Cta 3

Sec: INCOMING Sr.
IIT_CO-SC Date: 20-09-20

Time: 3HRS Max. Marks:180
Name of the Student: ___________________ H.T. NO:
20-09-20_INCOMING.SR_CO-SUPER CHAINA _Jee-Adv_CTA-3_SYLLABUS
PHYSICS: PT-1 & PT-5 SYLLABUS ONLY
CHEMISTRY: PT-1 & PT-5 SYLLABUS ONLY
MATHEAMTICS: PT-1 & PT-5 SYLLABUS ONLY

Narayana IIT Academy 20-09-20_Incoming.Sr.IIT_CO-SC _JEE-Adv_CTA-3(P-II)_Q’P
Time: 3:00 Hours IMPORTANT INSTRUCTIONS Max Marks: 180
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Sec– I(Q.N: 01 – 10) Questions with Single Correct Choice 3 -1 10 30
Questions with Comprehension Type
Sec– II(Q.N: 11 – 16) 3 -1 6 18
(3 Comprehensions – 2 +2+2 = 6Q)
Sec– III(Q.N: 17 – 20) Matrix Matching Type 3 -1 4 12
Total 20 60
CHEMISTRY:
Sec – I(Q.N : 21 – 30) Questions with Single Correct Choice 3 -1 10 30
Sec – II(Q.N : 31 – 36) 3 -1 6 18
Sec – III(Q.N : 37 – 40) Matrix Matching Type 3 -1 4 12
Total 20 60
MATHEMATICS:
Sec – I(Q.N : 41 – 50) Questions with Single Correct Choice 3 -1 10 30
Sec – II(Q.N: 51 – 56) 3 -1 6 18
Sec – III(Q.N : 57 – 60) Matrix Matching Type 3 -1 4 12
Total 20 60
SR.IIT_CO-SC Page. No. 2
A dull mind gets bored easily. A curious mind expands forever.

PHYSICS Max Marks: 60
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
1. In the diagram shown in figure, find the magnitude and nature of zero error. Given
10VSD=9MSD and 1MSD=1mm (the diagram represents fully closed jaws position)
A) + 0.05 cm B) – 0.05 cm C) + 0.04 cm D) – 0.4 mm
2. In Searle’s experiment, which is used to find Young’s modulus of elasticity, the

diameter of experimental wire is D = 0.05 cm (measured by a scale of least count 0.001
cm) and length is L = 110 cm (measured by a scale of least count 0.1 cm). A weight of 50
N causes an extension of l = 0.125 cm (measured by a micro meter of least count 0.001
cm). Find maximum possible error in the values of Young’s modulus. Screw gauge and
meter scale are free from error.
A) 1.09  1010 N / m 2 B) 1.09  109 N / m 2
C) 2.09  1010 N / m 2 D) 1.98  109 N / m 2
p2
3. During an experiment, an ideal gas is found to obey a condition = constant.
ρ
( ρ = density of the gas). The gas is initially at temperature T, pressure and density ρ .
The gas expands such that density changes to ρ /2.
A) The pressure of the gas changes to 2 p
B) The temperature of the gas changes to 2 T

C) The graph of the above process on p-T diagram is parabola
D) The graph of the above process on p-T diagram is an ellipse

4. The temperature of an iron piece is heated from 30C to 90C . What is the change in its
temperature on the Fahrenheit scale and on the kelvin scale?
A) 90F & 60 K B) 108F & 60 K C) 78F & 60 K D) 180F & 60 K
5. Find the potential at the circumference of a uniformly charged thin disc having surface
charge density  .
R R R 2 R
A) V  B) V  C) V  D) V 
 0 0  2 0  0
6. A non-conducting disc of radius a and uniform positive surface charge density  is

placed on the ground with its axis vertical. A particle of mass m and positive charge q is
dropped, along the axis of the disc from a height H with zero initial velocity. The
particle has q / m  4 0 g /  . Find the value of H if the particle just reaches the disc.
3a 4 5a
A) H  B) H  a C) H  D) H  a
2 3 4
7. Figure shows the part of a circuit. Calculate the power dissipated in 3 resistance. What
is the potential difference VC  VB ?
A) P  30W & VC  VB  30V B) P  27W & VC  VB  20V
C) P  40W & VC  VB  15V D) P  18W & VC  VB  25V

8. In the diagram shown, the charge +Q is fixed. Another charge +2q and mass M is
projected from a distance R from the fixed charge. Minimum separation between the two
1
charges if the velocity becomes times of the projected velocity, at this moment is
3
(Assume gravity to be absent)
3 1 1
A) R B) R C) R D) None of these
2 3 2
9. If T be period of revolution of a planet revolving around sun in an orbit of mean radius

R, then identify the incorrect graph.
A) B)
C) D) None of these

10. Distance between the centres of two stars is 10a . The masses of these stars are M and
16M and their radii a and 2a respectively. A body of mass m is fired straight from the
surface of the larger star towards the smaller star. What should be its minimum initial
speed to reach the surface of the smaller star? Obtain the expression in terms of G, M
and a .
5GM GM 15GM 3 5 GM
A) Vmin  B) Vmin  C) Vmin  D) Vmin 
2a a 2a 2 a
SECTION - II
(PARAGRAPH TYPE)
This section contains 3 Paragraph of questions. Each paragraph has 2 multiple choice questions based on
a paragraph. Each question has 4 choices A), B), C) and D) for its answer, out of which ONLY ONE IS correct.
Paragraph for Question Nos. 11 & 12:
To find index error (e) distance between object needle and pole of the concave mirror is
20 cm. The separation between the indices of object needle and mirror was observed to be
20.2 cm. In some observation, the observed image distance is 20.2 cm and the object
distance are 30.2 cm.
11. Find the index error.
A) – 0.2 cm B) 0.4 cm C) – 0.4 cm D) 0.2 cm
12. Assuming equal Index errors for object and image pin, what is the focal length of the
mirror?
A) – 15 cm B) + 15 cm C) – 12 cm D) – 20 cm

Paragraph for Question Nos. 13 &14:
One mole of a monoatomic ideal gas is taken through the cycle shown in figure.
A  B Adiabatic expansion
B  C Cooling at constant volume
C  D Adiabatic compression
D  A Heating at constant volume
The pressure and temperature at A, B, etc., are denoted by p A , TA ; pB , TB etc, respectively.
2 1
Given, TA  1000 K , pB    p A and pC    p A .
3 3
0.4
2
Given,    0.85 and R  8.31J / mol  K
3
13. Find the work done in process A  B
A) 1575J B) 1700J C) 2025.83J D) 1869.75J
14. Find the heat lost by the gas in process B  C
A) 5000J B) 4800J C) 6548J D) 5297.625J
A voltmeter of resistance R1 and an ammeter of resistance R2 are connected in series
across a battery of negligible internal resistance. When a resistance R is connected in
parallel to voltmeter, reading of ammeter increases three times while that of voltmeter
reduces to one third.

15. Find the value of R1 in terms of R

A) R1  8 R B) R1  4 R C) R1  2 R D) R1  16 R
16. Find the value of R2 in terms of R
8R 8R 8R
A) R2  B) R2  8 R C) R2  D) R2 
3 5 9
SECTION - III
(Matching List Type)
This section contains four questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
17. |Gravitational Potential| on the surface of a solid sphere is x and radius is y. Match the
following two columns.
COLUMN – I COLUMN – II
x
A) Field strength at distance 2y from centre P)
2y
y x
B) Potential at distance from centre Q)
2 2
y x
C) Field strength at distance from centre R)
2 4y
D) Potential at distance 2 y from centre S) None

A) A-R, B-S, C-P, D-Q B) A-R, B-S, C-Q, D-P
C) A-S, B-R, C-P, D-Q D) A-R, B-P, C-S, D-Q

18. Match the two columns
(A) Boltzmann constant (P)  ML2T 1 
(B) Coefficient of viscosity (Q)  ML1T 1 
(C) Planck constant (R)  MLT 3 K 1 
(D) Thermal conductivity (S)  ML2T 2 K 1 
A) A-S, B-R, C-Q, D-P B) A-S, B-Q, C-P, D-R
C) A-Q, B-S, C-P, D-R D) A-S, B-Q, C-R, D-P
19. Three liquids A, B and C having same specific heats have masses m, 2m and 3m. Their
temperatures are  , 2 and 3 respectively. For temperature of mixture, match the
following two columns.
5
(A) When A and B are mixed (P) 
2
5
(B) When A and C are mixed (Q) 
3
7
(C) When B and C are mixed (R) 
3
13
(D) When A, B and C all are mixed (S) 
5
A) A-P, B-Q, C-R, D-S B) A-R, B-S, C-Q, D-P
C) A-Q, B-P, C-S, D-R D) A-R, B-P, C-S, D-Q

20. Four charges Q1 , Q2 , Q3 and Q4 of same magnitude are fixed along the x axis at
x  2a , a ,  a and 2a , respectively. A positive charge q is placed on the positive
y axis at a distance b  0 . Four options of the signs of these charges are given in
Column I. The direction of the forces on the charge q is given in Column II. Match the
Column and select the correct answer using the code given below the columns.
(A) Q1 , Q2 , Q3 , Q4 all positive (P) x
(B) Q1 , Q2 positive; Q3 , Q4 negative (Q) x
(C) Q1 , Q4 positive; Q2 , Q3 negative (R) y
(D) Q1 , Q3 positive; Q2 , Q4 negative (S) y
A) A-R, B-S, C-P, D-Q B) A-R, B-S, C-Q, D-P
C) A-S, B-R, C-P, D-Q D) A-R, B-P, C-S, D-Q

CHEMISTRY Max Marks: 60
SECTION – I
21.
A) B)
C) D)
22. The correct statement describing the relationship between is
X Y Z
A) X and Y are resonance structures and Z is a tautomer
B) X and Y are tautomers and Z is a resonance structure
C) X, Y and Z are all resonance structures
D) X, Y and Z are all tautomers

23.
Product is
A) B)
C) D)
24.
A and B are respectively
A) B)
C) D)

25. Choose the correct statement(s) concerning reactions of the two stereoisomers 3-tert-
butyl-5-methylbromocyclohexane.
(i) (ii)
(i) 1 will undergo SN1 reactions faster than 2
(ii) 1 will undergo E1 reactions faster than 2
(iii) 1 and 2 undergo SN1 reactions at some rate
A) (i) B) (ii) C) (iii) D) (i) & (ii)
26. The major product of the following reaction is:
A) B)

C) D)
27. KI in acetone undergoes SN2 reaction with each of P, Q, R and S.
(P) H 3C  Cl (Q)
(R) (S)
The rate of the reaction vary as:
A) P > Q > R > S B) S > P > R > Q
C) P > R > Q > S D) R > P > S > Q
28. Identify correct reactivity order for ArSN reaction
A) B)

C)
D) (1) and (2) are correct
29. The aromaticity of the following heterocycles follows the order:
A) pyridine > thiophene > pyrrole > furan
B) furan > pyrrole > thiophene > pyridine
C) thiophene > pyridine > pyrrole > furan
D) pyrrole > furan > pyridine > thiophene
30. The value of ‘n’ for the following molecule according to Huckel’s rule is
A) 16 B) 4 C) 3 D) 14

SECTION - II
(PARAGRAPH TYPE)
Compound having atleast one   bond gives addition reaction. Alkene behaves as
nucleophile and hence it gives an electrophilic addition reaction. Electrophilic addition
reaction in most of the cases takes place by formation of carbocation as reaction
intermediate.
31. Which one of the following is NOT correct for electrophilic addition of alkenes?
A) In the first step, alkene reacts with electrophile to form a   complex .
B)   complex converts into carbocation and the step is rate-determination step.
C) Product formation takes place by formation of most stable reaction intermediate.
D) Rearrange product is not formed in addition reaction with HBr.
32. In the given reaction
A)
B)
C) Mixture of (1) and (2)

D)

24 gm of optically pure tartaric acid is dissolved in water to make 240 ml solution. It is

kept in 20 cm polarimeter tube and plane polarised light is passed through it to produce
rotation of – 2.4o. Answer the following questions:
33. If mixture of d and l tartaric acid has the specific rotation – 4.0o, calculate the % of optical
purity of this mixture?
A) 50 % B) 66.67 % C) 33.33 % D) None of these
34. Calculate the % of d tartaric acid in a mixture of d and l tartaric acid which has the
observed specific rotation + 6.0o.
A) 25 % B) 75 % C) 50 % D) 66.67 %

Doctor Sandy Robertson worked out following reaction sequence.
35. Select true statement(s):

A) When D is treated with D 2 / Pd  BaSO 4 it gives cis-alkene
B) When D is treated with Na liq. ND3 it gives trans-alkene
C) Both (1) and (2)
D) None of the above

36. True about D is -
A) It gives (+)ve Tollen’s Test
B) It gives (+)ve NaHCO 3 Test
C) It reacts with dilute NaOH
D) It gives faster electrophilic addition reaction than propene.
SECTION - III
37. Match the following columns:
(Common Name) (Systematic)
(A) (P) React with Na
(B) (Q) React with NaOH
(C) (R) React with NaHCO 3
(D) (S) React with NaNH 2
A) 1  PQR, 2  PQRS,3  QR,4  PS

B)1  PQRS,2  PQRS,3  PQS, 4  PQRS
C) 1  PQR,2  PQR,3  PQR,4  PQR
D)1  PQRS, 2  PQR,3  PQRS,4  PQR

38. Match the Column – I with Column – II (no. of structural isomers produced in
  E 2 elimination) and select the correct answer.
(A) (P) Three
(B) (Q) Zero
(C) (R) One
(D) (S) Two
A) A-S, B-P, C-Q, D-R B) A-S, B-R, C-P, D-Q

C) A-Q, B-P, C-R, D-S D) A-R, B-S, C-Q, D-P
39. For substrates in Column – I, match the number of mol of CH 3MgX required per mol.
(A) CH 3COOC 2 H 5 (P) 1
(B) CH 3COCI (Q) 2
(C) (R) 3
(D) HOCH 2COOC 2 H 5 (S) 4

A) A-P, B-R, C-Q, D-S B) A-Q, B-P, C-R, D-S
C) A-Q, B-Q, C-S, D-R D) A-R, B-P, C-S, D-Q
40. Matrix type
COLUMN – I (reaction) COLUMN – II (type of reaction)
CH 3CO CH 2  CH 2  F 
ALC . KOH


(A) (P) E1
CH 3COCH  CH 2
(B) (Q) E2
(C) (R) E 1CB
(D) (S) Ei
A) A-R, B-S, C-Q, D-P

B) A-S, B-R, C-P, D-S
C) A-R, B-Q, C-P, D-S
D) A-Q, B-S, C-R, D-P

MATHEMATICS Max Marks: 60
SECTION – I
41. Let f:{x, y, z}  {1, 2, 3} be a one-one mapping such that only one of the following
three statements is true and remaining two are false:
I)f  x   2,
II) f  y   2,
III)f  z   1
then select the CORRECT alternative
A) f ( x)  f ( y )  f ( z ) B) f ( x)  f ( y )  f ( z )
C) f ( y )  f ( x)  f ( z ) D) f ( y )  f ( z )  f ( x)
 ln  x( x 2  1)  is (Here A is the largest possible

1
42. The function f : A  R, f ( x) 
4x 1
2
domain of the given function)

A) One-one and Onto B) One –one and Into
C) Many-one and Onto D) Many one and Into
k n
1
43. Let f (k )  2k then the value of lim16
n 
f (n)
 k 1 2 2 f (k )
 2 f ( k )  1
is
1
A) 13 B) 1 C) D) 21
13
44. Let ' f ' be a bounded, differentiable and increasing function then
lim  f (sin x.tan x)  f ( x 2 )  , where [.] is greatest integer function is equal to
x 0
A) 1 B) 0 C) –1 D) does not exists

  x   
45. If lim x  tan 1      1 then ordered pair(s)   ,   can be
x 
  x  4 
A) (2000, 2011) B) (0, 1) C) (5, 3) D) (1, 0)

n 1
1
46. Let f ( x)  x lim
n 
 r  0 ( rx  1)  ( r  1) x  1
, then
A) f ( x) is continuous but not differentiable at x  0
B) f ( x) is both continuous and differentiable at x  0
C) f ( x) is neither continuous nor differentiable at x  0
D) f ( x) is a periodic function
47. Consider the following statements:
I) If the right hand limit of the derivative of the function at x  a is equal to left hand
limit of the derivative of the function at x  a , then the function is differentiable at x  a
II) The right hand derivative of the function f ( x) at x  a is also the right hand limit of
the derivative of the function f ( x) at x  a
f ( a  h)  f ( a  h)
III) lim 
 f '(a )
h 0 2h
IV) If the right hand limit of the function is equal to left hand limit of the function
at x  a , then the function is differentiable at x  a
Then the number of statements which are always CORRECT out of the four above is
A) 0 B) 1 C)2 D) 3
dx
48. If I   , then I equals
 
sin  x   cos x
 3
 
A) 2 log sin x  sin  x    C B) 2 log sin  x   sec x  C
 3  3

C) 2 log sin x  sin  x    C D) None of these
 3


49.  ln  cot a  tan x  dx , where a   0,  is
a
0  2
A) a ln (sin a) B) a ln (sin a) C) a ln (cos a) D) none of these


  x  4 x  ln 1  Tanx  dx 
4
2
50.
0
3 3 2 2
A) B) ln 2 C) D) ln 2
192 192 96 96
SECTION - II
(PARAGRAPH TYPE)
0 , x  a
The unit step function u  x  a  is defined as u  x  a    .
1 , x  a
Domain of u  x  a  is R and its range is 0,1 .
The graph of y  u  x  a  is as shown below:
y
1 
0 a x
Answer the following questions.
51. Let f  x    x  0  x  3 where   denotes the greatest integer function. The

representation of f  x  in terms of unit step function is
A) f  x   u  x   u  x  1  u  x  2    x  3 , 0  x  3
B) f  x   u  x  1  u  x  2   u  x  3 , 0  x  3
C) f  x   u  x  1  u  x  2   u  x  3 , 0  x  3
D) f  x   u  x  1  2u  x  2   3u  x  3 , 0  x  3

52. The graph of a function y  f  x  , 0  x  3 is shown below: (The function is right
continuous at integers, hence assume the values of the function at integers from right
continuity)
2  
1 
0 1 2 3 x
1  
Representation of f  x  in terms of the unit step function is given by

A) f  x   x  u  x   u  x  1   2u  x  2 
B) f  x   x  u  x   u  x  1   u  x  2   2u  x  3 , 0  x  3
C) f  x   x  u  x   u  x  1   u  x  1  3u  x  2  , 0  x  3
D) f  x   xu  x   u  x  1  2u  x  2  , 0  x  3
Let p  x be a polynomial with positive leading coefficient, p  0  0 ; and
x
p  p  x   x. p  t  dt ,  x  R. Then
0
53. The degree of p  x  is
A) 2 B) 1 C) 4 D) 3
54. A solution of p '  x   p  x  is
A) x=3 B) x=1 C) x=2 D) No solution
Let f ( x) be defined as f ( x)  maximum{a, b, c} where
 n sin x  cos x   n
a  lim lim
n   1  n   n
 n sin x  cos x   n
b  lim lim
n   1  n   n
   (n  1) 
c  lim 1  cos  ....  cos , then
n  4n  2n 2n 

55. The range of f ( x) is
1 1   1 
C)  , 2 
1
A) [0,1] B)  ,  D)  ,1
2 2  2   2 
56. The function is differentiable for all x 

  
A) R   2n  1 : n  I  B) R  n : n  I 
 4 
  
C) R D) R  n : n  I 
 2 
SECTION - III
57. Match the following

Column1 Column2
A) 2
( x 1) x
3 P) 0
If f ( x)  4  8 x 3
 72  4 2
is defined x  a , then the minimum
value of f (a) 
If 2 f ( x 2 )  3 f 
B) 1  Q) 4
2 
 x 2  1, ( x  0) then f (1) 
x 
C) 398
{ x  r} R) 3
f ( x)  [ x]   ,where [] denotes the greatest integer function
r 1 398
and {.} denotes the fractional part of x, then f (3) 

D) The number of points of discontinuity of S) 2
  
f ( x)  [tan x[cot x]]; x   ,  where [.] denotes the greatest integer
12 2 
function.
A) A-P, B-P, C-R, D-R B) A-P, B-Q, C-R, D-Q
C) A-Q, B-P, C-S, D-R D) A-P, B-Q, C-S, D-R

58. Column I lists some functions and Column II lists its properties. Match the items of
Column A with those of Column B.
x
A) n n
x
P) Continuous at all points in its
f ( x)  lim x
,xR
n  n  n
x
domain
B) 1 Q) Discontinuous at finite but
f ( x)  lim n 4n  x 2 n  , x  R  {0}
n  x2n nonzero number of point/s in its
domain
C) n(en  x n ) R) Not differentiable at finite but
f ( x)  lim , x  0, x  R
n  n nonzero number of point/s in its
domain
D) f ( x)  lim 2 n cos 2 n x  sin 2 n x, x  R S) Not differentiable at infinitely
n 
many points in its domain.
A) A-P,R; B-Q,R; C-P,R; D-P,S B) A-Q,R; B-P,R; C-P,R; D-P,S

C) A-Q,R; B-P,R; C-P,S; D-P,R D) A-P,S; B-P,R; C-P,R; D-Q,R
59. Match the following.

1
A) dx P)

tan x
 x
2
1
B) dx Q) 1  12 3

  1 3

n  x  x 2 
2 
2 x2  x2  
 
C) 1 1  3x R) n(1  x)
4  x(1  x)
dx
D) d x S) n(1  x )
 1 x
A) A-P, B-S, C-Q, D-P B) A-P, B-Q, C-R, D-S

C) A-R, B-P, C-Q, D-P 4) A-R, B-P, C-Q, D-S

60. Match the following:
 x   greatest integer less than or equal to 'x'
A)  4 P) 3
0  tan 6  x   x   tan  x   x   dx 
4
25
B) 2 Q) 2
x 6  3 x5  7 x 4
I1  
2 x4  2
dx
2  x  1  11 x  1  14
1 2
I2  
3  x  14  2
dx
then the I1  I 2 
2  1 x 1 x  1 
C) 3 2 R) 100
 1 
 tan  tan  dx 
x2  1 x  3
D) 2 x 1 S) 5
f  x  cos   x  3  2 sin   x  3 where
 
0  x  4. The number of points of local

extrema are
A) A-P, B-R, C-Q, D-Q B) A-S, B-R, C-Q, D-P

C) A-S, B-P, C-R, D-Q D) A-S, B-R, C-Q, D-Q

Sec: Inc.SR.IIT_CO-SC CTA-3 Date: 20-09-20
Time: 3HRS 2014_P2 Max. Marks: 180
KEY SHEET
PHYSICS
1 A 2 A 3 B 4 B 5 A
6 B 7 B 8 A 9 D 10 D
11 D 12 C 13 D 14 D 15 A
16 A 17 A 18 B 19 C 20 D
CHEMISTRY
21 B 22 A 23 D 24 D 25 D
26 A 27 B 28 A 29 * 30 C
31 D 32 D 33 C 34 B 35 A
36 A 37 B 38 B 39 C 40 A
MATHS
41 C 42 C 43 D 44 B 45 C
46 C 47 A 48 B 49 B 50 B
51 B 52 C 53 A 54 C 55 B
56 D 57 A 58 B 59 C 60 D
Narayana IIT Academy 20-09-20_Inc.Sr.IIT_CO-SC _JEE-Adv_CTA-3_KEY&SOL
SOLUTIONS
PHYSICS
1. Here, zero of Vernier scale lies to the right of zero of main scale, hence, it has positive zero error.
Further, N  0, x  5, LC or VC  0.01cm
Hence, Zero error  N  x  VC  0  5  0.01  0.05cm

Zero correction  0.05cm
 Actual length will be 0.05cm less than the measured length.
stress F / A FL FL
2. Young’s modulus of elasticity is given by Y    
strain l / L lA d2 
l 
 4 
50  1.1 4
Substituting the values, we get Y   2.24  1011 N / m2
1.25 10     5.0 10 
3 4 2
Y L l d  0.1   0.001   0.001 

Now,   2     2   0.0489
Y L l d  110   0.125   0.05 
Y   0.0489 Y   0.0489    2.24  1011  N / m2  1.09  1010 N / m2

3. Ans-(b)
Sol. Conceptual
4. TC  90C  30C  60C

9 9
Using Equation (iii), TF  TC   60C   108 F and T  TC  60 K
5 5
5. To calculate the potential at point P, let us divide the disc in large number of rings with P as centre.
The potential due to one segment between r and r + dr is given as
1 dq
dV  
4 0 r
Here dq   (Area of ring)    2r  dr

SR.IIT_CO-SC Page 2
Education consists mainly of what we have unlearned.

1   2r  dr 
 dV      dr
4 0 r 2 0
Further, r  2 R cos 
 dr  2 R sin  d

Hence, dV  2 R sin  d
2 0
0  R  /2
V   dV 
 0 0
 sin  d
 /2
R
Solving, we get V 
 0
6. Potential at a height H on the axis of the disc V  P . The charge dq contained in the right shown in
figure, dq   2 rdr 
1 dq
Potential of P due to this ring dV   ,
4 0 x
Where x  H 2  r2
1  2 rdr   rdr
dV   
4 0 H 2  r 2 2 0 H 2  r2
 Potential due to the complete disc,
r a  r a rdr   2
VP   dV    a  H2  H
r 0 2 0 r  0
H r
2 2 2 0  
SR.IIT_CO-SC Page 3

a
Potential at centre, O will be V0  (H = 0)
2 0
(a) Particle is released from P and it just reaches point O . Therefore, from conversion of mechanical
energy.
Decrease in gravitational potential energy = increase in electrostatic potential energy
( KE  0 , because Ki  K f  0 )
mgH  qVO  VP 
 q    
or gH     a  a  H  H 
2 2
 (i)
 m   2 0 
q 4 0 g q
   2g
m  2 0 m
Substituting in Equation (i), we get
gH  2 g  a  H  a 2  H 2 
 
H
or   a  H   a2  H 2
2
H
or a2  H 2  a 
2
H2
or a  H  a   aH
2 2 2
4
3 2
or H  aH
4
SR.IIT_CO-SC Page 4

4
or H  a and H  O
3
4
H   a
3
7. Applying Kirchhoff’s junction law at E current in wire DE is 8A from D to E. Now further applying
junction law at D, the current in 3 resistance will be 3A towards D.
Power dissipated in 3 resistance  i R   3   3  27W

2 2
VC  VB
VC  5  1  12  8  2  3  4  2  VB
VC  VB  5  12  16  3  8
or VC  VB  20V
8. Let us conserve angular momentum of 2q about the point at Q

mv1r1 sin 1  mv2 r2 sin  2
 v 
 m v  R sin150  m  rmin sin 90
 3
3
 rmin  R
2
9. Conceptual
10. Let there are two stars 1 and 2 as shown below.
SR.IIT_CO-SC Page 5

Let P is a point between C1 and C2 , where gravitational field strength is zero. Or at P field strength
due to star 1 is equal and opposite to the field strength due to star 2.
GM G 16 M  r
Hence, 2
 2
or 2  4 also r1  r2  10a
r1 r2 r1
 4 
 r2    10a   8a and r1  2a
 4 1
Now, the body of mass m is projected from the surface of larger star towards the smaller one. Between
C2 and P it is attached towards 2 and between C1 and P it will be attracted towards 1. Therefore, the
body should be projected to just cross point P because beyond that the particle is attracted towards the
1 2
smaller star itself from conservation of mechanical energy mvmin = potential energy of the body at P
2
– Potential energy at the surface of the larger star
1 2  GMm 16GMm   GMm 16GMm 

 mvmin      
2  r1 r2   10a  2a 2a 
 GMm 16GMm   GMm 8GMm 
    
 2a 8a   8a a 
1 2  45  GMm
or mvmin   
2  8  a
3 5  GM 
 vmin   
2  a 
11. Index error e = observed distance – actual distance
= separation between indices – distance between object needle and pole of the mirror =20.2 – 20.0 =
0.2 cm
12. u  30.2  0.2  30cm

 u  30cm
v  20.2  0.2  20cm
 v  20cm
1 1 1 1 1
Using the mirror formula,    
f v u 20 30
or f  12cm
Since, it is a concave mirror, therefore focal length is negative
SR.IIT_CO-SC Page 6

13. As for adiabatic change pV   constant

 nRT 
i.e. P    constant (as pV = nRT)
 p 
  1
T  TB   pB  5
i.e.  1  constant so     , where  
p  TA   p A  3
1 2
1
2   2 5
i.e. TB  TA    1000    850 K
3 3
nR TF  TI  1  8.311000  850
so, WAB  
1     5  
 3   1
  
i.e. WAB  1869.75 J
14. For B  C , V = constant so W  0
So, from first law of the thermodynamics Q  U  W  nCV T  0
3   3 
or Q  1   R  TC  850   as CV  R 
2   2 
Now, along path BC, V = constant; p T
pC TC
i.e. 
pB TB
TC 
1 / 3 pA  T  TB  850  452K (ii)
 2 / 3 p A B 2 2
3
So, Q  1   8.31 425  850   5297.625 J
2
[Negative heat means, heat is lost by the system]
15. Let E be the emf of the battery. In the second case main current increase three times while current
through voltmeter will reduce to i/3. Hence, the remaining 3i – i/3 = 8i/3 passes through R as shown in
figure.
i  8i 
VC  VD    R1    R
3 3
Or R1  8 R
SR.IIT_CO-SC Page 7

16.
In the second case, main current becomes three times. Therefore, total resistance becomes 1/3 times or
RR1 1
R2    R1  R2 
R  R1 3
8R
Substituting R1  8 R , we get R2 
3
GM
17.  x or GM  xy
y
GM xy x
(A) E   
 2 y  4 y2 4 y
2
GM  y 3   xy   11 2  11
(B) V  3 1.5 y  0.5    3   y   x
2
y  4   y  8  8
GM  y  xy y x
(C) E  3    3 
y  2  y 2 2y
GM xy x
(D) V   
2y 2y 2
18. Conceptual
19. Conceptual
20. Conceptual
CHEMISTRY
21.
22. Conceptual
24. Conceptual
25. Conceptual
SR.IIT_CO-SC Page 8

26.
It is easier to do nucleophilic substitution on alkyl halides than on aryl halides.

27. With  -bromo carbonyl compounds, substitution leads to two electrophilic groups on neighbouring
carbon atoms. Each has a low-energy empty orbital,  * from C=O and  * from C-Br (this is what
makes them electrophilic), and these can combine to form a molecular LUMO   *  * lower in
energy than either. Nucleophilic attack will occur easily where this new orbital has its largest
coefficients, shown in orange on the diagram.
28. Rate of ArSn reaction (is directionally proportional to) Meisenheimer Complex
29. Aromaticity  Resonance energy
30. Conceptual
 2.4
T 

33.   12
Cl 1  2
10
Optical purity =
 mix  100  4  100  33.33%
 pure 12
6
Optical purity =  100  50
12
34.
% d form = 50 + 25 = 75 %
35. Conceptual
36. Conceptual
37. Conceptual
38. Conceptual
39. Conceptual
40. Conceptual
SR.IIT_CO-SC Page 9

MATHS
41. Case – I f(x)  2 is true, f(y) = 2 and f(z)  1 are false, then
f(x) = 1 or 3, f(y) = 1 or 3 and f(z) = 1
 f is not one-one
Case – II f(x)  2 is false, f(y) = 2 is true, f(z)  1 is false, then
f(x) = 2, f(y) = 2, f(z) = 1
 not possible
Case – III f(x)  2 is false, f(y) = 2 is false, f(z)  1 is true, then
f(x) = 2, f(y) = 1 or 3 f(z) = 2 or 3
 f(x) = 2, f(z) = 3, f(y) = 1
43. Conceptual
44. since sin x . tan x > x2 x  (0, /2)
so, f(sin x . tanx )> f(x2)
hence required limit is 0.
45.
1 
x  
 x  4
tan
Lim   1
x ki 1
x
Apply L’ hospital rule and simplifying we get
    x
2
Lim
1
x 
2x  2x      
2
 2

2


 1
2
   2
  ,   can be (5,3)
x
46. t r 1 
 rx  1 r  1 x  1

 r  1 x  1   rx  1
 rx  1  r  1 x  1
1 1
 
 rx  1  r  1 x  1
n 1
1
 Sn   t r 1
r 0 nx  1
 1, x  0
= 0, x = 0
 1 
 Lt Sn  Lt 1  
n  n 
 nx  1 
Thus, f(x) is neither continuous nor differentiable at x = 0.
Clearly f(x) is not a periodic function.
SR.IIT_CO-SC Page 10

47. Conceptual
   
cos  x   x   
1   3 
48. I=
    
dx
cos   sin  x   cos x
3  3
49.
a
cos  a  x  a
cos x
I   ln dx   ln dx
0
sin a.cos x 0
sin a cos  a  x 
a a
1
adding 2 I   ln dx   2 ln sin a dx   2a ln sin a
0
sin 2 a 0
 
    
Let I   4 x   
4 4
50.  x  ln 1  tan x  dx   4   x  x ln  1  tan   x   dx
0
4  0
 4    4 

 
4
 4 ln 2  x   x  dx  I
0
 4 

 
4
 I  2 ln 2  x   x  dx
0
 4 
3
 ln 2
192
51.
Using the definition of u  x  , we can write f  x  as f  x   u  x  1  u  x  2   u  x  3 , 0  x  3 .

x 0  x  1

52. We have f  x   1 1  x  2 using the definition of u  x  , f  x  can be represented as
2 2  x  3

f  x   x u  x   u  x  1  u  x  1  u  x  2   2u  x  2 
 x u  x   u  x  1  u  x  1  3u  x  2  0 x3

55 & 56:
2 3
 x 1 x
57.. (1) 4x  83  72  4 2  0
 22x  22x  2  72  22x 3  0
 1 1
 22x 1     72
 4 8
2 2x  64 and x  3
f(3) = 0
398
 x  r  398
(3)   x   x
r 1 398 398
 f(x) = [x] + {x} = x
 f(3) = 3
(4)  f(x) is discontinuous when cot x  Integer
 
As x
12 2
 0  cot x  2  3
 Number of points of discontinuous = 3.
58. 1) f (x) =1 x>0

=0 x=0
=-1 x<0
2)
1
The graph shown are y  x 2 , y  and y = 4
x2
  x n 
n  ln  1    
ln  e n  x n   e 
 
3) f(x) = Lim
h   Lim
h 
h h
= 1, oxe
= lnx, x > e

4)
3   3
d d d d
60. 1)
2) Let in then
3) Let
4) at but is point of inflexion.

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Sec: INCOMING Sr.

IIT_CO-SC Date: 20-09-20

Name of the Student: ___________________ H.T. NO:

20-09-20_INCOMING.SR_CO-SUPER CHAINA _Jee-Adv_CTA-3_SYLLABUS

PHYSICS: PT-1 & PT-5 SYLLABUS ONLY

CHEMISTRY: PT-1 & PT-5 SYLLABUS ONLY

MATHEAMTICS: PT-1 & PT-5 SYLLABUS ONLY

SR.IIT_CO-SC Page. No. 2

A dull mind gets bored easily. A curious mind expands forever.

A) + 0.05 cm B) – 0.05 cm C) + 0.04 cm D) – 0.4 mm

2. In Searle’s experiment, which is used to find Young’s modulus of elasticity, the

A) The pressure of the gas changes to 2 p

B) The temperature of the gas changes to 2 T

D) The graph of the above process on p-T diagram is an ellipse

SR.IIT_CO-SC Page. No. 3

A dull mind gets bored easily. A curious mind expands forever.

A) 90F & 60 K B) 108F & 60 K C) 78F & 60 K D) 180F & 60 K

6. A non-conducting disc of radius a and uniform positive surface charge density  is

A) P  30W & VC  VB  30V B) P  27W & VC  VB  20V

C) P  40W & VC  VB  15V D) P  18W & VC  VB  25V

SR.IIT_CO-SC Page. No. 4

A dull mind gets bored easily. A curious mind expands forever.

9. If T be period of revolution of a planet revolving around sun in an orbit of mean radius

SR.IIT_CO-SC Page. No. 5

A dull mind gets bored easily. A curious mind expands forever.

11. Find the index error.

A) – 0.2 cm B) 0.4 cm C) – 0.4 cm D) 0.2 cm

SR.IIT_CO-SC Page. No. 6

A dull mind gets bored easily. A curious mind expands forever.

SR.IIT_CO-SC Page. No. 7

A dull mind gets bored easily. A curious mind expands forever.

15. Find the value of R1 in terms of R

D) Potential at distance 2 y from centre S) None

SR.IIT_CO-SC Page. No. 8

A dull mind gets bored easily. A curious mind expands forever.

(B) Coefficient of viscosity (Q)  ML1T 1 

(C) Planck constant (R)  MLT 3 K 1 

(D) Thermal conductivity (S)  ML2T 2 K 1 

A) A-S, B-R, C-Q, D-P B) A-S, B-Q, C-P, D-R

C) A-Q, B-S, C-P, D-R D) A-S, B-Q, C-R, D-P

A) A-P, B-Q, C-R, D-S B) A-R, B-S, C-Q, D-P

C) A-Q, B-P, C-S, D-R D) A-R, B-P, C-S, D-Q

SR.IIT_CO-SC Page. No. 9

A dull mind gets bored easily. A curious mind expands forever.

(A) Q1 , Q2 , Q3 , Q4 all positive (P) x

(B) Q1 , Q2 positive; Q3 , Q4 negative (Q) x

(C) Q1 , Q4 positive; Q2 , Q3 negative (R) y

(D) Q1 , Q3 positive; Q2 , Q4 negative (S) y

A) A-R, B-S, C-P, D-Q B) A-R, B-S, C-Q, D-P

C) A-S, B-R, C-P, D-Q D) A-R, B-P, C-S, D-Q

SR.IIT_CO-SC Page. No. 10

A dull mind gets bored easily. A curious mind expands forever.

22. The correct statement describing the relationship between is

A) X and Y are resonance structures and Z is a tautomer

B) X and Y are tautomers and Z is a resonance structure

C) X, Y and Z are all resonance structures

D) X, Y and Z are all tautomers

SR.IIT_CO-SC Page. No. 11

A dull mind gets bored easily. A curious mind expands forever.