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Hydrocarbons

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Electron sharing occurs when two atoms approach and their atomic orbitals

overlap. Bonds that have circular cross-section and are formed by head-on overlap
of atomic orbitals are called sigma(α) bonds. Bonds form by sideways overlap of p-
orbitals are called pi(π) bonds.
Two carbon atoms can form a covalent bond by sharing a pair of electrons,
which will either form into a structure of saturated hydrocarbon and unsaturated
hydrocarbon. A detailed discussion on Hydrocarbons will follow in the next lesson.

Carbon atom is a unique kind of elements that has four valence electrons, which
enables it to form four covalent bonds with atoms of other elements and other carbon
atoms.
The simplest and most commonly encountered class of carbon compounds
are the hydrocarbons. These are classified into two groups based on their structure:
the saturated carbon-hydrogen compounds known as alkanes that indicate a single
bond between the carbon - carbon atoms; and the unsaturated hydrocarbons
whichare further classified into alkenes and alkynes.

The type of bonds present in the compound affects the physical properties of
the hydrocarbons. The increasing number of carbons in the compound indicates a
high boiling point as it exists in a liquid state; on the other hand, as the number of
carbon atoms decreases in the compound with the presence of a double or triple
bond, the boiling point decreases as its phase changes to gaseous form.
Long chained hydrocarbons are polymers and many of them occur naturally.
Other polymers are synthetic. This means that, they are produced in labs or
factories. Synthetic polymers are created in synthesis reactions in which monomers
bond together to form much larger compounds. Plastics are examples of synthetic
polymers. The plastic items in Figure below are all made of polythene (also called
polyethylene). They consist of repeating monomers of ethene (C2H4).1
Carbon atom is a unique kind of elements that has four valence electrons, which
enables it to form four covalent bonds with atoms of other elements and other carbon
atoms.
The simplest and most commonly encountered class of carbon compounds
are the hydrocarbons. These are classified into two groups based on their structure:
the saturated carbon-hydrogen compounds known as alkanes that indicate a single
bond between the carbon - carbon atoms; and the unsaturated hydrocarbons
whichare further classified into alkenes and alkynes.

1
“A Chemistry of Carbon.”
The type of bonds present in the compound affects the physical properties of
the hydrocarbons. The increasing number of carbons in the compound indicates a
high boiling point as it exists in a liquid state; on the other hand, as the number of
carbon atoms decreases in the compound with the presence of a double or triple
bond, the boiling point decreases as its phase changes to gaseous form.
Long chained hydrocarbons are polymers and many of them occur naturally.
Other polymers are synthetic. This means that, they are produced in labs or
factories. Synthetic polymers are created in synthesis reactions in which monomers
bond together to form much larger compounds. Plastics are examples of synthetic
polymers. The plastic items in Figure below are all made of polythene (also called
polyethylene). They consist of repeating monomers of ethene (C2H4).2

2
“A Chemistry of Carbon.”

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