14-10-2023 SR - Super60 Nucleus & Sterling BT Jee-Main-Rptm-11 Q.paper
14-10-2023 SR - Super60 Nucleus & Sterling BT Jee-Main-Rptm-11 Q.paper
14-10-2023 SR - Super60 Nucleus & Sterling BT Jee-Main-Rptm-11 Q.paper
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Marking scheme: +4 for correct answer, 0 if not attempt and ‐1 in all other cases.
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SRI CHAITANYA IIT ACADEMY, INDIA 14‐10‐23_ Sr.Super60_ NUCLEUS & STERLING_BT _Jee‐Main_RPTM‐11_Q.P
14‐10‐23_Sr.Super60_ NUCLEUS & STERLING_BT _ Jee‐Main_RPTM‐11_Test Syllabus
PHYSICS : SHM : Forced and damped oscillation (in one dimension),
resonance, Linear and angular simple harmonic motions, SHM in
rigid body systems.
RPTM‐11(15Q‐RPTM.11 SYLLABUS+15Q CUMULATIVE SYLLABUS)
CHEMISTRY : 1.d‐block elements: Introduction; Electronic confugurations;
oxidation states and their stability; standard electrode potentials ;
interstitial compounds ; alloys; Catalytic properties; Ionization
enthalpy; atomic radii; colour; magnetic properties; complex
formation; and applications of d‐block metals and their compounds
2.Compounds of Cr and Mn: Preparation,Structure and reactions of
oxoanions of Chromium and manganese
3.Coordination compounds: Introduction, Definition of important
terms related to co‐ordination compound,types of ligands,IUPAC
Nomenclature, Isomerism (structural),Isomerism
(stereo)(complexes containing ligands with chiral centres not to be
tested),Bonding in coordination compounds ,Werner theory,
Sidgwick theory(EAN concept, 18 electron rule)V.B. theory,Basic
concepts of crystal field theory(J T distortion‐basic idea) ,Bonding in
metal carbonyls, Stability of co‐ordination compounds, Importance
and applications of coordination compounds
RPTM‐11(15Q‐RPTM.11 SYLLABUS+15Q CUMULATIVE SYLLABUS)
MATHEMATICS : Complete Circle & Parabola
RPTM‐11(15Q‐RPTM.11 SYLLABUS+15Q CUMULATIVE SYLLABUS)
2. For the damped oscillation shown in the figure, m 250 g , k 340 Nm 1 and b 70 g s 1
(Given ln 2 0.693 ).The period of motion is
m R
m
R
5. In the arrangement shown spring, pulleys, strings are ideal. The natural frequency of the
system for vertical oscillations is
1 8k 2 k 1 2k 2 2k
1) 2) 3) 4)
2 m m 2 m m
6. A screw gauge having 100 equal divisions and a pitch of length 1 mm is used to measure the
diameter of a wire of length 5.6cm.The main scale reading is 1 mm and 47th circular division
coincides with the main scale. The curved surface area of the wire to the approximate
significant figures is
r r r 2r
1) 2 2) 2 3) 2 4) 2
1 1 1 1
g 1 4 2 2 2 4 2
2 g 1 2 g 1 2 g 1 2
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9. A solid uniform cylinder of mass m performs small oscillations in horizontal plane. If
slightly displaced from its mean position shown in the figure. Initially springs are in natural
lengths and cylinder does not slip on ground during oscillations due to friction between
ground and cylinder. Force constant of each spring is k .The time period of oscillations are
k k
3m 3m 3m m
1) 2) 3) 4) 2
k 4 k 2 k 2k
10. An air chamber of volume V, has a long neck of cross-sectional area A.A ball of mass m is
fitted smoothly in the neck. The bulk modulus of air is B. If the ball is pressed down slightly
and released, the time period of its oscillation is
mV 2mV mV m
1) 2 2) 3) 2 4)
2 BA2 BA2 BA2 2 BA2
11. Statement-I: If a hole were drilled through the centre of earth, i.e along the diameter and a
ball is dropped into the hole at one end, it will not get out of the other end of the hole.
Statement-II: It will execute SHM and will be seen at the other end after 43.2 min from the
time it is dropped
1) Both statement-I and statement II are correct and statement II is the correct explanation of
statement I
2) Both Statement- I and statement II are correct but statement II is not the correct
explanation of statement I
3) Statement I is correct but statement II is incorrect
4) Statement II is correct but statement I is incorrect
A
d
B
3mv 3mv mv
1)0 2) 3) 4)
2T T T
15. In an experiment with a beam balance, an unknown mass m is balanced by two known
masses of 16 kg and 4 kg as shown in figure. The value of the unknown mass m is___
l1 l2 l1 l2
m m
32kg 8kg
a a
(3/2)R
v2
3L
The amplitude of oscillation of the wooden cylinder is .Then n is____
n
22. A mass of 4 kg oscillates on a spring with force constant 100 N/m. By what percent does the
frequency of oscillation decrease when a damping force with constant b=24 is introduced?
23. A 0.1 kg mass is suspended from a wire of negligible mass. The length of the wire is 1m and
its cross-sectional area is 4.9 107 m 2 .If the mass is pulled a little in the vertically
downward direction and released, it performs simple harmonic motion of angular frequency
210 rad s 1 .If the Young’s modules of the material of the wire is n 109 Nm2 , the value of
n is_____
24. A load of 10 kN is supported from a pulley which in turn is supported by a rope of cross-
sectional area103 mm2 and modulus of elasticity103 Nmm2 ,as shown in figure. Neglecting
the friction at the pulley, Then deflection of the load in millimeter___
1200mm
800mm
10kN
26. In the figure shown, the heavy cylinder(radius R) resting on a smooth surface separates two
x
liquids of densities 2 and 3 .The height ‘h’ for the equilibrium of cylinder is R. Then
2
x is_____
27. A 16 cm long capillary cube dipped in water. The water rises up to 8 cm. If the entire
arrangement is put in a freely falling elevator, the length of the water column in the capillary
tube will be in cm____
28. The radius of curvature of each surface of a convex lens having refractive index 1.6 to 20
cm. The lens is now immersed in a liquid of refractive index1.5.The ratio of power of lens in
air to its power in the liquid will be x:1. The value of x is_______
29. For a specific wavelength 700nm of light coming from a galaxy moving with velocity v, the
observed wavelength is 700.7 nm. The value of v is in x 105 m / s then x is___
30. The displacement of a damped harmonic oscillator is given by x t e 0.1t cos 10 t
.here t is in seconds. The time taken in seconds for its amplitude of vibration to drop to 1/4th
of its initial value is close to____( ln 2 0.693 )
CH 3 C Cl / AlCl3
(1eq)
B(Aromatic compound)
2) Zn-Hg / HCl
3) KMnO4 / H
1) Compound B gives positive tollen’s test.
2) Compound B gives CO2 gas with Aq NaHCO3
3) Compound B gives ceric ammonium nitrate test
4) Compound B converts red litmus to blue
33. Assertion (A): Cyanide ion is a ambident nucleophile
Reason (R): Structure of Cyanide group is a resonance hybrid of two contributing structures
C N : C N
1) Assertion and Reason are correct and Reason is correct explanation of Assertion
2) Assertion is wrong & Reason is correct
3) Assertion & Reason wrong
4) Assertion is correct & Reason is wrong
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Br2 in A + B
Anisole
34. ethanoic acid major minor
1) A: p- Bromoanisole 2) A: o- Bromoanisole
3) A: m –Bromoanisole 4) B: p –Bromoanisole
CH 3 O
NaOH Cl
CH 3 CH C C CH 3
2
A B
35.
B can be used in Reimer – Tiemann reaction then A is
OH Cl O
CH 3 CH C C O Na CH 3 O
CH 3 CH 3 CH C C O Na
1) 2)
Cl Cl O Cl OH O
CH 3 CH C C O Na CH 3 CH C C O Na
CH 3 CH 3
3) 4)
O
R C O Na H O
Electrolysis
R R CO H NaOH
36. Assertion(A): 2 2 2
COOH (III)
OH
(II)
1) I > II > III 2) II > III > I 3) III > II > I 4) I > III > II
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38. Assertion(A): Sucrose is a disaccharide and a non reducing sugar
Reason (R): In Sucrose molecule glycosidic linkage is present between C1 of - fructose
and C2 of – Glucose
1) Assertion and Reason are correct and Reason is the correct explanation of Assertion
2) Assertion is wrong & Reason is correct
3) Assertion & Reason wrong
4) Assertion is correct & Reason is wrong
39. Statement I: Permanent hardness is due to presence of MgCl2 , CaCl2 , MgSO4 & CaSO4 in
water
Statement II: Permanent hardness is removed by boiling of water
1) Statement I & Statement II both are correct
2) Statement I is correct & Statement II is wrong
3) Statement I is wrong & Statement II is correct
4) Statement I & Statement II both are wrong
40. Which of the following statements is incorrect regarding the importance of coordination
compounds in biological systems?
1) Vitamin B12 used to prevent anaemia is a complex compound of zinc
2) Haemoglobin is the red pigment of blood and contains iron.
3) Chlorophyll is the green pigment of plants and contains magnesium
4) All are correct
41. Which of the following ion(s) is/are act(s) as good oxidant(s).?
i) V 2 E
M 2 / M
1.18volts
ii) Mn3 E
M 3 / M 2
1.57volts
iii) Cr 2 E
M 2 / M
0.91volts
1) i and iii 2) only ii 3) ii and iii 4) only iii
a) Ti 2 p) 2.84B.M
b) Zn 2 q) 5.92B.M
c) Mn 2 r) 0B.M
d) Cr 2 s) 4.90 B.M
1) a – (s), b – (p), c – (q), d – (r). 2) a – (r), b – (p), c – (q), d – (s).
3) a – (p), b – (r), c – (q), d – (s) 4) a – (p), b – (s), c – (q), d – (r).
43. Assertion(A): Transition metals are good catalysts
Reason(R): V2O5 or Pt is used in the preparation of H 2 SO4 by contact process
1) Assertion is correct, Reason is correct; reason is a correct explanation for Assertion
2) Assertion is correct, Reason is correct; reason is not a correct explanation for Assertion
3) Assertion is correct, Reason is incorrect
4) Assertion is incorrect, Reason is correct
44. Why is HCl not used to make the medium acidic in oxidation reactions of KMnO4 in acidic
medium?
1) Both HCl and KMnO4 act as oxidizing agents
2) KMnO4 oxidises HCl into Cl2 which is also an oxidizing agent
3) KMnO4 is a weaker oxidizing agent than HCl
4) KMnO4 acts as a reducing agent in the presence of HCl
47. Cr H 2O Cl3 at no.of Cr = 24 has a magnetic moment of 3.83 B.M. The correct
6
1) platinumdiamminechloronitrate
2) chloronitrito – N- ammineplatinum (II)
3) diamminechloridonitrito – N- platinum (II)
4) diamminechloronitrate – N – palatinate (II)
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50. Among the following molecules/ions C22 , N 22 , O22 , O2 which is diamagnetic and has
shortest bond length.
1) C22 2) N 22 3) O2 4) O22
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
60. Acidified potassium dichromate reacts with potassium iodide and oxides it to I2. The
oxidation state of Chromium in the products of the reaction is _____
b b
1) f 2
x dx 2) f 2 x f 2 a dx
a a
b b
3) f 2 x f 2 b dx 4) f 2 x f 2 b dx
a a
62. Through the point P 3,4 a pair of perpendicular lines are drawn which meet x-axis at the
points A and B. The locus of incentre of triangle PAB is
1) x 2 y 2 6 x 8 y 25 0 2) x 2 y 2 6 x 8 y 25 0
3) x 2 y 2 6 x 8 y 25 0 4) x 2 y 2 6 x 8 y 25 0
63. If A is skew-symmetric matrix of order 2 and B,C are matrices 12 94 , 92 14 respectively,
then A3 BC A5 B 2C 2 A7 B3C 3 ...... A2n 1 B nC n , is
1) a symmetric matrix 2) a skew-symmetric matrix
3) an identity matrix 4) idempotent matrix
64. Statement-I: The shortest distance between the lines x y z and
1
2 x y z 1 0 3 x y 2 z 2 is
2
x2 y 1 z
Statement-II: Perpendiculars are drawn from points on the line to the plane
2 1 3
x 4 y 13 z 12
x y z 3 .The feet of perpendiculars lie on the line
4 14 10
1) S-1 false, S-II is true 2)S-I true, S-II true
3)S-I true, S-II is false 4)S-I false, S-II false
1) , 2) , 3) , 4) ,
3 1 3 1 3 1 3 1
5 5 5 5 5 5 5 5
67. The tangent to the circle x 2 y 2 4 at a point P intersect the parabola y 2 4 x at point Q
and R. Tangents to the parabola at Q and R intersect at S. If Q lies in the first quadrant such
that PQ=1 unit, then 16(area of SQR ) is
1) 21 2) 49 3) 63 4) 343
68. TP and TQ are tangents to parabola y 2 8 x and normal at P and Q intersect at a point R on
the parabola. The locus of circumcentre of TPQ is a parabola whose
1) Vertex is 2,1
7
2) Foot of perpendicular from focus on the directrix is ,0
4
3) Length of latus rectum is 4
9
4) Focus is ,0
2
69. Let P and Q be distinct points on the parabola y 2 2 x such that a circle with PQ as
diameter passes through the vertex O of the parabola. If P lies in the first quadrant and the
area of triangle OPQ is 3 2 , then P can be___
1) 4,2 2
2) 9,3 2 1 1
3) ,
4 2
4) 2,2
70.
If the function f x x3 3 a 7 x 2 3 a 2 9 x 1 has a point of maximum at positive
value of x then
29
1) a , 2) a ,7
7
29
3) a , 3 3, 4) a 3, , 3
7
71. If 2 p 2 3q 2 4 pq p 0 and a variable line px qy 1 always touches a parabola whose
axis is parallel to X-axis, then equation of the parabola is____
2 2
1) y 4 24 x 2 2) y 3 12 x 1
2 2
3) y 4 12 x 2 4) y 2 24 x 4
72. Let P be the plane 3 x 2 y 3 z 16 and let
7
S iˆ ˆj kˆ; 2 2 2 1and the distanceof , , from the plane P is .Let
2
u , v and be three distinct vectors in S such that u v v u .Let V be the
volume of the parallelopiped determined by vectors u , v and .Then the value of V is_____
9 3 9 3 3 3
1) 2) 3) 4)
16 16 16 16
dx 2
73. Let f x ,x .If f 0 0 then f 1 ____
3 4 x2 4 3x 2 3
1 3 1 3
1) tan 1 2) tan 1
5 3 5 10 3 5 3 5 10 3
1 3 1 1 3
3) tan 1 4) tan
2 3 2 10 3 2 3 2 10 3
74. Let four circles having radii r1 5 units , r2 5 , r3 8 units and r4 units are mutually,
touching each other externally, then r4
9 8 7 8
1) 2) 3) 4)
8 7 8 9
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75. The base BC of ABC passes through the point P(1,1) and its sides AB and AC are bisected
at right angles by x y 0 and x 2 y 0 .The locus of vertex A is a circle with radius r then
5
____
r
1) 3 2)4 3)5 4)6
76.
Statement-1: The sum of algebraic distances from the points n, n2 , where
n 1, 2,3,......2023 to a variable straight line is zero and if such a line always passes through
the point , then 1366200
Statement-2: If sum of algebraic distances from the points xi , yi i 1,2,3........n to a
n n
variable straight line is zero then that the line passes through the point xi , yi
i 1 i 1
1) Statement 1 is correct and statement 2 is incorrect
2) Statement 1 is incorrect and statement 2 is correct
3) Statement 1 is incorrect and statement 2 is incorrect
4) Statement 1 is correct and statement 2 is correct
1 cos 2 3 x sin 3 4 x
77. Statement-I: lim is equal to 18
x 0 cos3 4 x log 2 x 15
e
Statement-II: Let k and m be positive real numbers such that the function
2 f ' 8 309
f x 3 x 2 k 2 x 1, 0 x 1 is differentiable for all x>0.Then is equal to
mx k , x 1 1 8
f '
8
1) S-1 false, S-II is true 2) S-I true, S-II true
3) S-I true, S-II is false 4) S-I false, S-II false
78. The circle lying in the first quadrant whose centre lies on the curve y 2 x 2 27 is tangent to
4 x 3 y 0 and the y-axis then the diameter of the circle is____
1)6 2) 7 3) 8 4)9
x2 y 2 1
.If y 1 1 then y 2 is___
2
82. Let the slope of tangent to a curve y f x be
2 xy
83. If Q,S are two points on the circle x 2 y 2 4 such that tangents QP, SR are parallel. If
2 2
QT ST
PS,QR intersect at T on the circumference of the circle, then PQ.RS
PQ RS
=_____
84. The locus of the centroid of triangle PSQ, where PQ is any chord of the parabola
y 2 8 x 2 subtending right angle at the vertex and ‘S’ be its focus is also a parabola
whose latus rectum is equal to , then number of positive divisors of ‘ ’ is_____
3
a bc cb
86. If a c b c a 0 , the line ax by c 0 passes through the fixed point h, k then
ab a b c
h k is___
G.I.F and
. is fractional part function of x) is____
The length of the latus rectum of the parabola 169 x 1 y 3 5 x 12 y 17 is l then
2 2 2
88.
26 l is ___
89. The number of different normal’s that can be drawn from 2,1 to the parabola
y 2 4 x 2 y 3 0 is___
90. The area bounded by the curve x y 2 1 and the line y x 5 is A then 12A _____