MATERIAL SAFETY DATA SHEET

HIGH SPEED DIESEL

Section 1 – Chemical Product and Company Identification

Chemical Name: High Speed Diesel

Chemical Formula: Complex mixture of hydrocarbons 2
CAS Number: 1 0
Synonyms: Diesel, Gas oil, High Flash HSD (HF HSD)
General Use: Motor Fuel and in Defence aircrafts
NFPA 704 (Sec 16)
Manufacture’s Name: Bharat Petroleum Corporation Limited
Address: Refinery, Mahul, Chembur, Mumbai 400074
Telephone Number for Info: 25533888 /25533999 / 25524888 / 25524999
MSDS No. :
Date Prepared: June 2020
Revision: 2

Section 2 – Composition / Information on Ingredients

Composition: Complex mixture of hydrocarbons

Hazardous Components:
ACIGH TLV TWA: Not listed
There are two basic types of HSD depending on the flash points - the Normal HSD and the High
Flash HSD

Section 3 – Hazards Identification

Primary Entry Routes: Ingestion, inhalation, skin and eyes

Acute Effects: Inhalation can cause dizziness, headache and nausea,
depresses central nervous system and has an anesthetic effect.
Breathing of liquid droplets may lead to chemical pneumonia.
Ingestion can lead to nausea, diarrhea and affect central nervous
system. Skin irritant. Prolonged contact can result in skin drying
and dermatitis. Eye irritant.
Carcinogenicity : Not listed as carcinogenic
Chronic Effects : No data available

Section 4 – First Aid Measures

Eyes: Flush with water for 15 min. Get medical attention.

Skin: Wash with warm water & soap.
Inhalation: Remove to fresh air. Consult a physician if irritation persists.
Ingestion: Do not induce vomiting. Do not give liquids. Get medical help at
once.
Section 5 – Fire Fighting Measures

Flash Point: > 35 °C and > 66°C for HF HSD

Flash Point Method: Abel / Pensky Marten
Auto ignition Temperature: 230 °C to 250 °C (highly variable)
LEL: 0.5 %
UEL: 5.0 %
Flammability Classification: Flammable
Extinguishing Media: Foam, Dry Chemical Powder, CO2
Unusual Fire or Explosion: Heat produces vapours and can cause violent rupture of
Hazards: containers.
Hazardous Combustion Carbon di oxide, carbon mono oxide, benzene
Products:
Fire-Fighting Instructions: Small fires can be extinguished by hand held extinguishers.
Major fires may require withdrawal and allowing the tank to burn.
Fire fighters should wear self breathing apparatus while fighting
fire

Section 6 – Accidental Release Measures

Small Spills: Shut off leaks without risk. Absorb on sand or earth.
Containment: Prevent spillage from entering drains or water sources
Cleanup: After spills wash area with soap and water preventing runoff from
entering drains.

Section 7 – Handling and Storage

Handling Precautions: Do not use/store near heat/open flame. Use gumboots, gloves
while handling the product. Do not inhale. Stay upwind while
handling the product. Product should never be used to remove
oil or grease from skin. It should not be siphoned by mouth. It
should be stored in closed containers away from heat & source
of ignition. Avoid contact with skin and eyes. Wash thoroughly
after handling
Storage Requirements: Do not use/store near heat/open flame/water/acids

Section 8 – Exposure Controls / Personal Protection

Engineering Controls: Provide proper ventilation for environment to be below TWA

Respiratory Protection: Use respiratory protection if ventilation is improper
Protective Clothing / Use face shield, PVC gloves, safety boots while handling.
Equipment: Contaminated clothing to be immediately removed

Section 9 – Protection Physical and Chemical Properties

Physical State: Liquid

Appearance and Odour: Straw yellow or dark yellow liquid. Characteristic hydrocarbon
like odour
Vapor Pressure: 0.5 mm of Hg at 38 °C (RVP)
Specific Gravity: 0.82 to 0.86 gm / cc
Water Solubility: Insoluble
Boiling Point: 110 °C to 375 °C
Freezing Point: < 15 °C
Vapour Density: 3 to 5 (Air = 1)
Sulphur content : 10 ppm max.

Section 10 – Stability and Reactivity

Stability: Chemically stable.

Chemical Incompatibilities: Incompatible with oxidizing agents & chlorine. Reacts vigorously
with oxidising materials.
Conditions to Avoid:
Hazardous Decomposition Carbon di oxide, carbon mono oxide
Products:

Section 11 – Toxicological Information

ACIGH TLV TWA: Data not available

Toxicity Data: Data not available
Acute Inhalation Effects:

Section 12 – Ecological Information

Prevent spillage from entering drains or water sources. After spills wash area with soap and water
preventing runoff from entering drains. Can burn with lot of heat producing CO2 and CO.

Section 13 – Disposal Considerations

Disposal: Waste must be disposed of in accordance with federal, state and local environmental
control regulations

Section 14 – Transport Information

Shipping Name: High Speed Diesel, High Flash Diesel

Section 15 – Regulatory Information

Non - Toxic/Flammable Substance

Section 16 – Other Information

Prepared by: Process Safety Section, BPCL- Mumbai Refinery

Disclaimer: This M.S.D.S and the information it contains is offered to you in good faith as
accurate. We believe that information to be correct but cannot guarantee its accuracy or
completeness. Health and safety precautions in this data sheet may not be adequate for all
individuals and/or situations. It is the user’s obligation to evaluate and use this product safely and
to comply with all applicable laws and regulations. No statement made in this data sheet shall be
construed as a permission or recommendation for the use of any product in a manner that might
infringe existing patents.
 MATERIAL SAFETY DATA SHEET
LIGHT DIESEL OIL

Section 1 – Chemical Product and Company Identification

Chemical Name : Light Diesel Oil

Chemical Formula : Complex mixture of hydrocarbons 2
CAS Number : 68476-30-2 1 0
Synonyms : LDO
General Use : Fuel
NFPA 704 (Sec 16)
Manufacture’s Name : Bharat Petroleum Corporation Limited
Address : Refinery, Mahul, Chembur, Mumbai 400074
Telephone Number for Info : 25533888 /25533999 / 25524888 / 25524999
MSDS No. :
Date Prepared : June 2020
Revision # : 2

Section 2 – Composition / Information on Ingredients

Composition : Complex mixture of hydrocarbons

Hazardous Components :
ACIGH TLV TWA : Not listed

Section 3 – Hazards Identification

Primary Entry Routes : Ingestion, inhalation, skin and eyes

Acute Effects : Inhalation can cause dizziness, headache and nausea,
depresses central nervous system and has an anesthetic effect.
Breathing of liquid droplets may lead to chemical pneumonia.
Ingestion can lead to nausea, diarrhea and affect central nervous
system. Skin irritant. Prolonged contact can result in skin drying
and dermatitis. Eye irritant.
Carcinogenicity : Not listed as carcinogenic
Chronic Effects : No data available

Section 4 – First Aid Measures

Eyes : Flush with water for 15 min. Get medical attention.

Skin : Wash with warm water & soap.
Inhalation : Remove to fresh air. Consult a physician if irritation persists.
Ingestion : Do not induce vomiting. Do not give liquids. Get medical help at
once.

Section 5 – Fire Fighting Measures

Flash Point : > 66°C

Flash Point Method : Pensky Marten
Auto ignition Temperature : 230 °C to 250 °C (highly variable)
LEL : 0.5 %
UEL : 5.0 %
Flammability Classification : Flammable
Extinguishing Media : Foam, Dry Chemical Powder, CO2
Unusual Fire or Explosion : Heat produces vapours and can cause violent rupture of
Hazards : containers.
Hazardous Combustion Carbon di oxide, carbon mono oxide, benzene
Products :
Fire-Fighting Instructions : Small fires can be extinguished by hand held extinguishers.
Major fires may require withdrawal and allowing the tank to burn.
Fire fighters should wear self breathing apparatus while fighting
fire

Section 6 – Accidental Release Measures

Small Spills : Shut off leaks without risk. Absorb on sand or earth.
Containment : Prevent spillage from entering drains or water sources
Cleanup : After spills wash area with soap and water preventing runoff from
entering drains.

Section 7 – Handling and Storage

Handling Precautions : Do not use/store near heat/open flame. Use gumboots, gloves
while handling the product. Do not inhale. Stay upwind while
handling the product. Product should never be used to remove
oil or grease from skin. It should not be siphoned by mouth. It
should be stored in closed containers away from heat & source
of ignition. Avoid contact with skin and eyes. Wash thoroughly
after handling
Storage Requirements : Do not use/store near heat/open flame/water/acids

Section 8 – Exposure Controls / Personal Protection

Engineering Controls : Provide proper ventilation for environment to be below TWA

Respiratory Protection : Use respiratory protection if ventilation is improper
Protective Clothing / Use face shield, PVC gloves, safety boots while handling.
Equipment : Contaminated clothing to be immediately removed

Section 9 – Protection Physical and Chemical Properties

Physical State : Liquid

Appearance and Odour : Dark brownish liquid. Characteristic hydrocarbon like odour
Vapor Pressure : 0.5 mm of Hg at 38 °C (RVP)
Specific Gravity : 0.84 to 0.895 gm / cc
Water Solubility : Insoluble
Boiling Point : 207-535 Deg C
Pour Point : < 21 °C
Vapour Density : 3 to 5 (Air = 1)
Sulphur content : < 1.8 % w

Section 10 – Stability and Reactivity

Stability : Chemically stable.
Chemical Incompatibilities : Incompatible with oxidizing agents & chlorine. Reacts vigorously
with oxidizing materials.
Conditions to Avoid :
Hazardous Decomposition Carbon di oxide, carbon mono oxide
Products :

Section 11 – Toxicological Information

ACIGH TLV TWA : Data not available

Toxicity Data : Data not available
Acute Inhalation Effects :

Section 12 – Ecological Information

Prevent spillage from entering drains or water sources. After spills wash area with soap and water
preventing runoff from entering drains. Can burn with lot of heat producing CO2 and CO.

Section 13 – Disposal Considerations

Disposal: Waste must be disposed of in accordance with federal, state and local environmental
control regulations

Section 14 – Transport Information

Shipping Name : Light Diesel Oil

Section 15 – Regulatory Information

Non - Toxic/Flammable Substance

Section 16 – Other Information

Prepared by: Process Safety Section, BPCL- Mumbai Refinery

Disclaimer: This M.S.D.S and the information it contains is offered to you in good faith as
accurate. We believe that information to be correct but cannot guarantee its accuracy or
completeness. Health and safety precautions in this data sheet may not be adequate for all
individuals and/or situations. It is the user’s obligation to evaluate and use this product safely and
to comply with all applicable laws and regulations. No statement made in this data sheet shall be
construed as a permission or recommendation for the use of any product in a manner that might
infringe existing patents.
 MSDS: LPG

MATERIAL SAFETY DATA SHEET

1. CHEMICAL IDENTITY
CHEMICAL NAME : Liquefied petroleum gas
CHEMICAL CLASSIFICATION: Mixture of butane and propane
SYNONYMES :
TRADE NAME: Liquefied petroleum gas
FORMULA: Mixture of C3H8 & C4H10. C.A.S. NO.
U.N. NO: 1075 HAZCHEM CODE: 2WE
REGULATED IDENTIFICATION : NA
SHIPPING NAME CODES/ LABLE : Liquefied petroleum gas
HAZARDOUS WASTE I.D. NO. : NA
HAZARDOUS INGREDIENTS : C.A.S. No. :
1. Propane 106-97-8
2. Butane 74-98-6
3. Pentane 109-66-0

2. PHYSICAL AND CHEMICAL DATA

BOILING POINT (°C): >-40 PHYSICL STATE: APPEARANCE: Colorless
Liquefied gas

MELTING / FREEZING VAPOUR PRESSURE Odor: Odorless Gas.

POINT(°C): N/A @ 35 °C mm/Hg:
1311.56 mm hg @-20
Dg F
VAPOUR DENSITY (AIR= 1): 1.5 SOLUBILITY IN H2O @ 30 °C : Slight at
30 Deg. CG
SPECIFIC GRAVITY (H2O=1): 0.51 to PH: NA
0.58 at 50 Deg. CG

3. FIRE AND EXPLOSION HAZARD DATA

FLAMMABILITY : Yes LEL : 1.8 % UEL : 12.8 %

TDG FLAMMABILITY: FLASH POINT (°C): -76 AUTO IGNITION

 MSDS: LPG

2.1 to -156 Deg. FH TEMP(°C): 320 to 405 deg C

EXPLOSION EXPLOSION HAZARDOUS

SENSITIVITY TO SENSITIVITY TO COMBUSTION PRODUCTS
IMPACT: NA STATIC ELECTRICITY: : Carbon monoxide and
NA carbon dioxide

HAZARDOUS EXPLOSIVE CORROSSIVE MATERIAL:

POLIMERISATION : NA MATERIAL: NA NA

FLAMMABLE MATERIAL OXIDISER :NA OTHERS :NA

: NA
PYROPHORIC : NA ORGANIC PEROXIDE : NA

4. REACTIVITY DATA
CHEMICAL STABILITY : Stable
INCOMPATABILITY
WITH OTHER MATERIAL : With oxidizing materials
REACTIVITY : Yes
HAZARDOUS REACTION PRODUCTS : Carbon dioxide, Carbon monoxide
5. HEALTH HAZARD DATA
ROUTES OF ENTRY: Skin Absorption: NA. Skin Contact: Yes (liquid) Eye Contact: Yes
Inhalation: Acute: Yes Chronic: NA. Ingestion: No
EFFECTS OF
EXPOSURE / SYMPTOMS: Inhalation can cause headache, disorientation, dizziness,
drowsiness and possibly
Unconsciousness at concentrations that cause oxygen deficiency and asphyxiation.
Rapidly expanding gas or vaporized liquid
may cause frostbite to skin and eyes
EMERGENCY TREATMENT : Flush eyes and skin with plenty of water and get
medical aid.
TLV (ACGIH) : 100 PPM, 1800 mg/m3 STEL : PPM mg/m3
PERMISSIBLE ODOUR THRESHOLD
EXPOSURE LIMITS LD50 : 5000ppm to 20000 ppm
LD 50: PPM mg/m3
NFPA HELATH: NA FLAMABILITY STABILITY: SPECIAL: NA
HAZARD : Yes Stable
 MSDS: LPG

RATING
6. PREVENTIVE MEASURES
PERSONAL PROTECTIVE EQUIPMENTS : Respiratory protective equipment
required.
Eye & Face : Safety goggles.
Hand & Arm : Hand gloves (PVC synthetic only)
Other clothing and equipment : Gum boots, PVC apron.
HANDLING AND STORAGE PRECAUTION : Store the container in a cool, dry and
well ventilated specified place, away from heat, spark and flame.
7. EMERGENCY AND FIRST- AID MESURES
FIRE FIRE EXTINGUISHING MEDIA : Dry chemical powder,
carbon dioxide and water spray.
SPECIAL PROCEDURE : NA
UNUSUAL HAZARDS : Air vapour mixture highly
explosive.
EXPOSURE FIRST AID MEASURES : Skin: If freeze burn occurs, gently
bathe affected area in warm water (38 – 43) deg.C. Do not rub. Get
medical
attention.
Eye: Immediately flush with large amounts of luke warm water for
15 minutes, lifting upper and lower lids at
intervals. Seek medical attention if irritation persists.
Inhalation: Remove to fresh air. Give oxygen, artificial respiration,
or CPR if needed. Seek medical attention.
Ingestion: Usually no effect by this route.
ANTIDOTES / DOSAGES :NA

SPILLS STEPS TO BE TAKEN :

Do not enter in the gas area without protective wears.
Get the area evacuated.
Stop flow of gas if without risk.
Spray water to keep the container cool
WASTE DISPOSAL METHOD : Collect the spillage & wash
the effected area with plenty of water. Allow gas to burn
under control