Chemical Equilibrium (Assignment)

FIITJEE-DPS-MODERN INDIANSCHOOL
WT-2 and FINAL EXAM

Chemical equilibrium:Check List
1. Difference between reversible and irreversible reaction.
2. Equilibrium is also known as dynamic equilibrium. Why?
3. Graphical representation of equilibrium.
4. Definition of forward and backward reaction
5. At equilibrium Gibb's free Energy -0 and entropy change-0

6. Identification of homogenous and heterogenous equilibrium.
7. Characteristics of equilibrium-(3-5 important characteristics).
8. Law of mass action: Statements
9. Derivation for Ke and Kp expression.

10. Relation between Ke and Kp.Unit of Kc and Kp.
11. Numerical based on Kc and Kp.
(a) The following concentration were obtained for the formation of NH,from N, and H,
at equilibrium at 500 K. Find Kç- [N,] = 1.5 *10-2 M; [H,] = 3+ 1o-3 M; [NH] =
1.2 * 10-3 M
(b) Find out the value of K¢ for each of the following equilibria from the value of K,. R=
0.083 bal LK-mol-1
(1) 2NOCI(g) + 2NO() + Cl,(g); K, = 1.8 *10-2,T = 500 K
(ii) CaCO,(s) Ca0(s) + CO,(g); K, = 167; T= 1073 K
(c) What is the equilibrium concentration of each of the substance in equilibrium when
the initial concentrationof ICl was 0.78? 21CI(g) l,(g) + Cl,(g) ; Kç = 0.14
(a) What is the equilibrium concentration of each of the substance in equilibrium when
the initial concentration of BrCl was 3.3+ 10-3;Kç = 36
Note: Solve the Following questions of Chemical Equilibrium NCERT examples: 7.1, 7.2,
7.3,74,7.5,7.6,7.7,7.8,7.9,7.10,7.11.it is mandatory.
12. Relation between Gibbs free energy and equilibrium constant. And numerical based on it from
NCERT textbook.
13. Concept of Equilibrium Constant (Keg) and Reaction Quotient (). and numerical Based on
it
14. The value of AG Ofor the phosphorylation of glucose in glycolysis is 13.8 kJ/mol. Find the
value of K,at 298 K.
15. Hydrolysis of sucrose gives,
Sucrose + H0 GlucOse + Fructose
Equilibrium constant K for the reaction is 2x1013 at 300K.Calculate sG0 at 30OK.

16. Write the Kc and Kp Expression,relation between Kc and Kp and unit of Kc and Kp of the
following reactions:
(A) CaCO, (:)Co(:)+co,(e) (B NH, NH,
(B) 2NH, (g) 3H,(g)+N, (&) () 2H,0()=2H,(g) +0, (e)
() NH,C(s)= NH, (g) +HCI(g) (D) PCI, (s) PCI,(1)+CI, (8)
(D) 3Fe(s)+4H,0(g) Fe0,(s)+4H, (g)
17.Factor affecting the equilibrium constant.
18. Establish a relation between equilibrium Constant of the following Gaseous Reversible process.
(A) AB K, CD K, A+CB+D K,
(B) 2A 2B K. 2C2D K,, K,
(C) 24+ 2C4D+4E K,, A+C2D +2E K,
(D) 24+3B+ 2F 4C+5D+3E K, 4C+5D+3E2A+3B+2F K,
(E) N, +3H, 2NH, K NH, K,
19. Application of equilibrium constant.
20. Explain the effect of temperature, concentration, addition of inert gas on Equilibrium
Constant.
21. Lechleiter's principle and its application.
22. Explain the condition of temperature, pressure, catalyst, addition of inert gas for the maximum
yield in the industrial process:
(A) Synthesis of Ammonia (Haber's process) N,(&)+3H,(g)2NH,(g)+22.0 kcal
(B) Manufacture of Sulphuric process, (contact process) 280,(g)+0,(s) 2s0,(g) +42 kcal
() Manufacture of Nitric acid (Birkeland Eyed process) N,(g)+0,(e) 2NO(g)-43.2 kcal
23. Explain the increase and decrease of pressure on the following equilibrium.
(A) 4HCI+0, 2H,0+2CI, +284 kcal (B) H, +C1,2HCIH44.2 kcal
(B) CH,+20, 0,+2H,0+212.8 kcal () 200,+135.2 kcal 2CO+0,
( N,0,+14 kcal 2NO, (D) H,+I,+124 kcal 2HI
[Note: All Topics &Questions are Mandatory.]
*********
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FIITJEE-DPS-MODERN INDIANSCHOOL

WT-2 and FINAL EXAM

5. At equilibrium Gibb's free Energy -0 and entropy change-0

9. Derivation for Ke and Kp expression.

Equilibrium constant K for the reaction is 2x1013 at 300K.Calculate sG0 at 30OK.

Fowand Rat Baelewanl Frw a d and bacleuane ree

Baclenand Rn’A Yon tha

(k, xK) Did both lay 4

the gryto move Aneh a

At ey: Bacand RRn meese hen B added og

fp an Rxu me when addec oY

cataltyat G>Ke CBacewand)

Heu, ia solid, omd e don nedude so4 d

Thy hvesly ppnfonal ba each otthes.

P Kel Vbee () PU), v ()

TI), Key ) (Bacleusad)

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