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Physics Week 20 Reading Assignment - Theodore Kim

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IB Physics Revision Notes on Ideal Gases

The Ideal Gas Laws

An ideal gas is a gas that obeys these gas laws at all temperatures, pressures and volumes.

1. Boyle’s law
For a fixed number of moles of gas at constant temperature, the pressure of the gas is inversely
proportional to its volume.

2. Charles’ law
For a fixed number of moles of gas at constant pressure, the volume of the gas is directly
proportional to its absolute temperature.
3. Gay-Lussac’s law
For a fixed number of moles of gas at constant volume, the pressure of the gas is directly
proportional to its absolute temperature.

Empirical Gas Law Equation

P = pressure (Pa)
V = volume (m3)
T = absolute temperature (K)

Amedeo Avogadro’s Discovery

For a gas at constant temperature and pressure, the number of gas particles is directly
proportional to the volume of the gas.

N ∝V
N = number of gas particles
V = volume of gas (m3)
Since n = N / 6.02 x 1023, number of particles is proportional to the number of moles, so n ∝ N,
and hence, n ∝V
For a gas at constant pressure and temperature:

Ideal Gas Law Equation

PV = nRT

P = pressure (Pa)
V = volume (m3)
n = moles (mol)
R = 8.31 J K-1 mol-1
T = absolute temperature (K)

Equation for Gas Pressure

PV = NkBT

P = pressure (Pa)
V = volume (m3)
N = number of particles
kB = Boltzmann constant (1.38 x 10-23 J K-1)
T = absolute temperature (K)

Internal Energy of Ideal Gases

Since there are no intermolecular forces between particles in an ideal gas, potential energy = 0,
so the total internal energy = the total kinetic energy.

Equation for internal energy of an ideal monatomic gas

U = 3/2 NkBT

U = internal energy (J)


N = number of particles
kB = Boltzmann constant (1.38 x 10-23 J K-1)
T = absolute temperature (K)
Alternate equation for internal energy of an ideal monatomic gas

U = 3/2 nRT

(where NkB = nR)

U = internal energy (J)


n = moles (mol)
R = 8.31 J K-1 mol-1
T = absolute temperature (K)

Ideal Gases and Gas Pressure

In an elastic collision, the speed of the particle remains the same, but the direction gets
reversed, so the velocity changes, causing a change in momentum. Hence, when a particle
collides with the wall of its container at a certain velocity, it bounces back.
The collision exerts a force on the wall of the container, hence also exerting pressure.

Equation for gas pressure

P = ⅓ ⍴v2

P = gas pressure (Pa)


⍴ = density (kg m-3)
v = average velocity of particles (ms-1)

The velocity of any moving object has components in the x, y and z planes.
The “⅓” indicates that every gas particle has equal probability of moving in any of those 3
directions with average translational speed.
Kognity End of Section Questions:

Question 1

Since volume remains constant, we can cancel out the volumes in the equation.
100000 / (12 + 273) = pressure / (40 + 273),
100000 / 285 = pressure / 313,
pressure = P1T2 / T1 = 100000 x 313 / 285 = 109824.561 Pa → 110 kPa (2 s.f.)

Question 2

proportional

Question 3

PV = nRT, T = PV / nR = 180000 x (250 x 10-6) / 0.25 x 8.31 = 22 K (2 s.f.)


Question 4

P = ⅓ ⍴v2, v = (3P / ⍴)½ = (3 x 140000 / 1.98)½ = 460 ms-1 (2 s.f.)

Question 5

U = 3/2 nRT,
T = ⅔ U / nR = ⅔ (12000 / 3.2 x 8.31) = 300 K (2 s.f.)

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