Sharomix 824

Safety Data Sheet

According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Revision Date: 03/19/2015 Date of Issue: 03/19/2015 Supersedes: 01/15/2010 Version: 2.0

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY

1.1. Product Identifier
Product Form: Substance
Product Name: Sharomix 824
CAS No: 122-99-6; 99-76-3; 94-13-3; 120-47-8
Synonyms: Methyl, Propyl and Ethyl Parabens in Phenoxyethanol
1.2. Intended Use of the Product
Use of the substance/mixture: Cosmetics, Personal Care products
1.3. Name, Address, and Telephone of the Responsible Party
Company
Acme-Hardesty Co
450 Sentry Parkway
Blue Bell, PA 19422
T 866-226-3834 T 215-591-3610
www.acme-hardesty.com
1.4. Emergency Telephone Number
Emergency Number : 800-424-9300
For Chemical Emergency, Spill, Leak, Fire, Exposure, or Accident, call CHEMTREC – Day or Night
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the Substance or Mixture
Classification (GHS-US)
Acute Tox. 4 (Oral) H302
Eye Irrit. 2A H319
Aquatic Acute 2 H401
Full text of H-phrases: see section 16
2.2. Label Elements
GHS-US Labeling
Hazard Pictograms (GHS-US) :

GHS07

Signal Word (GHS-US) : Warning

Hazard Statements (GHS-US) : H302 - Harmful if swallowed
H319 - Causes serious eye irritation
H401 - Toxic to aquatic life
Precautionary Statements (GHS-US) : P264 - Wash exposed areas. thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P273 - Avoid release to the environment.
P280 - Wear eye protection, protective gloves, protective clothing.
P301+P312 - If swallowed: Call a poison center or doctor if you feel unwell.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P330 - Rinse mouth.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P501 - Dispose of contents/container in accordance with local, regional, national,
and international regulations.
2.3. Other Hazards
No additional information available

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Sharomix 824
Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

2.4. Unknown Acute Toxicity (GHS-US)

No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substance
Name : Sharomix 824
CAS No : 122-99-6; 99-76-3; 94-13-3; 120-47-8
Name Product Identifier % Classification (GHS-US)
2-Phenoxyethanol (CAS No) 122-99-6 70 - 74 Acute Tox. 4 (Oral), H302
Eye Irrit. 2A, H319
Methyl p-hydroxybenzoate (CAS No) 99-76-3 15 - 17 Comb. Dust, H232
Aquatic Acute 3, H402
Aquatic Chronic 3, H412
Propyl 4-hydroxybenzoate (CAS No) 94-13-3 7.5 - 8.5 Comb. Dust, H232
Aquatic Acute 2, H401
Ethyl 4-hydroxybenzoate (CAS No) 120-47-8 3.6 - 4.4 Comb. Dust, H232
3.2. Mixture
Not applicable
Full text of H-phrases: see section 16
SECTION 4: FIRST AID MEASURES
4.1. Description of First Aid Measures
First-aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible). IF exposed or concerned: Get medical advice/attention.
First-aid Measures After Inhalation: When symptoms occur: go into open air and ventilate suspected area.
First-aid Measures After Skin Contact: Remove contaminated clothing. Drench affected area with water for at least 15
minutes.
First-aid Measures After Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
First-aid Measures After Ingestion: Rinse mouth. Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or
doctor/physician.
4.2. Most Important Symptoms and Effects, Both Acute and Delayed
Symptoms/Injuries: Harmful if swallowed. Eye irritation.
Symptoms/Injuries After Inhalation: Not expected to present a significant inhalation hazard under anticipated conditions of
normal use.
Symptoms/Injuries After Skin Contact: May cause mild skin irritation.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.
Symptoms/Injuries After Ingestion: Swallowing a small quantity of this material will result in serious health hazard.
4.3. Indication of Any Immediate Medical Attention and Special Treatment Needed
If medical advice is needed, have product container or label at hand.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing Media
Suitable Extinguishing Media: Chemical type foam, carbon dioxide (CO2), dry chemical, water fog. Use extinguishing media
appropriate for surrounding fire.
Unsuitable Extinguishing Media: Do not use water jet. A heavy water stream may spread burning liquid.
5.2. Special Hazards Arising From the Substance or Mixture
Fire Hazard: Not considered flammable but may burn at high temperatures.
Explosion Hazard: Product is not explosive.
Reactivity: Do not distill to dryness. Product can oxidize at elevated temperatures.
5.3. Advice for Firefighters
Firefighting Instructions: Exercise caution when fighting any chemical fire.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Handle in accordance with good industrial hygiene and safety practice.
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Sharomix 824
Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

6.1.1. For Non-emergency Personnel

Protective Equipment: Use appropriate personal protection equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
6.1.2. For Emergency Responders
Protective Equipment: Equip cleanup crew with proper protection. Use appropriate personal protection equipment (PPE).
Emergency Procedures: Ventilate area.
6.2. Environmental Precautions
Prevent entry to sewers and public waters.
6.3. Methods and Material for Containment and Cleaning Up
For Containment: Absorb and/or contain spill with inert material, then place in suitable container.
Methods for Cleaning Up: Clear up spills immediately and dispose of waste safely.
6.4. Reference to Other Sections
See heading 8, Exposure Controls and Personal Protection.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for Safe Handling
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed
areas with mild soap and water before eating, drinking, or smoking and again when leaving work. Do not eat, drink or smoke
when using this product.
7.2. Conditions for Safe Storage, Including Any Incompatibilities
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use.
Incompatible Products: Strong acids. Strong bases. Strong oxidizers.
Storage Temperature: > 15 °C (59°F)
Storage Area: Keep away from sources of ignition - No smoking. Keep cool. Protect from sunlight.
Special Rules on Packaging: Do not store in aluminum, galvanized or other corrodable containers.
7.3. Specific End Use(s) Cosmetics, Personal Care products
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control Parameters
For substances listed in section 3 that are not listed here, there are no established exposure limits from the manufacturer,
supplier, importer, or the appropriate advisory agency including: ACGIH (TLV), NIOSH (REL), or OSHA (PEL).
8.2. Exposure Controls
Appropriate Engineering Controls : Emergency eye wash fountains should be available in the immediate vicinity of any
potential exposure.
Personal Protective Equipment : Gloves. Protective goggles. Protective clothing.

Materials for Protective Clothing : Chemically resistant materials and fabrics.

Hand Protection : Wear chemically resistant protective gloves.
Eye Protection : Chemical goggles or safety glasses.
Respiratory Protection : If exposure limits are exceeded or irritation is experienced, approved respiratory
protection should be worn.
Other Information : When using, do not eat, drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on Basic Physical and Chemical Properties
Physical State : Liquid
Appearance : Clear; Colorless
Odor : Characteristic
Odor Threshold : No data available
pH : 5.5 - 7
Relative Evaporation Rate (butylacetate=1) : No data available
Melting Point : < 10 °C (50 °F)

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Sharomix 824
Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Freezing Point : No data available

Boiling Point : 244 - 248 °C (471.2 - 478.4 °F)
Flash Point : 121 °C (249.80 °F)
Auto-ignition Temperature : 157 °C (314.60 °F)
Decomposition Temperature : No data available
Flammability (solid, gas) : No data available
Vapor Pressure : No data available
Relative Vapor Density at 20 °C : No data available
Relative Density : 1.125 @20°C
Specific Gravity : 1.120 - 131 @ 20°C
Solubility : Soluble.
Water: 2.67 g/100ml 2.3% by weight of main component
Organic solvent:Soluble.
Partition Coefficient: N-Octanol/Water : Not available
Viscosity : 29.84 mPa.s @20°C
Explosive Properties : No data available
Oxidizing Properties : No data available
Explosive Limits : Not applicable
9.2. Other Information No additional information available
SECTION 10: STABILITY AND REACTIVITY
10.1 Reactivity: Do not distill to dryness. Product can oxidize at elevated temperatures.
10.2 Chemical Stability: Product is stable.
10.3 Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
10.4 Conditions to Avoid: Direct sunlight. Extremely high or low temperatures.
10.5 Incompatible Materials: Strong acids. Strong bases. Strong oxidizers.
10.6 Hazardous Decomposition Products: Carbon oxides (CO, CO2).
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information On Toxicological Effects
Acute Toxicity : Oral: Harmful if swallowed.
Sharomix 824 ( \f )122-99-6; 99-76-3; 94-13-3; 120-47-8
ATE (Oral) 1702.703 mg/kg body weight
2-Phenoxyethanol (122-99-6)
LD50 Oral Rat 1260 mg/kg
LD50 Dermal Rabbit 5 ml/kg
ATE (Oral) 1260.000 mg/kg body weight
Methyl p-hydroxybenzoate (99-76-3)
LD50 Oral Rat > 2100 mg/kg
Propyl 4-hydroxybenzoate (94-13-3)
LD50 Oral Rat > 5000 mg/kg
Skin Corrosion/Irritation: Not classified
pH: 5.5 - 7
Serious Eye Damage/Irritation: Causes serious eye irritation.
pH: 5.5 - 7
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Carcinogenicity: Not classified
Sharomix 824 (122-99-6; 99-76-3; 94-13-3; 120-47-8)
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
Sharomix 824 (122-99-6; 99-76-3; 94-13-3; 120-47-8)
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Sharomix 824
Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Specific Target Organ Toxicity (Repeated Exposure): Not classified

Aspiration Hazard: Not classified
Potential Adverse Human Health Effects and Symptoms: Harmful if swallowed.
Symptoms/Injuries After Inhalation: Not expected to present a significant inhalation hazard under anticipated conditions of
normal use.
Symptoms/Injuries After Skin Contact: May cause mild skin irritation.
Symptoms/Injuries After Eye Contact: Causes serious eye irritation.
Symptoms/Injuries After Ingestion: Swallowing a small quantity of this material will result in serious health hazard.
SECTION 12: ECOLOGICAL INFORMATION
12.1. Toxicity
2-Phenoxyethanol (122-99-6)
LC50 Fish 1 344 mg/l
EC50 Daphnia 1 > 500 mg/l (Exposure time: 48 h - Species: Daphnia magna)
LC 50 Fish 2 366 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static])
Methyl p-hydroxybenzoate (99-76-3)
LC50 Fish 1 59.5 mg/l (Exposure time: 96 h - Species: Oryzias latipes)
EC50 Daphnia 1 11.2 mg/l
ErC50 (algae) 91 mg/l
NOEC chronic crustacea 0.2 mg/l (Species: Daphnia magna)
NOEC chronic algae 20 mg/l
Propyl 4-hydroxybenzoate (94-13-3)
LC50 Fish 1 4.1 (4.1 - 8.8) mg/l (Exposure time: 96 h - Species: Danio rerio)
EC50 Daphnia 1 7.97 (7.97 - 32.3) mg/l
NOEC chronic algae 2.1 mg/l
12.2. Persistence and Degradability
Sharomix 824 (122-99-6; 99-76-3; 94-13-3; 120-47-8)
Persistence and Degradability Not established.
Methyl p-hydroxybenzoate (99-76-3)
Persistence and Degradability Readily biodegradable, according to appropriate OECD test.
12.3. Bioaccumulative Potential
Sharomix 824 (122-99-6; 99-76-3; 94-13-3; 120-47-8)
Bioaccumulative Potential Not established.
2-Phenoxyethanol (122-99-6)
Log Pow 1.13 (at 25 °C)
Methyl p-hydroxybenzoate (99-76-3)
Bioconcentration factor (BCF REACH) 6.4
Log Pow 1.98
12.4. Mobility in Soil No additional information available
12.5. Other Adverse Effects
Other Information : Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and
international regulations.
SECTION 14: TRANSPORT INFORMATION
In Accordance With ICAO/IATA/IMDG/DOT
14.1. UN Number Not regulated for transport
14.2. UN Proper Shipping Name Not regulated for transport
14.3. Additional Information
Other information : No supplementary information available.

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Sharomix 824
Safety Data Sheet
According to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Transport by Sea Not regulated for transport

Air Transport Not regulated for transport
SECTION 15: REGULATORY INFORMATION
15.1 US Federal Regulations
2-Phenoxyethanol (122-99-6)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Methyl p-hydroxybenzoate (99-76-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Propyl 4-hydroxybenzoate (94-13-3)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
Ethyl 4-hydroxybenzoate (120-47-8)
Listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2 US State Regulations Neither this product nor its chemical components appear on any US state lists.

SECTION 16: OTHER INFORMATION

Revision Date : 03/19/15
Other Information : This document has been prepared in accordance with the SDS
requirements of the OSHA Hazard Communication Standard 29 CFR
1910.1200.
GHS Full Text Phrases:
------ Acute Tox. 4 (Oral) Acute toxicity (oral) Category 4
------ Aquatic Acute 2 Hazardous to the aquatic environment - Acute Hazard Category 2
------ Aquatic Acute 3 Hazardous to the aquatic environment - Acute Hazard Category 3
------ Aquatic Chronic 3 Hazardous to the aquatic environment - Chronic Hazard Category 3
------ Comb. Dust Combustible Dust
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ H232 May form combustible dust concentrations in air
------ H302 Harmful if swallowed
------ H319 Causes serious eye irritation
------ H401 Toxic to aquatic life
------ H402 Harmful to aquatic life
------ H412 Harmful to aquatic life with long lasting effects
The data herein are based on our current knowledge and believed to be reliable. Acme-Hardesty Co., provides this information
without any representation or warranty, expressed or implied, regarding its accuracy or correctness.

Users must make their own determination that handling, storage, use and disposal of the product in the anticipated manner is
safe and appropriate. Because these actions of the user are out of our control, and may be beyond our knowledge, we do not
assume responsibility and expressly disclaim liability for loss, damage, expense or any other claim arising out of or in any way
connected with the handling, storage, use or disposal of the product or container.

SDS US (GHS HazCom) - ACME Hardesty

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