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    Pauta A3

    Uploaded by

    kenny apata

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd

    Pauta A3

    Uploaded by

    kenny apata
    17 views8 pages

    Original Title

    PAUTA A3

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    © © All Rights Reserved

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    Copyright:

    © All Rights Reserved
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    Download as xlsx, pdf, or txt
    17 views8 pages

    Pauta A3

    Uploaded by

    kenny apata

    Copyright:

    © All Rights Reserved
    Download as XLSX, PDF, TXT or read online from Scribd
    Download as xlsx, pdf, or txt
    of 8

    Orden 0 Orden 1 Orden 2

    t (min CA (mol/L) ln(CA/CA0) (1/CA-1/CA0)


    Orden 1
    0 0.05 0 0 0
    0 f(x) =50 100 150 200x
    − 0.00385799058488069 250 300 350
    50 0.038 -0.27443685 6.31578947 -0.2 R² = 0.9887649495731
    100 0.0306 -0.491023 12.6797386 -0.4
    150 0.0256 -0.66943065 19.0625 -0.6
    200 0.0222 -0.81193072 25.045045 -0.8
    250 0.0195 -0.94160854 31.2820513 -1
    300 0.0174 -1.0555528 37.4712644 -1.2

    Orden 0 Orden 2
    0.06 40
    35 f(x) = 0.125336437229714 x
    0.05
    30 R² = 0.999968544195034
    0.04f(x) = − 0.000102285714285714 x + 0.0443857142857143 25
    0.03R² = 0.907339693102777 20
    0.02 15
    10
    0.01 5
    0 0
    0 50 100 150 200 250 300 350 0 50 100 150 200 250 300 350
    alpha 2
    k' 0.1253
    300 350 k 2.506

    CB (mol/L) 0.05

    −𝑟_𝐴=𝑘 𝐶_𝐴^𝛼
    〖 𝐶〗 _𝐵^𝛽
    −𝑟_𝐴=𝑘^′ 𝐶_𝐴^𝛼 : 〖 𝑘
    ′ =𝑘 〖 𝐶〗 _𝐵^𝛽 〗 ^′

    300 350
    t (min CA (mol/L) CB (mol/L) Suposiciones:
    0 0.05 0.05 1.- Reactivo B en exceso
    −(𝑑𝐶_𝐴)/𝑑𝑡=−𝑟_𝐴=𝑘′𝐶
    50 0.038
    100 0.0306 beta 1
    150 0.0256
    200 0.0222 −𝑟_𝐴=𝑘 𝐶_𝐴^𝛼 ln⁡(−(𝑑𝐶_𝐴)/𝑑𝑡)=ln⁡𝑘′+𝛼 l
    〖 𝐶〗 _𝐵^𝛽
    250 0.0195 −𝑟_𝐴=𝑘^′ 𝐶_𝐴^𝛼 : 〖 𝑘
    300 0.0174 ′ =𝑘 〖 𝐶〗 _𝐵^𝛽 〗 ^′

    t vs Ca
    0.06

    0.05
    f(x) = 3.69697E-12 x⁴ − 0.000000003484848 x³ + 0.000001343485 x² − 0.000297846 x
    + 0.0499902597
    0.04 R² = 0.999986967245954

    0.03

    0.02

    0.01

    0
    0 50 100 150 200 250 300 350
    (-dCA/dt) ln (CA) ln(-dCA/dt) alpha 2.0553
    0.0002978 -2.99573227 -8.11908844 ln(k') -1.9032
    −(𝑑𝐶_𝐴)/𝑑𝑡=−𝑟_𝐴=𝑘′𝐶_𝐴^𝛼
    0.00018773 -3.27016912 -8.58049781 k' 0.14909076
    0.00011883 -3.48675527 -9.03779983 K 2.98181529
    8.00105E-05 -3.66516293 -9.43335268
    ln⁡(−(𝑑𝐶_𝐴)/𝑑𝑡)=ln⁡𝑘′+𝛼 ln⁡〖𝐶 _𝐴 6.0176E-05
    〗 -3.80766299 -9.71823696
    4.82375E-05 -3.93734081 -9.93937383
    3.3104E-05 -4.05128507 -10.3158564

    ln(Ca) vs ln(-dCa/dt)
    0
    -4.3 -4.1 -3.9 -3.7 -3.5 -3.3 -3.1 -2.9 -2.7 -2.5

    -2

    -4

    -6

    -8
    f(x) = 2.05527820607479 x − 1.90317119448402
    R² = 0.995274526204978
    -10

    -12
    CA0 t(1/2) ln(CA0) ln(t(1/2)) 1-n = α 2.0129 "n es la pendiente"
    0.025 4.1 -3.68887945 1.41098697 k 10.5685906
    0.0133 7.7 -4.31999124 2.04122033
    0.01 9.8 -4.60517019 2.28238239
    0.05 1.96 -2.99573227 0.67294447
    0.075 1.3 -2.59026717 0.26236426

    ln(CA0) vs ln(t(1/2))
    2.5

    f(x) = − 1.01286984386326 x − 2.35287471483202


    R² = 0.999300447161167 2

    1.5

    0.5

    0
    -5 -4.5 -4 -3.5 -3 -2.5 -2
    es la pendiente"
    T(s) Ptotal(mmHg) ln[(2P0/(3P0-P)]
    ln⁡〖 [(2∙𝑃_0)/(3∙𝑃_0−𝑃 )]= 〗 𝑘∙𝑡
    390 408 0.171212705104
    777 488 0.3372243991238
    1195 562 0.5199975251284 k 0.0005
    3155 799 1.5479922465825 α 1
    ∞ 931 Por que la grafica de la ecuacion es lineal

    Chart Title
    P∞=3P0
    P0 310.333333333 1.8
    1.6
    1.4 f(x) = 0.000503598000614131 x − 0.0504808233623767
    R² = 0.998499342081476
    1.2
    1
    0.8
    0.6
    0.4
    0.2
    0
    0 500 1000 1500 2000 2500 3000 3500
    3000 3500

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