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E5® Internal Cure SDS

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Version 1.0 US/Z8 Revision Date: 12/08/2017

1. IDENTIFICATION

PRODUCT NAME: E5 Internal Cure


Manufacturer Detail
COMPANY NAME: E5 Incorporated
1718 Pleasant Street
Noblesville, IN 46060
Customer Contact: 1-888-881-1726
Email: sales@e5nanosilica.com

Recommended use of the chemical and restrictions on use


Recommended Use: Inorganic binder, surface modifier and flocculating agent.
2. HAZARDS
GHS classification
Not a hazardous substance or mixture.
GHS label elements
Not a hazardous substance or mixture.

Carcinogenicity:
IARC : No ingredient of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA : No component of this product present at levels greater than or equal to 0.1% is on
OSHA’s list of regulated carcinogens.
NTP : No component of this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Common Name : Amorphous Silica, aqueous colloidal solution.
Components
CHEMICAL NAME CAS-No. CONCENTRATION (% w/w)

silicon dioxide 7631-86-9 >= 30 - < 50

Actual concentration is withheld as a trade secret


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4. FIRST AID MEASURES

General advice : No hazards which require special first aid measures.

Inhalation : If breathed in, move person into fresh air. Consult a physician
after significant exposure.

Skin : Take off contaminated clothing and shoes immediately.


Wash the skin immediately with soap and water. If skin
irritation persists, call a physician.

Eye : Rinse with plenty of water. Remove contact lenses. Protect


unharmed eye. Keep eye wide open while rinsing. If eye
irritation persists, consult a specialist.

Oral : Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person.
Obtain medical attention.

Notes to Physician
Symptoms : No information available.
Risks : No information available.
Treatment : Treat symptomatically.

5. FIRE FIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are


appropriate to local circumstances and the
surrounding environment.

Specific hazards during fire fighting : No hazards to be specially mentioned.

Hazardous combustion products : No hazardous combustion products are known

Further information : Standard procedure for chemical fires.

Special protective equipment : In the event of fire, wear self-contained


for firefighters breathing apparatus.

See also Section 9. Physical and chemical properties: Safety data


6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal precautions : No conditions to be specially mentioned.

Emergency measures on
accidental release : Follow safe handling advice and personal
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E5® Internal Cure
Revision Date: 12/08/2017
Version 1.0 US/Z8 Date of Last Issue: - Date of First Issue: -

protective equipment recommendations.

Environmental precautions : No special environmental precautions required.

Methods for cleaning up /


Methods for containment : Wipe up with absorbent material (e.g. cloth,
fleece).
Keep in suitable, closed containers for disposal.
If liquid has been spilt in large quantities clean
up promptly by scoop or vacuum.

Reference to other sections : For disposal considerations see section 13.


For personal protection see section 8.
7. HANDLING AND STORAGE

Advice on protection : Normal measures for preventive fire protection.


against fire and explosion

Advice on safe handling : For personal protection see section 8.


No special handling advice required.

Requirements for storage


areas and containers : Keep container tightly closed in a dry and
well-ventilated place.
Store in closed dark containers made of
anti-corrosive material.

Advice on common storage : No special restrictions on storage with other


products.

Further information on : No decomposition if stored and applied as directed.


storage stability

Minimum storage : Avoid temperatures below: 5 °C (41 °F)


temperature

Maximum storage : 35 °C (95 °F)


Temperature

Other data : No decomposition if stored and applied as directed.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION


Ingredients with workplace control parameters
Components CAS-No. Value Type Control Basis
(Form of Parameter /
exposure) Permissible
Concentration
Silicon Dioxide 7631-86-9 TWA (Dust) 20 Million OSHA Z-3
particles per
cubic foot
(Silica)
Further : a: Based on impinger samples counted by light field techniques.
information mppcf X 35.3 = million particles per cubic meter = particles per
c.c Silica
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TWA (Dust) 80 mg/m3 / OSHA Z-3


%SiO2
(Silica)
Further : Silica
Information
TWA 6 mg/m3 NIOSH REL
(Silica)
Further : Silica
Information
PEL 6 mg/m3
CAL PEL
(Silica)

ACGIH: American Conference of Governmental Industrial Hygienists


BEI: Biological Exposure Index
MAC: Maximum Allowable Concentration
NIOSH: National Institute for Occupational Safety and Health
OEL: OEL: Occupational exposure limit.
STEL: Short term exposure limit
TWA: Time Weighted Average

Substance Name CAS-No. Value Control


Basis
Parameter
Immediately Dangerous to Life 3000 mg/m3 US IDLH
Silicon Dioxide 7631-86-9
or Health Concentration Value

Further Immediately Dangerous to Life or Health Concentrations (IDLH)


information

Appropriate engineering controls


Effective exhaust ventilation system
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment
normally required.

Hand protection : Glove Material: PVC


: Glove Material: Rubber Gloves

Eye protection : Safety glasses

Hygiene measures : General industrial hygiene practice.


Environmental exposure controls
General advice : No special environmental precautions required.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : liquid

Color : clear cloudy

Odor : slight
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Odor Threshold : No data available

pH : 9 - 11

Melting point/range : 0 °C

Boiling point/boiling range : 212 °F / 100 °C

Flash point : Not applicable

Evaporation rate : No data available

Flammability (solid, gas) : Not applicable

Flammability (liquids) : The product is not flammable.

Upper explosion limit / : Not applicable


Upper flammability limit

Lower explosion limit / : Not applicable


Lower flammability limit

Vapor pressure : ca. 23 hPa at 20 °C

Relative vapor density : No data available

Relative density : 1.100 - 1.300

Solubility(ies)
Water solubility : dispersible

Solubility in other solvents : No data available

Partition coefficient : Not applicable


n-octanol/water

Autoignition temperature : Not Applicable

Decomposition temperature : No data available

Viscosity
Viscosity, dynamic : < 50 mPa.s

Viscosity, kinematic : No data available

Explosive properties : Not Explosive

Oxidizing properties : Not classified as oxidizing

This material safety datasheet only contains information relating to safety and does not
replace any product information or product specification
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10. STABILITY AND REACTIVITY
Reactivity : Stable under normal conditions.

Chemical stability : Stable under recommended storage conditions.

Possibility of : No dangerous reaction known under conditions of


hazardous reactions normal use.

Conditions to avoid : Avoid allowing solution to dry as this can lead to a


build-up of dust.

Incompatible materials : Copper


Mild steel
Aluminum

Hazardous : No hazardous decomposition products are known.


decomposition
products

Thermal : No data available


decomposition
11. TOXICOLOGICAL INFORMATION
Hazard Summary
Acute toxicity : Not classified based on available information.
Skin corrosion/irritation: Not classified based on available information.
Serious eye damage/
eye irritation : Not classified based on available information.
Respiratory or
skin sensitization : Skin sensitization Not classified based on available
information.
Respiratory sensitization Not classified based on available
information.
Germ cell mutagenicity : Not classified based on available information.
Carcinogenicity : Not classified based on available information.
Reproductive toxicity : Not classified based on available information.

STOT-single exposure
Not classified based on available information.

STOT-repeated exposure
Not classified based on available information.

Aspiration toxicity
Not classified based on available information.

Potential Health Effects


Inhalation : May cause respiratory tract irritation.
Skin : Causes mild skin irritation.
Eyes : May cause eye irritation.
Ingestion : May cause irritation of the mucous membranes.
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Aggravated Medical
Condition : None known.

Symptoms of
Overexposure : No information available.

Toxicology Assessment
Further information : Information given is based on data on the ingredients and the
toxicology of similar products.
Test result
Acute oral toxicity : LD50: > 5,000 mg/kg
Species: Rat
The value is estimated from tests on similar products.
Sensitization : Result: Did not cause sensitization on laboratory animals.
Method: (Magnusson-Kligman):
The value is estimated from tests on similar products.
Germ cell
mutagenicity
Genotoxicity in vitro : Ames test
Result: negative
Method: OECD Test Guideline 471
The value is estimated from tests on similar products.
Carcinogenicity:
IARC No ingredient of this product present at levels greater than or equal to
0.1% is identified as probable, possible or confirmed human
carcinogen by IARC.
OSHA No component of this product present at levels greater than or equal
to 0.1% is on OSHA’s list of regulated carcinogens.
NTP No ingredient of this product present at levels greater than or equal to
0.1% is identified as a known or anticipated carcinogen by NTP.

TOXICOLOGY DATA FOR THE INGREDIENTS:


Test result
Component: silicon dioxide
Acute oral toxicity : LD50: > 10,000 mg/kg
Species: Rat

12. ECOLOGICAL INFORMATION


Ecotoxicology Assessment
Additional ecological
information : None known.

Test Result
Ecotoxicity Effects
Toxicity to fish : LC50: > 5,000 mg/l
Exposure time: 96 h
Species: Danio rerio (zebra fish)
The value is estimated from tests on similar products.
Toxicity to daphnia : EC50: 7,600 mg/l
and other aquatic Exposure time: 48 h
invertebrates Species: Ceriodaphnia dubia (water flea)
The value is estimated from tests on similar products.
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Toxicity to algae : NOEC: 60 mg/l
Exposure time: 48 h
Species: Selenastrum capricornutum (green algae)
The value is estimated from tests on similar products.

EC50: 120 mg/l


Exposure time: 48 h
Species: Selenastrum capricornutum (green algae)
The value is estimated from tests on similar products.

EC10: 140 mg/l


Exposure time: 48 h
Species: Selenastrum capricornutum (green algae)
The value is estimated from tests on similar products.

Elimination information (persistence and degradability)

Bioaccumulative
potential : Bioaccumulation is not expected.

Mobility in soil : No test results


Under extreme circumstances, transport from earth to
water may take place.

Distribution among
environmental
compartments : Transport to air is not expected.

Biodegradability : Result: Not applicable


inorganic

Further information on ecology


Biochemical Oxygen : No data available
Demand (BOD)

Hazardous to the ozone layer


Regulation : 40 CFR Protection of Environment; Part 82
Pro- tection of Stratospheric Ozone - CAA Section 602
Class I Substances
Remarks : This product neither contains, nor was
manufactured with a Class I or Class II ODS as defined by
the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A,
App.A + B).

INGREDIENTS:
Ecotoxicology Assessment
Component: silicon dioxide
Additional ecological
information : No data available

13.
13) DISPOSABLE CONSIDERATIONS
DISPOSAL CONSIDERATIONS
Contaminated
Packaging : Empty remaining contents.
Empty containers should be taken to an
approved waste handling site for recycling or disposal.
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Version 1.0 US/Z8 Date of Last Issue: - Date of First Issue: -
14. TRANSPORT INFORMATION
International Regulations

ADR
Not regulated as a dangerous good

UNRTDG
Not regulated as a dangerous good

IATA-DGR
Not regulated as a dangerous good

IMDG-Code
Not regulated as a dangerous good

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.

Further information for transport


Not classified as dangerous in the meaning of transport regulations.

Domestic regulation
49 CFR
Not regulated as a dangerous good
TDG
Not regulated as a dangerous good

NOM-002-SCT
Not regulated as a dangerous good

15. REGULATORY INFORMATION


Notification status
DSL : YES. All components of this product are on the Canadian DSL
AICS : YES. On the inventory, or in compliance with the inventory
NZIoC : YES. On the inventory, or in compliance with the inventory
ENCS : YES. On the inventory, or in compliance with the inventory
ISHL : YES. On the inventory, or in compliance with the inventory
KECI : YES. On the inventory, or in compliance with the inventory
PICCS : YES. On the inventory, or in compliance with the inventory
IECSC : YES. On the inventory, or in compliance with the inventory
TCSI : YES. On the inventory, or in compliance with the inventory
TSCA : YES. All chemical substances in this product are either listed on the
TSCA Inventory or in compliance with a TSCA Inventory exemption.
For explanation of abbreviations, see section 16.
TSCA list

TSCA 5(a)(2) : No substances are subject to a Significant New Use Rule.


TSCA 12(b) : No substances are subject to TSCA 12(b) export notification requirements.

EPCRA - Emergency Planning and Community Right-to-Know


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CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.

SARA 304 Extremely Hazardous Substances Reportable Quantity


This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity


This material does not contain any components with a section 302 EHS TPQ.

SARA 311/312 Hazards : No SARA Hazards

SARA 313 : This material does not contain any


chemical components with known CAS
numbers that exceed the threshold
(De Minimis) reporting levels established
by SARA Title III, Section 313.

Clean Air Act

This product does not contain any hazardous air pollutants (HAP), as defined by
the U.S. Clean Air Act Section 112 (40 CFR 61).

This product does not contain any chemicals subject to disclosure and listed
under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40
CFR 68.130, Subpart F).

This product does not contain any chemicals listed under the U.S. Clean Air Act
Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).

This product does not contain any chemicals listed under the U.S. Clean Air Act
Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489).

Clean Water Act

This product does not contain any Hazardous Substances listed under the U.S.
CleanWater Act, Section 311, Table 116.4A.
This product does not contain any Hazardous Chemicals listed under the U.S.
CleanWater Act, Section 311, Table 117.3.
This product does not contain any toxic pollutants listed under the U.S. Clean
Water Act Section 307

California Prop. 65
This product does not contain any chemicals known to the State of California to
cause cancer, birth, or any other reproductive defects.

16. OTHER INFORMATION


Full text of other abbreviations
CAL PEL : California permissible exposure limits for chemical contaminants (Title 8, Article 107)
NIOSH REL : USA. NIOSH Recommended Exposure Limits
OSHA Z-3 : USA. Occupational Exposure Limits (OSHA) - Table Z-3 Mineral Dusts
CAL PEL / PEL : Permissible exposure limit
NIOSH REL / TWA : Time-weighted average concentration for up to a 10-hour workday during a 40-hour
workweek
OSHA Z-3 / TWA : 8-hour time weighted average
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AICS - Australian Inventory of Chemical Substances; ANTT - National Agency for Trans-
port by Land of Brazil; ASTM - American Society for the Testing of Materials; bw - Body
weight; CMR - Carcinogen, Mutagen or Reproductive Toxicant; CPR - Controlled Prod-
ucts Regulations; DIN - Standard of the German Institute for Standardisation; DSL -
Domestic Substances List (Canada); ECx - Concentration associated with x% response;
ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS -
Existing and New Chemical Substances (Japan); ErCx - Concentration associated with
x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmo-
nized System; GLP - Good Laboratory Practice; IARC - International Agency for
Research on Cancer; IATA - International Air Transport Association; IBC - International
Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in
Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Aviation
Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - Inter-
national Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL -
Industrial Safety and Health Law (Japan); ISO - International Organisation for Standard-
ization; KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 %
of a test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal
Dose); MARPOL - International Convention for the Prevention of Pollution from Ships;
n.o.s. - Not Otherwise Specified; Nch - Chilean Norm; NO(A)EC - No Observed (Ad-
verse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No
Observable Effect Loading Rate; NOM - Official Mexican Norm; NTP - National Toxicolo-
gy Program; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pol-
lution Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Phil-
ippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative)
Structure Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the Europe-
an Parliament and of the Council concerning the Registration, Evaluation, Authorisa-
tion and Restriction of Chemicals; SADT - Self-Accelerating Decomposition Tempera-
ture; SDS - Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TDG -
Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act (United
States); UN - United Nations; UNRTDG - United Nations Recommendations on the
Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative;
WHMIS - Workplace Hazardous Materials Information System

HMIS Classification : Health Hazard: 0


Chronic Health Hazard: /
Flammability
Flammability: 0
0
Physical hazards: 0
Health 0 0 Stability
NFPA Classification : Health Hazard: 0
Fire Hazard: 0
Reactivity Hazard: 0 Special hazard
Notification status explanation
REACH 1907/2006 (EU)
DSL Canadian Domestic Substances List (DSL)
AICS Australia Inventory of Chemical Substances (AICS)
NZIoC New Zealand. Inventory of Chemical Substances
ENCS Japan. ENCS - Existing and New Chemical Substances Inventory
ISHL Japan. ISHL - Inventory of Chemical Substances
KECI Korea. Korean Existing Chemicals Inventory (KECI)
PICCS Philippines Inventory of Chemicals and Chemical Substances (PICCS)
IECSC China. Inventory of Existing Chemical Substances in China (IECSC)
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TCSI Taiwan Chemical Substance Inventory (TCSI)


TSCA United States TSCA Inventory

Further information
Revision Date 12/08/2017
n

Internal Cure® are trademarks of the company publishing this SDS.

The information in this material safety data sheet should be provided to all who will use, handle, store,
transport or otherwise be exposed to this product. The user must determine the appropriate measures that
need to be implemented for the use and handling of this product in the context of the user's operations and
use of this product. The information contained herein supersedes all previously issued bulletins on the
subject matter covered. If the date on this document is more than three years old,call to make certain that
this sheet is current. No warranty is made as to the product’s merchantability or fitness for any particular
purpose, or that any suggested use will not infringe any patent. User must determine for himself, by
preliminary tests or otherwise, the suitability of this product for his purposes, including mixing with other
products. Nothing contained herein shall be construed as granting or extending any license under any patent.
The information provided in this material Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a guidance for
safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and may
not be valid for such material used in combination with any other materials or in any process, unless
specified in the text.

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