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Assignment No 8

Chemistry

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8 views

Assignment No 8

Chemistry

Uploaded by

kanwaljitbaby
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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Chapter: Structure of an atom

Assignment no: Class-XI (Chemistry)

1. Maximum number of electrons in a subshell with l = 3 and n = 4 is:


a) 10 b) 12 c) 14 d) 16

2. The correct set of four quantum numbers for the valence electron of rubidium atom
(Z = 37) is:
a) 5, 0, 0, + ½ b) 5, 1, 0, + ½ c) 5, 1, 1, + ½ d) 6, 0, 0, + ½

3. The work function (f) of some metals is listed below. The number of metals which will
show photoelectric effect when light of 300 nm wavelength falls on the metal is:

Li Na K Mg Cu Ag Fe Pt W
2.4 2.3 2.2 3.7 4.8 4.3 4.7 6.3 4.75

a) 4 b) 6 c) 8 d) All of these.

4. A gas absorbs a photon of 355 nm and emits at two wavelengths. If one of the emissions is
at 680 nm, the other is at:
a) 518 nm b) 1035 nm c) 325 nm d) 743 nm

5. The energy of a 700-nm photon is


a) 1.77 eV b) 2.47 eV c) 700 eV d) 3.57 eV

6. The velocity of the de Broglie wave is given by:


c2 hv m c2
a) b) c) d) v
v mc h

7. Assume that the potential energy of a hydrogen atom in its ground state is zero. Then its
energy in the first excited state will be
a) 13.6 eV b) 27.2 eV c) 23.8 eV d) 10.2 eV

8. When the electron of a hydrogen atom jumps from the n = 4 to the n = 1 state, the number
of spectral lines emitted is
a) 15 b) 6 c) 3 d) 4

9. When the value of the azimuthal quantum number is 3, the maximum and the minimum
values of the spin multiplicities are
a) 4, 3 b) 8, 1 c) 1, 3 d) 8, 2

10. Four sets of values of quantum numbers (n, l, m and s) are given below. Which of these
does not provide a permissible solution of the wave equation?
a) 3, 2, -2, ½ b) 3, 3, 1, -½ c) 3, 2, 1, ½ d) 3, 1, 1, -½

11. Which of the following sets of quantum numbers represent the highest energy of an atom?
a) n = 4, l = 0, m = 0, s = +½ b) n = 3, l = 0, m = 0, s = +½
c) n = 3, l = 1, m = 1, s = +½ d) n = 3, l = 2, m = 1, s = +½

12. Which of the following sets of quantum numbers represent the 19th electron of chromium
(Z = 24)?
a) 4, 0, 0, +½ b) 4, 1, -1 , +½ c) 3, 2, 2, +½ d) 3, 2, -2, +½
13. Which option gives the values of the quantum numbers for the 21st electron of Scandium
(Z = 21)?
a) 3, 1, 1, +½ b) 3, 2, 2, +½ c) 3, 2, -2, -½ d) 3, 2, 2, +½

14. The electronic configuration of Fe3+ is


a) [Ar] 3d5 4s1 b) [Ar] 3d6 4s0 c) [Ar] 3d5 4s0 d) [Ar] 3d6 4s2

15. The number of unpaired electrons in Mn4+ (Z = 25)is


a) four b) two c) five d) three

16. After np orbitals are filled, the next orbital filled will be
a) (n + 1) s b) (n + 2) p c) (n + 1) d d) (n + 2) s

17. The value of the magnetic moment of a particular ion is 2.83 Bohr magneton. The ion is
a) Fe2+ b) Ni2+ c) Mn2+ d) Co3+

18. Which of the following sets of orbitals is arranged in the correct order of increasing
energy?
a) 3d < 4s < 4p < 6s < 4d b) 2s < 3d < 4p < 4f < 1s
c) 4s < 3d < 4p < 5s < 4d d) 1s < 2s < 2p < 4d < 3f

19. The number of spherical nodes in 3p orbitals is


a) one b) three c) two d) zero

20. Which of the following statements is wrong?


The probability of finding the electron in px orbital is
a) maximum on two opposite sides of the nucleus along x-axis
b) zero at the nucleus
c) same on all sides around the nucleus
d) zero on the z-axis.

21. In Aufbau principle, the word ‘Aufbau’


a) represents the name of scientist who developed the principle
b) is a German word which means “built up”
c) is related to the energy of the electron
d) is related to angular momentum of the electron.

22. Bohr’s model of atom is not in agreement with


a) Line spectra of hydrogen atom b) Pauli’s principle
c) Planck’s theory d) Heisenberg’s principle.

23. The transition of electrons in H atom that will emit maximum energy is
a) n 3  n 2 b) n 4  n 3 c) n 5  n 4 d) n 6  n 5

24. How many electrons in 19K have n = 3; l = 0?


a) 1 b) 2 c) 3 d) 4

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