Module 2
Module 2
Primary Memory
Random Access Memory (RAM)
Secondary Memory
I Hard disk drives (HDD) 7 USB Flash Drive
According to the device structure, electronic memory devices can be divided into following
categories: transistors, capacitors, resistors and Charge Transfer type memory devices.
With their respective ability to amplify electronic signals, to store charges, and to produce
proportional electric currents, electronic memory devices can be constructed from transistors.
capacitors and resistors.
Memory devices willhave two distinct stable states assigned as 0 and 1 or ON and
OFF states respectively. They contain a fine electronic circuit which includes a
complementary metal oxide semiconductor transistor and capacitor.
Organic (including polymer) transistors are also of great potential for memory
applications. Organic field-effect transistor (OFET) type memory devices have integrated
structure and the non-destructive reading ofa single transistor. In addition, the mechanical
flexibility of organic materials makes them compatible with plastic substrates for lightweight
and flexible device design.
An OFET memory device consists of at least one polymeric material either in its
dielectric insulator layer or active semiconductor layer or both. Au electrodes are often used
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for OFETs because the work function of gold is close to the ionization potential of many
polymer materials. The device is usually supported by aglass, wafer, or plastic substrate.
E.g., MOSFET (metal -oxide semiconductor ficld effect transistor).
A capacitor is a two-terminal clectrical device that can store energy in the form of an clcctric
charge.
Based on the amount of charge storcd in the cell, the bit level (cither 0" or "1") can be
encoded accordingly. When the medium betwcen the clectrodes is merely a dielectric, the
stored charge will be lost eventually. Thus, DRAM using a diclectric capacitor is volatile
memory. and the information stored in DRAM eventually fades unless the capacitor charge is
refreshed periodically.
A ferroelectric material can maintain permanent clectric
polarization that can be
repeatedly switched between two stable states by an external electric field. Thus, memory based
on ferroelectric capacitors (FeRAM) is non-volatile memory.
FeRAM needs no periodic
refreshing and it still retains its data in the case of power failure. Organic and polymeric
ferroelectric materials can also be used in DRAM and FeRAM applications. FeRAM
device
has a variable voltage level to enable the switching of the
polarization of the ferroelectric
capacitor.
These types of electronic devices are based on charge transfer effects of a charge
Acceptor A
8.0.4<$<0.7
(Charge transfer)
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D9AMixod-valonco compounds
Organic electronic memory devices based on organic molecules were first reported in
several acene derivatives including naphthalene, anthracene, tetracene, pentacene, perylene.
Organic memory devices with a triple-layer structure sandwiched betwcen two outer
metal electrodes can be electrically switched between the ON state and the OFF state.
The device is non-volatile and rewritable, with an ON/OFF ratio of more than 10 i.., more
than one million write-read-erase cycles can be performed on the device without failure.
When this organic bistable device is integrated with an organic light-emitting diode, the device
can be read out optically. Small organic molecules containing both an electron donor and an
electron acceptor are the important type of materials for organic electronic memory devices,
The arrangement of the donor and acceptor within the molecular backbone plays a key role in
the electrical memory behaviour of devices.
Pentacene
Perfluoropentacene (PFP) (C»F4) is an n-type planar crystalline organie
semiconductor, which is made by fluorination of the p-type semiconductor pentacene, and is
used for molecular thin-film devices (like OLEDs or OFETs).
Perfluoropentacene
These molecules together exhibit charge transfer processes,
therefore, used for memory
applications.
2 Polymeric Materials
The molecular structure of polymeric materials can be made using electron donors and
acceptors of difterent strengths, spacer moieties with different steric effects, and electroactive
pendant groups to induce different switching behaviours for electronic memory applications.
a) Functional Polyimides
Functional polyimides (Pls) are one of the most attractive polymeric materials for
organic electrical memory applications due to their good solution processability, high thermal
stability and mechanical strength.
In functional Pls, phthalimide acts as the electron acceptor, and
electron donors
(triphenylamine or carbazole moieties) are introduced to form a D-A structure. An electric
field-induced CT state can be. formed, which is the main mechanism responsible for the
memory behaviours.
A device with the sandwich structure ITO/PFOxPy/Al could write, read. erase and
refresh its electronic states, fulfilling the functionality of aDRAM device.
Conjugated polymers with good processability have been used to fabricate flexible
memory devices.
Eg. Benzodithiophene (BDT)-based conjugated polymers exhibit good performance in both
organic field-effect transistors and solar cells.
Transition-metal complex ferrocene (Fe) has reversible redox behaviour, and its
stable oxidized form ferrocenium (Fe*), renders the possibility of non-volatility for
memory
applications. Its switching mechanism involves ferrocene acting as a voltage-dependent dopant
during the redox process to result in the enhancement of conductivity of the polymer film.
3Organic-Inorganic Hybrid Materials
Polyimide (Pl) has been used as a dielectric and a mechanical-support material in the
electronics industry. Organic non-volatile memory devices on PET flexible substrates using P:
PCBM hybrid materials as active layers, have been fabricated. Three-dimensional (3D)
stacking of memory devices provides away to achieve agreat increase in memory cell density.
Graphene nanoshets are also being used in organic-inorganic hybrid material-based
memory devices.
b) Organic-Inorganic Nanocomposites
Hybrid electronic memory devices have been reported in some organic composites
containing metal nanoparticles (NPs), quantum dots (QDs) and metal oxide NPs.
Other kinds of inorganic nanomaterials, such as ZnO, TiO; and MoS2, have also been
introduced into the organic polymer layer for hybrid memory devices.
Display Systems:
Photoactive Materials
Photoactive materials belong to the field of photonics, where materials that actively
interact with light are tuned and optimized to achieve effects such as light emission (LEDs and
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lasers.) or light detection, with related signal amplification (e.g., in photomultiplicrs) and
processing operations. They can be used to develop light-sensitive circuits and switches (such
as with photoresistors), or to convert light into an electrical signal (i.e., to build photodiodes).
The principle behind is the absorption of light by the photoactive material (which can
be either solid or a molecule) to create a bound clectron-hole pair (exciton). This is followed
by the dissociation of the exciton to create a free electron and hole.
The electron and the hole then will diffuse through the (heterogeneous) photocatalyst
to reach the adsorbed reactant species, or diffuse through electron-transporting and hole
transporting media in solar cells to enter the electric cireuit.
Polymers with photoactive and electroactive properties have fine shape deformability
and shape memory characteristics.
Some of the examples are as ferroelectric polymers, liquid crystalline polymers, ionic
polymer-metal composite, conducting polynmers like polyurethane.
Electroactive polymers/materials
Electroactive polymers (EAPs) are a class of polymeric materials that can change
dimensions when electrically activated. They exhibit a change in size or shape when stimulated
by an electric field due to their inherent electro-mechanical properties.
These materials change reversibly their volume, optical, mechanical and other
properties by very small alterations of certain physical (e.g. electric field, light, temperature)
or chemical (concentrations) stimuli. The volume change of these materials occurs by
swelling/shrinking and is diffusion-based.
EAPs are more attractive than inorganic materials due to their properties of lightweight,
flexibility, cheapness and scalability.
PVDF(polyvinylidene fluoride) and its copolymers, are important the class of materials
due to their high dielectric constant, piezoelectric, pyroelectric and ferroelectric effects.
EAP can be divided into two principal classes: Dielectric and lonic.
Dielectric: In dielecctric EAP paterials ctuation is caused by electrostatic forces betwecen two
clectrodes which squecze the polyner. Eg. Ferroeleetric polymers
lonie: In these polymers, actuation is cnused by the displacenent of ions inside the polyner
and only a few volts are nccded for actuation, E.g, conductive polymers, ionic polymer-metal
composites
Optoclectronic devices
Optoclectronic devices and components are those clectronic devices that operate on both light
and electrical currents. Optoclectronic devices are primarily transducers i.e., they can convert
one energy form to another. These devices produce light by expending clectrical energy. They
can also detect light and transform light signals to clectrical signals for processing by a
computer.
This can include electrically driven light sources such as laser diodes and light-emitting diodes,
components for converting light to an electrical current such as solar and photovoltaic cells and
devices that can clectronically control the propagation of light.
Structure:
Electronic and optical properties of materials can be controlled by controlling their size and
shape. Group lIl-V materials are being increasingly used in integrated optoelectronics.
Nanocrystalline silicon (nc-Si), also known as microcrystalline silicon (4c-Si), is a form of
porous silicon. It is also used as organic light absorbing material.
" Silicon is a non-toxic material, which is naturally abundant and stable under ambient
conditions.
It represents one of the best investigated material systems available and several methods
to grow silicon nanoparticles or nanowires
nc-Si have a higher electron mobility, due to the presence of the silicon crystallites.
It also shows increased absorption in the red and infrared wavelengths, which make it an
important material for use in a-Si solar cells.
it has increased stability over Si.
" It is easier to fabricate.
Applications:
Due to excellent fluorescence intensity, low toxicity, good biocompatibility and stability.
silicon nanocrystals (Si NCs) and Si NCs-based composites have been widely applied in
analytical detection, biomarkers, photocatalysts, photodiodes, and solar cells.
2) Organie light emitting material
Structure:
printers), LEDs, Laser printers, organic solar cells, organic light-emitting diodes and
photovoltaic devices.
Liquid crystals
Liquid crystals are a unique state of matter, between solid (crystalline) and liquid
(isotropic) phases some compounds form a distinct, different intermediate phase, sometimes
referred to as the "fourth state of matter" or "mesophase".
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The molecules in the liquid phase, which have no intrinsic order. In the solid state, molecules
are highly ordered and have little translational freedom. The characteristic orientational order
of the liquid crystal state is between the traditional solid and liquid phases is the origin of the
term mesogenic state, used synonymously with liquid crystal state.
Properties
Liquid crystals display the properties of both solid and liquid. The molecules possess some
orientational or positional order but with a lower degree of organisation compared with a
crystalline solid.
I. The liquid crystal possesses liquid-like flowing behaviour, but because of their
positional order, such compounds are often more viscous.
2. Liquid crystals are attributed to their sensitivity to various stimuli, such as temperature,
electric and magnetic fields.
3. They generally consist of organic molecules that have an elongated shape, with a rigid
central region and flexible ends.
4. The molecules in a liquid erystal do not necessarily exhibit any positional order, but
they do possess a degree of orientational order.
5. They exhibit anisotropic behaviour caused due to the elongated shape of the molecules.
6. The physical properties of the molecules are different when measured parallel or
perpendicular to their length, and residual alignment of the rods (due to preferential
packing arrangements, and also clectrostatic interactions between molecules) in the
fluid leads to anisotropic bulk properties.
7. They undergo thermal expansion. When the temperature of a liquid crystal is raised.
the constituent molecules acquire more energy, and are able to move and rotate more,
so the liquid crystal becomes less ordered.
Classification
Liquid crystals can be classified into thermotropic (temperature dependent) and lyotropic
(concentration dependent) based on their behaviour.
The distinguishing characteristic of the liquid crystalline state is the tendency of the molecules
(mesogens) to point along a common axis, called the director(n). The long axes of the
molecules will tend to align in this direction.
Based on the orientation, there are three types of
liquid crystal, nematic, smectic and
cholesteric.
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Cholesteric
Application in Displays
Liquid crystals are used in many applications like in the display of
calculators, digital
watches and mobile phones.
Liquid Crystal Display
LCD uses a liquid crystal to produce a visible image.
Liquid crystal displays are super-thin
technology display screens that are generally used in laptop
computer screens, TVs, cell
phones, and portable video games. LCD's technologies allow
displays to be much thinner when
compared to a cathode ray tube(CRT) technology.
Liquid crystal display is composed of several layers wvhich include two polarized panel
filters and electrodes.
Light is projected from a lens on a layer of liquid crystal. This combinaion of coloured
light with the grayscale image of the crystal (formed as electric current lows through
the crystal) forms the coloured image. This image is then displayed on the screen.
The liquid crystal display has a unique advantage of having low power consumption
than the LED or cathode ray tube.
The liquid crystal display sereen works on the principle of blocking light rather than
emitting light. LCDs require a backlight as they do not emit light
" In Liquid crystal display (LCD) nematic type of liquid crystal molecular arrangement
is used in which molecules are oriented in some degree of alignment. For example.
when we increase the temperature the ice cube melts and liquid erystal is like the state
in between ice cube and water.
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Construction of LCD consists of two polarized glass pieces. Two electrodes are used, one is
positive and the other one is negative. External potential is applied to LCD through these
electrodes and it is made up of indium-tin-oxide. Liquid crystal layer of about 10um- 20um is
placed between two glass sheets. The light is passed or blocked by changing the polarization.
Working of Liquid Crystal Display
The basic working principle of LCD is blocking of light. It does not produce light on
its own. So external light source is used.
When the external light passes from one polarizer to the next polarizer, external supply
is given to the liquid crystal, the polarized light aligns itself so that the image is produced in
the screen.
The indium oxide conducting surface is a transparent layer which is placed on both the
sides of the sealed thick layer of liquid erystal. When no external bias is applied the molecular
arrangement is not disturbed.
When the external bias is applied the molecular arrangement is disturbed and it and that
area looks dark and the other area looks clear.
In the segment arrangement, the conducting segment looks dark and the other segment
looks clear. To display number 2. the segments A, B,G,E,D are energized.
Advantages:
1. It is thin and compact
2. Low power consumption
4. Low cost
Disadvantages:
1. Speed of operationis low
2. Lifespan is less
Applications:
They do not require back light like traditional LCD's, therefore, results in lov power
consumption.
Ther are extremely thin and flexible therefore used in flexible devises.
" Quick response time in microseconds results crisp motion picture quality and 3D
applications.
OLEDS have long life span, as they do not contain a back light that can degrade over
time.
Applications
OLED technology brings advantages of thinner and curved display form factor to wearable
devices.
OLED displays are mainly used in digital devices such as.
" high-end television systems (flat OLED display, curved OlLED display and OLED
wallpaper), computer monitors,
pocket-size systenms such as Android phones,
" media players, digital cameras, portable gaming consoles and mini-screens.
Rolltop Laptops
Wearable devices such as smart watches and fitness trackers.
" Digital cameras.
OLED light panels.
in automotive lighting (dash board displays) and street lighting.
These applications demand high reliability and readability. OLEDs fit in as these
consume less power and provide high-quality display. The current OLED technology
provides remarkable colour fidelity, high efficiency and operation stability.
2) QLED
LED, or quantum dot light-emitting diode (LED), is adisplay panel used in high
definition TVs (HDTV). The quantum dots nanocrystal semiconductors in a LED- backlit
liquid crystal display (LCD) reduces light losses and produce monochromatic red, green. and
blue (RGB) light. As a result, the device's display is clear and distinct, with better picture
quality than traditional LED sereens.
Introduction:
QLED Stands for Quantum dots Light Emitting Diode. QLED is made of Quantum
dots which are tiny semiconductor crystals having size from 2 nm to 10 nm. Quantunn
dots emit colour light based on their size and energy gap of materials used. Bigger the
dimension of it, larger is the wavelength of emitted light. Different semiconductor
combinations are used in the manufacturing of quantum dots which include CdSe,
CdS, PbSe, PbS, InAs, InP etc.
Properties
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QLEDs do not produce light by themselves. Instead QLEDS use backlight unit
illumination.
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lighting
QLED ae reliable, encrgy efticient, tuncable colour solution for display and
applications that reduce manufacturing costs.
Quantum dot-based LEDs are characterized by pure and saturated emission colours
with narrow bandwidth.
Their emission wavelength is casily tuned by changing the size of the quantum dots.
QD-LED offer high colour purity and durability combined with the dots.
QDLED structure can be tuned over the entire visible wavelength range from
460nm(blue) to 6SOnm.
" It is thin and light in weight.
" Highly flexible, used in flexible displays.
The switching speed (between ON/OFF) is very fast.
long life.
QLED resist moisture better and hence QLED based products will have
Applications
They are cost-effective electroluminescence devices ideal for large-area display
and lighting applications.
QLED TV panel has a better resolution so offer a better, brighter picture quality
A
setting.
in the home entertainment setting and office