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    Notefile 1 1691909316

    Uploaded by

    pkiitsamarth

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Notefile 1 1691909316

    Uploaded by

    pkiitsamarth
    5 views14 pages

    Original Title

    51065_noteFile_1_1691909316

    Copyright

    © © All Rights Reserved

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    PDF, TXT or read online from Scribd

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    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    5 views14 pages

    Notefile 1 1691909316

    Uploaded by

    pkiitsamarth

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 14

    OH CH3

    Me Me
    Cl OH
    Chloroxylenol Terpineol

    NH

    SO2NH2

    OH O OH
    NH2
    Sulphanilaimide Morphine

    Detergent

    Cationic Anionic Non-ionic


    They are acetate They contain long Formed by polyethylene
    of or chloride of chain sulphonic glycol and steric acid
    4° amines salt of alcohols
    CH3
    +
    CH3(–CH2)15 – N – CH3Br –
    CH3

    +
    CH3 SO3– N a


    CH3 (CH2 )10 CH2OSO3– N a

    C9H19 O—CH
    ( 2 – CH 2 – O)5 – CH 2 – CH2OH


     C17H35COO2 Ca CH3  CH2 16 CH2OSO3– Na

     +
    Me  (CH2 )15 N MeCl – Me(CH2)11 SO–3 N a

    Me(CH2)11 SO3Na
    H
    N

    N NH2

    NHCOCHCl2

    O2 N CH CH CH2OH

    OH

    O H H
    S CH3
    R C NH
    CH3
    N COOH
    O
    H

    H O O
    H
    N – C – C – N – CH – C
    H O – CH3
    CH2 H CH3
    C
    HO O

    Cl
    CH2 OH O
    H
    H OH H
    H
    H
    HO OH H HO CH2Cl
    O
    H
    ClCH2 O H



     
     
     
     
     
     

     
    CH
    ONa 125º H+
    +CO2 5 Atm B Ac O C
    2

    OH
    OH O COCH3 O COCH3
    COCH3
    COOCH3 COOH
    COOH
    COCH3

    O
    ONa OH O–C–CH3
    H
    +CO2 50125º
    atm. AC2O
    C–ONa C–OH
    (B) (C)
    O O

    OCOCH3
    COOH
    Item – I Item – II
    (drug) (test)
    (A) Chloroxylenol (P) Carbylamine
    Test
    (B) Norethindrone (Q) Sodium Hydrogen
    carbonateTest
    (C) Sulphapyridine (R) Ferric chloride test
    (D) Penicillin (S) Bayer’s test

           
           





    N
    (CH2)2
    N
    (Brompheniramine)

    Br

    List-I List-II
    (a) Valium (i) Antifertility drug
    (b) Morphine (ii) Pernicious anaemia
    (c) Norethindrone (iii) Analgesic
    (d) Vitamin B12 (iv) Tranquilizer
    
    
    
    

    O O O
    HO–C–CH
    2 2–CH–C–NH–CH–C–OCH
    2 2 3
    sp sp sp
    NH 2 CH2
    2
    6 sp carbon

    OH OH
    *
    * Cl
    O
    N NH CH
    O C Cl
    O

    O
    R – C – HN S
    * *
    * Chiral
    center = 3
    N
    O * COOH
    N NH2

    NH

     42 
       100
     111 

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