Net Chemicalscience June2015
Net Chemicalscience June2015
Net Chemicalscience June2015
JUNE 2015
SOLVED PAPER
IfAS
http://ifasonline.com
PART-A
Each letter moves one step to its right and the extreme
right letter takes the first position, completing one
operation. After which of the following numbers of
operations do the Cs not sit side by side?
(1) 3 (2) 10 (1) a (2) πa
(3) 19 (4) 25 (3) a/π (4) a/2π
4. An infinite row of boxes is arranged. Each box has half 10. The product of the perimeter of a triangle, the radius
the volume of the previous box. If the largest box has a of its in-circle, and a number gives the area of the
volume of 20 cc, what is the total volume of all the boxes? triangle. The number is:
(1) ¼ (2) 1/3
(1) Infinite (2) 400 cc (3) ½ (4) 1
(3) 40 cc (4) 80 cc
1. If
5. Find the missing element based on the given pattern: 2
PART-B
21. The biological functions of carbonic anhydrase and 28. Q value for the reaction 13N(n, p)13C is 3.236 MeV.
carboxypeptidase A, respectively' are The threshold energy (in MeV) for the reaction 13C(p,
A. interconversion of CO2 and carbonates, and hydrolysis n)13N is
of peptide bond A -3.236 B. -3.485
B. gene regulation and interconversion of CO2 and C. 3.485 D. 3.845
carbonates
C. gene regulation and hydrolysis of peptide. bond 29. The 119Sn NMR chemical shift (approximately in
D. interconversion of CO2 and carbonates and gene ppm) corresponding to (η5-Cp)2Sn (relative to Me4Sn) is
regulation A. -4 B. +137
C. +346 D. -2200
22. The Fe-Nporphyrin bond distances in the deoxy- and
oxy-hemoglobin, respectively, are 30. All forms of phosphorus upon melting, exist as:
A. 2.1 and 2.0 Å B. 2.0 and 2.0 Å
C. 2.2 and 2.3 Å D. 2.3 and 2.5 Å
40. Intense band generally observed for a carbonyl group 45. The correct relation between the following
in the IR spectrum is due to compounds is
A. The force constant of CO bond is large
B. The force constant of CO bond is small
C. There is no change in dipole moment for CO bond
stretching
D. The dipole moment change due to CO bond stretching
is large A. enantiomers B. diastereomers
C. homomers (identical) D. constitutional isomers
61. Heat capacity of a species is independent of 68. The lowest energy-state of an atom with electronic
temperature if it is configuration nslnp1 has the term symbol
A. tetratomic B. triatomic A. 3P1 B. lP1
C. diatomic D. monatomic C. 3P2 D.3P0
62. In a chemical reaction: PCl5(g) ⇌ PC13(g) + Cl2(g), 69. Energy of interaction of colloidal particles as a
xenon gas is added at constant volume. The equilibrium function of distance of separation can be identified as (1)
A. will shift towards the reactant van der Waals, (2) double layer, (3) van der Waals and
B. will shift towards the products double layer. The correct order of interactions in the
C. will not change the amount of reactant and products figure corresponding to curves (a). (b) and (c),
D. will increase both reactant and products respectively, is
PART-C
71. Differential pulse polarography (DPP) is more 76. The geometries of [Br3]+ and [I5]+, respectively, are
sensitive than D.C. Polarography (DCP). Consider A. trigonal and tetrahedral
following reasons for it B. tetrahedral and trigonal bipyramidal
l. Non-faradic current is less in DPP in comparison to C. tetrahedral and tetrahedral
DCP D. linear and trigonal pyramidal
2. Non-faradic current is more in DPP in comparison to
DCP 77. According to Wade's theory the anion [B12H12]2-
3. Polarogram of DPP is of different shape than that of adopts
DCP A. closo - structure B. arachno - structure
Correct reason(s) is/are: C. hypo - structure D. nido – structure
A. l and 3 B. 2 and 3
C. 2 only D. 1 only 78. Considering the inert pair effect on lead, the most
probable structure of
72. Considering the following parameters with reference
to the fluorescence of a solution: PbR2 [R = 2, 6-C6H3 (2, 6-Pr2C6H3)2] is:
80. Match the complexes given in column P with the 85. The reductive elimination of Ar-R (coupled product)
electronic transitions (mainly responsible for their from A is facile when
colours) listed in column Q
A. R = CH3 B. R = CH2Ph
C. R = CH2COPh D. R = CH2CF3
The correct answer is 86. The total number of metal ions and the number of
A. (i)-(a), (ii)-(c) and (iii)-(b) coordinated imidazole units of histidine in the active site
B. (i)-(d), (ii)-(h) and (iii)-(c) of oxy- hemocyanin, respectively, are
C. (i)-(a), (ii)-(c) and (iii)-(d) A. 2Cu2+ and 6 B. 2Fe2+ and S
D. (i)-(a), (ii)-(b) and (iii)-(c) C. 2Cu+ and 6 D. Fe2+ and 3
81. The following statements are given regarding the 87. Match the action of H2O2 in aqueous medium given in
agostic interaction C-H…Ir observed in [lr(Ph3P)3CI]. column P with the oxidation/ reduction listed in column
1. Upfield shift of C-H proton in 1H NMR spectrum Q:
2. Increased acid character of C-H
3. VC-H in IR spectrum shifts to higher wave number
The correct answer is/are
A. 1 and 3 B. 2 and 3
C. 1 and 2 D. 3 only
108. The correct reagent combination A and the major 110. The major product formed in the following reaction
product B in the following reaction sequence are: is:
118. Structure of the major product in the following 122. IR active normal modes of methane belong to the
synthetic sequence is: irreducible representation:
A. E + A1 B. E + A2
C. T1 D. T2
A. CH4 B. CH3Cl
C. CH2Cl2 D. CCl4
119. Major product formed in the following synthetic
sequence on the monoterpene pulegone is:
124. The nuclear -factors of 1H and 14N are 5.6 and 0.40
respectively. If the magnetic field in an NMR
spectrometer is set such that the proton resonates at 700
MHz, the 14N nucleus would resonate at
A. 1750 MHz B. 700 MHz
C. 125 MHz D. 50 MHz
A. S2 +I B. Co(NH3)5 Br2+ + OH
131. The equilibrium constants for the reactions
C. CH3COOC2H5 + OH D. H+ + Br- + H2O2
Ch4(g) + 2H20(g) ⇌ CO2(g) + 4H2(g) and
136. For a reaction on a surface:
CO(g) + H2(g) ⇌ CO2(g) + H2(g) are K1 and K2,
respectively. The equilibrium constant for the reaction
Ch4(g) + H2(g) ⇌ CO(g) + 3H2(g) is
A K1.K2 B. K1 - K2
C. K1/ K2 D. K2 -K1
A. [H2] B. 1/[H2]
C. [H2]1/2 D. 1/[H2]1/2