ANEES HUSSAIN COACHING CLASSES

EXCELLENCE IN EDUCATION SINCE 1989

COMPREHENSIVE EXAMINATION 2023-24
CHEMISTRY H.S.C. PART-II (PRE-ENGINEERING & MEDICAL)
According to the syllabus of the Board of Intermediate Education, Karachi

Time allowed: 20 Minutes SECTION ‘A’ Max. Marks: 17

(MULTIPLE CHOICE QUESTIONS)
NOTE: i) This section consists of 17 part questions and all are to be answered. Each question carries 1 mark.
ii) The correct answer bubble must be filled on OMR sheet 1) Ⓐ Ⓑ Ⓒ Ⓓ provided with answer script.
iii) Use only blue / black ballpoint pen or pointer on OMR sheet.
iv) Avoid using pencil / white-o pen on OMR sheet.
Q. 1: Choose the correct answer for each from the given options:
i. A is the element of III-A while B belongs to V-A group. When A reacts with B they form
(A) AB (B) AB2 (C) A3B2 (D) A2B3
ii. Li has many similarities to its diagonal neighbour in Be family. The elements is?
(A) K (B) Mg (C) Ca (D) Na
iii. The co-ordination number of cobalt in Na4[Co(C2O4)3]
(A) 3 (B) 4 (C) 6 (D) 7
iv. An example of bidentate ligand among the following is
(A) OH- (B) C2O4-2 (C) Cl- (D) CN-
v. The functional group present in cresol is:
(A) Phenolic, -OH (B) Carboxylic, -COOH (C) Alcoholic, -OH (D) Aldehydic, -CHO
vi. The formula of Caproic acid is:
(A) CH3.(CH2)2.COOH (C) CH3.CH2.COOH
(B) CH3.(CH2)3.COOH (D) CH3.(CH2)4.COOH
vii. The number of five membered and six membered rings in C60bucky ball are respectively
(A) 12 & 12 (B) 40 & 20 (C) 12 & 20 (D) 5 & 15
viii. The genera The general formula of alcohol is
(A) CnH2n (B) CnH2n+1OH (C) CnH2n-1OH (D) CnH2n+2
ix. The chlorination of methane (CH4) us an example of:
(A) Addition reaction (B) Substitution reaction
(C) Elimination reaction (D) Oxidation reaction
x. Ozonide on heating with zinc dust produce
(A) Alcohol (B) Alkene (C) Aldehyde (D) Ether
xi. Grignard’s reagent reacts with ketone to give:
(A) 10 –alcohol (B) 20 –alcohol (C) 30 –alcohol (D) Phenol
xii. Which of the following is anaesthetic agent
(A) Phenol (B) Ethyl alcohol (C) Diethyl ether (D) Acetone
xiii. Alkyl amine when reacts with nitrous acid in the presence of hydrochloric acid, yields
(A) Alcohol (B) Diazonium salt (C) Aldehyde (D) Ketone
xiv. Clemmensen reduction is the conversion of aldehydes and ketones into
(A) Alkanes (B) Alkenes (C) Alkyl halides (D) Alcohols
xv. Which of the following gives silver test with Tollen’s reagent?
(A) HCHO (B) C2H5OH (C) CH3-O-CH3 (D) CH3COOH
xvi. This is animal starch:
(A) Glycogen (B) Amylose (C) Cellulose (D) Amino acid
xvii. The region of sphere which extend from 11 km to 50 km from our Earth is known as
(A) Troposphere (B) Stratosphere (C) Mesosphere (D) Thermosphere
 ANEES HUSSAIN COACHING CLASSES
EXCELLENCE IN EDUCATION SINCE 1989
COMPREHENSIVE EXAMINATION 2023-24
CHEMISTRY H.S.C. PART-II (PRE-ENGINEERING & MEDICAL)
According to the syllabus of the Board of Intermediate Education, Karachi

Time allowed: 2 hours 40 Minutes SECTION ‘B’ Max. Marks: 68

(SHORT-ANSWER QUESTIONS)
NOTE: Answer any Nine part questions. Select Four part questions from Inorganic – General Chemistry
and Five part questions from Organic Chemistry. All questions carry equal marks.
Q. No. 2 (36 marks)
INORGANIC – GENERAL CHEMISTRY
i. What is meant by a diagonal relationship? Mention three pairs of representative elements that show
diagonal relationship.
OR Give reasons for any four of the following:
* Ionization energy decreases from top to bottom in s-block elements?
* Electronegativity decreases regularly from top to bottom in s-block elements?
* Acidity of hydrogen halides increase from HF to HI?
* Why Cu+2ion is blue but Zn+2is colourless?
* Multidentate ligands are known as chelating agents.
ii. Explain the following properties of transition elements. (any two)
* Catalytic property * Paramagnetic property
* Variable oxidation state *Colour formation
iii. Explain various types of ligands with examples.
iv. Write down the IUPAC names of the following complexes.
* Na2[Pt(OH)4] * K2[Fe(CN)5NO]
* [Zn(NH3)4] +2
* [Ni(SCN)4]−2
v. How can you define Cosmetics? Describe four cosmetics which are commonly used.
OR What are Pesticides? Write the name of three types of pesticides along with their
specific use.
vi. What is a catalytic converter? What are the main pollution targeted by catalytic converter?
vii. Explain λ max with the help of U.V-visible spectrum of ethanol

“ORGANIC CHEMISTRY”
viii. Describe homologous series of organic compounds? Write three main properties of homologous
series.
OR How is coal produced under the earth crust? Write the name of four types of coal and mention
the %age of carbon content in them.
 ANEES HUSSAIN COACHING CLASSES
EXCELLENCE IN EDUCATION SINCE 1989
COMPREHENSIVE EXAMINATION 2023-24
CHEMISTRY H.S.C. PART-II (PRE-ENGINEERING & MEDICAL)
According to the syllabus of the Board of Intermediate Education, Karachi

ix. Draw the orbital structures of the following (any two):

(i) Ethyne (ii) Methyl chloride (iii) Benzene (iv) Formaldehyde
OR Give the equations and write the name of final product in the following process.
* Ethene is burnt in air in the presence of per acetic acid.
* 1, 2-dibormoethane is heated with alcoholic KOH
* Ethene is heated at high temperature
* Ethyne is treated with H2O in the presence of H2SO4/HgSO4
x. Write the IUPAC name of the following organic compounds.
* CH2 = CH − C ≡ C − CH = CH2 * (CH3)2 CBr CHO
* CH3 – CH2 – OC (CH3)2 C2H5 * CH3 – CH = CH – CH2 – COOH
xi. Give the mechanism of following Electrophilic substitution reaction of benzene.
(a) Acylation (b) Nitartion
OR What is meant by sterio isomerism? Define optical isomerism
xii. What are organometallic compound ? Write the equation of its reaction with
* CH3CHO * CO2 * CH3NH2
OR Define Lipids and explain the following chemical behavior of fat and oil.
* Saponification * Rancidity
xiii. Write the equations for the following possible conversions.
(i) Ethyl alcohol to diethyl ether (ii) Phenol to benzoquinone
(iii) Ethyl bromide to ethanol (iv) 2°- alcohol to carboxylic acid
OR What is ozonolysis of alkenes and what are the main types of products that can be obtained
from this reaction?
xiv. Describe how aldehydes are distinguished from ketones by the following laboratory test.
(i) Tollen’s reagents (ii) Fehling solution
OR Name four derivative of carboxylic acid and write the equations of their preparation.
SECTION ‘C’
(DETAILED-ANSWER QUESTIONS) (32 marks)
Note: Attempt any Two questions ––– One question from Inorganic - General Chemistry and the other
from Organic Chemistry. Both questions carry equal marks.
(INORGANIC – GENERAL CHEMISTRY)
Q3 (a) With the help of a flow sheet diagram describe the manufacture of H2SO4 by contact process. Show
with the help of equation that
* H2SO4 is a dehydrating agent * H2SO4 is an oxidizing agent
OR Explain with the help of a diagram of Castner Kellner cell, how caustic soda is obtained by the
electrolysis of aqueous sodium chloride? Write equation
* NaOH reacts with FeCl3 * NaOH reacts with zinc
(b) Write the balance chemical equations for the following processes.
* Reaction of Sodium with water.
* Phosphorus is put into water
* Bleaching powder is treated with hydrochloric acid
* Chlorine gas is pass through hot aqueous solution of caustic soda
* Copper is treated with concentration nitric acid
* A piece of chromium is put into dilute hydrochloric acid
* Reaction between KMnO4 and FeSO4 (write ionic equation)
* Reaction between K2Cr2O7 and FeSO4 (write ionic equation)
 ANEES HUSSAIN COACHING CLASSES
EXCELLENCE IN EDUCATION SINCE 1989
COMPREHENSIVE EXAMINATION 2023-24
CHEMISTRY H.S.C. PART-II (PRE-ENGINEERING & MEDICAL)
According to the syllabus of the Board of Intermediate Education, Karachi

Q.4 (a) Discuss the group trend of atomic radii, ionization energy and electronegativity of alkali metals.
OR Describe various steps involve in the extraction of 99.99% pure copper from its chalcopyrite ore.
(b) What is acid rain? Explain the primary causes of acid rain and its environmental impacts.
(ORGANIC CHEMISTRY)
Q5 (a) What is meant by orientation of benzene? Explain orthopara and meta directing group. Write the equation
for the preparation of m-nitrobenzoic acid and m-nitro toluene from benzene.
(b) Draw the structure of the following organic molecules:
(i) Ethyl neo-pentyl ether (v) 1-Bromo-3-methyl hexane-2-one
(ii) Resorcinol (vi) α, β-dimethyl butyric acid
(iii) Picric acid (vii) Butyraldehyde
(iv) Isopropylbutanoate (viii) 3-Chlorobenzamide
Q6 (a) What is meant by nucleophile? Give the mechanism of
* SN1reaction between 2-bromo -2-methyl propane and NaOH
* SN2reactions between chloroethane and NaCN
OR What are Carbohydrates? Classify them on the basis of structure and give their biological significance.
(b) Write the equation for the following reactions.
* Dehydration of ethyl alcohol at 170°C in conc. H2SO4
* Reaction of ethylene glycol with periodic acid.
* Reduction of acetic acid with LiAlH4.
* Oxidation of 1°-alcohol with PCC.
* Hydration of propyne with H2SO4/HgSO4.
* Reaction of phenol with H2SO4 at 20°C.
* Reduction of acetaldehyde with Zn(Hg) amalgam
* Reaction of acetic acid with ammonia