 l l 
k  l is_____
1)6 2)7 3)8 4)9
80. If focus of the parabola which touches x  0, y  0, x  y  1  0 and 2 x  y  8  0 is

 ,   ,then is_____

1)2 2)3 3)4 4)5
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. In a regular tetrahedron, let  be the angle between any edge and a face not containing the

where a, b  I  also a and b are co-prime, then the value of


a
edge. If cos 2  
b
5
10a  b   ___
13

x2  y 2  1
.If y 1  1 then  y  2   is___
2
82. Let the slope of tangent to a curve y  f  x  be
2 xy

83. If Q,S are two points on the circle x 2  y 2  4 such that tangents QP, SR are parallel. If
2 2
 QT   ST 
PS,QR intersect at T on the circumference of the circle, then      PQ.RS
 PQ   RS 
=_____
84. The locus of the centroid of triangle PSQ, where PQ is any chord of the parabola

y 2  8  x  2  subtending right angle at the vertex and ‘S’ be its focus is also a parabola


whose latus rectum is equal to , then number of positive divisors of ‘  ’ is_____
3

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85. Equation of a circle which touches the line x  y  5 at the point  2,7  and cuts the circle

x 2  y 2  4 x  6 y  9  0 orthogonally is x 2  y 2  ax  by  c  0 , then a  4b  c  ____

a bc cb
86. If a  c b c  a  0 , the line ax  by  c  0 passes through the fixed point  h, k  then
ab a b c

h  k is___

87. Number of integers in domain of function f  x   log  2   4  x   log 2


x  x  (where . is
 

G.I.F and 
. is fractional part function of x) is____

The length of the latus rectum of the parabola 169  x  1   y  3    5 x  12 y  17  is l then
2 2 2
88.

26 l is ___

89. The number of different normal’s that can be drawn from  2,1 to the parabola

y 2  4 x  2 y  3  0 is___

90. The area bounded by the curve x  y 2  1 and the line y  x  5 is A then 12A  _____

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