Chemistry: A Molecular Approach (Tro) Chapter 7

The Quantu mMechani cal Model of the

A t o m

Calculat wavelength (in nm) of a the red light emitted by a neon sign with a frequency of 4.74 1014 Hz. e the A)

633 nm B)

158 nm C)

142 nm D)

704 nm E)

466 nm Answer:

A 2)

Calculat wavelength (in nm) of the blue light emitted by a mercury lamp with a frequency of 6.88 1014 e the Hz. A)

229 nm B)

436 nm C)

206 nm D)

485 nm E)

675 nm Answer:

B 3)

Calculat e the frequency of the red light emitted by a neon sign with a wavelength of 659.9 nm. A)

2.20 1014 s-1 B)

1.98 1014 s-1 C)

4.55 1014 s-1 D)

5.05 1014 s-1 E)

3.32 1014 s-1 Answer:

C 4)

Calculat e the frequency of the green light emitted by a hydrogen atom with a wavelength of 486.1 nm. A)

1.46 1014 s-1 B)

6.86 1014 s-1 C)

4.33 1014 s-1 D)

6.17 1014 s-1 E)

1.62 1014 s-1 Answer:

D 5)

Calculat e the energy of the red light emitted by a neon atom with a wavelength of 703.2 nm. A)

3.54 10B)

19 J

4.27 10C)

19 J

2.34 10D)

19 J

6.45 10E)

19 J

19 J 2.83 10Answer:

6)

Calculat e the energy of the violet light emitted by a hydrogen atom with a wavelength of 410.1 nm. A)

4.85 10B)

19 J

2.06 10C)

19 J

1.23 10D)

19 J

8.13 10E)

19 J

5.27 x 10-19 J Answer:

A 7)

Calculat e the energy of the green light emitted by a mercury lamp with a frequency of 5.49 1014 Hz. A)

2.75 10B)

19 J

3.64 10C)

19 J

5.46 10D)

19 J

1.83 10E)

19 J

19 J 4.68 10Answer:

B 8)

Calculat e the energy of the orange light emitted by a neon sign with a frequency of 4.89 1014 Hz. A)

3.09 10B)

19 J

6.14 10C)

19 J

3.24 10D)

19 J

1.63 10E)

19 J

19 J 5.11 10Answer:

C 9)

Place of electromagnetic radiation in order of increasing wavelength. the followin ultraviolet light gamma rays radio waves g types A)

gamma rays < radio waves < ultraviolet light B)

radio waves < ultraviolet light < gamma rays C)

radio waves < gamma rays < ultraviolet light D)

ultraviolet E)

light < gamma rays < radio waves

gamma rays < ultraviolet light < radio waves Answer:

E 10)

Place of electromagnetic radiation in order of increasing frequency. the followin visible light microwaves X-rays g types A)

microwaves < visible light < X-rays B)

X-rays < C)

visible light < microwaves

microwaves < X-rays < visible light D)

X-rays < E)

microwaves < visible light

visible light < X-rays < microwaves Answer:

11)

Place of electromagnetic radiation in order of decreasing energy. the followin ultraviolet light radio waves microwaves g types A)

radio waves > microwaves > ultraviolet light B)

ultraviolet C)

light > microwaves > radio waves

radio waves > ultraviolet light > microwaves D)

ultraviolet E)

light > radio waves > microwaves

microwaves > radio waves > ultraviolet light Answer:

B 12)

Which

of the following visible colors of light have the largest frequency? A)

green B)

red C)

blue D)

yellow E)

orange Answer:

C 13)

Which

of the following visible colors of light have the longest wavelength? A)

blue B)

green C)

yellow D)

red E)

violet Answer:

D 14)

Which

of the following types of electromagnetic radiation has the shortest wavelength? A)

blue B)

violet C)

orange D)

green E)

yellow Answer:

B 15)

Which

of the following types of electromagnetic radiation has the smallest frequency? A)

yellow B)

blue C)

orange D)

green E)

purple Answer:

C 16)

How many

photons are contained in a burst of yellow light (589 nm) from a sodium lamp that contains 609 kJ of energy? A)

3.37 1019 photons B)

3.06 1030 photons C)

1.81 1024 photons D)

4.03 1028 photons E)

2.48 1025 photons Answer:

17)

How

many photons are contained in a flash of green light (525 nm) that contains 189 kJ of energy? A)

5.67 1023 photons B)

2.01 1024 photons C)

1.25 1031 photons D)

4.99 1023 photons E)

7.99 1030 photons Answer:

D 18)

Which

of the following statements is TRUE? A)

The emission

B)

spectrum of a particular element is always the same and can be used to identify the element.

Part of the proposed that electrons in the hydrogen atom are located in "stationary states" or particular Bohr model orbits around the nucleus. C)

The principle states that we can never know both the exact location and speed of an electron. uncertainty D)

An orbital is the volume in which we are most likely to find an electron. E)

All of the

above are true. Answer:

E 19)

Calculat e the wavelength of an electron (m = 9.11 10-28 g) moving at 3.66 106 m/s. A)

1.99 10B)

10 m

5.03 10C)

10 m

1.81 10D)

10 m

5.52 10-9 m E)

2.76 10-9 m Answer:

A 20)

Calculat e the wavelength of a baseball (m = 155 g) moving at 32.5 m/s. A)

7.60 10B)

36 m

1.32 10C)

34 m

2.15 10D)

32 m

2.68 10E)

34 m

32 m 3.57 10Answer:

B 21)

Determi ne the velocity of a marble (m = 8.66 g) with a wavelength of 3.46 10-33 m. A)

45.2 m/s B)

11.3 m/s C)

22.1 m/s D)

38.8 m/s E)

52.9 m/s Answer:

C 22)

Determi ne the velocity of a medicine ball (m = 10.0 kg) with a wavelength of 1.33 10-35 m. A)

8.81 m/s B)

12.3 m/s C)

2.21 m/s D)

4.98 m/s E)

6.44 m/s Answer:

D 23)

Which of the

following transitions (in a hydrogen atom) represent emission of the longest wavelength photon? A)

n = 1 to n = 2 B)

n = 3 to n = 1 C)

n = 3 to n = 4 D)

n = 4 to n = 2 E)

n = 5 to n = 4 Answer:

E 24)

Which of the

following transitions (in a hydrogen atom) represent absorption of the smallest frequency photon? A)

n = 5 to n = 6 B)

n = 5 to n = 4 C)

n = 4 to n = 1 D)

n = 1 to n = 3 E)

n = 1 to n = 2 Answer:

A 25)

Choose transition (in a hydrogen atom) below that represents the absorption of the shortest wavelength the photon. A)

n = 1 to n = 2 B)

n = 2 to n = 3 C)

n = 4 to n = 5 D)

n = 6 to n = 3 E)

n = 3 to n = 1 Answer:

A 26)

Which

of the following transitions represent the emission of a photon with the largest energy? A)

n = 2 to n = 1 B)

n = 3 to n = 1 C)

n = 6 to n = 3 D)

n = 1 to n = 4 E)

n = 2 to n = 5 Answer:

B 27)

Determi ne the energy change associated with the transition from n=2 to n=5 in the hydrogen atom. A)

-2.18 10- 19 J B)

+6.54 10- 19 J C)

+4.58 10- 19 J D)

-1.53 10- 19 J E)

+3.76 10- 19 J Answer:

C 28)

Determi ne the energy change associated with the transition from n=3 to n=2 in the hydrogen atom. A)

+3.03 10- 19 J B)

-1.82 10- 19 J C)

+5.51 10- 19 J D)

-3.03 10- 19 J E)

+2.69 10- 19 J Answer:

29)

Calculat e the energy change associated with the transition from n=4 to n=1 in the hydrogen atom. A)

+4.89 10- 19 J B)

+1.64 10- 19 J C)

-6.12 10- 19 J D)

+3.55 10- 19 J E)

-2.04 10- 19 J Answer:

E 30)

Calculat e the wavelength of light associated with the transition from n=1 to n=3 in the hydrogen atom. A)

103 nm B)

155 nm C)

646 nm D)

971 nm E)

136 nm Answer:

A 31)

Calculat e the frequency of light associated with the transition from n = 2 to n = 3 in the hydrogen atom. A)

2.19 1014 s-1 B)

5.59 1014 s-1 C)

4.57 1014 s-1 D)

1.79 1014 s-1 E)

3.28 1014 s-1 Answer:

C 32)

It is determine the ionization energy for hydrogen using the Bohr equation. Calculate the ionization possible energy for an atom of hydrogen, making the assumption that ionization is the transition from n=1 to to n=. A)

-2.18 10- 18 J B)

+2.18 10- 18 J C)

+4.59 10- 18 J D)

-4.59 10- 18 J E)

+4.36 x 10- 18 J Answer:

B 33)

It is determine the ionization energy for hydrogen using the Bohr equation. Calculate the ionization possible energy (in kJ) for a mole of hydrogen atoms, making the assumption that ionization is the to transition from n=1 to n=. A)

7.62 103 kJ B)

2.76 103 kJ C)

1.31 103 kJ D)

3.62 103 kJ E)

5.33 103 kJ Answer:

34)

How

much energy (in kJ) is required to ionize 2.78 moles of hydrogen atoms? A)

2.74 103 kJ B)

4.72 103 kJ C)

1.66 103 kJ D)

3.65 103 kJ E)

5.89 103 kJ Answer:

D 35)

Determi end (final) value of n in a hydrogen atom transition, if the electron starts in n = 4 and the atom ne the emits a photon of light with a wavelength of 486 nm. A)

1 B)

5 C)

3 D)

4 E)

2 Answer:

E 36)

Determi end (final) value of n in a hydrogen atom transition, if the electron starts in n = 2 and the atom ne the absorbs a photon of light with a frequency of 4.57 1014 Hz. A)

3 B)

1 C)

4 D)

6 E)

7 Answer:

A 37)

Determi end (final) value of n in a hydrogen atom transition, if the electron starts in n = 1 and the atom ne the absorbs a photon of light with an energy of 2.044 10-18 J. A)

3 B)

4 C)

2 D)

5 E)

6 Answer:

B 38)

Each of following sets of quantum numbers is supposed to specify an orbital. Which of the following sets the of quantum numbers contains an error? A)

n = 2, l = 1 , ml = -1 B)

n = 4, l = 2, ml =0 C)

n = 3, l =3 , ml = -2 D)

n = 1, l = 0, ml =0 E)

n = 3, l = 0, ml =0 Answer:

39)

Each of following sets of quantum numbers is supposed to specify an orbital. Choose the one set of the quantum numbers that does not contain an error. A)

n = 2, l = 2, ml =-1 B)

n = 2, l = 2, ml =0 C)

n = 3, l = 2, ml =-3 D)

n = 4, l = 3, ml =-2 E)

n = 4, l = 2, ml =+4 Answer:

D 40)

Each of following sets of quantum numbers is supposed to specify an orbital. Choose the one set of the quantum numbers that does not contain an error. A)

n = 4, l = 4, ml =0 B)

n = 3, l = 2, ml =+3 C)

n = 4, l = 0, ml =-1 D)

n = 3, l = 1, ml = -2 E)

n = 5, l = 3, ml =-3 Answer:

E 41)

How

many orbitals are contained in the third principal level (n=3) of a given atom? A)

9 B)

3 C)

18 D)

7 E)

5 Answer:

A 42)

How

many sublevels are contained in the second shell (n=2) of a given atom? A)

1 B)

2 C)

9 D)

4 E)

3 Answer:

B 43)

Which

of the following statements are TRUE? A)

The principal quantum number (n) describes the shape of an orbital. B)

The angular momentum quantum number (l) describes the the size and energy associated with an orbital. C)

The D)

magnetic quantum number (ml) describes the orientation of the orbital.

An orbital is the path that an electron follows during its movement in an atom. E)

All of the

above are true. Answer:

C 44)

Which

of the following statements are TRUE? A)

We can B)

sometimes know the exact location and speed of an electron at the same time.

All orbitals in a given atom are roughly the same size. C)

Since electrons

D)

have mass, we must always consider them to have particle properties and never wavelike properties.

Atoms are roughly

E)

spherical because when all of the different shaped orbitals are overlapped, they take on a spherical shape.

All of the

above are true. Answer:

D 45)

Which

of the following occur as the energy of a photon increases? A)

the B)

frequency decreases.

the speed C)

increases.

the D)

deBroglie wavelength increases

the E)

wavelength gets shorter.

None of the above occur as the energy of a photon increases. Answer:

E 46)

Which

of the following occur as the wavelength of a photon increases? A)

the B)

frequency decreases

the energy C)

increases

the speed D)

decreases

Planck's E)

constant decreases

None of the above occur as the wavelength of a photon increases. Answer:

A 47)

How

much energy (in kJ) do 3.0 moles of photons, all with a wavelength of 655 nm, contain? A)

183 kJ B)

303 kJ C)

394 kJ D)

548 kJ E)

254 kJ Answer:

D 48)

What

total energy (in kJ) is contained in 1.0 mol of photons, all with a frequency of 2.75 1014 Hz? A)

182 kJ B)

219 kJ C)

457 kJ D)

326 kJ E)

110 kJ Answer:

E 49)

Determi shortest frequency of light required to remove an electron from a sample of Ti metal, if the ne the binding energy of titanium is 3.14 103 kJ/mol. A)

7.87 x 1015 Hz B)

4.74 x 1015 Hz C)

2.11 x 1015 Hz D)

1.27 x 1015 Hz E)

6.19 x 1015 Hz Answer:

A 50)

Determi longest wavelength of light required to remove an electron from a sample of potassium metal, if ne the the binding energy for an electron in K is 1.76 103 kJ/mol. A)

147 nm B)

68.0 nm C)

113 nm D)

885 nm E)

387 nm Answer:

51)

Which

of the following quantum numbers describes the shape of an orbital? A)

principal B)

quantum number

magnetic C)

quantum number

spin D)

quantum number

shrdinger E)

quantum number

angular

momentum quantum number Answer:

E 52)

Which

of the following quantum numbers describes the orientation of an orbital? A)

magnetic B)

quantum number

principal C)

quantum number

angular D)

momentum quantum number

spin E)

quantum number

schrdinger quantum number Answer:

A 53)

How

many different values of ml are possible in the 4f sublevel? A)

1 B)

7 C)

3 D)

5 E)

2 Answer:

B 54)

How

many different values of l are possible in the third principle level? A)

1 B)

2 C)

3 D)

0 E)

4 Answer:

C 55)

How

many different values of ml are possible in the 3d sublevel? A)

2 B)

1 C)

3 D)

5 E)

7 Answer:

D 56)

If two

electrons in the same atom have the same value of "l", they are A)

in the same level and sublevel. B)

in the same level, but different sublevel. C)

in the same orbital. D)

in different E)

levels and in different shaped orbitals.

None of the above Answer:

57)

In which orbital below would an electron (on average) be farthest from the nucleus? A)

1s B)

4f C)

3s D)

3d E)

2p Answer:

B 58)

In which orbital below would an electron (on average) be closest to the nucleus? A)

2p B)

4s C)

2s D)

5d E)

3p Answer:

C 59)

Sketch

one of the 3p orbitals below. How are they different from the 2p orbitals? Answer:

They are larger in size and contain additional nodes.

60)

How

many orbitals are contained in the n=2 level? Give the l and ml values of each of them. Answer:

Four. The 2s and three 2p orbitals. 2s, l = 0, ml = 0; 2p, l = 1, ml = -1 and l = 1, ml = 0 and l =1, ml = +1.

61)

Why do atoms only emit certain wavelengths of light when they are excited? (Why do line spectra exist?) Answer:

The energies of atoms are quantized. When an electron moves from one energy level to another during emission, a specific wavelength of light (with specific energy) is emitted. The electrons are not allowed "in between" quantized energy levels and thus there is no continuous spectrum observed.

62)

What is the photoelectric effect? Answer:

It is the observation that many metals emit electrons when light of high enough energy is shone on them. This observation brought our classical view of light into question.

63)

Why

don't we observe the deBroglie wavelength of everyday macroscopic objects? Answer:

Due to the large mass of macroscopic objects, the deBroglie wavelength is extremely small. The wavelength is so small that it is impossible to detect compared to the size of the object.

Match the following. 64)

n = 1 to n=2

A) 1 03 nm 6 5 )

n = 3 to n=1

B) 1 22 nm 6 6 )

n = 2 to n=3

C) 7 460 nm 6 7 )

n = 6 to n=5

D) 1 280 nm 6 8 )

n = 5 to n=3

E) 6 57 nm 6 4 )

65)

66)

67)

68)