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Net Chemicalscience June2015

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CSIR UGC NET CHEMICAL SCIENCE

JUNE 2015
SOLVED PAPER

IfAS

http://ifasonline.com

IFAS PUNE, Shivranjan Tower, Someshwarwadi, Pashan, Pune (+91-9172266888)


IFAS JODHPUR, B-7, Saraswati Nagar, Basni – I, Jodhpur (+91-9460660533)

INDIA’S NO: 1 CSIR NET INSTITUTE

[Type text] Page 0


CSIR UGC NET CHEMICAL SCIENCE JUNE 2015

PART-A

1. Let r be a positive number satisfying: 8. Which of the following values is same as ?


r(l/1234) + r(-l/1234) = 2
(1) 26 (2) 28
Then r4321 + r-4321=? (3) 216 (4) 2222
(1) 2 (2) 2(4321/1234)
(3) 23087 (4)21234 9. ABC is a right angled triangle inscribed in a semicircle.
Smaller semicircles are drawn on sides BC and AC. If the
2. Find the height of a box of base area 24 cm × 48 cm, in area of the triangle is a, what is the total area of the
which the longest stick that can be kept is 56 cm long. shaded lunes?
(1) 8 cm (2) 32 cm
(3) 37.5 cm (4) 16 cm

3. Consider a series of letters placed in the following


way:
U_G_C_C_S_I_R

Each letter moves one step to its right and the extreme
right letter takes the first position, completing one
operation. After which of the following numbers of
operations do the Cs not sit side by side?
(1) 3 (2) 10 (1) a (2) πa
(3) 19 (4) 25 (3) a/π (4) a/2π

4. An infinite row of boxes is arranged. Each box has half 10. The product of the perimeter of a triangle, the radius
the volume of the previous box. If the largest box has a of its in-circle, and a number gives the area of the
volume of 20 cc, what is the total volume of all the boxes? triangle. The number is:
(1) ¼ (2) 1/3
(1) Infinite (2) 400 cc (3) ½ (4) 1
(3) 40 cc (4) 80 cc
1. If
5. Find the missing element based on the given pattern: 2

Here a, b, c and d are digits.


Then a + b =
6. Each of the following pairs of words hides a number,
based on which you can arrange them in ascending (1) 4 (2) 9
order. Pick the correct answer: (3) 11 (4) 16
(1) L, K, J, I (2) I, J, K, L
12. By reading the accompanying graph, determine the
(3) K, L, J, I (4) K, J, I, L
INCORRECT statement out of the following:

7. A man start his journey at 0100 Hrs local time to reach


another country at 0900 Hrs local time on the same date.
He starts his return journey on the same night at 2100
Hrs local time to his original place, taking the same to
travel back. If the time zone of his country of visit lags by
10 hours, the duration for which the man was away from
his place is:

(1) 48 hours (2) 20 hours


(3) 25 hours (4) 36 hours

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
(1) Melting point increases with pressure 20. What is the maximum number of parallel, non-
(2) Melting point decreases with pressure overlapping cricket pitches (length 24 m, width 3 m) that
(3) Boiling point increases with pressure can be laid in a field of diameter 140 m, if the boundary
(4) Solid, liquid and gas can co-exist at the same pressure is required to be at least 60 m from the centre of any
and temperature pitch?
(1) 6 (2) 7
13. A float is drifting in a river, 10 m downstream of a (3) 12 (4) 4
boat that can be rowed at a speed of 10 m/minute in still
water. If the boat is rowed downstream, the time taken
to catch up with the float
(1) will be 1 minute
(2) will be more than 1 min
(3) will be less than 1 min
(4) can be determined only if the speed of the river is
known

14. If you change only one observation from a set of 10


observations, which of the following will definitely
change?
(1) Mean (2) Median
(3) Mode (4) Standard deviation

15. In a fast moving car with open windows, the driver


feels a continuous incoming breeze. The pressure inside
the car, however, does not keep increasing because,
(1) air coming in from the front window goes out from
the rear.
(2) air comes in as well as goes out through every
window but the driver only feels the incoming one.
(3) no air actually comes in and the feeling of breeze is
an illusion.
(4) cool air reduces the temperature therefore the
pressure does not increase

16. The maximum number of points formed by


intersection of all pairs of diagonals of convex octagon is
(1) 70 (2) 400
(3) 120 (4) 190

17. A 12 m × 4 m rectangular roof resting on four 4 m tall


thin poles. Sunlight falls on the roof at an angle of 45o
from the east, creating a shadow on the ground. What
will be the area of the shadow?
(1) 24 m2 (2) 36 m2
(3) 48 m 2 (4) 60 m2

18. An ant can lift another ant of its size whereas an


elephant cannot lift another elephant of its size, because
(1) ant muscle fibers are stronger than elephant muscle
fibers.
(2) ant has proportionately thicker legs than elephant
(3) strength scales as the square of the size while weight
scales as cube of the size
(4) ants work cooperatively, whereas elephants work as
individuals

19. An inclined plane rests against a horizontal cylinder


of radius R. If the plane makes an angle of 30° with the
ground, the point of contact of the plane with the
cylinder is at a height of:
(1) 1.500 R (2) 1.866 R
(3) 1.414 R (4) R

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015

PART-B

21. The biological functions of carbonic anhydrase and 28. Q value for the reaction 13N(n, p)13C is 3.236 MeV.
carboxypeptidase A, respectively' are The threshold energy (in MeV) for the reaction 13C(p,
A. interconversion of CO2 and carbonates, and hydrolysis n)13N is
of peptide bond A -3.236 B. -3.485
B. gene regulation and interconversion of CO2 and C. 3.485 D. 3.845
carbonates
C. gene regulation and hydrolysis of peptide. bond 29. The 119Sn NMR chemical shift (approximately in
D. interconversion of CO2 and carbonates and gene ppm) corresponding to (η5-Cp)2Sn (relative to Me4Sn) is
regulation A. -4 B. +137
C. +346 D. -2200
22. The Fe-Nporphyrin bond distances in the deoxy- and
oxy-hemoglobin, respectively, are 30. All forms of phosphorus upon melting, exist as:
A. 2.1 and 2.0 Å B. 2.0 and 2.0 Å
C. 2.2 and 2.3 Å D. 2.3 and 2.5 Å

23. The binding modes of NO in 18 electron compounds


[Co(CO)3(NO)] and [Ni(η5-Cp)(NO)], respectively, are
A linear and bent B. bent and linear
C. linear and linear D. bent and bent

24. The role of copper salt as co-catalyst in Wacker


process is
A. Oxidation of Pd(O) by Cu(II)
B. oxidation of Pd(O) by Cu(I)
C. oxidation of Pd(II) by Cu(I)
D. oxidation of Pd(II) by Cu(II)

25. For typical Fischer and Schrock carbenes, consider


the following statements
1. Oxidation state of metal is low in Fischer carbene and 31. For the oxidation state(s) of sulphur atoms in S2O2
high in Schrock carbine consider the following:
2. Auxilliary ligands are π-acceptor in Fischer carbene 1. -2 and +4
and non-n-acceptor in Schrock carbene 2. 0 and +2
3. Substituents on carbene carbon are non π -donor in 3. +4 and O
Fischer carbene and π -donor in Schrock carbene
4. Carbene carbon is electrophilic in Fischer carbene and The correct answer(s) is/(are):
nucleophilic in Schrock carbene A. 1 and 2 B. 1 and 3
The correct statements are C. 2 and 3 D. 3
A. l, 2 and 3 B. 1, 2 and 4
C. 2, 3 and 4 D. 1, 3 and 4 32. The correct set of pseudohalide anions is
A CN-, ClO4-, BF4-, PF6- B. N3-, N03-, HS04-, AsF6-
26. The species having the strongest gas phase proton C. SCN , PO4 , H2P04 , N3
- 3- - - D. CN-, N3-, SCN-, NCN2-
affinity among the following:
A. N3- B. NF3 33. In transition metal phosphine (M-PR3) complexes,
C. NH3 D. N(CH3)3 the back-bonding involves donation of electrons from
A. M(t2g) PR3( *) B. M(t2g) PR3( *)
27. Consider the following statements regarding the C. M(eg) P(d) D. PR3( ) M(t2g)
diffusion current at dropping mercury electrode
1. It does not depend on mercury flow rate 34. The refluxing of RhCl3.3H2O with an excess of PPh3 in
2. It depends on drop time ethanol gives a complex A. Complex A and the valence
3. It depends on temperature electron count on rhodium are, respectively,
A. I only B. 2 only A. [RhCl(PPh3)3], 16 B. [RhCl(PPh3)5], 16
C. 1 and 2 D. 2 and 3 C. [RhCl(PPh3)3], 18 D. [RhCl(PPh3)5], 18

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
35. The β-hydrogen elimination will be facile in: 41. The compound that gives precipitate on warming
with aqueous AgNO3 is:

42. Following reaction goes through


36. The reaction [Co(CN)5H2O]2- + X [Co(CN)5X]2- +
H2O follows a/an:
A. Interchange dissociative (Id) mechanism
B. Dissociative (D) mechanism
C. Associative (A) mechanism
A Free radical intermediate B. Carbanion intermediate
D. Interchange Associative (Ia) mechanism
C. Carbocation intermediate D. Carbene intermediate
Wrong Question: Marks to all who attempted
43. The most stable conformation for the following
37. Correct statement on the effect of addition of aq. HCI compound is:
on the equilibrium is

A. Equilibrium will shift towards right in case of both A


and B
B. Equilibrium will shift towards left in case of both A
and B
C. Equilibrium will shift towards right in A and left in
case of B 44. The major product formed in the following reaction
D. Equilibrium will shift towards right in B and left in is:
case of A

38. The compound that exhibits sharp bands at 3300 and


2150 cm-1 in the IR spectrum is
A. 1-butyne B. 2-butyne
C. butyronitrile D. butylamine

39. The 1H NMR spectrum of a dilute solution of a


mixture of acetone and dichloromethane in CDCl3
exhibits two singlets of l : l intensity. Molar ratio of
acetone to dichloromethane in the solution is
A. 3: l B. 1 : 3
C. 1 : 1 D. 1 : 2

40. Intense band generally observed for a carbonyl group 45. The correct relation between the following
in the IR spectrum is due to compounds is
A. The force constant of CO bond is large
B. The force constant of CO bond is small
C. There is no change in dipole moment for CO bond
stretching
D. The dipole moment change due to CO bond stretching
is large A. enantiomers B. diastereomers
C. homomers (identical) D. constitutional isomers

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
46. The correct order of heat of hydrogenation for the 52. The major product formed in the following reaction
following compounds is is:

A. I >II>III>IV B. I > III > II > IV


C. IV > I > III > II D. IV>II> I >III

47. Among the following, the correct statement(s) about


ribose is (are)
1. On reduction with NaBH4 it gives optically inactive
product
2. On reaction with methanolic HCl it gives a furanoside
3. On reaction with Br2-CaCO3-water it gives optically
inactive product
4. Ji gives positive Tollen's test
A. 1, 2 and 4 B. 1, 2 and 3
C. 2 and 3 D. 4 only 53. The magnitude of the stability constants for K+ ion
complexes of the following supramolecular hosts follows
48. Biogenetic precursors for the natural product
the order:
umbelliferone among the following are:

1. L-tryptophan 2. cinnamic acid


3. L-methionine 4. L-phenylalanine
A. 1 and 2 B. 2 and 4 A. ii > i > iii B. iii > I > ii
C. 2 and 3 D. 3 and 4 C. i > ii > iii D. iii > ii > i
49. Number of signals in the 13C{1H} NMR spectrum of
54. Antitubercular drug(s) among the following is (are)
(R)-4-methylpentan-2-ol are
1. Salbutamol 2. Ethambutanol
A. 3 B. 4 C. 5 D. 6
3. Isoniazid 4. Diazepam
50. The major product formed in the following reaction A.1 and 2 B. 2 and 3
is: C. 3 and 4 D. 4 alone

55. A particle is in a one-dimensional box with a


potential V0 inside the box and infinite outside. An
energy state corresponding to n = 0 (n: quantum
number) is not allowed because
A. the total energy becomes zero
B. the average momentum becomes zero
C. the wave function becomes zero everywhere
D. the potential V0 0

56. An eigenstate of energy satisfies HΨn = EnΨn. In the


51. The major product formed in the following reaction presence of an extra constant potential V0
is: A. both En and Ψn will change.
B. both En and the average kinetic energy will change.
C. only En will change, but not Ψn
D. only Ψn will change, but not En.

57. The intensity of a light beam decreases by 50% when


it passes through a sample of 1.0 cm path length. The
percentage of transmission of the light passing through
the same sample, but of 3.0 cm path length, would be
A. 50.0 B. 25.0
C. 16.67 D. 12.5

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
58. The electric-dipole allowed transition among the 67. The correct G for the cell reaction involving steps:
following is
A. 3S 3D B.3S 3P
C. S
3 1 D D. 3S 1F

59. The product xy ( is the two-fold rotation axis


around the x-axis and xy is the xy mirror plane) is
A. xz B. yz
C. D.

60. The simplest ground-state VB wave function of a


diatomic molecule like HCl is written as:
Ψ = ΨH (1s, 1) Ψcl(3pz,2) + B
Where B stands for
A. ΨH (3pz, 2) Ψcl(1s,1) B. ΨH (1s, 2) Ψcl(3pz,1)
C. Ψcl (1s, 2) Ψcl(3pz,1) D. Ψcl (1s, 2) ΨH(3pz,1)

61. Heat capacity of a species is independent of 68. The lowest energy-state of an atom with electronic
temperature if it is configuration nslnp1 has the term symbol
A. tetratomic B. triatomic A. 3P1 B. lP1
C. diatomic D. monatomic C. 3P2 D.3P0

62. In a chemical reaction: PCl5(g) ⇌ PC13(g) + Cl2(g), 69. Energy of interaction of colloidal particles as a
xenon gas is added at constant volume. The equilibrium function of distance of separation can be identified as (1)
A. will shift towards the reactant van der Waals, (2) double layer, (3) van der Waals and
B. will shift towards the products double layer. The correct order of interactions in the
C. will not change the amount of reactant and products figure corresponding to curves (a). (b) and (c),
D. will increase both reactant and products respectively, is

63. The temperature-dependence of a reaction is given


by: k = AT2 exp(-E0/RT)

The activation energy (Ea) of the reaction is given by


A. E0 + RT B. E0
C. E0 + 2RT D. 2E0 + RT

64. For a reaction, 2A + B 3Z, If the rate of


consumption of A is 2 x 10-4 mol dm-3s-1, the rate of
formation of Z (in mol dm-3s-1) will be:
A. 0 3 10-4 B. 2 10-4 A. 1, 2, 3 B. 2, 3, 1
C. 10-3 D. 4 10-4 C. 3, l, 2 D. 1, 3, 2

70. The packing factor (PF) and number of atomic sites


65. Dominant contribution to the escaping tendency of a
per unit cell (N) of an FCC crystal system are
charged particle with uniform concentration in a phase,
A. PF = 0.52 and· N = 3
depends on
B. PF = 0.74 and N = 3
A. chemical potential of that phase
C. PF = 0.52 and N = 4
B. electric potential of the phase
D. PF = 0.74 and N = 4
C. thermal energy of that phase
D. gravitational potential of that phase

66. The intrinsic viscosity depends on the molar mass as:


[ ] = KMa
The empirical constants K and a are dependent on
A. solvent only
B. polymer only
C.-polymer-solvent pair
D. polymer-polymer interaction

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015

PART-C

71. Differential pulse polarography (DPP) is more 76. The geometries of [Br3]+ and [I5]+, respectively, are
sensitive than D.C. Polarography (DCP). Consider A. trigonal and tetrahedral
following reasons for it B. tetrahedral and trigonal bipyramidal
l. Non-faradic current is less in DPP in comparison to C. tetrahedral and tetrahedral
DCP D. linear and trigonal pyramidal
2. Non-faradic current is more in DPP in comparison to
DCP 77. According to Wade's theory the anion [B12H12]2-
3. Polarogram of DPP is of different shape than that of adopts
DCP A. closo - structure B. arachno - structure
Correct reason(s) is/are: C. hypo - structure D. nido – structure
A. l and 3 B. 2 and 3
C. 2 only D. 1 only 78. Considering the inert pair effect on lead, the most
probable structure of
72. Considering the following parameters with reference
to the fluorescence of a solution: PbR2 [R = 2, 6-C6H3 (2, 6-Pr2C6H3)2] is:

1. Molar absorptivity of fluorescent molecule


2. Intensity of light source used for excitation
3. Dissolved oxygen

The correct answer for the enhancement of fluorescence


with the increase in these parameters is/are
A. 1 and 2 B. 2 and 3
C. 1 and 3 D. 3 only

73. The geometric cross section of 125Sn (in barn) is


nearly
A. 1.33 B. 1.53
C. l.73 D. 1.93

74. Match column P (coupling reactions) with column Q


(reagents)

79. The reaction of SbCl3 with 3 equivalents of EtMgBr


yields compound X. Two equivalents of SbI3 react with
one equivalent of X to give Y. In the solid state, Y has a
ID-polymeric structure in which each Sb is in a square
pyramidal environment. Compounds X and Y
respectively, are
The correct match is: A. SbEt3 and [Sb(Et)I2]n
A. (a)-II, (b)-I, (c)-IV, (a)-III B. Sb(Et2)Cl and [Sb(Et2)Cl]n
B. (a)-I, (b)-V, (c)-III, (d)-IV C. SbEt3 and [SbEt2Br2]n
C. (a)-IV, (b)-III, (c)-II, (d)-I D. Sb(Et) Br2 and [SbEt(I)(Br)]n
D. (a)-II, (b)-III, (c)-IV, (d)-V

75. The oxoacid of phosphorus having P atoms in +4, +3,


and +4 oxidation states respectively is:
A. H5P3P10 B. H5P3P7
C. H5P3O8 D. H5P3O9

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015

80. Match the complexes given in column P with the 85. The reductive elimination of Ar-R (coupled product)
electronic transitions (mainly responsible for their from A is facile when
colours) listed in column Q

A. R = CH3 B. R = CH2Ph
C. R = CH2COPh D. R = CH2CF3

The correct answer is 86. The total number of metal ions and the number of
A. (i)-(a), (ii)-(c) and (iii)-(b) coordinated imidazole units of histidine in the active site
B. (i)-(d), (ii)-(h) and (iii)-(c) of oxy- hemocyanin, respectively, are
C. (i)-(a), (ii)-(c) and (iii)-(d) A. 2Cu2+ and 6 B. 2Fe2+ and S
D. (i)-(a), (ii)-(b) and (iii)-(c) C. 2Cu+ and 6 D. Fe2+ and 3

81. The following statements are given regarding the 87. Match the action of H2O2 in aqueous medium given in
agostic interaction C-H…Ir observed in [lr(Ph3P)3CI]. column P with the oxidation/ reduction listed in column
1. Upfield shift of C-H proton in 1H NMR spectrum Q:
2. Increased acid character of C-H
3. VC-H in IR spectrum shifts to higher wave number
The correct answer is/are
A. 1 and 3 B. 2 and 3
C. 1 and 2 D. 3 only

82. Amongst the following:


The correct answer is:
(a) [Mn(η5-Cp)(C0)3], (b) [Os(η5-Cp)2], A. I – a , II – b , III – c , IV – d
(c) [Ru(η5-Cp)2], and (d) [Fe(η5-Cp)2], B. I – b , II – d , III – c , IV – a
C. I – c , II – d , III – b , IV – a
the compounds with most shielded and deshielded Cp D. I – d , II – a , III – c , IV - b
protons respectively, are
88. The reduced form of a. metal ion M in a complex is
A (d) and (a) B. (d) and (b)
NMR active. On oxidation, the complex gives an EPR
C. (c) and (a) D. (c) and (b)
signal with g11 2.2 and g1 2.0. Mossbauer
83. Total number of vertices in metal cluster spectroscopy cannot characterise the metal complex. The
[Ru6(C)(C0)17], [Os5(C)(CO)15] and [Ru5(C)(C0)16] are 6, 5 M is:
and 5, respectively. The predicted structures of these A Zn B. Sn C. Cu D. Fe
complexes, respectively, are 89. The least probable product from A on reductive
A closo, nido and nido · elimination is:
B. closo, nido and arachno
C. arachno, closo and nido
D. arachno, nido and closo

84. Among the complexes:

K4[Cr(CN)6] (a), K4[Fe(CN)6] (b),

K3[Co(CN)6 (c), and K4[Mn(CN)4 (d),

Jahn-Teller distortion is expected in:

A (a), (b) and (c) B. (b), (c) and (d)


C. (a) and (d) D. (b) and (c)

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
90. Water plays different roles in the following reactions:
(i) 2H2O + Ca Ca2+ + 2OH2- + H2
(ii) nH2O + Cl- [Cl(H2O)n]-
(iii) 6H2O + Mg2+ [Mg(H2O)6]2+
(iv) 2H2O + 2F2 4HF + O2

The correct role of water in each reaction is:


For the above conversion, which of the following
statements are correct?
A. (i) oxidant, (ii) acid, (iii) base and (iv) reductant
(a) CO2 combines with Ni(PR3)2 (1, 5- cyclooctadiene)
B. (i) oxidant, (ii) base, (iii) acid and (iv) reductant
(b) Insertion of C02 occurs
C. (i) acid, (ii) oxidant, (iii) reductant and (iv) base
(c) Insertion of Et Et takes place
D. (i) base, (ii) reductant, (iii) oxidant and (iv) base
The correct answer is
A (a) and (b) B. (b) and (c)
91. With respect to and bonding in Pt-lll in the
C. (c) and (a) D. (a), (b) and (c)
structure given below, which of the following represent
the correct bonding:
95. Consider the following statements for:
(NH4)2[Ce(N03)6] (Z)
(a) Coordination number of Ce is 12
(b) Z is paramagnetic
(c) Z is an oxidising agent
(d) Reaction of Ph3PO with Z gives a complex having
coordination number 10 for Ce.

The correct statements are


A (a), (b) and (c) B. (b), (a) and (d)
C. (b), (c) and (d) D. (a), (c) and (d)

96. The major product formed in the following reaction


sequence is:
92. The complex [Fe(phen)2(NCS)2] (phen = 1, 10-
phenanthroline) shows spin cross-over behaviour. CFSE
and µeff at 250 and 150 K, restively are:
A.0.4 0, 4.90 BM and 2.4 0, 0.00 BM
B. 2.4 0, 2.90 BM and.0.4 0, 1.77 BM
C. 2.4 0, 0.00 BM and 0.4 0, 4.90 BM
D. 1.2 0, 4.90 BM and 2.4 0, 0.00 BM

93. Consider the following statements with respect to


uranium
(a) UO2+ disproportionates more easily than UO22+
(b) U3O8 is its most stable oxide of U
(c) Coordination number of U in [UO2(N03)2(H20)2].4H20
is six.
(d) UO22+is linear

The correct set of statements is


A. (a), (b) and (d) B. (a), (c) and (d)
C. (b), (c) and (d) D. (a), (b) and (c)

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
97. The major products A and B in the following reaction 99. The major products A and B in the following reaction
sequence are: sequence are:

100. The major products formed in the following


reaction are:

98. The major product formed in the following reaction


is:

101. The correct statement about the following reaction


is

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
A. The product is 2-fluoropyridin-3-amine and reaction 104. The major products A and B formed in the following
involves nitrene intermediate reactions are:
B. The product is 2-fluoropyridin-3-amine and reaction
involves radical intermediate
C. The product is 2-hydroxynicotinamide and reaction
involves benzyne-like intermediate ·
D. The product is 2-hydroxynicotinamide and reaction
involves addition-elimination mechanism

102. The major product formed in the following reaction


is:

105. An organic compound shows following spectral


data:
IR (cm-1): 1680
1H NMR (CDC1 ): 7.66 (m, lH), 7.60 (m, lH), 7.10 (m,
3
lH), 2.50 (s, 3H)
13C NMR (CDC1 ): 190, 144, 134, 132, 128, 28
3
m/z (El): 126 (M+, 100%), 128 (M+ +2, 4.9%)

The structure of the compound is:

103. The major products A and B formed in the following


reactions are:
106. The correct set of reagents to effect the following
transformation is

A (i) (a) NaOMe, Mel;

(b) NaCl, wet OMSO, 160°C;

(ii) (a) LDA, -78 °C, TMSCl;

(b) t-BuCl, TiC14, 50 °C

B. (i) (a) NaOMe, Mel;

(b) aq. NaOH then HCl, heat

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
(ii) (a) Et3N, TMSCI, rt;
109. The major product of the following reaction
(b) t-BuCI, TiC14, 50 °C sequence is:
C. (i) LDA, t-BuCl;

(ii) LDA, Mel;

(iii) aq, NaOH then HCl, heat

D. (i) (a) NaCl, wet OMSO, 160 °C;

(b) NaH, t-BuCl

(ii) (a) morpholine, H+;

(b) Mel then H3O+

107. The correct structures of the intermediates [A] and


[B] in the following reaction are:

108. The correct reagent combination A and the major 110. The major product formed in the following reaction
product B in the following reaction sequence are: is:

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113. The hydrocarbon among the following having
conformationally locked chair-boat-chair form is:

111. The major products A and B in the following


synthetic sequence are:

114. The major product formed in the following reaction


sequence is:

112. The major product formed in the following reaction


is:

115. The major product in the following reaction


sequence is:

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116. Structures of A and B in the following synthetic
sequence are:

120. Optically pure isomers A and B were heated with


NaN3 in DMF. The correct statement from the following
is

A. A gives optically pure D and B gives optically pure C


B. A gives racemic mixture of C and B gives optically pure
117. In the following reaction, the ratio of A:B:C is (* C
indicates labelled carbon): C. A gives optically pure C and B gives racemic C
D. A gives optically pure D and B gives racemic D

121. A molecular orbital of a diatomic molecule changes


sign when it is rotated by 180° around the molecular
axis. This orbital is
A. 1 : 1 : 1 B. 1 : 2 : 1
C. 2 : 1 : 1 D. 3 : 2 : 1 A.

118. Structure of the major product in the following 122. IR active normal modes of methane belong to the
synthetic sequence is: irreducible representation:

A. E + A1 B. E + A2
C. T1 D. T2

123. The symmetric rotor among the following is

A. CH4 B. CH3Cl
C. CH2Cl2 D. CCl4
119. Major product formed in the following synthetic
sequence on the monoterpene pulegone is:
124. The nuclear -factors of 1H and 14N are 5.6 and 0.40
respectively. If the magnetic field in an NMR
spectrometer is set such that the proton resonates at 700
MHz, the 14N nucleus would resonate at
A. 1750 MHz B. 700 MHz
C. 125 MHz D. 50 MHz

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CSIR UGC NET CHEMICAL SCIENCE JUNE 2015
125. The spectroscopic technique, by which the ground 132. Consider the progress of a system along the path
state dissociation energies of diatomic molecules can be shown in the figure. S (B C) for one mole of an ideal
estimated, is gas is then given by
A. microwave-spectroscopy
B. infrared spectroscopy
C. UV-visible absorption spectroscopy
D. X-ray spectroscopy

126. The term symbol for the first excited state of Be


with the electronic configuration 1s22s13s1 is
A. 3S1 B. 3So
C. S0
1 D. 2S1/2

127. Which of the following statements is INCORRECT?


A. A Slater determinant is an antisymmetrized
wavefunction
B. Electronic wavefunction should be represented by
Slater determinants Wrong question: Marks to all who attempted
C. A Slater determinant always corresponds to a
particular spin state 133. A thermodynamic equation that relates the
D. A Slater determinant obeys the Pauli exclusion chemical potential to the composition of a mixture is
principle known as
A. Gibbs-Helmholtz equation
128. Compare the difference of energies of the first B. Gibbs-Duhem equation
excited and ground states of a particle confined in (i) a 1- C. Joule-Thomson equation
d box ( 1), (ii) a 2-d square box ( 2) and (iii) a 3-d cubic D. Debye-Huckel equation
box ( 3). Assume the length of each of the boxes is the
same. The correct relation between the energy 134. According to transition state theory, the
differences 1, 2 and 3 for the three cases is temperature-dependence of pre-exponential factor (A)
A. 1 > 2 > 3 B. 1 = 2 = 3 for a reaction between a linear and a non-linear
C. 3 > 2 > 1 D. 3 > 1> 2 molecule, that forms products through a non-linear
transition state, is given by
129. The correct statement about both the average value A. T B. T2
of position (<x>) and momentum (<p>) of a l-d harmonic C. T-2 D. T-1.5
oscillator wavefunction is
135. For a given ionic strength, (I) rate of reaction is
A <.x> 0and<p> 0 B. <.x> = 0 but <p> 0 given by
C. <.x> = 0 and <p> = 0 D. <.x> 0 and <p> = 0
Log =4 0.5 l(I)1/2.
130. The value of the commutator [x, [x, px]] is
A ihx B. -ih Which of the following reactions follows the above
C. ih D. 0 equation?

A. S2 +I B. Co(NH3)5 Br2+ + OH
131. The equilibrium constants for the reactions
C. CH3COOC2H5 + OH D. H+ + Br- + H2O2
Ch4(g) + 2H20(g) ⇌ CO2(g) + 4H2(g) and
136. For a reaction on a surface:
CO(g) + H2(g) ⇌ CO2(g) + H2(g) are K1 and K2,
respectively. The equilibrium constant for the reaction
Ch4(g) + H2(g) ⇌ CO(g) + 3H2(g) is

A K1.K2 B. K1 - K2
C. K1/ K2 D. K2 -K1

A. [H2] B. 1/[H2]
C. [H2]1/2 D. 1/[H2]1/2

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137. The temperature-dependence of an electrochemical 143. The stability of a lyophobic colloid is the
cell potential is: consequence of
A G/nFT B. H/nF A. van der Waals attraction among the solute- solvent
C. S/nF D. S/nFT adducts ·
B. Brownian motion of the colloidal particles
138. The single-particle partition function (f) for a C. Insolubility of colloidal particles in solvent
certain system has the form f = A VeBT. The average D. Electrostatic repulsion among double- layered
energy per particle will then be (k is the Boltzman colloidal particles
constant)
A. B kT B. B kT2 144. In a conductometric experiment for estimation of
C. kT/B D. kT/B2 acid dissociation constant of acetic acid, the following
values were obtained in four sets of measurements:
139. The indistinguishability correction in the Boltzmann
formulation is incorporated in the following way: (N = 1.71 10-5, 1.77 10-5, 1.79 10-5 and 1.73 10-5.
total number of particles; J =. single-particle partition The standard deviation of the data would be in the range
function) of:
A. Replace f by f/N!
B. Replace fN by fN/N! A. 0.010 10-5 - 0.019 10-5
C. Replace f by f/ln(N!) B. 0.020 10-5 - 0.029 10-5
D. Replace fN by fN/ln(N!) C. 0.030 10-5 - 0.039 10-5
D. 0.040 10-5 - 0.049 10-5
140. In a photochemical reaction, radicals are formed
according to the equation 145. Silver crystallizes in face-centered cubic structure.
The 2ndorder diffraction angle of a beam of X-ray ( = l ̇ )
of (111) plane of the in the range of crystal is 30°.
Therefore, the unit cell length of the crystal would be
A. a= 3.151 ̇ B. a= 3.273 ̇
If l is the intensity of light absorbed, the rate of the C. a= 3.034 ̇ D. a= 3.464 ̇
overall reaction is proportional to
A. I B. I1/2
C. I[C4H10] D. I1/2[C4H10]l/2

141. Conductometric titration of a strong acid with a


strong alkali (MOH) shows linear fall of conductance up
to neutralization point because of:
A. formation of water
B. increase in alkali concentration
C. faster moving H+ being replaced by slower moving M+
D. neutralization of acid

142. Find the probability of the link in polymers where


average values of links are (a) 10, (b) 50 and (c) 100.
A (a) 0.99, (b) 0.98, (c) 0.90
B. (a) 0.98, (b) 0.90, (c) 0.99
C. (a) 0.90, (b) 0.98, (c) 0.99
D. (a) 0.90, (b) 0.99, (c) 0.98

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