ExamI Answer

Chem-182
Fall -09
Exam – I
Materials: Chapter; 12, 13, and 14
Professor: Dr. N. Marashi
1. Hydrogen bonding is present in all of the following molecular solids EXCEPT

_______ .
a) H2SO4 b) NH3 c) CH3 d) HF e) H2O2
Answer: c
2. Place the following cations in order from lowest to highest hydration enthalpy.
a) Na+ < Rb+ < H+
b) Rb+ < H+ < Na+
c) Rb+ < Na+ < H+
d) H+ < Na+ < Rb+
e) H+ < Rb+ < Na+
Answer: c
3. As pure molecular solids, which of the following exhibits dipole-dipole intermolecular

forces: PBr3, SO2, I2, and CO2?
a) PBr3 only
b) PBr3 and SO2
c) SO2 and CO2
d) I2 and CO2
e) PBr3, SO2, and I2
Answer: b
4. Arrange H2O, H2S, and H2Se in order from lowest to highest boiling point.
a) H2O < H2S < H2Se
b) H2O < H2Se < H2S
c) H2Se < H2O < H2S
d) H2Se < H2S < H2O
e) H2S < H2Se < H2O
Answer: e
5. What intermolecular force or bond is primarily responsible for the solubility of CH 3OH
in water?
a) ion-dipole force
b) dipole-dipole force
c) ionic bonding
This study source was downloaded by 100000847528773 from CourseHero.com on 07-11-2024 15:10:44 GMT -05:00
https://www.coursehero.com/file/8273044/ExamI-answer/
d) covalent bonding
e) hydrogen bonding
Answer: e
6. At its boiling point of -34.0 °C, 6.33 kJ of heat is required to vaporize 22.0 g of
chlorine (Cl2). What is the molar enthalpy of vaporization of chlorine?
a) 0.0893 kJ/mol b) 0.286 kJ/mol c) 1.96 kJ/mol d) 20.4 kJ/mol e) 139
kJ/mol
Answer: d
7. Ethanol has an enthalpy of vaporization of 42.3 kJ/mol. The compound has a vapor
pressure of 1.00 atm at 78.3 °C. At what temperature is the vapor pressure equal to
0.500 atm? (R = 8.314 J/K·mol), In(P2/P1) = - ∆ vaprH/R (1/T1-1/T2).
a) -96.2 °C b) 7.19 °C c) 36.0 °C d) 62.2 °C e) 281 °C
Answer: d
8. Which of the following are valid reasons why vegetable oil has a greater viscosity than
diethyl ether, CH3OCH3?
1. Unlike diethyl ether, oil molecules are not held together by hydrogen
bonds.
2. Oil molecules have long chains that become entangled.
3. Intermolecular forces are greater for the larger oil molecules.
a) 1 only b) 2 only c) 3 only d) 1 and 3 e) 2 and 3
Answer: e
9. How many unit cells share an atom which is located at a corner (or lattice point) of a
unit cell?
a) 1 b) 2 c) 4 d) 6 e) 8
Answer: e
10. Which equation represents the number of atoms in a face-centered cubic unit cell?
1
a) # atoms = ( 8 )
8
1
b) # atoms = ( 8 )
4
1
c) # atoms = 1 + ( 8 )
8
1 1
d) # atoms = (6) + ( 8 )
2 8
1 1
e) # atoms = 1 + (6) + ( 8 )
2 8
Answer: d
11. Which of the following is NOT a network solid?

a) elemental silicon, Si(s)
b) diamond, C(s)
c) nylon
d) silicon dioxide, SiO2(s)
e) aluminum oxide, Al2O3(s)
Answer: c
12. Which process requires the greatest endothermic change in enthalpy for water?
a) freezing b) condensation c) sublimation d) melting e)
vaporization
Answer: c
13. If a pure substance begins at point B on the phase diagram below and the pressure on
the substance is reduced until point C is reached, what process occurs?
a) fusion
b) vaporization A B
c) condensation P
d) sublimation
e) none of the above
D C
Answer: b T
14. What is the definition of molality?

a) moles of solute per kg of solvent
b) grams of solute per kg of solution
c) grams of solute per liter of solution
d) moles of solute per liter of solvent
e) moles of solute per liter of solution
Answer: a
15. If 355 g of ethanol (C2H5OH) is added to 645 g of water, what is the molality of the
ethanol?
a) 0.550 m b) 7.71 m c) 11.9 m d) 21.7 m e) 55.0 m
Answer: c
16. What is the mole fraction of water in a solution that is 37.9% by weight ethylene
glycol? The molar mass of ethylene glycol, HOCH2CH2OH, is 62.07 g/mol.
a) 0.177 b) 0.379 c) 0.849 d) 0.901 e) 5.63
Answer: c
17. What is the weight percent of acetic acid in 2.73 m CH3CO2H(aq)?

a) 3.95 × 10-5% b) 0.0455% c) 2.73% d) 14.1% e) 16.4%
Answer: d
18. The Henry’s law constant for O2 in water at 25 °C is 1.66 × 10-6 M/mm Hg. What
partial pressure of O2 is necessary to achieve an equilibrium concentration of 1.5 ×
10-3 M O2?
a) 2.5 × 10-9 mm Hg
b) 1.1 × 10-3 mm Hg
c) 1.5 × 10-3 mm Hg
d) 9.0 × 102 mm Hg
e) 4.1 × 108 mm Hg
Answer: d
19. The vapor pressure of pure water at 55 °C is 118 mm Hg. What is the equilibrium
vapor pressure of water above a mixture of 77.0 g ethanol (CH3CH2OH, molar mass =
46.07 g/mol) and 32.0 g water?
a) 2.72 mm Hg b) 34.6 mm Hg c) 49.0 mm Hg d) 57.2 mm Hg e) 60.8
mm Hg
Answer: e
20. What is the molar mass of a nonpolar molecular compound if 3.42 grams dissolved in
41.8 grams benzene begins to freeze at 1.17 °C? The freezing point of pure benzene is
5.50 °C and the freezing point depression constant, Kfp, is -5.12 °C/m.
a) 2.89 g/mol b) 69.2 g/mol c) 96.7 g/mol d) 126 g/mol e) 358
g/mol
Answer: c
Powered by TCPDF (www.tcpdf.org)

ExamI Answer

Uploaded by

Copyright:

Available Formats

ExamI Answer

Uploaded by

Document Information

Original Title

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

ExamI Answer

Uploaded by

Copyright:

Available Formats

Chem-182

1. Hydrogen bonding is present in all of the following molecular solids EXCEPT

3. As pure molecular solids, which of the following exhibits dipole-dipole intermolecular

a) -96.2 °C b) 7.19 °C c) 36.0 °C d) 62.2 °C e) 281 °C

11. Which of the following is NOT a network solid?

14. What is the definition of molality?

17. What is the weight percent of acetic acid in 2.73 m CH3CO2H(aq)?

You might also like